Title: STAO - Fire Safety Resource Marketing Abstract This workshop will present the components of a Grades 9-12 Science Fire Safety resource that focuses on mitigating safety issues arising from the handling of flammable and combustible substances in school laboratories when conducting curriculum-linked activities. Table of Contents Introduction: Laboratory Mishaps – 15 minutes Components of Resource – 10 minutes Overview of Legislation and Regulations – 10 minutes Curriculum Connections – 10 minutes Videos - 30-35 minutes Demonstrations/Hands-on Activities – 40 minutes Scientific Investigation Skills (SIS) – 5 minutes Length of Workshop 120 minutes Maximum number of participants Dependent on materials and facilities available if hands-on activities are part of workshop Type of facility required Chairs Data projector and laptop Flipchart, stand, and markers Space at sides for participant-conducted demonstrations where possible* (e.g., 5 stations - 3 for Gas Tests (H2, O2 and CO2) and 2 for metal reactivity (Li and Na)) 1 Materials: Materials for the facilitator Data projector and cable connection for laptop computer Flipchart, stand, and markers Copies of handouts for participants, including evaluation form Gas Tests - Chemicals/Materials Required: Chemicals Ca metal (small lumps) MnO2 3% H2O2 vinegar baking soda limewater solution – Ca(OH)2 Materials candle and BBQ lighter wooden splints two clean, dry scoopulas a safety shield 100, 250 mL, and 400mL beakers three 100 mL beakers test tube a strip of cardboard test tube holder 250 mL and 125 mL Erlenmeyer flasks a flask stopper with a rubber tubing attached Gas Tests - Safety Equipment: Prep Room (Teacher) Gloves Safety goggles Lab coat MSDS sheets for Ca metal, MnO2, 3% H2O2 Classroom Safety shield Bucket of sand Teacher Gloves Safety goggles Lab coat Student Safety goggles Alkali Metals - Chemicals/Materials Required: Chemicals Li metal Na metal K metal Mineral oil Phenolphthalein solution Vinegar 0.1 mol/L NaOH Materials Glass or wax tray Mineral oil Sharp knife 3 plastic petri dishes with covers workplace labels 1000 mL beakers 150 mL beakers overhead projector 250 mL beaker wire mesh that covers mouth of 250 mL beaker 3 droppers Alkali Metals - Safety Equipment: Prep Room (Teacher) Gloves Safety goggles Lab coat Face shield MSDS sheets for Li, Na, K metals; 0.1 mol/L NaOH; and Phenolphthalein solution Classroom Safety shield Bucket of sand Teacher Gloves Safety goggles Lab coat Student Safety goggles 2 TIME Intro Facilitator Notes Welcome This presentation will take about 2 hours and involve group work. * The experiments will ONLY take place in facilities where they can be safely performed. Materials Slide STAO Fire Safety Resource What You Will Learn The format of the STAO Fire Safety Resource We have three goals today, you will learn The format of the STAO Fire Safety Resource The proper and safe use of flammable and combustible materials in secondary classrooms The legislation and curriculum linkages related to working with flammable and combustible materials in secondary classrooms The proper and safe use of flammable and combustible materials in secondary classrooms The legislation and curriculum linkages related to working with flammable and combustible materials in secondary classrooms The Fire Safety resource will be freely available on the STAO website (in English and French) 3 TIME Intro Facilitator Notes Organize the participants into smaller groups (about 4 per group) to discuss the articles and identify key points for flip chart. This honours their ability to analyze the information and recognizes the importance of small group discussion to learning. 3 Recent Classroom Accidents 1. Students injured in Science classroom fire demonstration of how different chemicals burn nearby bunsen burner ignited 1L beaker of methanol in teacher’s hand flames scattered onto students in front row 2. Science experiment burns student demonstration of whoosh bottle experiment more alcohol added after first demo flame shoots out of jug burning student about 2 metres away from demo 3. Teacher and students suffer lacerations in Science lab explosion demonstration of exothermic reaction – potassium chlorate, manganese dioxide, sugar and glycerine teacher wearing safety goggles; students moved back several students taken to hospital **The facilitator may pre-read the three articles.** Materials Slides, flipchart Articles on 3 school lab accidents Slide STAO Safety Resource Recent Accidents in Ontario Science Classrooms 1. A beaker of methanol was ignited accidentally by a bunsen burner flame. The beaker was dropped, the flames spread, and several students were taken to hospital. 