Honors Chemistry Summer Assignment The goal of this summer assignment is to review information that was previously covered in middle school and 9th grade to adequately prepare you for the rigor of honors chemistry. This class is fast-paced and the honors chemistry teachers expect that you are entering class prepared from the first day. Each topic covered has associated links listed with it. If you need a refresher on any of the material, these links are where you should begin. We highly recommend that you take formal notes from these links as they will serve as your class notes for the year on the selected topics. The summer assignment is due on the first day of class: September 2, 2015 Please come to class with your completed summer assignment and any questions you may have on the material covered. Look forward to seeing you in class! Section I – Matter & Properties Matter & Properties, Part I: https://www.youtube.com/watch?v=TF8rxXs-QSY Matter & Properties, Part II: https://www.youtube.com/watch?v=WGhGcrTVDVI – through 7:00 Classifying Matter, Part I: https://www.youtube.com/watch?v=ZZYjleLadlc Classifying Matter, Part II: https://www.youtube.com/watch?v=SoFywULNF3s Chemical Reaction Basics: https://www.youtube.com/watch?v=9Jpr8UoDOj0 1. Classify each of the following as either an intensive (I) or extensive (E) property. Water’s density is 1.0 g/mL Grass is green I E Metal conducts heat I Boiling point is 100°C I A cup has 500 mL of water E I A stone weighs 10 lbs. 2. Fill in the following concept map for the classification of matter: Classify each of the following as an element (E), compound (C), heterogeneous mixture (HE), or homogeneous mixture (HO). Sodium chloride __C___ Concrete _HE____ Air HO Water __C___ Salad _HE____ Lead 14-carat gold __HO___ Oxygen __E___ Kool-Aid drink E___ HO Classify each of the following as either a physical (P) or chemical (C) property. Ice melts at 0°C _P__ Copper conducts electricity __P___ Getting tan in sun __C_ Iron rusts Iron is magnetic __P_ __C_ The sky is blue __P___ The gas is colorless _P___ Baking a cake __C___ Density is 1 g/cm3 __P_ 3. List the 5 signs of a chemical reaction: a. _____bubbling/gas released________________ b. _____color change_______________________ c. ____heat absorbed or released_____________ d. ____precipitate formation when mixing two liquids or solutions e. _____change in physical properties_________ Section II: Chemical Math LINKS: Density: https://www.youtube.com/watch?v=4fUJQiLhfhU SI Units: https://www.youtube.com/watch?v=WuaxXcgX6Rc Metric Units: https://www.youtube.com/watch?v=5EcNAxweb44 (through 5:05) Dimensional Analysis: https://www.youtube.com/watch?v=WrIOeKtqNz8 12. Simple density problems: a. Determine the density of an object with a mass of 13.25 g and occupies of volume of 3.7 cm3. 13.25𝑔 3.7𝑐𝑚3 = 3.6g/cm3 b. Gold has a density of 19.30 g/cm3. What is the mass of a piece of gold that has a volume of 5.35 cm3? 19.30g = 1 cm3 for gold 19.3𝑔 𝑥 = x = 103g 5.35cm3 x 19.30g = 103g 1 𝑐𝑚3 5.35𝑐𝑚3 1 cm3 c. What is the volume of a piece of aluminum with a density of 2.70 g/cm3 and a mass of 415 g? 415𝑔 𝑥 = 2.70𝑔 1𝑐𝑚3 x = 154cm3 2.70g = 1 cm3 for aluminum 415g x 1 cm3 = 154cm3 2.70g 4. Fill in the following table depicting the SI units: Type of Measurement Units (words) Units (symbol) amount of substance mole mol mass kilogram kg temperature Kelvin K time second s Length meter m 5. Fill in the following table depicting metric prefixes: giga mega kilo deci centi milli micro nano pico G M k d c m µ n p 109 106 103 10-1 10-2 10-3 10-6 10-9 10-12 **Memorize highlighted units 6. Use dimensional analysis to