EE580 – Solar Cells Todd J. Kaiser • Lecture 03 • Nature of Sunlight Montana State University: Solar Cells Lecture 3: Nature of Sunlight 1 Wave-Particle Duality • Light acts as – Waves: electromagnetic radiation • Refraction - bending of light through a prism • Diffraction - bending of light around an edge • Interference – adding of light waves – Particles: photons – individual packets of energy • Photoelectric Effect • Blackbody Radiation Montana State University: Solar Cells Lecture 3: Nature of Sunlight 2 Properties of Light • Sunlight contains photons of many different frequencies ( we see as different colors) • Visible Light – 0.38 microns – 0.77 microns (10-6 meters) – Blue - Red • Frequency (f) and Wavelength ( l) are inversely related: f = 1/ l – High Energy High Frequency Short Wavelength – Low Energy Low Frequency Long Wavelength Montana State University: Solar Cells Lecture 3: Nature of Sunlight 3 Electromagnetic Spectrum Color, wavelength and frequency are interrelated Wavelength (meters) Roy G. BIV 0.77 microns Red Orange 0.6 microns Blue 10-1 109 10-2 10-4 1012 1013 Visible Ultraviolet 1015 1016 1017 X Rays 10-10 1018 10-11 1019 10-12 (Hz) 1014 10-7 0.4 microns Montana State University: Solar Cells Lecture 3: Nature of Sunlight Infrared Frequency 1010 1011 10-9 0.38 microns Microwaves 10-3 10-8 Indigo Violet 108 10-6 0.5 microns Radio Waves 107 1 10-5 Yellow Green 10 Gamma Rays 1020 4 Photon Energy E hf hc l E eV 1.24 l High energy photon for blue light Low energy photon for red light Very low energy photon for infrared (invisible) Montana State University: Solar Cells Lecture 3: Nature of Sunlight 5 Photon Flux & Energy Density Number of Photons Photon Flux second Area W hc Energy Density : Photon Flux Energy per Photon : H 2 J m l For the same intensity of light shorter wavelengths require fewer photons, since the energy content of each individual photon is greater Montana State University: Solar Cells Lecture 3: Nature of Sunlight 6 Radiant Power Density • The total power density emitted from a light source N H F l dl F li li 0 i 0 F(V) F(I) F(B) F(G) F(Y) F(O) F(R) • The spectral irradiance is multiplied by the wavelength range for which is was measured and summed over the measurement range l1 l2 l3 l4 l5 l6 l7 Montana State University: Solar Cells Lecture 3: Nature of Sunlight 7 Spectral Irradiance Visible Xenon – (left axis) Sun - (right axis) Halogen – (left axis) Mercury – (left axis) Power Density at a particular wavelength Montana State University: Solar Cells Lecture 3: Nature of Sunlight 8 Solar Radiation Montana State University: Solar Cells Lecture 3: Nature of Sunlight 9 Blackbody Radiation • • • A body in thermal equilibrium emits and absorbs radiation at the same rate A body that absorbs all the radiation incident on it is an ideal blackbody The power per area radiated is given by the Stefan-Boltzmann Law H T • 4 This function has a maximum given by Wien’s Displacement Law 2900 l peak T K • The spectral irradiance of a blackbody radiator is given by Planck’s Law FBB l 2hc 2 l5 1 e hc klT 1 Montana State University: Solar Cells Lecture 3: Nature of Sunlight 10 Plot of Planck’s Law 2900 l peak T K 30 25 'T=3500' 'T=4000' 'T=4500' 'T=5000' 'T=5500' 'T=6000' x10 12 20 15 10 5 0 0.5 1.0 Wavelength (microns) FBB l 2hc 2 l5 1.5 2.0 1 e hc klT 1 Montana State University: Solar Cells Lecture 3: Nature of Sunlight 11 Sun’s maximum at visible spectrum 15 10 13 10 11 10 9 10 Visible 7 10 5 10 3 10 1 10 2 3 4 0.1 5 6 7 8 9 1 Wavelength (microns) Montana State University: Solar Cells Lecture 3: Nature of Sunlight 12 Sun Fusion reaction at 20,000,000 