2. One cup of alcohol placed in a water cooler was ignited, a flame shot out and a ball of fire landed 2 meters away on a student’s jeans. 3. Reaction with Potassium Chlorate, Manganese Dioxide, Sugar and Glycerine in a test tube resulted in an explosion. Three students injured. Lead a group discussion: What happened in each situation? Were these demonstrations or student investigations? What went wrong? What could have been done to prevent the accident? o In the set-up? In the choice of reactions? Summarize answers on flip chart. As facilitator, choose answers to highlight key safety considerations that teachers should remember for demonstrations and student investigations: Reduce quantities Choose safer alternatives Use dilute concentrations 4 TIME Intro Facilitator Notes Fire Safety Knowledge and Skills are outlined in the STAO Fire Safety Resource. These Fire Safety rules are summarized in the Fire Safety Triangle Materials Slide Fire Safety Knowledge and Skills Knowledge for Handling Flammable and Combustible Substances 1. Type of Flammable and Combustible Materials Knowledge for Handling Flammable and Combustible Substances 1. Type of Flammable and Combustible Materials 2. Quantity of Flammable and Combustible Materials 3. Concentration of Flammable and Combustible Materials 2. Quantity of Flammable and Combustible Materials 3. Concentration of Flammable and Combustible Materials Fire Safety Knowledge and Skills Knowledge and Skills for Preparation of Activities 4. Room Readiness Safety equipment Prior activities in classroom 5. Storage and Disposal 6. Classroom Management Assessment of student skill level and readiness Distribution and control of materials in the classroom 7. Choice of Heat Source Suitable flame source Use of hotplate Knowledge and Skills for Preparation of Activities 4. Room Readiness ― Safety equipment 5. Storage and Disposal 6. Classroom Management ― Assessment of student skill level and readiness 7. Choice of Heat Source ― Suitable flame source Knowledge and Skills for Emergencies 8. Dealing with Unintended Flame Knowledge and Skills for Emergencies 8. Dealing with Unintended Flame - Evacuation plan 5 TIME Components Facilitator Notes The Fire Safety Resource Components 1. Educators’ Guide 2. Video clips 3. Student Information Materials 4. Workshop or Training Materials Materials Slide Fire Safety Resource Components The Fire Safety Resource Components 1. Educators’ Guide 2. Video clips 3. Student Information Materials 4. Workshop or Training Materials The learning goals for the STAO Fire Safety Resource are: Fire Safety Resource Learning Goals Learning Goals 1. Identify and clarify legislation and regulations related to fire safety 2. Identify and clarify curriculum expectations 3. Demonstrate procedures necessary to plan and supervise safe student learning activities 4. Provide classroom resources aligned with the curriculum expectations 5. Provide training materials for teachers and students 1. Identify and clarify legislation and regulations related to fire safety 2. Identify and clarify curriculum expectations 3. Demonstrate procedures necessary to plan and supervise safe student learning activities 4. Provide classroom resources aligned with the curriculum expectations 5. Provide training materials for teachers and students 6 TIME Components Facilitator Notes The first component is the Educator’s guide. The Fire Safety Resource Components 1. Educators’ Guide 2. Video clips 3. Student Information Materials 4. Workshop or Training Materials Materials Slide Fire Safety Resource: Educators’ Guide Educators’ Guide An outline of legislation and curriculum linkages Links to curriculum policy for Grades 9-12 Science with a focus on safety Links to science courses with curriculum expectations that may involve working with flammable and combustible materials Student and teacher reflection tools for learning sustainment Teacher supports for videos Educators’ Guide An outline of legislation and curriculum linkages Links to curriculum policy for Grades 9-12 Science with a focus on safety Links to science courses with curriculum expectations that may involve working with flammable and combustible materials Student and Teacher Reflection tools for learning sustainment Teacher Supports for videos 7 TIME Legislation/ Regulations Facilitator Notes A key aspect of the Educator’s guide is outlining the legislation and curriculum linkages. Some of the relevant legislation and regulations related to Fire Safety in the classroom (more details are available in Safe ON Science) are: Materials Slide Overview of Legislation Occupational Health and Safety Act/Ministry of Labour SCIENCE TEACHER Education Act: O. Reg. 298/Ministry of Education Science WHMIS (Workplace Hazardous Materials Information System) Involves a check that: hazardous materials or controlled products are properly labelled or identified; Material Safety Data Sheets are present in the workplace; and worker education programs have been carried out. WHMIS/ Ministry of Labour Biology Chemistry Environmental Science Earth and Space Science Physics Office of Ontario Fire Marshal The Environmental Protection Act Legislation related to Safety in general: Legislation related to Safety in general Education Act: O. Reg 298, 20.