All data is due to Water’s Senior Chemist (via the Database supervisor) by March 31 st. Before beginning the CCR, ensure that all relevant data is in released (or possibly rejected) status. This includes: o Inorganics and Organics batches with data from the City plants and the Distribution system o Outside data including UCMR data (make sure that outside data has been entered in the database…it sometimes gets missed) o Field data (Field_data table)and all Field_Analyses data (Result table) Getting Started Guidance Manual---Search the internet for CDPH CCR. This instruction is not specific as to the location of this guidance manual, as CDPH (California Department of Public Health) periodically updates their website, resulting in changes to the url. This query should return a title like ‘Consumer Confidence Reports –California Department of Public Health’. Once you’re in their website, choose the link to CCR Guidance for Water Suppliers. Its title is : “Preparing Your CALIFORNIA Drinking Water Consumer Confidence Report (CCR) Guidance for Water Suppliers January (?), YYYY update” Print out the document in color, as all changes made from the previous year will be highlighted in yellow. Read through the guidance manual and mark any sections about which you have a question. Clarify your questions before beginning the report. Note: Many of the instructions in the guidance manual are for the PIOs (Public Information Officers) who prepare the final report. The job of the laboratory is to provide the PIOs with the relevant data for this report. Have the following references on hand: 1. MCLs, DLRs, and PHGs for Regulated Drinking Water Contaminants (found on the CDPH website) 2. OEHHA PHG list (found at http://www.oehha.org/water/phg/allphgs.html). 3. California’s Detection Limits for Purposes of Reporting (DLRs)---look at Appendix B in your CCR Guidance Manual for this document’s url. 4. Some City of San Diego CCRs from years past (for reference). 5. Hard copies of the water lab’s monthly reports from past years. See examples of these documents at the end of this document. Preparing the Report Go to y:\emts\41.sections\wql\reports\state\ccr\ReportOutputs\YYYY (previous year) and open the file for Table 1 (named something like ccr_2013_cst_data_tables1_and_6.xls). Change the year within the file and then save it in the correct folder with the appropriate year in the name. Table 1. A lot of the data in Table 1 corresponds to the instructions in Appendix A-1. Therefore, before you begin, make sure to check through Appendix A-1 to see if there have been any changes made (highlighted in yellow). If you see any changes, ensure that the XR_ANALYTE table in the database reflects those changes before beginning. Table 1 contains Detected Regulated CCR contaminants with Primary MCLs (or MRDLs, TTs or ALs). The exception is that Disinfection Byproducts, Residuals and Byproduct Precursors go into Table 4. Table 1 is divided into 5 sections: 1. 2. 3. 4. 5. Chemical Contaminants Radioactive Contaminants Microbiological Contaminants Turbidity At the Tap Contaminants (Lead and Copper) Table 1, Section 1---To help identify the chemicals which may go into Table 1, Section 1, run the following command file: Y:\emts\41.sections\wql\reports\state\ccr\table1_primary_mcl_greater_than_dlr.cmd Respond to the prompts by putting in the report name, the date span and the year. A report will run which will return results such as (see example below). Analytes with Primary MCLs with values >= DLR Between 01-JAN-2013 and 31-DEC-2013 Analytes in this report may not belong in a section of Table1 - verify the source and data through the Result table Analyte , Name ,REPORT_GROUPING --------------------------------------------------,-------------------Fluoride ,Inorganic_Constit Fluoride values above the state DLR, both from plant influents(untreated) and plant effluents (treated) were found in the 2013 data from the database. Therefore, Fluoride values belong in Table 1, Section1. Run either Adhoc reports or view the LIMS Result Table for each treatment plant, influents and effluents (Alvarado, Miramar, and Otay). Obtain both the averages and ranges of Fluoride data for the year. View a previous year’s report for examples. Table1 Section2---To identify the radiologicals and the values which go into Section 2, run the following command file: Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table1_radioactive.cmd Respond to the prompts by putting in the report name, the date span(the last 3 years) and the year. A report will run which will return results such as (see example below). Radiologicals >= DLR Between 01-JAN-2011 and 31-DEC-2013 Source,SAMPLE_ID ,SAMPLE_DA,Analyte ,QU, Value, DLR ------,----------,---------,---------,--,-------,-----3 SYS ,W881820 ,03-OCT-12,RAD_ALPHA, , 2.61, 3.00 3 SYS ,W881819 ,03-OCT-12,RAD_BETA , , .38, 4.00 3 SYS ,W881821 ,03-OCT-12,URANIUM , , 1.70, 1.00 87 SYS,W812352 ,27-JUL-11,RAD_ALPHA, , 2.57, 3.00 87 SYS,W881824 ,03-OCT-12,RAD_ALPHA, , 3.29, 3.00 87 SYS,W944075 ,16-OCT-13,RAD_ALPHA, , 4.55, 3.00 87 SYS,W881822 ,03-OCT-12,RAD_BETA , , .91, 4.00 87 SYS,W812351 ,27-JUL-11,URANIUM , , 1.60, 1.00 87 SYS,W881823 ,03-OCT-12,URANIUM , , 1.90, 1.00 87 SYS,W944074 ,16-OCT-13,URANIUM , , 2.40, 1.00 95 SYS,W881826 ,03-OCT-12,RAD_ALPHA, , 1.52, 3.00 95 SYS,W881825 ,03-OCT-12,RAD_BETA , , 2.03, 4.00 95 SYS,W881827 ,03-OCT-12,URANIUM , , 1.20, 1.00 Report all analytes for each plant. Use data from the most recent year available. (With the exception of Alvarado, which requires analysis of Alpha and Uranium data each year, regulations require Water to collect radiological data every 3 years). Table 1 Section 3 (Microbiological Contaminants)-This section includes Total Coliform Bacteria and Fecal Coliform and E. coli per Appendix A-1 of the Guidance for Water Suppliers. It is usually necessary to report only on Total Coliform on the CCR because there are generally no positives for Fecal Coliform or E. coli from San Diego drinking water. To determine the values entered in this section, go through each of the monthly complete reports from the year in question and locate the report labeled “MONTHLY SUMMARY OF DISTRIBUTION SYSTEM COLIFORM MONITORING” To determine the Total Coliform average(in percentage), sum the number of