• • • • • • • CHEMISTRY DISCLOSURE OVERVIEW Homework packet (40 pts each) • Bookwork and worksheets • Practice packet with examples!! Quizzes (10 pts each) • Same as HW problems– different #s. • Keep up with the HW → Free points Labs (10 pts each)– about 3 each unit Tests (100-120 pts each)– multiple choice and free response Participation (100 pts per term) • Be respectful of everybody else, you’ll be fine. • Class parties ο • Be a jerk, lose 10 points OR class pop-quiz ο Office Hours/Help Sesh • 7:00am-7:30am AND 2:25pm-3:30pm Have parents email me with your name and period as subject • If you get it done by tonight, I’ll let you drop your lowest HW score at the end of the term ο REQUIRED MATERIALS Binder + Paper Pen, pencil, Colored pen Composition Notebook (graph paper) Scientific Calculator FEES $6 Canvas $5 Lab fee LAB SAFETY RULES 1. Safety Goggles must be worn at all times when directed. 2. No unauthorized experiments are allowed 3. No horseplay is allowed. 4. Keep work areas clean. 5. Roll up loose, long sleeves. 6. Tie back long hair 7. Notify the teacher of any spills, broken glass immediately. 8. Never taste chemicals unless instructed to do so. 9. Never return unused chemicals to the stock bottles. 10. Avoid contact of chemicals with the skin- wash with soap and water if contact occurs, and notify the teacher. LAB SAFETY RULES 11. Waft; don’t snort when testing for odors. 12. Do not place hot glassware directly on the counter. 13. Remember- hot glass looks like cool glass. Be careful. 14. Turn off burners when not in use. 15. When heating a substance, never look in the container. 16. Stay in your lab group- do NOT wander around. Remember we have the following safety items in the room: A fire extinguisher A fire blanket An emergency shower and eyewash. **Safety quiz at end of period. **Tape your copy to front of lab notebook TEXTBOOK CHECKOUT • You will be given class time to work on homework every class (if you’re good) • It’s a good idea to bring your textbook to class everyday • Grab your student ID card and textbook and get in line for checkout UNIT 1. MEASUREMENTS & CALCULATIONS CHAPTER 5 5.1 (Goal 7) 5.2 (Goal 1) 5.3 (Goal 3) 5.4 (Goal 5) 5.5 (Goal 6) 5.6 (Goal 2) 5.7 (Goal 4) 5.8 (Goal 8) Scientific Notation Units Measurements of Length, Volume, and Mass Uncertainty in Measurement Significant Figures Dimensional Analysis Temperature Conversions Density Section 5.1: Scientific Notation Universe clip Powers of Ten clip What is it? • Writing very LARGE or SMALL numbers as a product of 1-10 and power of 10. Ex. 25000 = 2.5 × 104 0.00135 = 1.35 × 10−3 45 πππππππ = 45,000,000,000 = 4.5 × 1010 1 ππππππππ‘β = 0.000001 = 1 × 10−6 Why do we do it? • More convenient way to write big or small numbers • Makes number manipulation easier (×, ÷, x-1) Section 5.1: Scientific Notation In Class Problems (HW 5.1 - 3, 5, 69) 1. Express in scientific notation π. 7240 = 7.24 × 103 π. 5.408 = 5.408 × 100 π. 0.0005519= 5.519 × 10−4 π. 0.721 = 7.21 × 10−1 2. Express scientific notation as ordinary numbers π. 9.752 × 101 = 97.52 π. 1.8 × 10−4 = 0.00018 π. 5.321 × 104 = 53210 π. 2.34 × 10−2 = 0.0234 Why do we do it? • More convenient way to write big or small numbers • Makes number manipulation easier (×, ÷, x-1) Section 