Personal Profile Name Birth date What was your favorite experience this summer? How do you like to spend your time? Who do you like to hang out with? What activities or hobbies do you do? What are your parent professions? What do you hope to learn in Chemistry? Student Email: Parent Email: Vocabulary 1 Scientific method, observation, data, hypothesis, independent (manipulated) variable, dependent (responding) variable, controlled variable, controlled experiment, scientific law, theory, mass, volume, precision, accuracy, infer, conclusion, analyze, matter, element, mixture, atom, molecule, homogeneous, heterogeneous, solution, colloid, suspension, metals, non-metals, compound, ionic compound, covalent compound, metal, non-metal, metalloid, solute, solvent, significant figure Vocabulary of the Week Matter Pure substance Mixture Element Atom Compound Solution Homogeneous solution Heterogeneous solution Solvent Solute Colloid Suspension Dilute solution Concentration solution Polar solvent Non-polar solvent Metal Non-metal Metalloid Malleable Luster Brittle Ductile Tensile strength Decant Centrifuge Filter Chromatography Distillation Miscible Residue Group period Unit 1 The Nature of Chemistry Chapters 1 and 2 Chemistry and Matter Science Science is trying to explain the world around us Science is a way of thinking “Science is a system of knowledge based on facts or principles” Pattern Puzzles – Experimental Method A) B) C) D) E) F) G) ottffentettff mirror numbers roses & petals Grandma likes Coffee, but she doesn’t like tea Days in the months of the year Next Box? 1st Letters of Months, of 9 Planets Branches of Science Science Biological Science Physical Science Earth Science Branches of Science Science Biological Science Physical Science Zoology Botany Ecology Science of living things Earth Science Branches of Science Science Biological Science Physical Science Earth Science Physics Science of matter and energy Chemistry Branches of Science Science Biological Science Physical Science The systems of the earth Earth Science Geology Meteorology Astronomy Science Skills Observe gathering of information by using your five senses Infer applying reason to explain an observation Observations Qualitative – describe with words Quantitative – describe with numbers Hot , red, large 100° , 10 meters, 3.46 grams Scientists prefer quantitative Easy to agree upon No personal bias Scientific Method Notes (1 of 3) 1. Observations – sensed, measured 2. Question – How explain observations? 3. Hypothesis – Proposed explanation that must be testable, should be able to predict behavior. if (change, manipulated variable), then (responding variable) statement because …. 4. Experiment – test 1 factor at a time, record procedures used and results observed Controlled Experiments (2 of 3) Controlled experiments insure that scientists can make clear interpretations of results. Purposefully change 1 factor at a time – the independent (manipulated) variable. Measure 1 key effect – the dependent (responding) variable. Graphs reflect the experimental variables: independent = x, dependent = y All other variables are kept constant (controlled) to eliminate their possible influence on the results. Example: Chocolate causes zits? or testing the effectiveness of a new drug on mice? Scientific Method (3 of 3) 5. Data – collected measurements & observations 6. Conclusions – interpretation of results to confirm or reject experimental hypothesis. (Use #s as examples) 7. Theory (mistakenly used in place of hypothesis) – an explanation of a wide range of observations well supported by experimental results. Examples? Evolution, Relativity, Quantum, Germ, Cell 8. Scientific Law – a description of common predictable behavior, not an explanation. Examples? Newton’s 3 Laws of Motion, Law of Gravity, Laws of Thermodynamics Scientific Method The scientific method is the systemized testing of ideas, inferences, predictions, and hypotheses. A way of thinking about and solving problems It is a logical method You do it all the time 10 Criteria of Science 1. 2. 3. 4. 5. Science is logical and rational. Science makes well-defined claims. Scientific hypotheses are testable. Scientific experiments are repeatable. Science requires that claims be examined by peers. 10 Criteria of Science (2 of 2) 6. Science views unexplained gaps in theories with suspicion. 7. Science requires caution in examining evidence. 8. Science requires objectivity. 9. Science does not accept coincidence as proof. 10. Science does not accept anecdotal evidence as proof. Scientific Theory A reasoned explanation tested by many observations and experiments Tells why things are Three things Must explain clearly and simply Must be repeatable Must be able to make predictions Theories can be changed or modified by new evidence Scientific Laws Describe what happens Quantitative – use numbers and equations to describe Often equations are part of the law Mathematics is a universal language Law vs. Theory Law Describes how Summarizes observations Usually an equation Theory Explains why Agrees with observations Predicts new discoveries Chemistry is… …the study of the composition, structure, and properties of matter and the changes it undergoes C2H5OH + 3 O2 2 CO2 + 3 H2O + Energy Reactants Products Energy Energy is the ability