Coliform Positives (from all 12 months) and divide by the sum of the Number Collected (from all 12 months). Multiply this value by 100. To determine the Total Coliform range(in percentage), Each month, divide the number of Coliform Positives for that month by the Number Collected for that month and multiply by 100. This will give you 12 values. The range is the lowest percentage to the highest percentage. Table 1 Section 4 (Turbidity) To determine the values entered in this section, go through each of the monthly complete reports from the year in question and locate the reports from each of the treatment plants with Turbidity data for finished water. For Miramar the report is named “Miramar Finished Water, Daily Turbidity – 15 Minutes, Values in NTU” For Alvarado the report is named “Alvarado Finished Water—Filters 1 Through 8 (and/or 9 through 16) For Otay the report is named “Otay Water Treatment Plant, Daily Turbidity – 15 Minutes, Values in NTU” Determine 2 things for each plant: 1. If there were any samples with turbidity >0.3 NTU. 2. The maximum turbidity value for the year. Report these values in Table 1. Table 1 Section 5 (Lead and Copper Rule) The Lead and Copper Rule studies are conducted by the City of San Diego Water Laboratory every 3 years (2011, 2014, 2017, etc.). Obtain the data for this section from the Lead & Copper Rule report. It will be located at Y:\EMTS\32.Reports\Water\State\PbCuRule. Put the values into Table 1. Table 1 Section 1--- Scripts/Command Files Below is the text for the command file for Table 1, Section 1: REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table1_primary_mcl_greater_than_dlr.cmd set /p rpt_name=PLEASE TYPE THE REPORT NAME: set /p beg_date=PLEASE ENTER THE BEGINNING DATE (format DD-MON-YYYY): set /p end_date=PLEASE ENTER THE ENDING DATE (format DD-MON-YYYY): set /p year=PLEASE ENTER THE YEAR FROM WHICH DATA IS BEING REPORTED (format YYYY): sqlplus.exe REPORT/REPORT@WPL @Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\Scripts\table1_primary_mcl_greater_than_dlr.sql %rpt_name%.TXT %beg_date% %end_date% %year% Below is the text for the script for Table 1, Section 1 REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\Scripts\table1_primary_mcl_greater_than_dlr.sql define report_name=&1 define beg_date=&2 define end_date=&3 define year=&4 set echo off SET VERIFY OFF set feedback off set colsep , SET LINESIZE 250 set pagesize 1000 TTITLE LEFT 'Analytes with Primary MCLs with values >= DLR Between &beg_date and &end_date' REPHEADER LEFT 'Analytes not belong in Table1 - verify source and data thru Result table' spool Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\&report_name set linesize 100 COLUMN ANALYTE_NAME HEADING 'Analyte|Name' FORMAT A50 COLUMN ANALYTE HEADING 'Analyte' FORMAT A15 SELECT DISTINCT ANALYTE_NAME,REPORT_GROUPING FROM XR_ANALYTE WHERE REPORT_GROUPING NOT IN('Do_not_report','Radiological') AND ANALYTE NOT IN (SELECT ANALYTE FROM XR_ANALYTE WHERE REPORT_GROUPING2='DBP') and MCL IS NOT NULL AND ANALYTE IN (SELECT DISTINCT ANALYTE FROM RESULT WHERE TEST_TYPE='SAMP' AND VALUE>=DLR AND REPORTABLE=1 AND MCL IS NOT NULL AND SAMPLE_ID IN (SELECT SAMPLE_ID FROM SAMPLE WHERE SAMPLE_DATE BETWEEN '&beg_date' and '&end_date' AND SOURCE IN ('3 SYS','5 SYS','6 SYS','87 SYS','95 SYS'))) AND ANALYTE NOT IN (SELECT DISTINCT ANALYTE FROM RESULT WHERE BATCH_ID IN (SELECT BATCH_ID FROM BATCH WHERE LAB_GROUP IN ('MICROBIOLOGY','WATERSHED','RESERVOIR MGNMT'))); SPOOL OFF HOST C:\PROGRAM FILES\MICROSOFT OFFICE\OFFICE12\WINWORD.EXE Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\&report_name Table 1 Section 2--- Scripts/Command Files Below is the text for the command file for Table 1, Section 2: REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table1_radioactive.cmd set /p rpt_name=PLEASE TYPE THE REPORT NAME: set /p beg_date=PLEASE ENTER THE BEGINNING DATE (format DD-MON-YYYY): set /p end_date=PLEASE ENTER THE ENDING DATE (format DD-MON-YYYY): set /p year=PLEASE ENTER THE YEAR FROM WHICH DATA IS BEING REPORTED (format YYYY): sqlplus.exe wpl/bug@wpltst @Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\Scripts\table1_radioactive.sql %rpt_name%.TXT %beg_date% %end_date% %year% Below is the text for the script for Table 1, Section 2 REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\Scripts\table1_RADIOACTIVE.sql define report_name=&1 define beg_date=&2 define end_date=&3 define year=&4 set echo off SET VERIFY OFF set feedback off set colsep , SET LINESIZE 250 set pagesize 1000 TTITLE LEFT 'Radiologicals >= DLR Between &beg_date and &end_date' spool Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\&report_name set linesize 100 COLUMN QUALIFIER HEADING 'QU' FORMAT A2 COLUMN ANALYTE HEADING 'Analyte' FORMAT A9 COLUMN SOURCE HEADING 'Source' FORMAT A6 COLUMN VALUE HEADING 'Value' FORMAT 999.99 COLUMN DLR HEADING 'DLR' FORMAT 99.99 SELECT DISTINCT S.SOURCE,R.SAMPLE_ID,S.SAMPLE_DATE,R.ANALYTE,R.QUALIFIER,R.VALUE,R.DLR FROM RESULT R, SAMPLE S WHERE SOURCE IN ('3 SYS','87 SYS','95 SYS') AND S.SAMPLE_DATE BETWEEN '&BEG_DATE' AND '&END_DATE' AND TEST_TYPE='SAMP' AND REPORTABLE=1 and ANALYTE IN (SELECT ANALYTE FROM XR_ANALYTE WHERE REPORT_GROUPING='Radiological') AND S.SAMPLE_ID=R.SAMPLE_ID ORDER BY SOURCE,ANALYTE,SAMPLE_DATE; SPOOL OFF HOST c:\PROGRAM FILES\MICROSOFT OFFICE\OFFICE12\WINWORD.EXE Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\&report_name EXIT; Table 2 – Detected Regulated Contaminants with Secondary MCLs The data in Table 2 corresponds to the instructions in Appendix A-2. Therefore, before you begin, make sure to check through Appendix A-2 to see if there have been any changes made (highlighted in yellow). If you see any changes, ensure that the XR_ANALYTE table in the database reflects those changes before beginning. Go to y:\emts\41.sections\wql\reports\state\ccr\ReportOutputs\YYYY (previous year) and open the file for Table 2 (named something like ccr_2013_cst_data_table_2_4.xls). Change the year within the file and then save it in the correct folder with the appropriate year in the name. To help identify the chemicals which may go into Section 2, run the following command file: Y:\emts\41.sections\wql\reports\state\ccr\table2.cmd Respond to the prompts by putting in the report name, the date span and the