Volatile oil Volatile oils • different from fixed – secreted in oil cells in specialised structures • ducts, gland, cell or glandular hairs – frequently associated with other substances • gums, resins (resinify on exposure to air) • mainly terpenoid – some phenol ethers and phenols • Terpenoids – based on the 5C isoprene unit – Monoterpenes • most important, most volatile – di-, tri-, sesquiterpenes also important • contain 2 condensed 5C units head-tail Monoterpene components • Hydrocarbons • Alcohols • Aldehydes Citral – all produced via the terpenoid pathway • Ketones • Esters • Oxides Sesquiterpenes (C15) Hydrocarbons Phenols Phenolic esters Anethole Chemical and physical properties • volatile liquids with no colour – keep in amber bottles with minimum air • odour • asymetric centres, isomers with optical activity – only one isomer occurs naturally • refractive index normally high – is a means to characterise the oil • miscible in water and soluble in organic solvents – more soluble if contains –OH fatty acids • reasonably heat stable – can be steam distilled • tend to be used as solvents for resins Families • Economically only a few family groups are commercially useful [1] Labiatae Lavender, Mentha Sp. • oil occurs in special organs – synthesized in glandular trichomes (mint) [2] Umbelliferae Fruits (best if ripe): anise, caraway, fennel, coriander • found in “vittae” in the outer layer is characteristic [3] Pinaceae Pine, juniper • found in resin ducts in outer old xylem or bark • released when bark removed [4] Rutaceae Citrus fruits • typical ductless sacs in outer part of fruit – rind • less stable, need more care [5] Lauraceae Cinnamon, camphor • from region immediately below bark Uses as inhalations, orally, gargles, mouthwashes, trans-dermally [1] Flavours & carminatives [2] Local stimulants and antiseptics (containing phenols) [3] Perfumes [4] Insect repellant, antimating device [5] Starting materials