5.1: Scientific Notation Multiplication • Multiply front # and change to scientific notation • Add exponents. Ex. 104 β 103 = 104+3 = 107 10−3 β 104 = 10−3+4 = 101 = 10 −13 10−8 β 10−5= 10−8+−5 = 10−8−5 = 10 9430 β 106 = 9.43 × 103 β 106 = 9.43 × 103+6 = 9.43 × 109 0.000046 β 103 = 4.6 × 10−5 β 103 = 4.6 × 10−5+3 = 4.6 × 10−2 (4.1 × 107 )(3.2 × 10−5 ) = 13.12 × 107 β 10−5 3 = 1.312 × 101 × 107 × 10−5 = 1.312 × 101+7−5 = 1.312 × 10 Section 5.1: Scientific Notation Division • Divide front # and change to scientific notation • Subtract exponents. Ex. −3 10 104 −3−4 = 10−7 = 104−3 = 101 = 10 104 103 10−8 −8−−7 = 10−8+7 = 10−1 = 10 10−7 0.0054 5400 5.4 × 10−3 = 5.4 × 103 5.4 = × 10−3−3 = 1.0 × 10−6 5.4 2.3 × 108 2.3 8−4 = 0.38 × 104 = 3.8 × 10−1 × 104 = × 10 6.0 × 104 6.0 = 3.8 × 103 Section 5.1: Scientific Notation Inverse • Inverse front number (1/front #) • Switch sign of exponent Ex. 1 1 1 −500 11 = 10 = = 10 (10−4 )(10−7 ) 10500 10−11 1 1 1 −4 −4 = = × 10 = 0.17 × 10 5.8 × 104 5.8 58000 = 1.7 × 10−1 × 10−4 = 1.7 × 10−5 1 1 1 3 = = × 10 4.8 × 10−3 4.8 0.0048 = 0.21 × 103 = 2.1 × 10−1 × 103 = 2.1 × 102 Section 5.1: Scientific Notation In Class Problems (HW 5.1 - 8) 3. Manipulate these numbers to have your ending answer in scientific notation π. 999 × 104 = 9.99 × 106 π. 0.000045 × 10−3 = 4.5 × 10−8 (8.2 × 10−4 ) 0 = 2.3 × 10 π. (3.6 × 10−4 ) (9.6 × 10−4 ) −2 = 3.2 × 10 π. (3.0 × 10−2 ) 1 = 2.23 × 10−6 π. 448000 1 π. (3 × 104 )(2 × 108 ) = 1.6 × 10−13 1 = 5 × 102 π. 0.002 (104 )(10−6 ) (108 ) 4 = 10 β. (102 ) Sections 5.2 and 5.3: Units of Measurement Length, Volume, Mass, and Time Scientific Observations **Qualitative: Describes a property without using measurements • The sky is blue. • Fire is hot. **Quantitative: Uses measurements to describe a property. Measurements consist of two parts: – number – scale (unit) Examples • 20 grams • 6.63 × 10–34 joule·seconds Sections 5.2 and 5.3: Units of Measurement Length, Volume, Mass, and Time Systems of Measurement English- only used in USA. ex. Lbs, fl. oz, ft, in, etc. Metric/SI (Systeme Internationale)used by rest of world ex. Grams, liters, meters, centimeters. VERY IMPORTANT TO PAY ATTENTION AND RECORD UNITS!!! In SI, prefixes are used to change the size of the unit (base 10) ex. Main unit of length = meter → used to measure height of a person kilo-meter → distance between cities micro-meter → thickness of human hair SLC→Provo 72 kilometers Ruler activity & Prefix chart Sections 5.2 and 5.3: Units of Measurement Length, Volume, Mass, and Time In Class Problems (HW 5.2 – 9, 10, 70) 4. Match the prefix to the correct base 10 and abbreviation a. centi- 106 μ b. kilo- 10-1 M c. deci- 103 n d. micro- 10-3 c e. mega- 10-9 k f. nano- 10-2 d g. milli- 10-6 m Sections 5.2 and 5.3: Units of Measurement Length, Volume, and Mass **Length-Measurement of Distance (1D space) ex. Convert 3.2 m to cm. SI unit- meter Conversion 1 ππ English unit- foot 1 in = 2.54 cm 3.2 π 10−2 π = 3.2 × 102 ππ Volume-Measurement of 3D space πππ = 1 ππ × 1 ππ × 1 ππ = π πππ = 10−3 πΏ = π ππ³ πππππππ‘ = π × π€ × β 1 dm SI unit- liter (L) English unit- quart (q) 1 cm Conversion 1 L = 1.06 q ex. Convert 12 ML to L 1m πππ = 1π × 1π × 1π = 1 π3 1 dm πππ = 1 ππ × 1 ππ × 1 ππ = π π ππ = π π³ 106 