AOARD Nano- Micro Systems, Mechanics, Materials and Aerospace Program March 29 2007 Dr. Jim C Chang Program Director AFOSR/AOARD Air Force Research Laboratory ECE Department North Carolina State University Where AOARD Fits Air Force Materiel Command Air Force Research Laboratory 3 Technical Directorates International Office Air Force Office of Scientific Research AOARD Detachment 2 EOARD Detachment 1 9 other Technology Directorates AFOSR Within the AF Research Lab HQ AFRL TECHNOLOGY AIR VEHICLES SPACE VEHICLES PROPULSION SENSORS DIRECTED ENERGY DIRECTORATES MATERIALS & MANUFACTURING MUNITIONS HUMAN EFFECTIVENESS INFORMATION AFOSR BASIC RESEARCH IS THE FOUNDATION AFOSR is the Sole Manager of US Air Force Basic Research Funds Challenges Example Transformational Capabilities Long Range Strike Sensor Craft Persistent ISR Cyber Craft Combined Air Operations Center of the Future Reusable Launch Vehicle Rapid Access to Space Strategic Technologies Rapid Decision Management Thermal Management Airborne Laser Cooperative Aerospace Operations Nanoscience & Technology Local Environment NanoSensors (LENS) Integrated-Automated Target Recognition 20 Km Spot Biological Materials & Systems Exploitation AFOSR Research Areas Aerospace and Materials Sciences Physics and Electronics Chemistry and Life Sciences Mathematics and Information Sciences Sub-thrusts • Solid Mechanics and Structures • Materials • Fluid Mechanics • Propulsion • Physics • Electronics • Space Sciences • Chemistry • Info Sciences • Bio Sciences • Mathematics • Human Performance Areas of enhanced emphasis: • • • • • Information Science Computer-Assisted Human Decision-Making Micro UAV Swarms Nanoscience Novel Energy Technology 1999 Nobel Prize in Chemistry: Femtochemistry •1999 Nobel Prize in chemistry •Awarded for development of “femtochemistry” methods to visualize, understand, and predict reactions Prof. Ahmed Zewail Caltech • Funded by AFOSR since 1986 • AFOSR support established initial femtosecond facilities • Allows new insights into reaction mechanisms, the effects of solvation, and HEDM synthesis. 2000 Nobel Prize in Chemistry: Conductive Polymers •2000 Nobel Prize in chemistry •Awarded "for the discovery and development of conductive polymers" 300 fs - Prof. Alan J. Heeger UCSB • Funded by AFOSR since 1989 • AFOSR support branched into other applications of conjugated polymers • Discovery of Ultrafast (300 fs) photoinduced charge transfer led to organic solar cell research and bio-chemical sensor development + Donor Acceptor h e- R O R O R O O R 1Opt. O R Commun. 141, 243 (1997) 2Phys. Rev. B56, 4573 (1997) O R n AFOSR Leadership Roles • Foster Revolutionary Basic Research for Air Force Needs – 728 extramural research grants at 211 universities – 194 intramural research projects at Air Force laboratories – 133 STTR small business - university contracts – 368 transitions to DOD and industry • Build Relationships with Leading Researchers – Here and Abroad – 79 summer faculty; 40 postdocs at AFRL – 264 short-term foreign visitors; 37 personnel exchanges – 58 technical workshops; 205 conferences sponsored – Liaison Offices in Europe and Asia World S&T Investment 1996* to 2004** 2% Asia Share 1996: 26% 2004: 35% 2% EU 28% 38 % <1% 3% * UIS S&T database; World Bank - PPP data 4% 3% 1% 2% 1% 16% Lyons, Mikami 2005, AOARD +78% 2% 33% 2% EU 25% 12% 5% 3% <1% 13% 3% 1% 1% Lyons, Mikami 2006, AOARD ** OECD 2005 