to do work. Work - cause a change or move an object. Many types- all can be changed into the other. Heat- the energy that moves because of a temperature difference. Chemical energy- energy released or absorbed in a chemical change. Electrical energy - energy of moving charges Types of energy Kinetic Energy is energy of motion KE = ½ m v 2 Potential Energy is stored energy or energy of position Batteries (chemical potential energy) Spring in a watch (mechanical potential energy) Water trapped above a dam (gravitational potential energy) Measuring Energy Calorie (cal) – one calorie is the amount of heat needed to raise the temperature of 1 gram of water by 1 degree Celsius. Joule (J) – metric system unit for energy 1 cal =4.184 Conservation of Energy The Law of Conservation of Energy states that energy can be neither created or destroyed in ordinary changes (not nuclear), it can only change form. Kinetic Energy “HOT” Fast Kinetic Energy (KE) = ½ m v2 *Vector = gives direction and magnitude “COLD” Slow Temperature Scales Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 136 273 K Measuring Temperature Kelvin starts at absolute zero (-273 º C) degrees are the same size K -273 = C C + 273 = K Kelvin is always bigger. Kelvin can never be negative. Wednesday, September 15, 2010 Give three examples of kinetic energy? Give three examples of potential energy? What is the metric system unit for temperature? Energy? What is absolute zero? Matter Chemistry is……the study of the composition, structure, and properties of matter and the changes it undergoes Matter is anything that has mass and occupies space Mass is a measure of the amount of matter Types of Matter Pure Substance- a single element or compound Mixture- contain more than one kind of matter Building Blocks of Matter Atom The smallest unit of an element that maintains the properties of that element Element A pure substance made of only one kind of atom Building Blocks of Matter Compound A substance that is made from the atoms of two or more elements that are chemically bonded Sucrose – C12H22O11 Sucrose is also known as table sugar, and is used to make Gummy Bears! Physical Properties A characteristic that can be observed or measured without changing the identity of the substance Physical Properties Extensive Property Dependent upon the amount of matter present Examples: volume, mass, and energy content Intensive Property Independent of the amount of matter present Examples: melting point, boiling point, density States of Matter States of Matter Solids very low kinetic energy particles vibrate but can’t move around Retains size and shape Definite shape and volume States of Matter Liquids low kinetic energy particles can move around but are still close together Takes the shape of its container definite volume States of Matter Gases high KE - particles can separate and move throughout container Easily compressed No definite shape No definite volume States of Matter Plasma very high KE - particles collide with enough energy to break into charged particles (+/-) gas-like, variable shape & volume stars, fluorescent light bulbs, CRTs Physical Change A change in a substance that does not involve a change in the identity of the substance. Examples: Phase Changes – boiling point, melting point, freezing point A substance dissolving in another substance solubility Separation Lab Simulation How do you separate the following mixture based on the physical properties: Sand, salt, iron filings, waxy flakes, sawdust A. List properties of each of the substances B. Create a flow chart showing how you would separate these items sequentially & return them to the dry solid state. Chemical Properties Relates to a substances ability to undergo change that transform it into a different substance Ability to : combust, oxidize, neutralize, etc Chemical Change A change in which one or more substances are converted into different substances. Evidence of Chemical Change: Heat and light Change in color Production of gas Precipitation of a solid Physical & Chemical Quiz Stage Breathe in O2 & CO2 out Shower steam on mirror Boiled water at 100C Stirred cocoa mix Digested cereal Brushed teeth Lit bunsen burner Marker ink on board Change (P or C) Specific property of substance Monday, September 20, 2010 Draw pictures of the 3 states of matter? Identify the process which describe each change in state of matter? How is matter separated? What are the key groupings? Properties of Matter Classification of Matter (elements video) Matter Element Compounds Atoms Mixtures Molecules Metals Non-metals Ionic Homogeneous Covalent Solutions Suspension Metalloids Solute Heterogeneous Solvent Colloid Classification of Matter Pure Substance Fixed Composition A single compound or element Mixtures A blend of two or more kinds of matter, each with its own properties Components of mixtures can be separated using physical properties Can be heterogeneous or homogeneous Mixtures Homogeneous Mixture – two or more substances that are evenly distributed Solution Solute – matter which is present in smaller quantity Solvent – matter which is present in highest quantity Heterogeneous solution – unevenly distributed matter Colloid – does not settle over time Suspension – settles over time Classification of Matter Tuesday, September 21, 2010 