solve the following questions. ** purple answers are rounded with the correct number of significant figures. We will cover this later in the unit. a. 35.0 grams to decigrams 35.0g x 101 dg = 350 dg 1g (350. dg) b. 16.4 pounds to grams (1 kg = 2.2 lbs) 16.4 lb x 1 kg x 103g = 7455g 2.2 lb 1 kg (7460g) 1 month to seconds (assume that 1 month = 30 days) 30 days x 24 hr x 3600 sec = 2,592,000 sec (2.592 x 106 sec) 1 day 1 hr c. (3 x 106 seconds) 2.8 days to milliseconds 2.8 days x 24 hr x 3600 sec x 103 msec = 1 day 1 hr 1 sec 241,920,000 msec (2.4192 x 108 msec) (2.4 x 108 msec) Section III: The Atom LINKS: Democritus & Dalton: https://www.youtube.com/watch?v=gmwgJ6bDLHM Thomson – Rutherford: https://www.youtube.com/watch?v=4Gymoej6N2A Structure of Atom: https://www.youtube.com/watch?v=9l1HZwn2tOA Bohr: https://www.youtube.com/watch?v=CUk3enr-m0w Heisenberg – Schrödinger: https://www.youtube.com/watch?v=cy2rEt63Af4 – until 3:50 7. Fill in the chart below. This will be your reference for the history of the atom as we progress through the year. Main Ideas Scientist Experiment Sketch of Model Democritus 400 BC All matter is made of indivisible particles called “atomos”. Dalton 1800s Father of Modern Atomic Theory 1. All matter is composed of atoms 2. All atoms of a given element are identical 3. Atoms can’t be created, subdivided or destroyed 4. In a chemical reaction atoms can combine to form compounds 5. Atoms of different elements can be distinguished from one another by mass (1897) Discovered that cathode rays are composed of negatively charged particles with a large charge/mass ratio (discovered electrons) Thomson Cathode ray experiments https://www.youtube. com/watch?v=O9Go yscbazk Millikan Measured the charge of an electron (1909) Oil drop experiment https://www.youtube. com/watch?v=XMfY Hag7Liw Rutherford Atoms are mostly empty space, with a small, positively charged nucleus. (1910) 1917 – discovers protons 1921 – hypothesizes presence of neutrons Gold Foil Experiment https://www.youtube. com/watch?v=5pZj0 u_XMbc Bohr Described specific behavior and position of electrons; electrons travel in fixed orbits at set distances from the nucleus. The amount of energy each electron has is determined by which orbit it is in. (1913) Studied spectrum for hydrogen; his equations only work for hydrogen Heisenberg Uncertainty Principle (1926) It is impossible to know both the position of a particle and its speed/direction at the same time. Not necessary, (or Heisenberg’s experiment) but good link explaining the Uncertainty Principle further if you are curious: https://www.youtube. com/watch?v=a8FTr 2qMutA Schrödinger Quantum Mechanical Model of the atom; series of equations describing the clouds where there is a high probability of finding the electron in the atom (1926) 8. Fill in the table below for the various atoms. NAME SYMBOL ATOMIC MASS PROTONS ELECTRONS NEUTRONS NUMBER NUMBER Lithium Li 3 7 3 3 4 Lead Pb 82 207 82 82 125 Manganese Mn 25 55 25 25 30 Nickel Ni 28 59 28 28 31 Mercury Hg 80 202 80 80 122 Tungsten W 74 187 74 74 113 Iodine-131 131 I 53 131 53 53 78 U 92 236 92 92 144 56 141 56 56 85 Uranium-236 236 Barium-141 141 Ba 9. Atoms are neutral, meaning that the number of protons equals the number of electrons. Atoms that have charges are called ions. Positive ions mean that electrons have been lost. Negative ions mean that electrons have been gained. Use this information to fill in the chart below. NAME SYMBOL ATOMIC MASS PROTONS NEUTRONS ELECTRONS NUMBER NUMBER sodium ion Na+1 11 23 11 12 10 calcium ion Ca2+ 20 10 20 20 18 sulfide S-2 16 32 16 16 18 nitride N3- 7 14 7 7 10