Date: Name: Teacher: S5/6 Chemistry Review Sheet – Unit 2 Before beginning this topic you should be able to: o o o o o o o o o o describe the way fossil fuels have been formed; describe the main constituents of crude oil; define and use the terms: fractional distillation and cracking; define the term "greenhouse effect"; describe what is meant by the terms hydrocarbon; homologous series; saturated; unsaturated; name and draw structural formulae for straight chain alkanes (C1 - C8), alkenes (C2 - C6) and cycloalkanes (C3 - C6); use, appropriately, molecular formulae and full and shortened structural formulae; identify and draw structural formulae for isomers; use the bromine test to show the presence of an alkene; identify the functional group in alkenes. The following tasks are designed to test how confident you are with this learning. Complete the tasks to the best of your ability. Task 1-Sequencing Sort the following fossil fuel formation statements into the correct order. A: They were covered by layers of mud and rocks. Over a long period of time more of these layers began to build up. B: Our seas and oceans are inhabited by sea creatures, plants and microscopic organisms. C: The continued pressure from the layers of mud and rock, lack of oxygen and heat changed the plants and animals into gas and oil. D: Millions of years ago, when these sea creatures, plants and microscopic organisms died, they sank to the bottom of the sea bed. E: We drill down underground to retrieve the oil and gas formed over millions of years. ……………………………………………………………………………………….. Task 2-Definition match Match the correct word to the correct definition Fuel A means of separating crude oil into groups of hydrocarbons with similar boiling points. Cracking The breaking up of larger hydrocarbon molecules (usually alkanes) to produce a mixture of smaller molecules. Fractional distillation A compound containing the elements carbon and hydrogen only. Hydrocarbon The trapping of the sun’s warmth in the planet’s lower atmosphere. Greenhouse effect A substance which burns and releases energy. Task 3-Fantastic fractions Look at the diagram below which shows how crude oil is separated into fractions and answer the questions which follow. Fractional distillation is a process used to separate the hydrocarbons in crude oil into their useful consumer products. (a) Which fraction could be used to tarmac roads? (b) Which fraction could be used to fill camping gas stoves? (c) What is meant by the term viscosity? (d) What is meant by the term flammability? (e) Which fraction is the least flammable? (f) The temperature at the top of the tower is cooler than at the bottom of the tower. What is the relationship between the number of carbons in the molecule and the boiling point? Task 4-Get cracking Octane is a hydrocarbon. The diagram shows the apparatus used to crack octane. Octane is cracked using an aluminium oxide catalyst. Bromine solution is used to show that some of the products are unsaturated. (a) Label the diagram of the apparatus used to crack octane. (b) One of the reactions taking place is: C8H18 C3H6 + X Identify X. Task 5-Odd one out Look at the compounds shown below. In each set decide which is the odd one out and circle it. Say why you think it is the odd one out. Use the terms hydrocarbon, homologous series, saturated and unsaturated to describe why the compound you have chosen is the odd one out. Set 1: propene ethane cyclobutane cyclopentene It is the odd one out because………………………………………………………………………………………………………. Set 2: CH3OH C2H5OH C3H7OH C4H8O It is the odd one out because………………………………………………………………………………………………………. Set 3: C2H4 C3H6O C5H12 C50H102 It is the odd one out because………………………………………………………………………………………………………. Set 4: C4H8O propene C2H5OH C5H12 It is the odd one out because………………………………………………………………………………………………………. Task 6-Naming and drawing From the name draw the full structural formulae and vice versa. Butane H H _C_ H H Pentene H H Cyclopropane _ C _C H H H H _ C _H _ H C H _ C _ C_H H H Task 7-Fabulous formulae Complete the following table. Name Molecular formula Full structural formula Shortened structural formula propane CH3CH2CH2CH3 ethene CH2CHCH3 cyclohexane H2C H2C CH2 CH2 Task 8-Past paper practice 2010 SG Credit The structures of some hydrocarbons are shown in the grid. (a) Identify the hydrocarbon which is the first member of a homologous series. (b) Identify the two isomers of CH2 CH2 2008 Intermediate 2 Which of the following molecules is an isomer of heptane? Task 9-Isomers Draw three isomers of C5H12. Task 10-The bromine test Use a coloured pencil to shade in the colour that would be seen in each of the following test tubes. Complete labels for each test tube using the wordbank below. Statement bank saturated hydrocarbon rapidly decolourises unsaturated hydrocarbon does not rapidly decolourise Test: Test: Alkane + Alkene + bromine solution bromine solution Result: Result: Task 11-Identifying alkenes Circle the molecules that are alkenes. C5H12 CH3CH2CH2CH2CH2CH3 CH2CHCH3 CH3COCH3 C6H6 Which functional group is found in alkenes? Next Steps: If you feel you need to review the work covered in this section log onto the website www.evans2chemweb.co.uk using the username: dunbar and the password: atoms Navigate your way to the revision materials section and focus on Standard Grade Topic 5&6. There is also a good section on fuels and hydrocarbons on http://www.bbc.co.uk/bitesize/standard/chemistry/materialsfromoil/