(g), Duties of Teachers ‘ensure that all reasonable safety procedures are carried out in courses and activities for which the teacher is responsible’ Occupational Health and Safety Act (OHSA) Teachers need to be aware that under the OHSA every worker has the right to know about the hazards in their workplace, to bring issues to the employer’s attention and to refuse work that is unsafe. Ministry of Labour Inspections The Ministry of Labour is responsible for enforcing the Occupational Health and Safety Act (OHSA) and consequently regularly inspects workplaces, including schools, to ensure that employers and/or employees are not in breach of the Act or one of its associated regulations as well as to protect workers’ (e.g., teachers) health and safety on the job. On the Ministry of Labour web site an inspector explains what he looks for when visiting chemistry labs and shop classes in schools. http://www.labour.gov.on.ca/english/gallery/v_schools_hs.php Education Act: O. Reg 298, 20.(g), Duties of Teachers ‘ensure that all reasonable safety procedures are carried out in courses and activities for which the teacher is responsible’ http://www.elaws.gov.on.ca/html/regs/english/elaws_regs_900298_e .htm Legislation related to Safety in general: Occupational Health and Safety Act (OHSA) and its Regulations: Teachers need to be aware that under the OHSA every worker has the right to know about the hazards in their workplace, to bring issues to the employer’s attention and to refuse work that is unsafe Science teachers should have adequate training in the procedures for the safe use and handling of all chemicals used in the curriculum including flammable and combustible liquids ……. http://www.elaws.gov.on.ca/html/statutes/english/elaws_statutes_90o01_e.htm 8 Legislation/ Regulations Legislation related to Safe Handling of Flammable and Combustible Liquids Teachers electing to conduct demonstrations using flammable and combustible liquids, need to be aware of specific legislation : Office of the Fire Marshal (OFM): Ontario Fire Code – ‘Personnel working in laboratories shall be trained in the safe handling of flammable liquids and combustible liquids’ The OFM guideline, Handling Flammable and Combustible Liquids in School Laboratories, which ‘provides procedures that must be used in conducting demonstrations using flammable and combustible liquids in Ontario classrooms.’ Legislation related to Safe handling of Flammable and Combustible Liquids: - Office of the Fire Marshall (OFM): Ontario Fire Code -Sentence 4.12.4.1.(3), Division B states: "Personnel working in laboratories shall be trained in the safe handling of flammable liquids and combustible liquids“ http://www.elaws.gov.on.ca/html/source/regs/english/2007/elaws_src_regs_r07 213_e.htm -OFM guideline, ‘Handling Flammable and Combustible Liquids in School Laboratories’ http://www.ofm.gov.on.ca/en/Legislation%20Directives%20and%2 0Technical%20Guidelines/Technical%20Guidelines%20and%20Re ports/pdf/OFM-TG-01-2011.pdf The Environment EPA (Environmental Protection Act) This is Ontario's key legislation for environmental protection and grants the Ministry of the Environment broad powers to deal with the discharge of contaminants which cause negative effects. Curriculum linkages What does curriculum policy say about Safety in the classroom? What does Curriculum Policy say about Safety in the Classroom? ‘Teachers must model safe practices at all times and communicate safety expectations to students in accordance with school board and Ministry of Education policies and Ministry of Labour regulations’ Refer to ‘Health and Safety in Science’ in ‘Some Considerations for Program Planning’ section of: The Ontario Curriculum, Science, Grades 9 and 10 (2008) The Ontario Curriculum, Science, Grades 11 and 12 (2008) Implementation of the provincial Grades 9-12 Science curriculum policy requires that: ‘Teachers must model safe practices at all times and communicate safety expectations to students in accordance with school board and Ministry of Education policies and Ministry of Labour regulations’ The Ontario Curriculum, Grades 9 and 10 Science, 2008: Health and Safety in Science http://www.edu.gov.on.ca/eng/curriculum/secondary/science910curr.pdf The Ontario Curriculum, Grades 11 and 12 Science, 2008: Health and Safety in