PPP; Global S&T Report (Batelle) - PPP data Window-on-Science Visits (WOSs) • AOARD invites prominent Asian Scientists to USAF labs/centers: – Visitor provides a seminar and engages in technical discussions with USAF S&T’s – Official travel expenses are paid by AOARD – Short-term visits to one or more locations Photo courtesy of Mr. William Rieken • Foreign military and civilian government employees may not be eligible, unless they are academicians • AOARD sends out Base Clearance Data -- FDO and Hosting POC • Lead time: At least 60 days before travel start date Conference Support (CSP) • AOARD funds workshops and conferences in Asia to promote scientific interactions: – We provide financial support to Asian conference organizers – AOARD sponsorship must be separate from corporate sponsorship – The support may be for a stand-alone workshop or for an individual session within a large conference • Lead time: As early as possible AOARD, 2006 R & D Contracts/Grants (R&D) • AOARD funds small research proposals submitted in response to AFOSR Broad Area Announcement (BAA) and USAF interests: – USAF S&Ts evaluate the proposals – The Proposer’s Guide is on the AFOSR web page through AOARD web page http://www.tokyo.afosr.af.mil AOARD, 2006 • Follow-on contracts are cost-shared by other USAF organization • AOARD administers larger contracts on behalf of AFOSR and AFRL • Lead time: Usually 60-90 days to complete the process (White paper → Proposal → Evaluation → Contract) AOARD Program Activities FY-06 WOS CSP R&D TOTAL KOREA 30 11 16 57 JAPAN 16 15 16 47 AUSTRALIA 16 5 18 39 TAIWAN 9 3 14 26 INDIA 8 8 10 26 SINGAPORE 4 5 7 16 CHINA 3 2 0 5 MALAYSIA 3 2 0 5 THAILAND 0 2 1 3 VIETNAM 2 1 0 3 NEW ZEALAND 1 0 1 2 INDONESIA 0 1 0 1 COUNTRY PROGRAM GOALS • Seek and Cultivate • Teaming and Leverage • Harvest and Discovery OVERVIEW TOPICS • Power and Energy • Intelligent Structures/Systems for Aerospace Systems • Multi-Scale and Interfaces for “Materials-byDesign” • AFOSR/Taiwan Nanotechnology Initiative BEST RESEARCH – CELL EFFICIENCIES 36 Spectrolab Multijunction Concentrators Three-junction (2-terminal, monolithic) Two-junction (2-terminal, monolithic) Crystalline Si Cells Single crystal Multicrystalline Thin Si Thin Film Technologies Cu(In,Ga)Se2 CdTe Spire Amorphous Si:H (stabilized) Emerging PV Westing- ARCO Dye cells house Organic cells 32 28 Efficiency (%) 24 20 16 Spectrolab Japan Energy NREL 12 8 Monosolar Kodak Boeing 4 RCA 0 1975 Georgia Tech UNSWNREL NREL NREL Euro-CIS Boeing University RCA of Maine RCA RCA RCA RCA 1980 Boeing AstroPower RCA Solarex UCSB 1990 AstroPower 2011 Goal: 15 % NREL AIST Princeton University Linz University of Lausanne 1985 NREL University of Lausanne United Solar Photon Energy Kodak NREL NREL United Solar AMETEK Masushita UNSW NREL Cu(In,Ga)Se2 14x concentration Georgia Tech Sharp ARCO Boeing Solarex UNSW UNSW University So. Florida State University Kodak UNSW UNSW Varian (various technologies)No. Carolina Boeing NREL Spire Stanford NREL/ Spectrolab 1995 Cambridge 2000 Siemens 2011 Goal: 10 % (Dr. Jenekhe) ECN, The Netherlands UC Berkeley 2005 Taken from a presentation by Baldwin “Energy Efficiency and Renewable Energy; Energy: A 21st Century Perspective; National Academy of Engineering; June 2, 2005” 2010 POWER AND ENERGY Bio-Inspired Light Harvesting Research Prof. Mamoru Nango, Nagoya Institute of Technology, Japan • Starting with a One-year