year. A report will run which will return results such as (see example below). Table2 Detected Regulated chems with 2ndary MCLs between 01-JAN-2013 and 31-DEC-2013 Analyte --------------ALUMINUM SULFATE TDS COLOR CHLORIDE MANGANESE TON IRON TURBIDITY COPPER ========================================================================== Go through the above list and determine, one line at a time, whether or not the listed analytes belong in Table 2. Some analytes with SMCLs have DLRs; some do not. Analytes with DLRs are reported here only if the detected values are >= the DLR. If there is no DLR, report the analyte if it is above the MDL. Both Turbidity and Copper are reported elsewhere (Turbidity and Copper are both reported in Table 1).For TONs, I recommend going directly into the result table and pulling up the results for the year one plant at a time. This is because “not detecteds” are reported as <1 and the adhoc report does not average them properly.For the remaining analytes in the list, determine the range and average on reportable values for each plant effluent. Sample adhocs are included below. Report Selection Criteria Analyte IN ('ALUMINUM') Reportable(1/0) = 1 Sample Date BETWEEN '01-Jan-2013' AND '31-Dec-2013' Source IN ('95 SYS') Test Type IN ('SAMP') Output Specification Analyte name Note that the Max Value in the top row is Analysis 7.62. Since the value is less than the DLR, smcl this is considered “nd” for CCR purposes. Avg Units Avg MDL Min Qualifier Min Value Avg Value Max Value DLR Analyte name Aluminum (Al) Aluminum (Al) Avg Units Avg MDL ICPMS 200 UG/L 5 ICPMS_DIG 200 UG/L Analysis smcl Min Qual 15 ND Min Avg Value Value 0 0.953 Max Value DLR 7.62 50 50 Report Selection Criteria Analyte IN ('COLOR') Reportable(1/0) = 1 Sample Date BETWEEN '01-Jan-2013' AND '31-Dec-2013' Source IN ('95 SYS') Test Type IN ('SAMP') Output Specification Analyte name Since the Max Value is above the MDL (1) Analysis and there is no DLR, this data will be smcl included in Table 2. Avg Units Avg MDL Min Qualifier Min Value Avg Value Max Value DLR Analyte name Color, Apparent (Unfiltered) Analysis smcl COLOR Avg Units 15 COLOR Avg MDL 1 Min Qual Min Avg Max Value Value Value DLR 0 0.833 2 After determining the ranges and averages, enter the values into Table 2 in the CCR report. Below is the text for the command file for Table 2 REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table2.cmd REM Run by clicking on Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table2.cmd REM This script is provided as a hard copy in case the e-copy is lost or corrupted. set /p rpt_name=PLEASE TYPE THE REPORT NAME: set /p beg_date=PLEASE ENTER THE BEGINNING DATE (format DD-MON-YYYY): set /p end_date=PLEASE ENTER THE ENDING DATE (format DD-MON-YYYY): set /p year=PLEASE ENTER THE YEAR FROM WHICH THE DATA IS BEING REPORTED (format YYYY): sqlplus.exe REPORT/REPORT@WPL @Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\Scripts\table2.sql %rpt_name%.TXT %beg_date% %end_date% %year% Below is the text for the script for Table 2 REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\Scripts\table2.sql REM Run this report by clicking on Y:\EMTS\41.Sections\WQL\Reports\State\CCR\scripts\table2.cmd REM This script is provided as a hard copy in case the e-copy is lost or corrupted. define report_name=&1 define beg_date=&2 define end_date=&3 define year=&4 set echo off SET VERIFY OFF set feedback off set colsep , SET LINESIZE 250 set pagesize 1000 TTITLE LEFT 'Table2 Detected RegulaTed chems with 2ndary MCLs between &beg_date and &end_date' REM REPHEADER LEFT 'All ccr analytes ordered by analyte_name' spool Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\PreliminaryReports\&report_name set linesize 100 COLUMN ANALYTE_NAME HEADING 'Analyte|Name' FORMAT A50 COLUMN ANALYTE HEADING 'Analyte' FORMAT A15 REM COLUMN REPORT_GROUPING HEADING 'Report|Grouping' FORMAT A20 SELECT DISTINCT analyte from result WHERE ANALYTE IN (SELECT DISTINCT ANALYTE FROM XR_ANALYTE WHERE SMCL IS NOT NULL) AND TEST_TYPE='SAMP' AND VALUE IS NOT NULL AND VALUE>=MDL AND REPORTABLE=1 AND sample_id in (select sample_id from sample where sample_date between '&beg_date' and '&end_date' and source in ('3 SYS','5 SYS','6 SYS','87 SYS','95 SYS')); SPOOL OFF HOST c:\PROGRAM FILES\MICROSOFT OFFICE\OFFICE12\WINWORD.EXE Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\PreliminaryReports\&report_name Table 3 Table 3 contains Detected Unregulated Contaminants Requiring Monitoring. This includes chemicals listed in Appendices A-3 and A-4 of the Guidance Manual. Section A – Table3, Section A Run the command file: Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table3A.cmd Below is an example of the results from the above script: Table3A Unregulated Contaminants between 01-JAN-2013 and 31-DEC-2013 PROJECT Analyte -----------BORON BORON BORON BORON BORON BORON BORON BORON BORON BORON BORON BORON BORON BORON CHROMIUM_VI CHROMIUM_VI CHROMIUM_VI CHROMIUM_VI CHROMIUM_VI VANADIUM VANADIUM ANALYSIS --------------ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG ICPMS_DIG EPA218.7_UCMR EPA218.7_UCMR EPA218.7_UCMR EPA218.7_UCMR EPA218.7_UCMR ICPMS_UCMR ICPMS_UCMR Source ------5 SYS 5 SYS 5 SYS 5 SYS 5 SYS 5 SYS 87 SYS 87 SYS 87 SYS 95 SYS 95 SYS 95 SYS 95 SYS 95 SYS 3 SYS 3 SYS 87 SYS 87 SYS 95 SYS 3 SYS 87 SYS ID ------PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS PLANTS UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR LIMS Value DLR DLR ------- ------- ---------106 100 100 110 100 100 114 100 100 116 100 100 117 100 100 119 100 100 89.8 100 100 90.9 100 100 120 100 100 118 100 100 120 100 100 122 100 100 123 100 100 130 100 100 0.03 0.03 1 0.17 0.03 1 0.09 0.03 1 0.11 0.03 1 0.09 0.03 1 0.21 0.2 3 0.25 0.2 3 From the data above, only Boron goes into Table 3, Section A (corresponds to A-3 in the CCR instruction manual) . In the case of Chromium_VI and Vanadium, the PROJECT ID is UCMR3, so this data goes into Table 3, Section B. Table 3 Table 3 contains Detected Unregulated Contaminants Requiring Monitoring. This includes chemicals listed in Appendices A-3 and A-4 of the Guidance Manual. Section B – Table3, Section B Plants contains UCMR Plants data Run the command file: Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table3B_PLANTS.cmd Below is