Science http://www.edu.gov.on.ca/eng/curriculum/secondary/2009science11_12.p df 9 Curriculum Connection s Science courses with curriculum expectations that may involve the use of flammable or combustible materials are highlighted in the curriculum roadmap chart or the ‘Guide Chart for Curriculum Linked Activities Involving Flammables and Combustibles’. The curriculum expectations of the following highlighted courses may involve the use of flammable or combustible materials: Grade 9 Science, Academic and Applied Grade 10 Science, Academic and Applied Grade 11 Biology, College Grade 11 Chemistry, University Grade 12 Biology, University Grade 12 Chemistry, University Grade 12 Chemistry, College Grade 12 Science, Workplace Grade 12 Science, University/College Educators’ Guide: Curriculum Connections - Course Roadmap Science courses with curriculum expectations that may involve the use of flammable or combustible materials are highlighted in the curriculum roadmap chart. Summary Yellow indicates a course with a single specific expectation that may involve flammable or combustible materials, Orange indicates a course with 2-3 specific expectations that may involve flammable or combustible materials, and Red indicates a course with 4 or more specific expectations that may include flammable or combustible materials. 10 Curriculum Connection s STAO chose 6 videos to demonstrate investigations that address key curriculum expectations, with [PR] (Performing & Recording) appended, in key courses. This chart in the Educators’ Guide provides a list of these curriculum expectations. NOTE: The abbreviation(s) for the broad area(s) of investigation skills – IP, PR, AI, and/or C – are provided in square brackets at the end of the expectations in strands B – E/F to which the particular area(s) relate. - IP – Initiating and Planning PR – Performing and Recording AI – Analysing and Interpreting C – Communicating Educators’ Guide: Curriculum Connections - Expectations Addressed by Videos Grade/ Course Grade 9 Academic SNC1D Expectation Number C2.2 C2.3 Applied SNC1P Expectation Description Possible Fire Hazards conduct an inquiry to identify the physical and chemical properties of common • Combustion of solids, liquids, elements and compounds (e.g., magnesium sulfate, water, carbon, copper II) or gases [PR] plan and conduct an inquiry into the properties of common substances found in • Combustion of solids, liquids, the laboratory or used in everyday life (e.g., starch, table salt, wax, toothpaste), or gases and distinguish the substances by their physical and chemical properties (e.g., physical properties: hardness, conductivity, colour, melting point, solubility, density; chemical properties: combustibility, reaction with water) [IP, PR, AI] C2.4 conduct appropriate chemical tests to identify some common gases (e.g., • Large volumes of gases oxygen, hydrogen, carbon dioxide) on the basis of their chemical properties, and combusting record their observations [PR, C] C2.2 use an inquiry process to identify the physical and chemical properties of common elements and simple common compounds, including gaseous substances (e.g., sulfur is a yellow solid; sodium chloride is water soluble; nitrogen gas is colourless, odourless, and very unreactive) [PR, AI] C2.5 investigate and compare the chemical properties (e.g., combustibility, reaction with water) of representative elements within groups in the periodic table families of elements (e.g., Mg and Ca; N and P) [PR, AI] • Mixing volumes of gases • Inappropriate heat source • Combustion of solids, liquids, or gases • Combustion of solids • NOTE: phosphorus should not be used in a school lab Video # 2 2 1 1, 2 1, 2 Please note that the curriculum expectations listed in the chart may involve an investigation that requires flammable or combustible materials. However, in many cases, safer, non-flammable alternatives may exist. Also note that there is always the potential for serious injury if high concentrations, large masses/volumes, or inappropriate lab equipment is used. (see section 7 in Safe ON Science, ‘Considerations for Chemistry Activities’) 11 Videos The second part of the STAO Fire Safety resource is comprised of 6 videos. Fire Safety Resource: Videos Videos The Fire Safety Resource Components 1. Educators’ Guide 2. Video clips 3. Student Information Materials 4. Workshop or Training Materials Videos: 1. 2. 3. 4. 5. 