πΏ 12 ππΏ 1 ππΏ = 1.2 × 107 πΏ Sections 5.2 and 5.3: Units of Measurement Length, Volume, Mass, and Time **Mass- Measurement of Quantity of Matter SI unit- **kilogram (kg) Main unit- gram (g) English unit- pound (lb) Conversion 1 lb = 453.6 g ex. Convert 68 kg to mg DOES MASS=WEIGHT? No! Mass is always the same! **Weight depends on the pull of gravity and is measured in Newtons (N) --This is why you would weigh less on the moon, But your mass would stay the same! 68 ππ 103 π 1 ππ 1 ππ 10−3 π = 6.8 × 107 ππ Time-Interval between to occurences SI unit- second (s) ex. Convert 17 years to seconds Conversions 1 min = 60 s 365 πππ¦π 24 βπ 60 πππ 17 π¦ππ 1 hr = 60 min 1 π¦π 1 πππ¦ 1 βπ 1 day = 24 hr 1 year = 365 days 60 π 1 πππ = 536112000 π = 5.4 × 108 Sections 5.2 and 5.3: Units of Measurement Length, Volume, and Mass In Class Problems (HW 5.2 – 9, 10, 13, 70) 5. Fill in the blank. 1 kg = 103 g 1 cm = 10−2 m 1 g = 10−3 kg 1 m = 109 nm 1 cm = 101 mm 1 mm = 10−1 cm 1 mL = 10−6 kL 1 Mg = 1015 ng 1 kg = _______ g 1 cm = _______ m 1 g = _______ kg 1 m = _______ nm 1 cm = _______ mm 1 mm = _______ cm 1 mL = _______ kL 1 Mg = _______ ng 6. Convert between the SI Units a. How many L in 460 mL? 1mL = 10-3 L b. How many kg in 14 mg? 1 mg = 10-3 g, 1 kg = 103 g a. How many cm3 in 45 mL? 1 mL = 1 cm3 10−3 πΏ 460 ππΏ 1 ππΏ 10−3 π 14 ππ 1 ππ 1 ππ3 45 ππΏ 1 ππΏ = 0.46 L 1 ππ 103 π = 45 ππ3 = 1.4 × 10−5 kg Sections 5.2 and 5.3: Units of Measurement Length, Volume, and Mass In Class Problems (HW 5.2 – 13, 18) 7. Convert 45 s to the following units a. ns 1ns = 10-9 s b. Ms 1 Ms = 106 s c. μs 1 μs = 10-6 s 1 ππ 10−9 π 45 π 1 ππ 106 π 1 ππ 45 π 10−6 π 45 π = 45 × 109 ns = 4.5 × 1010 ns = 45 × 10−6 Ms = 4.5 × 10−5 Ms = 45 × 106 μs = 4.5 × 107 μs 8. Fill in the table SI Unit English Unit Conversion(s) Measuring Instrument mass kilogram, gram pound 1 lb = 453.6 g = 0.4536 kg balance/scale volume liter quart 1 L = 1.06 q graduated cylinder length meter foot 1 in = 2.54 cm meter stick time second second -------------------------- stop watch Sections 5.2 and 5.3: Units of Measurement Length, Volume, and Mass How your prefix chart works (REVIEW) Right column = multiplier Left column= prefix 1 π___ 1 π___ 1 π___ = 106 ____ = 103 ____ = 10−1 ____ 1 π___ = 10−2 ____ 1 ππ = 10−2 m 1 π___ 1 π___ = 10−3 ____ = 10−6 ____ 1 ππ 1 ππ = 10−3 g = 10−6 s 1 π___ = 10−9 ____ 1 ππ = 10−9 m Convert 5 mL to L = 10−3 L 1 ππΏ 5ππΏ −3 πΏ ___πΏ 10 ___ππΏ 1ππΏ = 5 × 10−3 L 1 ππ 1 ππΏ 1 ππ = 106 g = 103 L = 10−1 s Sections 5.4 & 5.5: Uncertainty in Measurements and Significant Figures Every measurement has some degree of uncertainty • usually due to visual estimates from person to person and precision of the measuring device • A digit that must be estimated is called uncertain. 