an example of the results from the above script: Table3B UCMR3 Contaminants from Plants SAMPLE DATE Analyte Source ---------------------------21-Aug-13 BRCLMETHANE 95 SYS 20-Aug-13 CHLORATE 3 SYS 21-Aug-13 CHLORATE 95 SYS 13-Nov-13 CHLORATE 95 SYS 20-Aug-13 CHROMIUM_VI 3 SYS 12-Nov-13 CHROMIUM_VI 3 SYS 19-Aug-13 CHROMIUM_VI 87 SYS 12-Nov-13 CHROMIUM_VI 87 SYS 21-Aug-13 CHROMIUM_VI 95 SYS 20-Aug-13 MOLYBDENUM 3 SYS 12-Nov-13 MOLYBDENUM 3 SYS 19-Aug-13 MOLYBDENUM 87 SYS 12-Nov-13 MOLYBDENUM 87 SYS 21-Aug-13 MOLYBDENUM 95 SYS 13-Nov-13 MOLYBDENUM 95 SYS 20-Aug-13 STRONTIUM 3 SYS 12-Nov-13 STRONTIUM 3 SYS 19-Aug-13 STRONTIUM 87 SYS 12-Nov-13 STRONTIUM 87 SYS 21-Aug-13 STRONTIUM 95 SYS 13-Nov-13 STRONTIUM 95 SYS 20-Aug-13 VANADIUM 3 SYS 12-Nov-13 VANADIUM 3 SYS 12-Nov-13 VANADIUM 87 SYS PROJECT ID ------UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 UCMR3 Value ------0.07 25 200 140 0.17 0.03 0.09 0.11 0.09 3.4 3.9 3.2 3.4 3.3 2.8 750 790 560 550 660 510 0.21 0.21 0.25 UCMR DLR ------0.06 20 20 20 0.03 0.03 0.03 0.03 0.03 1 1 1 1 1 1 0.3 0.3 0.3 0.3 0.3 0.3 0.2 0.2 0.2 Include all of the analytes from the above table in Table 3, Section B Plants section. Note: UCMR studies occur every 5 years (UCMR4 will probably occur in 2018). UCMR data must be included in the CCR for 5 years. Therefore, no date span is included in the script. It searches for data with the project_id UCMR3. This will need to be changed when the next study takes place. Table 3A – Command File and Script Command File --- Table 3A REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table3.cmd REM Run by clicking on Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table3.cmd REM This script is provided as a hard copy in case the e-copy is lost or corrupted. set /p rpt_name=PLEASE TYPE THE REPORT NAME: set /p beg_date=PLEASE ENTER THE BEGINNING DATE (format DD-MON-YYYY): set /p end_date=PLEASE ENTER THE ENDING DATE (format DD-MON-YYYY): set /p year=PLEASE ENTER THE YEAR FROM WHICH THE DATA IS BEING REPORTED (format YYYY): sqlplus.exe wpl/bug@WPLTST @Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\Scripts\table3A.sql %rpt_name%.CSV %beg_date% %end_date% %year% Script --- Table 3A REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\Scripts\table3.sql REM Run this report by clicking on Y:\EMTS\41.Sections\WQL\Reports\State\CCR\scripts\table3.cmd REM This script is provided as a hard copy in case the e-copy is lost or corrupted. define report_name=&1 define beg_date=&2 define end_date=&3 define year=&4 set echo off SET VERIFY OFF set feedback off set colsep , SET LINESIZE 250 set pagesize 1000 TTITLE LEFT 'Table3A Unregulated Contaminants between &beg_date and &end_date' REM REPHEADER LEFT 'All ccr analytes ordered by analyte_name' REM spool Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\PreliminaryReports\&report_name spool h:\&report_name set linesize 100 COLUMN dlr HEADING 'UCMR|DLR' FORMAT 999.99 COLUMN ANALYTE HEADING 'Analyte' FORMAT A12 COLUMN VALUE HEADING 'Value' FORMAT 999.99 COLUMN SOURCE HEADING 'Source' FORMAT A7 COLUMN PROJECT_ID HEADING 'PROJECT|ID' FORMAT A7 SELECT DISTINCT r.analyte,b.analysis,S.SOURCE,S.PROJECT_ID,R.VALUE,r.dlr ,xa.dlr AS "LIMS DLR" from result r, xr_analyte xa, sample s, batch b WHERE TEST_TYPE='SAMP' AND REPORTABLE=1 AND R.ANALYTE IN ('BORON','CHROMIUM_VI','2CL2FLMETHANE','ETBE','TAME','T_BUTYL_ALCOHOL','123_3CLPROPANE','VANADIUM') AND VALUE>=MDL AND R.SAMPLE_ID IN (SELECT SAMPLE_ID FROM SAMPLE WHERE SAMPLE_DATE BETWEEN '&BEG_DATE' AND '&END_DATE' AND SOURCE IN ('3 SYS','5 SYS','87 SYS','95 SYS')) and xa.analyte=r.analyte and s.sample_id=r.sample_id and r.batch_id=b.batch_id ORDER BY ANALYTE; Table 3B – Command File and Script Command File --- Table 3B REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table3.cmd REM Run by clicking on Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\table3.cmd REM This script is provided as a hard copy in case the e-copy is lost or corrupted. set /p rpt_name=PLEASE TYPE THE REPORT NAME: set /p beg_date=PLEASE ENTER THE BEGINNING DATE (format DD-MON-YYYY): set /p end_date=PLEASE ENTER THE ENDING DATE (format DD-MON-YYYY): set /p year=PLEASE ENTER THE YEAR FROM WHICH THE DATA IS BEING REPORTED (format YYYY): sqlplus.exe wpl/bug@WPLTST @Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\Scripts\table3B.sql %rpt_name%.TXT %beg_date% %end_date% %year% Script --- Table 3B REM Y:\EMTS\41.Sections\WQL\Reports\State\CCR\Scripts\table3.sql REM Run this report by clicking on Y:\EMTS\41.Sections\WQL\Reports\State\CCR\scripts\table3.cmd REM This script is provided as a hard copy in case the e-copy is lost or corrupted. define report_name=&1 define beg_date=&2 define end_date=&3 define year=&4 set echo off SET VERIFY OFF set feedback off set colsep , SET LINESIZE 250 set pagesize 1000 TTITLE LEFT 'Table3B Unregulated Contaminants between &beg_date and &end_date' REM REPHEADER LEFT 'All ccr analytes ordered by analyte_name' REM spool Y:\EMTS\41.SECTIONS\WQL\Reports\state\ccr\ReportOutputs\&year\PreliminaryReports\&report_name spool h:\&report_name set linesize 100 COLUMN dlr HEADING 'UCMR|DLR' FORMAT 999.99 COLUMN ANALYTE HEADING 'Analyte' FORMAT A12 COLUMN VALUE HEADING 'Value' FORMAT 999.99 COLUMN SOURCE HEADING 'Source' FORMAT A7 COLUMN PROJECT_ID HEADING 'PROJECT|ID' FORMAT A7 SELECT DISTINCT S.SAMPLE_DATE,r.analyte,S.SOURCE,S.PROJECT_ID,R.VALUE,xa.dlr from result r, xr_analyte xa, sample s WHERE TEST_TYPE='SAMP' AND REPORTABLE=1 AND VALUE>=MDL AND PROJECT_ID='UCMR3' and xa.analyte=r.analyte and s.sample_id=r.sample_id ORDER BY S.SAMPLE_DATE,S.SOURCE; SPOOL OFF HOST c:\PROGRAM FILES\MICROSOFT OFFICE\OFFICE12\EXCEL.EXE H:\&report_name exit; Table 4 Table 4 contains Disinfection By-Products, Disinfectant Residual (chloramines) and Disinfectant Precursors (TOC). This table does not correspond to Appendix A-3. See note below. Note: The contaminants in this section are listed in the back of Appendix A-1. Although they all have MCLs or MRDLs (normally go into Table 1), they are reported in Table 4. Section A – Table4, Section A contains disinfection by-products and disinfectant precursors from Plant Effluent data. 1. Bromate is the first chemical in Table 4, Section A. Bromate is a disinfection by-product found at the Alvarado and Miramar Treatment