Section 20.2-Brönsted-Lowry Theory of Acids & Bases Hebden: Section 4-5 - Do Exercises p 119-121 #15-19 Name: Date: 1. The conjugate base of H2BO3– is 9601 A. BO3 B. H3BO3 C. HBO3 D. H3BO3 2. Which of the following is amphiprotic in water? 9601 A. SO2 B. SO3 C. HSO3 D. H2SO3 3. Water acts as a base when it reacts with 9601 A. CN B. NH3 C. NO2 4. Consider the following equilibrium: 9604 A. acid, base, acid, base. B. acid, base, base, acid. C. base, acid, acid, base. D. base, acid, base, acid. 13. The equation representing the reaction of ethanoic acid with water is 9701 D. NH4 14. The conjugate acid of C6H5Ois 9704 A. C6H4O B. C6H5OH C. C6H4O The sequence of Brönsted-Lowry acids and bases in the above equilibrium is A. acid, base, base, acid. B. acid, base, acid, base. C. base, acid, base, acid. D. base, acid, acid, base. 5. Which of the following is a conjugate acid-base pair? 9604 A. H3PO4 and PO43– B. H2PO4and PO4 C. H3PO4 and HPO4 D. H2PO4and HPO4 6. Water will act as a Brönsted-Lowry acid with 9604 A. NH3 B. H2S C. HCN D. HNO3 7. Consider the following equilibrium: 9606 D. C6H5OH+ 15. A Brönsted-Lowry base is defined as a chemical species that 9706 A. accepts protons. B. neutralizes acids. C. donates electrons. D. produces hydroxide ions in solution. 16. Consider the following equilibrium: The order of Brönsted-Lowry acids and bases is A. acid, base, acid, base B. acid, base, base, acid C. base, acid, acid, base D. base, acid, base, acid 17. A base is converted to its conjugate acid by 9708 A. adding a proton. B. adding an electron. C. removing a proton. D. removing an electron. The Brönsted-Lowry acids and bases are, respectively, A. acid, base, base, acid. B. acid, base, acid, base. C. base, acid, base, acid. D. base, acid, acid, base. 18. Consider the following: 9708 8. An aqueous solution that contains more hydronium ions than hydroxide ions is a(n) 9606 A. basic solution. B. acidic solution. C. neutral solution. D. standardized solution. 9. Consider the following equilibrium: 9608 The NO2is acting as a A. Brönsted-Lowry acid by donating a proton. B. Brönsted-Lowry base by donating a proton. C. Brönsted-Lowry acid by accepting a proton. D. Brönsted-Lowry base by accepting a proton. Which of the above are amphiprotic in an aqueous solution? A. I and II only B. II and III only C. I, II and III only D. II, III and IV only 19. In which of the following equilibrium systems is HCO3acting as a Brönsted-Lowry base? 9801 10. The conjugate acid of H2PO4is 9608 A. PO4 B. H3PO4 C. HPO4 D. H3PO4 11. An amphiprotic substance can act as 9608 A. a base only. B. an acid only. C. both an acid and a base. D. neither an acid nor a base. 12. Consider the following equilibrium: 9701 The order of Brönsted-Lowry acids and bases is Section -Document1 p 1 o f 2 20. The conjugate acid of H2O is 9801 A. O B. OH C. H3O D. H2O2 21. Which of the following could act as a Brönsted-Lowry acid, but not as a Brönsted-Lowry base? 9804 A. NH3(aq) B. H2O(l) C. HClO4(aq) D. HCO3–(aq) 22. A substance which produces hydrogen ions in solution is the definition of 9806 A. an Arrhenius acid. B. an Arrhenius base. C. a Brönsted-Lowry acid. D. a Brönsted-Lowry base. 23. The number of conjugate pairs in a Brönsted-Lowry acid-base equation is 9806 A. 1 B. 2 C. 3 D. 4 24. The conjugate acid of the monohydrogen phosphate ion, HPO42– , is 9808 A. PO4 B. H2PO4 C. H2PO4 D. H2PO4 25. Which of the following are amphiprotic in aqueous solution? 9808 I - HBr II - H2O III- HCO3– IV H2C6H5O7– A. I and II only B. III and IV only C. II, III and IV only D. I, II, III and IV 26. Consider the following acid-base equilibrium: 9901 32. Water will act as an acid with which of the following? 0001 I. H2CO3 II. HCO3– III. CO32– A. I only. B. III only. C. I and II only. D. II and III only. 33. The conjugate base of H2PO4– is 0006 A. OH– B. PO43– C. H3PO4 D. HPO42– MC: 12.C 22.A 32.D 1.C 2.C 3.D 4.A 5.D 6.A 7.A 8.B 9.D 10.B 11.C 13.C 14.B 15.A 16.C 17.A 18.B 19.C 20.C 21.C 23.B 24.B 25.C 26.C 27.B 28.D 29.B 30.A 31.D 33.D PART B: Written Response: 1. a) Write the balanced equation representing the reaction of HF with H2O. (1 mark) 9704 HF + H2O qwe F– + H3O+ b) Identify the Brönsted-Lowry bases in the above equation. (1 mark) In the reaction above, the Brönsted-Lowry acids are A. H2O and OH B. HCO3and OH C. H2O and H2CO3 D. HCO3and H2CO3 27. Consider the following: I- PO4 II- HPO4 Identify the Brönsted-Lowry bases in this equilibrium. 9908 A. H2BO3and H3BO3 B. HC2O4and H3BO3 C. HC2O4 and C2O4 D. H2BO3and C2O4 F– , H2O 2. Define the term Brönsted-Lowry acid. (2 marks) 9801 III- H2PO4 IV- H3PO4 The term amphiprotic can be used to describe 9901 A. I only. B. II and III only. C. I, II and III only. D. II, III and IV only. 28. The conjugate acid of HAsO4is 9904 A. H3O B. AsO4 C. H3AsO4 D. H2AsO4 29. Consider the following Brönsted-Lowry equilibrium system: What are the two Brönsted-Lowry bases in the equilibrium above? 9906 A. HSO3and SO3 B. H2PO4and SO3 C. HSO3 and H3PO4 D. H2PO4and H3PO4 30. Consider the following: 9906 A chemical species that is a proton donor 3. a) Define the term Brönsted-Lowry base. (2 marks) 9804 A chemical species that is a proton acceptor b) Give an example of a compound that acts as a weak base. (1 mark) F– NaF, NH3 etc 4. a) Define the term amphiprotic. (1 mark) 9806 0001 An ion or molecule that can accept or donate a proton. b) Give an example of an amphiprotic anion. (1 mark) HSO3– , or H2PO4–, or HPO42– The amphiprotic ions are A. I and II only. B. I and III only. C. II and III only. D. I, II, III. 31. Consider the acid-base equilibrium system: Section -Document1 p 2 o f 2 20.2 MC: 1.C 2.C 3.D 4.A 5.D 6.A 7.A 8.B 9.D 10.B 11.C 12.C 13.C 14.B 15.A 16.C 17.A 18.B 19.C 20.C 21.C 22.A 23.B 24.B 25.C 26.C 27.B 28.D 29.B 30.A 31.D 32.D 33.D Section -Document1 p 3 o f 2