6. Student Informati on Materials 1. Testing Gases – H2, O2, and CO2 2. Reactivity of Metals – Li, Na, and K 3. Oxidation of an Alcohol using a Catalyst 4. Acetylene Production from Calcium Carbide 5. Safely Synthesizing Esters 6. Aseptically Preparing a Bacterial Streak Plate Testing Gases: H2, O2, and CO2 Reactivity of Metals: Li, Na, and K Oxidation of an Alcohol using a Catalyst Acetylene Production from Calcium Carbide Safely Synthesizing Esters Aseptically Preparing a Bacterial Streak Plate The third part of the STAO Fire Safety resource is comprised of the Student Information Materials The Fire Safety Resource Contents 1. Educators’ Guide 2. Video clips 3. Student Information Materials 4. Workshop or Training Materials Fire Safety Resource: Student Information Materials Student Information Materials Posters and handouts to: Be used prior to student activity Help students be aware of and understand their responsibilities Provide guidelines for working with flammable and combustible substances Student Information Materials Posters and handouts These handouts are reflection materials that the students can use prior to their activities to provide guidelines for their responsibilities during investigations in school labs 12 Workshop Materials The fourth part of the STAO fire safety resource are the Workshop Materials, which facilitate Professional Development days and include classroom handouts. The Fire Safety Resource Contents 1. Educators’ Guide 2. Video clips 3. Student Information Materials 4. Workshop or Training Materials Fire Safety Resource: Workshop or Training Materials Workshop or Training Materials to Facilitate PD Sessions Introduce and clarify components of fire safety resource including: ― Related legislation and curriculum policy ― Fire Safety Knowledge and Skills set Provide teacher supports/handouts for videos ― Teacher notes ― Safety points ― Worksheets Workshop Materials Introduce and clarify components of the resource including: Related legislation and curriculum policy Fire Safety Knowledge and Skills set Provide teacher supports/handouts for the videos Teaching notes Safety points Worksheets 13 Videos To participants: While watching the video, answer the questions on the reflection sheet: 1. 2. 3. 4. What categories (classes) of chemicals are used in this activity? What specialised equipment is used? What safety precautions are taken during this activity? What classroom management concerns are addressed in the video? Video Outline While watching the video, answer the reflection sheet questions: 1. What categories (classes) of chemicals are used in this activity? 2. What specialised equipment is used? 3. What safety precautions are taken during this activity? 4. What classroom management concerns are addressed in the video? Video 1 - H2, O2, and CO2 Ask participants to fill out their participant reflection sheet during the video Play Video 1 – Testing Gases: H2, O2, and CO2 Video 1 - Testing Gases – H2, O2, and CO2 Video 1 14 Videos and support materials Answers Video 1: Testing Gases: H2, O2, and CO2 1. What categories (classes) of chemicals are used in this activity? Calcium pellets – (general) Manganese dioxide – (general) 3% fresh hydrogen peroxide – (oxidizer) 5% Dilute acetic acid (non water reactive acid) Lime water (non water reactive base) Sodium bicarbonate – (general) 2. Video 1 – Testing Gases H2, O2, and CO2 Discussion Questions 1. What categories (classes) of chemicals are used in this activity? 2. What specialised equipment is used? 3. What safety precautions are taken during this activity? 4. What classroom management concerns are addressed in the video? What specialised equipment is used? Wooden splints, scoopula, rubber tubing attached to a one hole stopper Beakers, Erlenmeyer flasks, test tubes Candles 3. What safety precautions are taken during this activity? Label beakers Use dilute H2O2 (3%) Use small quantities Use proper eye protection Long handled lighter to ignite candle 4. What classroom management concerns are addressed in the video? Small fire source – candles Students can use a test tube rather than Erlenmeyer flask Extinguish flame once used Lab coat, safety goggles, gloves 15 Chemical Segregation in the Storage Room – more detail is available in Safe ON Science (page 37) Chemical Segregation in the Storage Room Chemical Storage Groups (adapted from SOS page 37) Explain the categories Flammable and Combustible liquids Flammable and Combustible Water-reactive Solids (e.g., alkali metals) Highly Toxic Chemicals (e.g., Mercury) Corrosive Liquids, acids (e.g., conc. HCl) Corrosive Liquids, bases (e.g., NaOH solution) Corrosive Solids (e.g., NaOH) Oxidizing Agents (e.g., peroxides, chlorates) General Chemicals Group Storage Provision Flammable and Combustible liquids (e.g., alcohols) Flammable and Combustible Water-reactive Solids (e.g., alkali metals) Fire-resistant Oxidizers and toxics ‘Flammables Cabinet’ Separate cupboard Oxidizers, corrosive or cabinet liquids, and flammable liquids Store Away From Highly Toxic Chemicals (e.g., Mercury) Corrosive Liquids, acids (e.g., conc. HCl) Usually