When two or more atoms really love each other… they bond Chemical Bonds Attractions arising from the sharing or transfer of valence electrons. Bonds can be INTER-molecular or INTRA-molecular Intramolecular: within a molecule Covalent – sharing Ionic – transferring Covalent Bonds Sharing of a pair of valence electrons. 2+ atoms covalently bonded = MOLECULE Pure substances vs. Compounds H2 H2O More on covalence… Electronegativity: attraction of a particular atom for the electrons of a covalent bond. Nonpolar covalent bonds: when electrons share equally Polar covalent bonds: when electrons are not shared equally Ionic Bonds Occurs when there’s an imbalance in electrons When electrons are transferred, ions are formed Types of ions Ions = charged particles Cation = positive ion Break down these ions: Na+ Anion = negative ion Cl- MgO K2O CaCl2 Ionic Compounds = Salts Environmental conditions impact strength of ionic bonds. Dry conditions: Ionic bonds are stronger In water: ions dissociate (water = universal solvent) Weaker Chemical Bonds Hydrogen bonds: Attraction of “charged” hydrogen bonded with another atom to another different atom nearby. Weaker Chemical Bonds Van der Waals Interactions: Electrons distribute unevenly creating slightly positive and negative regions. Molecular Shape and Function Molecular shape dictates their function in ALL of biology! Ex: Proteins, hormone receptors, blockers Chemical Reactions Formation and destruction of chemical bonds are called chemical reactions. Reactants: starting materials Products: materials after chemical conversion Photosynthesis & Cellular Respiration Photosynthesis: 6CO2 + 6H2O C6H12O6 + 6O2 Photosynthesis & Cellular Respiration Photosynthesis: 6CO2 + 6H2O C6H12O6 + 6O2 Cellular Respiration: C6H12O6 + 6O2 6CO2 + 6H2O + ENERGY!!!!! Properties of Water Water Lab – Activity #1 Penny Challenge. Determine how many drops of water you can fit onto the HEADS side of a penny vs. the tails side of a penny. Record data for two trials for each side in your notebook. Leave space for class data before recording information for Challenge #2. Challenge #2: Spread a thin layer of dish soap on top of your penny and try the Penny Challenge again. BEFORE YOU START, write down your hypothesis for what will happen. If dish soap is spread onto the heads/tails side of my penny, the number of drops will... because… Why is water so important? Cells are mostly water (70-95%) Cells are mostly surrounded by water. The Water Molecule POLARITY: Oxygen has a stronger pull of the electrons than the hydrogen atoms. Oxygen – slightly negative at any given time. Hydrogen – slightly positive. Water takes on bent shape. Water molecules can attract each other Because water molecules are charged, they can attract each other or other ions. (Hydrogen Bonds!) COHESION – attraction of water molecules to itself ADHESION – attraction of molecules to other substances. Examples of Forces Surface Tension: A measure of how difficult it is to stretch/break liquid surfaces Capillary Action: Forces that draw water out of the roots of a plant and up the step and leaves. Capillary Action Moderation of Temperature Water can store/release heat without too much change in its own temperature. Thermal energy is a reflection of both the mass and movement of water. Bodies of water have a large mass therefore have high thermal energy! When two temperatures are brought together, they try to reach equilibrium. Measures of Heat Calorie = amount of heat it takes to raise the temperature of 1 g of water 1 degree Celsius. Kilocalorie = 1,000 cal. SPECIFIC HEAT = the amount of heat needed to change 1 g of that substance by 1 degree. Water resists changing temperature. Evaporative Cooling Heat of Vaporization: Quantity of heat a liquid must absorb for 1 g to be converted from liquid to gas. High compared to other liquids. H-bonds?! Evaporative Cooling: As liquid evaporates, it pulls heat away with the vaporized liquid. Remaining liquid is cooler! Water, when it gets chilly! Why do ice cubes float in water? •I C E E X P A N D S W H E N I T F R E E Z E S ! ( 0 - 4 0C ) •T H I S M A K E S I T L E S S D E N S E THAN WATER – SO IT FLOATS! •W H A T I M P A C T D O E S T H I S HAVE ON THE WORLD? SOLUTIONS & SUSPENSIONS MIXTURES – material composed of two or more elements or compounds that are physically mixed but not chemically combined. SOLUTIONS – Homogenous mixture of two or more substances. The dissolving agent is the SOLVENT the dissolved substance is the SOLUTE. SUSPENSIONS – Heterogeneous mixture Dissolving Salts Positively charged H in water surround chlorine anions. Negatively charged O in water surround sodium cations. Polar water molecules form a HYDRATION SHELL. Hydrophilic and Hydrophobic Substances Hydrophilic - <3’s water! Affinity for water, doesn’t necessarily dissolve! Hydrophobic – hates water Hydrogen has had ENOUGH! Hydrogen will leave a water molecule, leaving the electron behind. Hydrogen ion: H+ (a lonely proton). Hydroxide ion: OH- (what H+ left behind!). Hydronium ion: H+ can’t exist on it’s own, it attaches to the other water molecule (H3O+) CONVENTION: H+ represents H3O+ This is RARE 1.0×10−14 moles of ions per LITER of water. BUT, important things happen when the balance between H+ and OH- ions is broken… **Convention** H+ represents H30+ Acids & Bases ACIDS have higher [H+] ions than pure water, pH value is below 7. Examples of Acids Stomach acid – HCl (~1.5) Juices (~3.5) Milk (~6.5) Basic, or alkaline, solutions have lower concentrations of [H+] ions. pH value is above 7. Examples of Bases: Blood (~7.4) Milk of Magnesia (~10.5) Ammonia (~11.5) Bases Some bases are H+ acceptors. Others dissolve to form hydroxide ions [OH-]. BOTH of these will reduce overall [H+]. The pH Scale pH = Potential Hydrogen Indicates concentration of H + ions in solution [H+] If [H+] = [OH-] the solution is neutral (like water!) pH = -log[H+] Change in pH is TENFOLD! BUFFERS pH of our body must stay around 6.5-7.5; certain systems have a smaller range of acceptable pH. BUFFERS – Weak acids or bases that can prevent sharp changes in pH. Accepts or donates H+ ions. Example – Carbonic Acid Bicarbonate in Blood. Acidification! Burning of fossil fuels creates an abundance of carbon compounds in the atmosphere. Reaction with water ACIDIC! 25% of the CO2 is absorbed into the ocean and impacts the marine ecosystems.