Plants. Below is an example of a Bromate adhoc report output run on the Alvarado Treatment Plant for 2013 data. Report Selection Criteria Analyte IN ('BROMATE') Reportable(1/0) = 1 Sample Date BETWEEN '01-Jan-2013' AND '31-Dec-2013' Source IN ('87 SYS') Test Type IN ('SAMP') Output Specification Analyte name Avg Units Avg MDL Min Qualifier Min Value Avg Value Max Value DLR Analyte Avg name Units Bromate UG/L Avg MDL Min Qualifier 5 Min Value Avg Max Value Value DLR 0 0.147 7.04 5 2. Chlorate is the second chemical in Table 4, Section A. Chlorate is a disinfection by-product found at the Otay Treatment Plant. Below is an example of a Chlorate report output (and parameters) run on the Otay Treatment Plant for 2013 data. Report Selection Criteria Analyte IN ('CHLORATE') Reportable(1/0) = 1 Sample Date BETWEEN '01-Jan-2013' AND '31-Dec2013' Source IN ('95 SYS') Test Type IN ('SAMP') Output Specification Analyte name Avg Units Avg MDL Min Qualifier Min Value Avg Value Max Value DLR Analyte name Chlorate Avg Units UG/L Avg MDL Min Qualifier 20 Min Avg Max Value Value Value DLR 63.1 135 239 20 3. Chlorite is the third chemical in Table 4, Section A. Chlorite is a disinfection by-product found at the Otay Treatment Plant. Below is an example of a Chlorite report output (and parameters) run on the Otay Treatment Plant for 2013 data. Report Selection Criteria Analyte IN ('CHLORITE') Sample Date BETWEEN '01-Jan-2012' AND '31-Dec-2012' Source IN ('95 SYS') Test Type IN ('SAMP') Report Data Number of result records queried: 430 Number of summary records found: 1 Max Source Avg Value Min Value Value 95 SYS 320 0 464 The data is reported on the CCR in ppm, but it is reported in the database as ppb, so results must be divided by 1000 . 4. TOC is the last chemical in Table 4, Section A. The min, max and average is reported from all three plant effluents. See example below. Report Selection Criteria Analyte IN ('TOC') Sample Date BETWEEN '01-Jan-2012' AND '31-Dec-2012' Source IN ('95 SYS','3 SYS','87 SYS') Test Type IN ('SAMP') Output Specification Source Avg Value Min Value Max Value Report Data Max Source Avg Value Min Value Value 3 SYS 2.25 1.88 2.64 87 SYS 2.79 1.96 6.28 95 SYS 4.27 3.11 5.47 Section B – Table4, Section B contains disinfection by-products and disinfectant precursors from Distribution System data. Analytes included here are listed in the “Preparing your California Drinking Water Consumer Confidence Report” in Appendix A-1 in the Section titled Disinfection Byproducts, Disinfectant Residuals, and Disinfection Byproduct Precursors. The first analyte is Chlorite. Report the Chlorite data (min,max, avg) in mg/L (divide by 1000). Report Selection Criteria Analyte IN ('CHLORITE') Reportable(1/0) = 1 Sample Date BETWEEN '01-Jan-2013' AND '31-Dec-2013' Source IN ('204A SYS','284 SYS','300 SYS') Test Type IN ('SAMP') Output Specification Analyte name Analysis Avg Units Avg MDL Min Qualifier Min Value Avg Value Max Value DLR Analyte name Chlorite Analysis EPA300.1 Avg Avg Min Min Avg Max Units MDL Qualifier Value Value Value DLR UG/L 20 0 237 438 20 Table 4, Section B (line 2) contains Disinfectant Residual Data from the distribution system. To obtain the Minimum, Average and Maximum values, run Y:\EMTS\41.Sections\WQL\Reports\State\CCR\CommandFiles\Chloramine_Values.CMD MCLs, DLRs, and PHGs for Regulated Drinking Water…. Example: MCLs, DLRs, and PHGs for Regulated Drinking Water Contaminants (Units are in milligrams per liter (mg/L), unless otherwise noted.) Last Update: March 21, 2014 This table includes: CDPH's maximum contaminant levels (MCLs) CDPH's detection limits for purposes of reporting (DLRs) Public health goals (PHGs) from the Office of Environmental Health Hazard Assessment (OEHHA) Also, PHGs for NDMA and 1,2,3-Trichloropropane (which are not yet regulated) are included at the bottom of this table. MCL DLR PHG Date of PHG Chemicals with MCLs in 22 CCR §64431—Inorganic Chemicals Aluminum Antimony Antimony Arsenic Asbestos (MFL = million fibers per liter; for fibers >10 microns long) Barium Beryllium Cadmium Chromium, Total - OEHHA withdrew the 0.0025-mg/L PHG 1 0.006 -0.010 0.05 0.006 -0.002 0.6 0.02 0.0007 0.000004 2001 1997 2009 draft 2004 7 MFL 0.2 MFL 7 MFL 2003 1 0.004 0.005 0.1 0.001 0.001 2003 2003 2006 0.05 0.01 2 0.001 0.00004 withdrawn Nov. 2001 1999 Chromium, Hexavalent (Chromium-6) MCL to be established - currently regulated under the total chromium MCL Cyanide Fluoride -- 0.001 0.00002 2011 0.15 2 0.1 0.1 0.15 1 Mercury (inorganic) 0.002 0.001 0.0012 0.1 45 1 as N 10 as N 0.006 -0.05 0.01 2 0.4 -0.004 -0.005 0.012 45 1 as N 10 as N 0.006 0.001 0.03 0.002 0.001 0.0001 1997 1997 1999 (rev2005)* 2001 1997 1997 1997 2004 2012 draft 2010 1999 (rev2004) Nickel Nitrate (as NO3) Nitrite (as N) Nitrate + Nitrite Perchlorate Perchlorate Selenium Thallium Copper and Lead, 22 CCR §64672.3 Values referred to as MCLs for lead and copper are not actually MCLs; instead, they are called "Action Levels" under the lead and copper rule Copper Lead 1.3 0.015 0.05 0.005 0.3 0.0002 2008 2009 Radionuclides with MCLs in 22 CCR §64441 and §64443—Radioactivity [units are picocuries per liter (pCi/L), unless otherwise stated; n/a = not applicable] Gross alpha particle activity - OEHHA concluded in 2003 that a PHG was not practical Gross beta particle activity - OEHHA concluded in 2003 that a PHG was not practical Radium-226 Radium-228 Radium-226 + Radium-228 Strontium-90 Tritium Uranium 15 3 none n/a 4 mrem/yr 4 none n/a --5 8 20,000 20 1 1 -2 1,000 1 0.05 0.019 -0.35 400 0.43 2006 2006 -2006 2006 2001 Chemicals with MCLs in 22 CCR §64444—Organic Chemicals (a) Volatile Organic Chemicals (VOCs) Benzene Carbon tetrachloride 0.001 0.0005 0.0005 0.0005 0.00015 0.0001 1,2-Dichlorobenzene 0.6 0.0005 0.6 1,4-Dichlorobenzene (p-DCB) 1,1-Dichloroethane (1,1-DCA) 0.005 0.005 0.0005 0.0005 0.006 0.003 1,2-Dichloroethane (1,2-DCA) 0.0005 0.0005 0.0004 1,1-Dichloroethylene (1,1-DCE) cis-1,2-Dichloroethylene trans-1,2-Dichloroethylene 0.006 0.006 0.01 0.0005 0.0005 0.0005 0.01 0.1 0.06 2001 2000 1997 (rev2009) 1997 2003 1999 (rev2005) 1999 2006 2006 Dichloromethane (Methylene chloride) 0.005 0.0005 0.004 2000 1,2-Dichloropropane 0.005 0.0005 0.0005 1,3-Dichloropropene 0.0005 0.0005 0.0002 Ethylbenzene Methyl tertiary butyl ether (MTBE) Monochlorobenzene Monochlorobenzene Styrene 1,1,2,2-Tetrachloroethane Tetrachloroethylene (PCE) Toluene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane (1,1,1-TCA) 0.3 0.013 0.07 -0.1 0.001 0.005 0.15 0.005 0.2 0.0005 0.003 0.0005 -0.0005 0.0005 0.0005 0.0005 0.0005 0.0005 0.3 0.013 0.2 0.07 0.0005 0.0001 0.00006 0.15 0.005 1 1999 1999 (rev2006) 1997 1999 2003 2014 draft 2010 2003 2001 1999 1999 2006 1,1,2-Trichloroethane (1,1,2-TCA) Trichloroethylene (TCE) Trichlorofluoromethane (Freon 11) Trichlorofluoromethane (Freon 11) 1,1,2-Trichloro-1,2,2-Trifluoroethane (Freon 113) Vinyl chloride Xylenes 0.005 0.005 0.15 -- 0.0005 0.0005 0.005 -- 0.0003 0.0017 0.7 1.3 1.2 0.01 4 0.0005 1.75 0.0005 0.0005 0.00005 1.8 2006 2009 1997 2014 draft 1997 (rev2011) 2000 1997 (b) Non-Volatile Synthetic Organic Chemicals (SOCs) Alachlor Atrazine 0.002 0.001 0.001 0.0005 0.004 0.00015 Bentazon 0.018 0.002 0.2 Benzo(a)pyrene Carbofuran 0.0002 0.018 0.0001 0.005 0.000007 0.0017 Chlordane 0.0001 0.0001 0.00003 0.2 0.01 0.79 1,2-Dibromo-3-chloropropane (DBCP) 0.0002 0.00001 0.0000017 1999 2,4-Dichlorophenoxyacetic acid (2,4-D) 0.07 0.01 0.02 2009 Di(2-ethylhexyl)adipate Di(2-ethylhexyl)phthalate (DEHP) 0.4 0.004 0.005 0.003 0.2 0.012 Dinoseb 0.007 0.002 0.014 Diquat 0.02 0.004 0.015 Endrin 0.002 0.0001 0.0018 Endothal Endothal Ethylene dibromide (EDB) Glyphosate Heptachlor Heptachlor epoxide Hexachlorobenzene Hexachlorocyclopentadiene Hexachlorocyclopentadiene 0.1 -0.00005 0.7 0.00001 0.00001 0.001 0.05 -- 0.045 -0.00002 0.025 0.00001 0.00001 0.0005 0.001 -- 0.58 0.094 0.00001 0.9 0.000008 0.000006 0.00003 0.05 0.002 Lindane 0.0002 0.0002 0.000032 Methoxychlor Molinate Oxamyl Pentachlorophenol Picloram Polychlorinated biphenyls (PCBs) Simazine 2,4,5-TP (Silvex) 0.03 0.02 0.05 0.001 0.5 0.0005 0.004 0.05 0.01 0.002 0.02 0.0002 0.001 0.0005 0.001 0.001 0.00009 0.001 0.026 0.0003 0.5 0.00009 0.004 0.025 2003 1997 1997 (rev2010) 2000 1999 (rev2008) 1997 2014 draft 2003 2007 1999 1999 2003 1999 2014 draft 1999 (rev2005) 2010 2008 2009 2009 1997 2007 2001 2003 Dalapon 1997 1999 1999 (rev2009) 2010 2000 1997 (rev2006) 1997 (rev2009) 2,4,5-TP (Silvex) 2,3,7,8-TCDD (dioxin) Thiobencarb Toxaphene -3x10-8 0.07 0.003 -5x10-9 0.001 0.001 0.003 5x10-11 0.07 0.00003 2014 draft 2010 2000 2003 Chemicals with MCLs in 22 CCR §64533—Disinfection Byproducts Total Trihalomethanes Bromodichloromethane Bromoform Chloroform Dibromochloromethane Haloacetic Acids (five) (HAA5) Monochloroacetic Acid Dichloroacetic Adic Trichloroacetic Acid Monobromoacetic Acid Dibromoacetic Acid 0.080 ----0.060 ------ -0.0010 0.0010 0.0010 0.0010 -0.0020 0.0010 0.0010 0.0010 0.0010 0.0008 ----------- 2010 draft ----------- Bromate 0.010 0.0050** 0.0001 2009 Chlorite 1.0 0.020 0.05 2009 Chemicals with PHGs established in response to CDPH requests. These are not currently regulated drinking water contaminants. N-Nitrosodimethylamine (NDMA) 1,2,3-Trichloropropane --- --- 0.000003 0.0000007 2006 2009 *OEHHA's review of this chemical during the year indicated (rev20XX) resulted in no change in the PHG. **The DLR for Bromate is 0.0010 mg/L for analysis performed using EPA Method 317.0 Revision 2.0, 321.8, or 326.0. OEHHA PHG List --- Example: Chemical (follow links below to download a copy of the PHG document) California PHG (ppb) 1,1-Dichloroethane 3 1,1-Dichloroethylene 10 1,1,1-Trichloroethane 1000 1,2-Dibromo-3-chloropropane 0.0017 1,2-Dichloroethane (updated 09/16/05) 0.4 1,2-Dichloroethylene, cis 100 1,2-Dichloroethylene, trans 60 1,2-Dichloropropane 0.5 1,1,2-Trichloroethane 0.3 1,1,2,2-Tetrachloroethane 0.1 1,2,3-Trichloropropane 0.0007 1,2,4-Trichlorobenzene 5 1,2-Dichlorobenzene(updated 08/13/09) 600 1,3-Dichloropropene (Telone II®) (updated 12/22/06) 0.2 1,4-Dichlorobenzene 6 2,4-Dichlorophenoxyacetic acid (updated 01/02/09) 20 Alachlor 4 Aluminum 600 Antimony 20 Arsenic 0.004 Asbestos 7x106 fibers/L Atrazine 0.15 Barium 2,000 Bentazon (updated 09/28/09) 200 Benzene 0.15 Benzo[a]pyrene (updated 09/16/10) 0.007 Beryllium 1 Bromate 0.1 Cadmium (updated 12/22/06) 0.04 Carbofuran 1.7 Carbon Tetrachloride 0.1 Chlordane (updated 12/22/06) 0.03 Chlorite 50 Chlorobenzene 200 Chromium, Hexavalent 0.02 Copper (updated 02/08/08) 300 Cyanide 150 Dalapon (updated 06/19/09) 790 Dichloromethane 4 Diethylhexyl adipate 200 Diethylhexylphthalate (DEHP) 12 Dinoseb (updated 06/17/10) 14 Diquat 15 Endothall 580 Endrin (updated 10/10/08) 1.8 Ethylbenzene 300 Ethylene dibromide 0.01 Fluoride 1,000 Glyphosate (updated 06/29/07) 900 Gross Alpha Particle Activity N/A Gross Beta Particle Activity N/A Heptachlor 0.008 Heptachlor epoxide 0.006 Hexachlorobenzene 0.03 Hexachlorocyclopentadiene 50 Lead (updated 04/24/09) 0.2 Lindane (updated 06/22/05) 0.032 Mercury, inorganic (updated 06/01/05) 1.2 Methoxychlor (updated 09/16/10) 0.09 Methyl tertiary butyl ether (MTBE) 13 Molinate 1 N-Nitrosodimethylamine 0.003 Nickel 12 Nitrate 10,000 as N Nitrate and Nitrite 10,000 as N Nitrite 1,000 as N Oxamyl (updated 04/24/09) 26 Pentachlorophenol (updated 04/24/09) 0.3 Perchlorate Picloram Polychlorinated Biphenyls (PCBs) Radium-226 6 500 0.09 ppb 0.05 pCi/L Radium-228 0.019 pCi/L Selenium 30 Silvex 25 Simazine 4 Strontium-90 0.35 pCi/L Styrene 2,3,7,8-tetrachlorodibenzo-p-dioxin 0.5 (TCDD) 0.00005 parts per trillion (ppt) Tetrachloroethylene 0.06 Thallium (updated 11/16/04) 0.1 Thiobencarb 70 Toluene 150 Toxaphene 0.03 Trichloroethylene (updated 7/09/09) 1.7 Trichlorofluoromethane (Freon 11) 700 Trichlorotrifluoroethane (Freon 113) updated 02/11/11 Tritium 4,000 400 pCi/L Uranium (updated 08/17/01) 0.5 Vinyl Chloride 0.05 Xylene 1,800 California’s Detection Limits for Purposes of Reporting…. Example: Drinking Water Analyses: Chemicals and Characteristics Last Update: March 5, 2013 This lookup table is a compilation of chemicals and characteristics that are contained in the Storet.dbf. WQM Documentation.doc is a reference guide for the Storet.dbf and both files can be found on the Download webpage (http://www.cdph.ca.gov/certlic/drinkingwater/Pages/EDTlibrary.aspx). In case of discrepancies on this list of analytes or the information presented in Write-On, please refer to the Storet.dbf documentation. Reporting units include micrograms per liter (µg/L), milligrams per liter (mg/L), picograms