banned by most boards Vented ‘Acid Cabinet’; HNO3 should be isolated Flammable liquids Non-acid corrosive liquids, water-reactive solids and toxics Chemical Segregation in the Storage Room Chemical Storage Groups (adapted from SOS page 37) Group Storage Provision Store Away From Corrosive Liquids, bases (e.g., NaOH solution) Corrosive Solids (e.g., NaoH) Oxidizing Agents (e.g., peroxides, chlorates) Not in glass containers Acids, water-reactive solids and toxics General Chemicals Inorganics/organics With general chemicals In plastic trays Flammable liquids/solids, water-reactive solids, organics, corrosive liquids Hazardous Materials Identification System (HMIS) Rating For chemicals in video #1 (highest hazard rating is 4) 1. Calcium 2. Manganese Dioxide HMIS (0 to 4) Health 3 Fire 3 Hazard Reactivity 2 HMIS (0 to 4) Health 2 Fire 0 Hazard Reactivity 0 3. 3% Hydrogen Peroxide HMIS (0 to Health Fire Hazard Reactivity 4) 2 0 HMIS Rating for Chemicals Hazardous Materials Identification System (HMIS) Rating: for chemicals in Video #1 (The highest hazard rating is 4) 1. Calcium 2. Manganese Dioxide HMIS (0 to 4) 3. 3% Hydrogen Peroxide HMIS (0 to 4) Health 3 Fire Hazard 3 Reactivity 2 Health Fire Hazard Reactivity HMIS (0 to 4) 2 0 0 Health Fire Hazard Reactivity 2 0 0 0 4. Dilute Acetic Acid 5. Lime Water 6. Sodium Bicarbonate HMIS (0 to 4) HMIS (0 to 4) HMIS (0 to 4) Health 2 Health 1 Health 1 Fire 0 Fire 0 Fire 0 Hazard Hazard Hazard Reactivity 0 Reactivity 0 Reactivity 0 HMIS Rating for Chemicals Hazardous Materials Identification System (HMIS) Rating: for chemicals in Video #1 (The highest hazard rating is 4) 4. 5% Acetic Acid HMIS (0 to 4) Health 2 Fire Hazard 0 Reactivity 0 5. Lime Water 6. Sodium Bicarbonate HMIS (0 to 4) Health Fire Hazard Reactivity HMIS (0 to 4) 1 0 0 Health Fire Hazard Reactivity 1 0 0 16 Videos and support materials Play Video 2: Reactivity of Metals: Li, Na, and K Video 2 – Reactivity of Metals Li, Na, and K Video 2 - Reactivity of Metals – Li, Na, and K Discussion Questions 1. What categories (classes) of chemicals are used in this activity? alkali metals – Sodium, lithium, potassium (water incompatible flammable solids) mineral oil – (general) water – (general storage) Dilute acetic acid (non-water reactive acid) NaOH – (strong corrosive base) 2. What specialised equipment is used? Knife Tweezers Petri dish Wire mesh Overhead projector Explosion shield 3. What safety precautions are taken during this activity? Cut metals in preparation room Leave stock bottles in prep room Use small quantities – pea size Label petri dishes Use mineral oil to transport metals Wear proper eye protection Use explosion shield Use safe alternatives – water in place of acid Use beakers instead of flasks Use a wire mesh 4. What classroom management concerns are addressed in the video? Students wear eye protection Students move back Video 2 Video 2 – Reactivity of Metals: Li, Na, and K Discussion Questions 1. What categories (classes) of chemicals are used in this activity? 2. What specialised equipment is used? 3. What safety precautions are taken during this activity? 4. What classroom management concerns are addressed in the video? 17 Hands-on Activities 30 min Station Passport:A This is a 30 minute activity where you will be able to perform some of the experiments outlined in the Fire Safety Resource. (* ONLY to be done in facilities where hands-on experiments can be safely performed) You will rotate through 5 stations. The first 3 stations (Experiment #1) are testing gases H2, O2 and CO2. The other 2 stations (Experiment #2) are reacting Li or Na with water. Station Passport: A Instructions Choose a partner Rotate through stations in partners 5 minutes per station Fill in Teacher Worksheets for videos 1 and 2 Stations 1-5 Experiment #1: 1. Test for H2 gas 2. Test for O2 gas 3. Test for CO2 gas Experiment #2: 4. Reaction of lithium with water 5. Reaction of sodium with water Participants will: Choose a partner Rotate through stations in partners 5 minutes per station Fill in Teacher Worksheets for videos 1 and 2 OR Station Passport: B When hands-on experiments cannot be safely performed. Participants will: Working in small groups discuss answers to the worksheets for videos 1 and 2 Provide group answers to worksheets for discussion and feedback with large group 18 Summarize station activity Fire Safety in the Classroom Highlight student and teacher responsibilities to classroom safety Classroom Safety - Teacher and Student Responsibility ‘Teachers are also responsible for ensuring the safety of students during classroom activities and for encouraging and motivating students to assume responsibility for their own safety and the safety of others. They must also ensure that students acquire the knowledge and skills needed for safe participation in science activities.’ ‘Roles and Responsibilities in the Science Program’: The Ontario Curriculum, Science, Grades 9 and 10 (2008) Highlight that safe practice is related to the Fire Safety Knowledge and Skills set: Knowledge for Handling Flammable and Combustible Substances 1. Type of Flammable and Combustible Materials 2. Quantity of Flammable and Combustible Materials 3. Concentration of Flammable and Combustible Materials Knowledge and Skills for Preparation of Activities 4. Room Readiness Safety equipment Prior activities in classroom 5. Storage and Disposal 6. Classroom Management Assessment of student skill level and readiness Distribution and control of materials in the classroom 7. Choice of Heat Source Suitable flame source Use of hotplate Fire Safety Knowledge and Skills Knowledge for Handling Flammable and Combustible Substances 1. Type of Flammable and Combustible Materials 2. Quantity of Flammable and Combustible Materials 3. Concentration of Flammable and Combustible Materials Fire Safety Knowledge and Skills Knowledge and Skills for Preparation of Activities 4. Room Readiness ― Safety equipment 5. Storage and Disposal 6. Classroom Management ― Assessment of student skill level and readiness 7. Choice of Heat Source ― Suitable flame source Knowledge and Skills for Emergencies 8. Dealing with Unintended Flame Knowledge and Skills for Emergencies 8. Dealing with Unintended Flame - Evacuation plan 19 Remind the participants to use the Fire Triangle when designing their experiments. Ask: Does your school board or school have a Safety Contract? Fire Safety in the Classroom Classroom Safety • Create an atmosphere of safety • Create a safety contract (STAO has one) • Have a system in place from cradle to grave • Do a prelab, lab, postlab format • Deliver just in time instructions • Leave stock bottles in prep room • Keep work areas clean (benches, fume hood) Fire Safety in the Classroom Planning an Activity Consider how the activities relate to the curriculum Use the smallest possible quantity/volume of a chemical Use lower/safer concentrations of reagents Use safer alternative i.e., not flammable or combustible and less toxic Use hot plates instead of open-flame burners Use the minimum reagent temperature (10 fold increase for every 10°C change) Do the labs yourself ahead of time, consult experienced teachers Videos Outline of Videos Each video includes: Intro sequence Specific curriculum expectations addressed List of materials Chemical Equations Safe procedure for preparing and conducting the investigation Summary of Fire Safety Knowledge and Skills considerations Outline of Videos Each Video includes: - Intro Sequence - Specific Curriculum Expectations addressed - List of materials - Chemical equations - Safe procedure for preparing and conducting the investigation - Summary of Fire Safety Knowledge and Skills considerations 20 Videos Highlight different parts of the Video Support materials: - - - Curriculum connections – expectations are clearly outlined and teaching points highlight how instructors can meet curriculum expectations Fire Safety Knowledge and Skills Set -outlines which fire safety knowledge and skills are needed to prepare the classroom for each experiment Safety Points and Materials - summarized to allow for easy preparation Procedure – includes preparatory work, lab work, and clean-up and disposal Student Resource – e.g., Observation Charts in videos 1 and 2 Teacher Worksheets - enabling easy facilitation of PD workshops Debrief: Video Support Materials Curriculum connections - Teaching points outline how instructors can meet curriculum expectations Fire Safety Knowledge and Skills Set -outlines which fire safety knowledge and skills are needed to prepare the classroom Safety Points and Materials: summarized to allow for easy preparation Procedure: includes prep work, lab work, clean up and disposal Student Resource: e.g., Observation charts in Videos 1 and 2 Teacher Worksheets: enabling easy facilitation of PD workshops Debrief: Video Support Materials Student Resource: e.g., Observation Chart for Video 1 Gas Physical Characteristics Description of the Test Positive Test for the Gas Teacher Observation Worksheet for PD 1. What is the flame source shown in the video? ………. 