degrees Converts H to He Convection heat transfer Photosphere (sun’s surface) at 5760±50 K Montana State University: Solar Cells Lecture 3: Nature of Sunlight 13 Sunlight in Space The energy is emitted from the surface of the sun as a sphere of light The size of the sphere grows as the light moves farther from the sun causing the power density to reduce 2 2 4 Rsun Rsun 2 H D H H H 1353 W / m 0 0 EarthOrbit 4 D 2 D2 Montana State University: Solar Cells Lecture 3: Nature of Sunlight 14 Sunlight at Earth’s Orbit 360(n 2) 2 H EarthEllipticalOrbit 13531 0.033 cos W / m 365 n is the day of the year Montana State University: Solar Cells Lecture 3: Nature of Sunlight 15 Sunlight at Earth’s Surface • Atmospheric Effects – Absorption – Scattering – Local Variations • Clouds • Pollution • Weather • Latitude • Season of Year • Time of Day Montana State University: Solar Cells Lecture 3: Nature of Sunlight 16 100 % input Clear Sky Absorption & Scattering 2% Absorbed 1% Absorbed 18% Absorbed 8% Absorbed BOR0606C Ozone 20-40 km 3% Scattered To Space Upper Dust Layer 15-35 km 0.5% Scattered to Space Air Molecules 0-30 km 1% Scattered to Space 1% Scattered to Earth 4% Scattered to Earth 0.5% Scattered to Space 6% Absorbed Water Vapor 0-3 km 0.5% Scattered to Space 1% Absorbed Lower Dust 0-3 km Montana State University: Solar Cells Lecture 3: Nature of Sunlight 70% Direct to Earth 1% Scattered to Earth 1% Scattered to Earth 7% Scattered To Earth 17 Air Mass • The path length that light takes through the atmosphere normalized to the shortest possible path length x 1 h h 1 h AM cos q cos q q x h Montana State University: Solar Cells Lecture 3: Nature of Sunlight 18 Measuring the Air Mass q cos q L h 1 h AM cos q L S 2 L2 S 1 L L 2 h q Object of height (L) Neglects the curvature of the earth’s atmosphere Shadow from object (S) Montana State University: Solar Cells Lecture 3: Nature of Sunlight 19 EAST SOUTH NORTH WEST March 22: Spring Equinox What time of year is this image true? Montana State University: Solar Cells Lecture 3: Nature of Sunlight Sept 23: Fall Equinox 20 Declination Angle Mar 23 Declination (d) = 0º Jun 23 Dec 23 Declination (d) = 23.45º Declination (d) = -23.45º 360 d 81 d 23.45 sin 365 Sep 23 Declination (d) = 0º Montana State University: Solar Cells Lecture 3: Nature of Sunlight 21 Declination Angle of Sun Summer Solstice d = 23.45º North Pole d Fall Equinox d = 0º d Winter Solstice Montana State University: Solar Cells Lecture 3: Nature of Sunlight d = -23.45º 22 Elevation Angle The elevation angle is the angular height the sun makes with the horizontal Montana State University: Solar Cells Lecture 3: Nature of Sunlight 23 Polar Plot of Sun Position for Bozeman Summer Spring/Fall Winter Montana State University: Solar Cells Lecture 3: Nature of Sunlight 24 Passive Solar Heating Summer Sun Winter Sun Overhang designed to remove direct sunlight from window during the heat of summer and allow the sunlight in during cooler winters Montana State University: Solar Cells Lecture 3: Nature of Sunlight 25 Insolation Montana State University: Solar Cells Lecture 3: Nature of Sunlight 26 Solar Cell Land Area Requirements for the USA’s Energy with Solar PV • 100 miles by 100 miles in Nevada would provide the equivalent of the entire US electrical demand • Distributed (to sites with less sun) it would take less than 25% of the area covered by US roads. Montana State University: Solar Cells Lecture 3: Nature of Sunlight 27 Solar Cell Land Area Requirements for the World’s Energy with Solar PV 6 Boxes at 3.3 TW Each Montana State University: Solar Cells Lecture 3: Nature of Sunlight 28