20 cm 21 cm What would you record the length of this pencil to be? a. 20.93 cm? I would record it as b. 20.94 cm? 20.94 cm c. 20.95 cm? Certain digits: 20.94 d. 20.96 cm? Uncertain digit: 20.94 e. Any others? Final reading looks like: 20.94±0.01 cm # sig figs: 3+1=4 #π ππππππππππ‘ ππππ’πππ = #ππππ‘πππ πππππ‘π + 1π’πππππ‘πππ πππππ‘ 21 Sections 5.4 & 5.5: Uncertainty in Measurements and Significant Figures In Class Problem 9. Record the following measurements properly 4cm 5cm For graduated cylinders, read the bottom of the meniscus 35.0 ± 0.1 mL 36.4 ± 0.1 mL 4.72 ± 0.01 cm Sections 5.4 & 5.5: Uncertainty in Measurements and Significant Figures Rules for Counting Sig Figs • • • • 1-9 Leading 0’s Captive 0’s Trailing 0’s ALWAYS count NEVER count ALWAYS count NEVER count (unless with decimal) All front numbers in scientific notation are significant digits. (another advantage to writing in scietific notation ο) Ex. How many sig figs? a. 453 a. b. 0.00001534 b. c. 0.084601 c. d. 1200 d. e. 1200. e. f. 1.20×103 f. 3 4 5 2 4 3 Sig Figs Calculating Rules (in packet) Addition and Subtraction -Number with lowest amount of digits after decimal limits the answer’s sig figs ex. How many sig figs in the answer? 22.102 300.956 18.3 −10. +4.01 290.956 = 291 44.412 = 44.4 3 π ππ ππππ 3 π ππ ππππ Multiplication and Division -Number with lowest number of sig figs limits the answer’s sig figs ex. How many sig figs in the answer? 3.012 4.22 × 104 1.9 × 10−2 8.018 × 102 = 8.0 × 102 2 π ππ ππππ (3.012+4.2) 1.8456 7.2 1.8456 +4.2 7.212 → = 3.9011703 = 3.9 2 π ππ ππππ Sections 5.4 & 5.5: Uncertainty in Measurements and Significant Figures In Class Problems (HW 5.5 – 24, 26-31, 33, 34) 10. How many sig figs are there? 11. How many sig figs will the answer have? a. b. c. d. e. f. 93750 586.200 0.0000007 5.01×10-8 π 3000001.0 8325 =1 4 a. 6 (2.5)(0.002) 1 (4.319 − 1.23) =3 3 π. −7 ∞- **natural (counting) 5.601 × 10 #’s don’t effect s.f. of π. 853.0 + 48.258 − 0.00005 8 answer =4 12. Calculate the following with the correct sig figs. = 1.35712 × 103 = 1.36 × 103 b. (9.06×10−4 ) (3.0×10−2 ) = 3.02 × 10−2 = 3.0 × 10−2 c. 2 58500 = 3.41880341 × 10−5 a. 4.241 × 107 3.20 × 10−5 = 3 × 10−5 Sections 5.4 & 5.5: Uncertainty in Measurements and Significant Figures Accuracy vs. Precision **Accuracy: How close measurements **Precision: How close measurements are to the true value are to each other PRECISE? ACCURATE? Precise Not Accurate Precise Accurate Not Precise Not Accurate Not Precise Accurate ex. You measure the length of a 2.50 cm pencil to be 2.54 cm. What’s the Is there a way to calculate how accurate your percent error? measurement it?? 2.50 ππ − 2.54 ππ Yes!! It’s called “Percent Error” % πΈππππ = × 100 2.50 ππ (% error=0 → 100% accuracy) π½ππππππππ − π½ππππππππππππ % π¬ππππ = × πππ π½ππππππππ = − 0.04ππ × 100 2.50 ππ = 0.04 × 100 2.50 ππ = 1.60% Packet Problems Section 5.6: Dimensional Analysis Why? A way convert between units --Did similar stuff in section 5.3 Goal: Use equivalence statements to write conversion factors π ππ = πππ π π ππ πππ π ππ π ππ π π ππ π ππ = ππ ππ π ππ ππ ππ ππ ππ ππ π ππ ππ π¬ = π πππ π πππ ππ π ππ ππ π π πππ π. ππ π = π π³ ππ³ π. ππ π ππ π. ππ π ππ³ ex. How many inches in 2.4 ft? 12 ππ = 28.8 ππ Plan: Ft → in 2.4 ππ‘ 1 ft = 12 in 1 ππ‘ = 29 ππ How many feet in 50.0 cm? Plan: cm → in→ ft 2.54 cm = 1 in 1 ft = 12 in 1 ππ 50.0 ππ 2.54 ππ 1 ππ‘ 12 ππ = 1.6404 ππ‘ How many in in 15 cm? 1 ππ = 5.90551 ππ Plan: in → cm 15ππ 2.54 ππ = 5.9 ππ 1 in = 2.54 cm Convert 65 mph to km/s? Plan: miles → km 1 mile = 1.6093 km hours → min 1 hour = 60 min 1 min = 60 s min → s 1.6093 ππ 1 βπ 1 πππ 1 ππ 60 πππ 60 π = 1.64 ππ‘ ππ ππ = 0.029 = 0.029056 (Packet Problems) π π 65 ππ βπ Section 5.6: Dimensional