14,100 7,220,000 “It would take an elephant, balanced on a pencil, to break through a sheet of graphene the thickness of Saran Wrap.” NSF-funded researchers Richard Smalley, Robert Curl (both of Rice http://nanularity.com/default.aspx University) and Harry Kroto (University of Sussex, UK; non-NSF funded) shared the 1996 Nobel Prize in Chemistry for the discovery of "buckminsterfullerene." James yHeath, then a graduate student at a1 Rice and now a faculty member at a2 UCLA, also played a key role. x Single-Walled Carbon Nanotubes Real time Nanotube length = 10 mm Size Matters Bulk Gold = Yellow Nanogold = Red Types of Nanomaterials Gold nanoshell Why is it so exciting? Human Health Gold nanoshells for cancer therapy Live (green)/Dead (red) assays shows where immunotarged gold nanoshells and a near infrared laser destroyed prostate cancer cells Environmental Health Nanorust to clean drinking water • http://science.discovery.com/videos/brinkpackage-nano-water.html Optical vs. Electron Microscopy Radiolarian (amoeboid protozoa) Optical microscopy image Electron microscopy image Why do electron beams give superior resolution to light rays? Shorter wavelength! Timeline of Microscopy c. 1625 1938 SEM AFM 1981 1986 http://www.nobel.se/physics/educational/microscopes/powerline/index.html STM: Manipulating Atoms Iron atoms on Copper surface http://www.almaden.ibm.com/vis/stm/library.html#ref2 l Scanning Tunneling Microscopy Nobel Laureates (1986) Heinrich Rohrer and Gerd Binnig http://www.nobel.se/physics/educational/microscopes/scanning/index.html http://www.almaden.ibm.com/vis/stm/library.html#ref2 l http://www.almaden.ibm.com/vis/stm/library.html#ref2 l http://www.almaden.ibm.com/vis/stm/library.html#ref2 l http://www.nanotech-now.com/images/Art_Gallery/ASAFM.jpg What is Nanotechnology? Nanotechnology is the creation of functional materials, devices, and systems through control of matter on the nanometer length scale, exploiting novel phenomena and properties (physical, chemical, biological) present only at that length scale. “If I were asked for an area of science and engineering that will most likely produce the breakthroughs of tomorrow, I would point to nanoscale science and engineering.” Neal Lane University Professor, Rice University Former NSF Director Assistant to President Clinton for Science and Technology http://www.kqed.org/quest/television/view/189?gclid=CJnCjsCu xJ0CFSENDQodDmMxrQ Scanning Electron Microscopy http://mse.iastate.edu/microscopy/whatsem.html http://mse.iastate.edu/microscopy/path2.html http://www.mos.org/sln/sem/seminfo.html Transmission Electron Microscopy (magnifies up to 50 million times [HRTEM]) http://www.nobel.se/physics/educational/microscopes/tem/index.html CdSe quantum dot, Colvin Trina Mandel and the TEM 300 nm Hollow colloidal ellipses, Colvin