AOARD Seed Grant - 2006 • AFOSR MURI: Energy Harvesting and Storage Systems and their Integration to Aero Vehicles • Team Members: UW, UCLA, UC, AFRL/VA, AFRL/ML, AOARD • Technical Effort Energy Harvesting - Mechanical & Solar ・Solar Cell - Low Cost & Efficient ・Polymeric: 3% to 10% ・Bio-Inspired Design: 8% to 15% (Prof. Nango + 40 people team through AOARD) POWER AND ENERGY BIO-INSPIRED LIGHT HARVESTING RESEARCH Scientific Approach ・Mimic biosystem photosynthesis “structure”, “function”, “process” ・New Energy & Industrial Technology Development Organization, Japan, UK, USA Accomplishment 1. X-ray crystal structure identification of LH1-RC and LH2 O N N Mg N LH2 LH1-RC N O COOCH3 O O Absorption 3 Bacteriochlorophyll a (BChl a) OCH3 OCH3 Carotenoid POWER AND ENERGY BIO-INSPIRED LIGHT HARVESTING RESEARCH 2. Reconstitute LH1-RC (photosynthetic proteins) on electrode using bio-selfassembly RC or LH-RC MV++ Au electrode h e- Zn RC or LH/RC complex Photocurrent on electrode e- e- Zn e- Photocurrent on electrode e- S S S Au ITO electrode Glass substrate Rb.sphaeroides LH1-b SH ADKSDLGYTGLTDEQAQELHS VYMSGLWLFSAVAIVAHLAVYIW RPWF VYMSGLWLFSAVAIVAHLAVYIW RPWFGGC N-terminal hydrophobic core C-terminal 3. Stabilized APS(3-aminopropylsilane)-ITO POWER AND ENERGY BIO-INSPIRED LIGHT HARVESTING RESEARCH 4. Synthesized LH1 polypeptide/pigments complex for broadband (UV to IR) absorption for device efficiency and stability Normalized absorbance 1.2 Spheroidene isolated from Rb. sphaeroides (Left) Spirilloxanthin isolated from Rs. rubrum (Right) 1 no carotenoid with spirilloxanthin with spheroidene 870 880 0.8 0.6 469 513 0.4 0.2 0 300 400 500 600 700 800 Wavelength (nm) 900 1000 • Future plan Develop nano-TiO2 electrode and device model for functionalized LH1-RC & LH2 to increase performance & stability FINITE ELEMENT APPROACH USING ATOMS Atoms move to the minimum-energy position Arbitrary two atoms ’i’ and ’j’ are regarded as two nodes, and their potential as one element Element Shape Function Formation Advantages of Our Approach Computationally efficient Reflects physical reality Conducive for the observation of deformation mechanisms FINITE ELEMENT APPROACH USING ATOMS Nanomechanics and Nanoplasticity Strain Gradient Distributions at Three Different Indentation Depths Jeng et al., Applied Physics Letters, 2006 Mechanical Characteristics of Nanotube Junctions Physical Review B, 2006 NANO-SMA/SMP FOR COMPOSITES Impurity-Free High-Performance SMA and SMP Gas-atomization-produced Nickel-Titanium SMA powders Electro-dissolving SMA Fiber NEW AND IMPROVED MATRIX PROPERTIES MORPHING AND SHAPE CONTROL FOR PERFORMANCE Recent Results • Taiwan/Korea Nano-Science Initiatives: Leveraging Asia’s $1.5 billion nanotechnology investment • National Central University, Taiwan: ROCSAT: Studying low-latitude ionospheric scintillations - communication/navigation outage forecasting • Tohoku University, Japan: Tackling Hurdles in Micro-turbine Research: lunch-boxsize 100 watt power source, 10 mm rotor, 1 million rpm bearing • Univ. of Queensland, Brisbane, Australia: Gaining access to HyShot flight data from world’s 1st in-flight scramjet combustor test (Mach 7.5) • Cooperative Operation of UAVs: Australian Center for Field Robotics (ACFR): Multiobjective control laws & cooperative airborne inertial - SLAM Photo courtesy of Dr. Sukkarieh Photo courtesy of Dr. Isomura Photo Courtesy of Dr. Allan Paull