per liter (pg/L), million fibers per liter (MFL), millirems per year (mrem/yr), and picocuries per liter (pCi/L). MCL = maximum contaminant level; DLR = detection limit for purposes of reporting. Storet No. or Assigne d ID No. Reportin g Units 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane (1,1,1-TCA) 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane (1,1,2-TCA) 1,1-Dichloroethane (1,1-DCA) 1,1-Dichloroethylene (1,1-DCE) 1,1-Dichloropropane 1,1-Dichloropropene 1,2,3-Trichlorobenzene 77562 34506 34516 34511 34496 34501 A-007 77168 77613 µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L 1,2,3-Trichloropropane 1,2,3-Trimethylbenzene 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 1,2-Dichlorobenzene (o-DCB) 1,2-Dichloroethane (1,2-DCA) 1,2-Dichloropropane 1,2-Diphenylhydrazine 1,3,5-Trichlorobenzene 1,3,5-Trimethylbenzene 1,3-Dichlorobenzene (m-DCB) 1,3-Dichloropropane 1,3-Dichloropropene, Total 1,3-Dinitrobenzene 1,4-Dichlorobenzene (p-DCB) 1,4-Dichlorobutane 1,4-Dioxane 17-B estradiol 77443 77221 34551 77222 34536 34531 34541 34346 77614 77226 34566 77173 34561 A-083 34571 77285 A-032 A-052 µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L Analyte MCL DLR 200 1 5 5 6 0.5 0.5 0.5 0.5 0.5 0.5 600 0.5 5 0.5 0.5 0.00 5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 5 0.5 5 1 1-Naphthol 2,2',4,4',5,5'-Hexabromobiphenyl 2,2',4,4',5,5'-Hexabromodiphenyl Ether 2,2',4,4',5-Pentabromodiphenyl Ether 2,2',4,4',6-Pentabromodiphenyl Ether 2,2',4,4'-Tetrabromodiphenyl Ether 2,2-Dichloropropane 2,3,7,8-TCDD (Dioxin) 2,4,5-TP (SILVEX) 2,4,6-Trichlorophenol 2,4,6-Trinitrotoluene (TNT) 2,4-D 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dinitrotoluene 2-Chloroethylvinyl Ether 2-Chloronaphthalene 2-Chlorophenol 2-Chlorotoluene 2-Methyl-4,6-Dinitrophenol 2-Methylphenol 2-Nitrophenol 3,3-Dichlorobenzidine 3-Hydroxycarbofuran 4,4’-DDD 4,4’-DDE 4,4’-DDT 4,6-Dinitro-o-cresol 4-Bromophenyl Phenyl Ether 4-Chloro-3-Methylphenol 4-Chlorophenyl phenyl Ether 4-Chlorotoluene 4-Nitrophenol Acenaphthene Acenaphthylene Acetaldehyde Acetaminophen Acetochlor Acetochlor Ethane Sulfonic Acid (ESA) Acetochlor Oxanilic Acid (OA) Acetone Acrylonitrile (Acritet) Aggressiveness Index Alachlor (ALANEX) (also UCMR 2 MonitoringTM 525.2) Alachlor Ethane Sulfonic Acid (ESA) Alachlor Oxanilic Acid (OA) Aldicarb (TEMIK) 77441 A-086 A-087 A-085 A-088 A-084 77170 34676 39045 34621 81360 39730 34601 34606 34616 34611 34626 34576 34581 34586 A-008 34657 A-046 34591 34631 A-021 39310 39320 39300 A-050 34636 34452 34641 A-009 34646 34205 34200 77001 A-058 04240 A-089 A-090 81552 34216 82383 µg/L µg/L µg/L µg/L µg/L µg/L µg/L pg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L 77825 A-094 A-091 39053 µg/L µg/L µg/L µg/L 30 50 70 0.5 5 1 5 10 5 5 5 5 5 5 5 0.5 5 5 20 3 0.02 0.01 0.02 5 5 5 0.5 5 5 5 2 1 3 Aldicarb Sulfone Aldicarb Sulfoxide A-020 A-019 µg/L µg/L 4 3 0.07 5 Aldrin Alkalinity, (Total) (as CaCO3 equivalents) alpha-BHC 39330 00410 39337 µg/L mg/L µg/L Aluminum (Al) Ammonia Amoxicillin Anthracene Antimony Arsenic Asbestos Atrazine (AATREX) Azithromycin Barium (Ba) Bentazon (BASAGRAN) Benzene Benzidine Benzo (a) Anthracene Benzo (b) Fluoranthene Benzo (ghi) Perylene Benzo (k) Fluoranthene Benzo(a)pyrene Benzyl Butyl Phthalate Beryllium beta-BHC Bicarbonate (as HCO3) bis (2-Chloroethoxy) methane bis (2-Chloroethyl) Ether bis (2-Chloroisopropyl) Ether bis-1,1-Dimethylethylperoxide bis-1,1-Dimethylperoxide Bisphenol A Boron Bromacil (HYVAR) 01105 00612 A-059 34220 01097 01002 81855 39033 A-060 01007 38710 34030 39120 34526 34230 34521 34242 34247 34292 01012 39338 00440 34278 34273 34283 A-018 A-015 81651 01020 82198 ug/L mg/L µg/L µg/L ug/L ug/L MFL µg/L µg/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L 1000 50 6 10 7 1 5 6 2 0.2 0.5 Bromate Bromide Bromobenzene Bromochloroacetic Acid (BCAA) Bromochloromethane Bromodichloroacetic Acid (BDCAA) Bromodichloromethane Bromoform Bromomethane (Methyl Bromide) Butachlor Cadmium (Cd) Caffeine Calcium (Ca) Carbamazepine A-027 82298 81555 A-038 A-012 A-039 32101 32104 34413 77860 01027 81436 00916 A-061 ug/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L mg/L µg/L 10 5.0 5 0.5 1 0.5 1 1.0 1.0 0.5 0.38 1 0.01 1000 18 1 0.2 4 100 2 0.5 5 10 10 10 10 0.1 10 1 0.05 5 5 100 10 Carbaryl (Sevin) Carbofuran (FURADAN) Carbon Dioxide Carbon Disulfide Carbon Tetrachloride Carbonate (as CO3) Chlorate Chlordane 77700 81405 77000 77041 32102 00445 A-037 39350 µg/L µg/L ug/L µg/L µg/L mg/L ug/L µg/L 18 5 5 0.5 0.5 0.5 0.1 20 0.1 Chloride Chlorine Dioxide 00940 50070 mg/L mg/L 500 Chlorite Chloroethane Chloroform (Trichloromethane) Chloromethane (Methyl Chloride) Chlorothalonil (DACONIL, BRAVO) Chromium (Total Cr) Chromium, hexavalent (CrVI) Chrysene Ciprofloxacin cis-1,2-Dichloroethylene (c-1,2-DCE) Cobalt Color, Apparent (Unfiltered) Combined Ra 226 + Ra 228 Combined Ra 226 + Ra 228 Counting Error Combined Ra 226 + Ra 228 MDA95 50074 34311 32106 34418 70314 01034 01032 34320 A-062 77093 01035 00081 11503 11504 A-076 mg/L µg/L µg/L µg/L µg/L ug/L ug/L µg/L µg/L µg/L ug/L UNITS pCi/L pCi/L pCi/L 1.0 Copper (Cu) Cyanide Dalapon DCPA (total di & mono acid degradates) delta-BHC Di(2-ethylhexyl) Adipate Diazinon Dibenzo (a,h) anthracene Dibromoacetic Acid (DBAA) Dibromochloroacetic Acid (CDBAA) Dibromochloromethane Dibromochloropropane (DBCP) Dibromomethane Dicamba (BANVEL) Dichloroacetic Acid (DCAA) Dichlorodifluoromethane (Freon 12) Dichloromethane (Methylene Chloride) Dieldrin Diethylbenzene Diethylhexylphthalate (DEHP) Diethylphthalate Diisopropyl Ether (DIPE) Dimethoate (CYGON) Dimethyl phthalate 01042 01291 38432 A-045 34259 A-026 39570 34556 82721 A-040 32105 38761 77596 82052 77288 34668 34423 39380 78214 39100 34336 A-036 38458 34341 ug/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L 1000 150 200 50 100 10 400 0.05 5 50 6 0.02 0 0.5 1.0 0.5 5 10 1 5 0.5 15 5 0.2 5 4 5 1.0 2 1.0 0.01 0.5 1.5 1.0 0.5 0.5 0.02 3 5 3 5 di-n-Butylphthalate di-n-Octylphthalate Dinoseb (DNBP) Diquat Diuron Endosulfan I Endosulfan II Endosulfan Sulfate Endothall Endrin Endrin Aldehyde Estrone Ethinyl estradiol Ethyl Benzene Ethylene Dibromide (EDB) Ethylenediamine tetra-acetic acid (EDTA) Ethyl-tert-Butyl Ether (ETBE) Field pH Field Turbidity Fluoranthene Fluorene