Analysis In Class Problems (HW 5.6 – 14, 19, 39, 40, 43, 64, 65 and Packet Problems) 13. A baby is born to be 19 inches long. Convert to m. Plan: in → cm → m 1 in = 2.54 cm = 0.48 π -2 1 cm = 10 m 14. How much money do I have if I measure a row of quarters to be 55.0 cm long? Plan: cm → # quarters→ $ 2.5 cm = 1 quarter = $5.50 1 quarter = $0.25 15. Convert the following Plan: mg → g → kg 4.3×10-6 kg 5.0 gallons to mL Plan: gal → L → mL 1.9×104 mL c. 3.0 m3 to mL Plan: m3→ cm3 → mL 3.0×106 mL d. π 210 ππΏ a. 4.3 mg to kg b. to ππ ππ3 Plan: top: g→ lb bottom: mL → cm3 → dm3 460 ππ ππ3 Section 5.7: Temperature Conversions • (°F) Fahrenheit- used by US and England, elongated scale • (°C) Celsius- used by Canada, Europe and Scientists • ( K) **Kelvin- SI unit for temp, absolute scale (can’t go below 0K) Celsius ↔ Kelvin K = β + 273 ex. Convert 55 °C to Kelvin. πΎ = 55β + 273 = 328 β = πΎ − 273 ex. Convert 267 K to °C. β = 267πΎ − 273 = −6β Section 5.8: Density **What is it? Tells you how much matter is in a given volume ππππ ππ‘π¦ = π πππ π (π) = π£ π£πππ’ππ (ππΏ ππ ππ3 ) How to determine density of an object? • Mass• Volume- measure on a **balance. →liquid? Measure in a graduated cylinder →perfect geometry? Measure dimensions →imperfect or perfect? Measure displacement of water in a graduated cylinder π£πππ’ππππ¦ππππππ = π£πππ’ππππππ = 68.0ππΏ − 64.0ππΏ 29.0ππΏ − 19.0ππΏ = 10.0ππΏ = 4.0ππΏ π£πππ’ππππππππ‘ = π£πππ’πππππππ − π£πππ’ππππππ‘πππ Section 5.8: Density In Class Problems (HW 5.8 and Lab) 15. A student wants to find the density of a necklace that weighs 40.58 g. She puts it in a graduated cylinder that has 10.1 mL water in it, and the new volume reads 12.2 mL. What is her necklace made out of? (Use table 5.8 in book) πππππππππ = 40.58 π π£ππππππππ = 12.2ππΏ − 10.1ππΏ π π= π£ = 2.1ππΏ 40.58 π = 2.1 ππΏ π = 19.3238 ππΏ π = 19 ππΏ 16. What is the density of a 20.2 mL sugar solution that weighs 28.89 g? ππ ππ = 28.89 π π£π ππ = 20.2 mL π= π π£ π 28.89 π = 1.43019 = ππΏ 20.2 ππΏ π = 1.43 ππΏ 17. The diameter of a silver sphere is 5.12 cm, and the weight is 723.85 g. What is the density? % Error? 723.85 π π π ππ πβπππ = 723.85 π 4 3 3 4 = 70.3 ππ 3 ππ 3 π πβπππ = 3 π(2.56ππ) ππ πβπππ 5.12 ππ = = = 2.56 ππ 2 2 π£π πβπππ = ππ πβπππ π= π£ = 70.3 ππ3 = 10.29658 ππ3 π π = 10.3 3 ππ Section 5.8: Density In Class Problems (HW 5.8 and Lab) 18. How much mass is in 18.6 mL of ethanol? (Density in table 5.8) πππ‘βππππ =? π£ππ‘βππππ = 18.6 ππΏ πππ‘βππππ = 0.785 π∗ π = π π =πβπ£ Multiply up π = 0.785 π β 18.6ππΏ ππΏ = 14.6 π ππ‘βππππ π ππΏ 19. How much volume is in 12.42 g of copper? (Density in table 5.8) ππΆπ’ = 12.42 π π£πΆπ’ = ? ππΆπ’ π = 8.96 ππΏ π π = ∗ π£ Switch places π π£= π π£= 12.42 π π 8.96 ππΏ = 1.39 ππΏ Section 5.8: Density For your lab GOALS/PROCEDURE 1. Measure the density of water a) Weigh empty beaker b) Add some amount of water– read volume to 0.1 mL c) Weigh grad. cylinder + water 2. Measure density of unknown liquid a) Same procedure with 10 mL grad. cyl. b) SOME LIQUIDS HARMFUL TO BODY!! CAREFUL!! 3. Density of solid a) Weigh object b) Fill 100 mL grad. cyl. half way with water (Record volume (vinitial)) c) Add object (Record new volume (vfinal) π£πππ’ππππππππ‘ = π£πππ’πππππππ − π£πππ’ππππππ‘πππ π= π π£