2. Consider the following scenario? ………… 3. … 21 Video Summary Summary – Application of Knowledge to Video 5 – Safely Synthesizing Esters Video 5 – Safely Synthesizing Esters STOP VIDEO BEFORE Fire Safety Knowledge and Skills considerations are displayed at the end of the clip ... Video 6 3. What safety precautions are taken during this activity? Assessment of student skill level and readiness Proper storage of chemicals by category Stock bottles remain in stock room Preparation in stock room Using small quantities Wearing proper eye protection Appropriate heat source for flammables No unintended flame - sand bucket, room readiness Fume hood working Personal Protective Equipment - safety goggles, closed toe shoes, lab coat’, gloves (latex gloves are sufficient for the reagents used in this lab) Availability of eyewash, fire extinguisher, and well ventilated space Safe disposal: -left over acid should be put into inorganic acids and acid salts waste -left over methyl alcohol and salicylic acid should be disposed of in a waste bin for flammable liquids, halogenated solvents and organic acids -the test tubes where the ether was synthesized should be placed in a completely separate container with special labeling, since the sulfuric acid used as a catalyst will be incompatible with the organic waste Summary - Application of Knowledge Video 5 – Safely Synthesizing Esters 1. What safety precautions are taken during this activity? 22 Scientific Investigation Skills This section will demonstrate some of the curriculum linkages of the Fire Safety Resource with reference to a few photocopied pages of the provincial curriculum for the Grade 9 Science Academic course. Curriculum Connections Refer to the Curriculum Handout Strand A describes the Student Investigation Skills (SIS). Strands, B-E/F, describe the major topics or content areas. The curriculum expectations in the content strands incorporate the SIS through abbreviations in square brackets after each specific expectation. These abbreviations link a specific expectation to the applicable broad area of investigation. IP – Initiating and Planning PR – Performing and Recording AI - Analysing and Interpreting C – Communicating Strand A contains expectations describing Scientific Investigation Skills (SIS) Strands B-E/F contain expectations describing major topics or content areas Strand A expectations are to be developed through instruction of the B-E/F strands, by means of hands-on student practice where appropriate (i.e., these skills are not developed in isolation) Curriculum Connections Four Types of SIS/Strand A Expectations IP – Initiating and Planning PR – Performing and Recording AI –Analysing and Interpreting C – Communicating NOTE: “[PR]” indicates that students achieving the specific expectation will have developed skills in performing and recording. Only specific expectations with [PR] appended require students to perform an investigation. Students learn and practice the Strand A skills while conducting investigations in the lab. 23 SIS Pose the Question: What Grade 9 classroom activities could incorporate these SIS/ Performing and Recording [PR] curriculum expectations? Refer to the sample Grade 9 Curriculum Expectations in your participant package. Video 1 – Testing for Gases Discussion Question 1. What Grade 9 classroom activities could incorporate the [PR] expectations to the right? Answers can include: Students are given data about a terrestrial ecosystem and asked to decide, between line, pie and bar graphs, and then are required to use the graphs to interpret and communicate the results to the students in the class Students are asked to organize data in a table during a field trip, laboratory or a homework activity Students are asked to research the properties of the planets, collect the data and organize it in a report that includes tables and diagrams Examples Elaborate on the expectations with [PR] appended. What do Curriculum Expectations in strands B - E/F require for Scientific Investigations? Many of the specific expectations are accompanied by examples which: are meant to clarify the requirements specified in the expectation, illustrating the kind of knowledge or skill ...... are intended as suggestions for teachers rather than as exhaustive or mandatory lists allow teachers to choose ones that are appropriate for their classrooms and courses, or they may develop their own approaches that reflect a similar level of complexity. Only specific expectations with [PR] (under “Developing Skills of Investigation and Communication”) require students to perform an investigation. Many of the specific expectations are accompanied by examples which: are meant to clarify the requirements specified in the expectation, illustrating the kind of knowledge or skill..... are intended as suggestions for teachers rather than as exhaustive or mandatory lists allow teachers to choose ones that are appropriate for their classrooms and courses, or they may develop their own approaches that reflect a similar level of complexity. 24 Evaluation of Workshop Please fill out your workshop evaluation form, in your participant package! THANK-YOU! THANK YOU! 25 26