Fluoride (F) (Natural-Source) Fluoride (Treatment Related-Distribution) Foaming Agents (MBAS) Fonofos gamma-BHC Gemfibrozil Glyoxal Glyphosate Gross Alpha Gross Alpha Counting Error 39110 34596 81287 78885 39650 34361 34356 34351 38926 39390 34366 A-053 A-051 34371 77651 78151 A-033 00400 82078 34376 34381 00951 A-035 38260 04095 39340 A-063 A-048 79743 01501 01502 µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L Std Units NTU µg/L µg/L mg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L pCi/L pCi/L Gross Alpha MDA95 Gross Beta Gross Beta Counting Error Gross Beta MDA95 Gross Beta, Calculated Dose Equivalent Haloacetic Acids (five) (HAA5) Hardness, (Total) as CACO3 Heptachlor Heptachlor Epoxide Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane Hexanol Hydrazine Hydrogen Sulfide Hydroxide (as OH) Ibuprofen Indeno (1,2,3-cd) Pyrene A-072 03501 03502 A-077 A-071 A-049 00900 39410 39420 39700 34391 34386 34396 81591 81313 71875 71830 A-064 34403 pCi/L pCi/L pCi/L pCi/L mrem/yr µg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L mg/L mg/L µg/L µg/L 7 20 100 2 300 0.05 5 5 2 4 0.01 0.01 0.05 45 0.1 0.05 0.5 0.02 3 2.0 0.1 5 5 0.1 0.1 0.5 0.2 0.2 700 15 25 3 50 4 4 60 0.01 0.01 1 50 0.01 0.01 0.5 0.5 1 5 10 Iodide Iodinated contrast media Iron (Fe) Isophorone Isopropyl alcohol Isopropylbenzene (Cumene) Kerosine Langelier Index at 60 C Langelier Index at Source Temp. Lead (Pb) Lindane (gamma-BHC) Lipitor Lithium m,p-Xylene Magnesium (Mg) Manganese (Mn) MBAS (Foaming Agents) Mercury (Hg) Methadone Methomyl Methoxychlor Methyl Ethyl Ketone (MEK, Butanone) Methyl Isobutyl Ketone (MIBK) 71865 A-065 01045 34408 77015 77223 78878 71813 71814 01051 39340 A-066 01132 A-014 00927 01055 38260 71900 A-067 39051 39480 81595 81596 mg/L µg/L ug/L µg/L µg/L µg/L µg/L Methyl tert-Butyl Ether (MTBE) Metolachlor Metolachlor Ethane Sulfonic Acid (ESA) Metolachlor Oxanilic Acid (OA) Metribuzin Molinate (ORDRAM) Molybdenum Monobromoacetic Acid (MBAA) Monochloroacetic Acid (MCAA) Monochlorobenzene (Chlorobenzene) Morphine m-Xylene Naphthalene n-Butylbenzene Nickel Nitrate (as NO3) 46491 39356 A-092 A-093 81408 82199 01062 A-041 A-042 34301 A-068 81710 34696 A-010 01067 71850 µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L mg/L Nitrate + Nitrite as Nitrogen (N) Nitrite as Nitrogen (N) Nitrobenzene N-Nitrosodiethylamine (NDEA) N-Nitrosodimethylamine (NDMA) N-Nitrosodi-n-butylamine (NDBA) N-Nitrosodi-n-propylamine (NDPA) N-Nitrosodiphenylamine N-Nitrosomethylethylamine (NMEA) N-Nitrosopiperidine (NPIP) A-029 00620 34447 78200 34438 78207 34428 34433 A-070 73283 ug/L ug/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L µg/L ug/L µg/L mg/L ug/L mg/L ug/L µg/L µg/L µg/L µg/L µg/L 300 100 10 0.5 0.2 5 0.2 0.5 50 0.5 2 30 20 1 2 10 5 5 13 3 20 2 70 1.0 2.0 0.5 100 45 1000 0 1000 0.5 0.5 0.5 10 2 400 400 N-Nitrosopyrrolidine (NPYR) n-Octacosane Nonylphenol Nonylphenol polyethoxylate n-Propylbenzene Octylphenol Octylphenol polyethoxylate 78206 78116 77745 A-054 77224 A-055 A-056 µg/L µg/L µg/L µg/L µg/L µg/L µg/L Odor Threshold @ 60 C 00086 TON Oxamyl (Vydate) 38865 µg/L O-Xylene 77135 µg/L Parachlorometa cresol 34453 µg/L PCB-1016 (as decachlorobiphenyl (DCB)) 34671 µg/L PCB-1221 (as DCB) 39488 µg/L PCB-1232 (as DCB) 39492 µg/L PCB-1242 (as DCB) 39496 µg/L PCB-1248 (as DCB) 39500 µg/L PCB-1254 (as DCB) 39504 µg/L PCB-1260 (as DCB) 39508 µg/L PCBs, total -- See "Polychlorinated Biphenyls, Total, as DCB" (below) Pentachloroethane 81501 µg/L Pentachlorophenol (PCP) 39032 µg/L Perchlorate A-031 ug/L pH, Laboratory 00403 Std Units Phenanthrene 34461 µg/L Phenol (Carbolic Acid) 34694 µg/L Phosphate (as PO4) 00650 mg/L Phosphate, Ortho (as PO4) 00660 mg/L Picloram 39720 µg/L p-Isopropyltoluene A-011 µg/L Polybrominated diphenyl ethers A-057 µg/L Polychlorinated Biphenyls, Total, as DCB 39516 µg/L Potassium (K) 00937 mg/L Prometryn (CAPAROL) 39057 µg/L Propachlor 38533 µg/L Propane 82358 µg/L P-Xylene 78132 µg/L Pyrene 34469 µg/L 0.5 3 50 1 20 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 1 6 0.2 4 5 5 500 1 0.5 0.5 2 0.5 0.5 5 RA-226 for CWS or Total RA for NTNC by 903.0 RA-226 or Total RA by 903.0 C.E. A-080 A-081 pCi/L pCi/L RA-226 or Total RA by 903.0 MDA95 Radium 226 Radium 226 Counting Error A-082 09501 09502 pCi/L pCi/L pCi/L 1 Radium 226 MDA95 Radium 228 Radium 228 Counting Error A-074 11501 11502 pCi/L pCi/L pCi/L 1 Radium 228 MDA95 Radon 222 Radon 222 Counting Error RDX (Hexahydro-1,3,5-trinitro-1,3,5-triazine) A-075 82303 82302 81364 pCi/L pCi/L pCi/L µg/L 100 Salicylic acid sec-Butylbenzene Selenium (Se) Silica Silver (Ag) Simazine (PRINCEP) Sodium (Na) Sodium Absorption Ratio Source Temperature 77403 77350 01147 00955 01077 39055 00929 00931 00010 µg/L µg/L ug/L mg/L ug/L µg/L mg/L Specific Conductance (E.C.) Strontium – 90 Strontium – 90 Counting Error 00095 13501 13502 umhos pCi/L pCi/L Strontium – 90 MDA95 Styrene Sulfate (SO4) Sulfide Terbacil Terbufos Terbufos Sulfone tert-Amyl Methyl Ether (TAME) tert-Butyl Alcohol (TBA) tert-Butyl Formate (TBF) tert-Butylbenzene Tetrachloroethylene (PCE) Thallium Thiobencarb (BOLERO) Toluene Total 1,3-Dichloropropene Total Anions Total Filterable Residue @ 180 C (TDS) Total Organic Carbon (TOC) Total Trihalomethanes (TTHMs) Total Xylenes (m,p, & o) Toxaphene trans-1,2-Dichloroethylene (t-1,2-DCE) Tribromoacetic Acid (TBAA) Trichloroacetic Acid (TCAA) Trichloroethylene (TCE) Trichlorofluoromethane (FREON 11) Trichlorotrifluoroethane (FREON 113) Triclosan A-078 77128 00945 00745 38882 82088 45612 A-034 77035 A-047 77353 34475 01059 A-001 34010 34561 70300 00680 82080 81551 39400 34546 A-043 82723 39180 34488 81611 A-069 pCi/L µg/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L ug/L µg/L µg/L µg/L me/L mg/L mg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L µg/L Tritium Tritium Counting Error 07000 07001 pCi/L pCi/L Tritium MDA95 Turbidity, Laboratory Uranium Uranium Uranium Counting Error A-079 82079 28011 28012 A-028 pCi/L NTU ug/L pCi/L pCi/L 50 0.5 5 100 4 10 1 1600 8 2 100 500 0.5 0.5 C 3 2 5 2 70 150 0.5 0.5 0.5 1 1 0.5 0.5 1000 0.3 80 1750 3 10 5 150 1200 1 0.5 4 1.0 0.5 5 10 2000 0 1000 5 20 0.1 1 1 Uranium MDA95 Vanadium Vinyl Acetate Vinyl Chloride (VC) A-073 01087 77057 39175 pCi/L ug/L µg/L µg/L 0.5 0.5 Zinc (Zn) 01092 ug/L 5000 50 3