Classify each of the following kinds of matter: Obsidian Marble Granite Asprin Tungsten Compound or Mixture Compound Mixture One kind of piece- More than one kind - Molecules Molecule or atoms Making is a Making is a chemical change physical change Only one kind Variable composition Chromatography Lab (2/2?) Measure your chromatographs Distance (start to end of each color) Distance (start to end of solvent front) Calculate your Rf value Rf value = Distance color moved Distance to solvent front Compare your Rf values for each solvent. Do any two solvents have the same Rf value? Explain. How could you prove that single colors from different solvents are the same compound? Separation of a Compound The Electrolysis of water Compounds must be separated by chemical means. With the application of electricity, water can be separated into its elements Reactant Water H2O Products Hydrogen + Oxygen H2 + O2 Separation of a Mixture The constituents of the mixture retain their identity and may be separated by physical means. Methods of Separating Mixtures Magnet Filter Decant Evaporation Centrifuge Chromatography Distillation Filtration separates a liquid from a solid Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 40 Setup to heat a solution Zumdahl, Zumdahl, DeCoste, World of Chemistry 2002, page 42 A Distillation Apparatus Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 282 Centrifugation Spin sample very rapidly: denser materials go to bottom (outside) Separate blood into serum and plasma Serum (clear) Plasma (contains red blood cells ‘RBCs’) Check for anemia (lack of iron) AFTER Before Serum Blood RBC’s A B C The Periodic Table Group or family Period Periodic Table Groups or Families Vertical columns These elements have similar chemical properties Periods Horizontal rows Metals and Nonmetals A zigzag line separates the metals from the nonmetals Metalloids, which straddle the line, are considered non-metals Lanthanide and Actinide Series Metals Properties of Metals Metals are good conductors of heat and electricity Metals are malleable Metals are ductile Metals have high tensile strength Metals have luster Examples of Metals Potassium, K reacts with water and must be stored in kerosene Copper, Cu, is a relatively soft metal, and a very good electrical conductor. Zinc, Zn, is more stable than potassium Mercury, Hg, is the only metal that exists as a liquid at room temperature Properties of Nonmetals Carbon, the graphite in “pencil lead” is a great example of a nonmetallic element. Nonmetals are poor conductors of heat and electricity Nonmetals tend to be brittle Many nonmetals are gases at room temperature Examples of Nonmetals Sulfur, S, was once known as “brimstone” Graphite is not the only pure form of carbon, C. Diamond is also carbon; the color comes from impurities caught within the crystal structure Microspheres of phosphorus, P, a reactive nonmetal Properties of Metalloids Metalloids straddle the border between metals and nonmetals on the periodic table. They have properties of both metals and nonmetals. Metalloids are more brittle than metals, less brittle than most nonmetallic solids Metalloids are semiconductors of electricity Some metalloids possess metallic luster Silicon, Si – A Metalloid Silicon has metallic luster Silicon is brittle like a nonmetal Silicon is a semiconductor of electricity Other metalloids include: Boron, B Germanium, Ge Arsenic, As Antimony, Sb Tellurium, Te Which is it? Mixture Element Compound Measuring Skills Interpreting Scales – May be 1/10ths, 1/5ths, 1/4ths, 1/2s, 1s, 2s, 5s, 10s Estimating Between the Lines – The last digit of your measurement is estimated 1 digit beyond what the hashmarks give. Parallax & Meniscus Estimating Between the Lines You are expected to estimate 1 digit beyond what is given by the lines. The estimate will have an understood uncertainty of +/-1 of the estimated last digit. A final zero is used to indicate that the measurement is right on the line. Odd scales are estimated to round #s in between lines with adjusted uncertainty. Parallax & Meniscus The meniscus is the curvature of water as it creeps up the sides. Always look for the bottom of the meniscus. Parallax demo with fingers vs stars. Parallax causes error when viewing is not straight on. (Fuel gauge) Graduated cylinders have hexagonal bases, plastic bumpers & circles (for avoiding parallax errors) Parallax & Meniscus http://www.wisc-online.com/objects/index_tj.asp?objID=GCH302 The Metric System A metric unit has two parts. A prefix and a base unit. prefix tells you how many times to divide or multiply by 10. Nature of Measurement Measurement - quantitative observation consisting of 2 parts Part 1 - number Part 2 - scale (unit) Examples: 20 grams 6.63 x 10-34 Joule seconds The Fundamental SI Units (le Système International, SI) Physical Quantity Mass Name kilogram Abbreviation kg Length meter m Time second s Temperature Kelvin K Electric Current Ampere A mole mol candela cd Amount of Substance Luminous Intensity Metric Units UNIT meter liter second joule gram celsius Kelvin Mole Molarity (Abbreviation) (m) (L) (s) (J) (g) (oC) (K) (mol) (M) QUANTITY distance volume time heat mass temperature absolute temperature substance concentration Metric Prefixes Prefix nano micro milli centi deci Deca Hecto Kilo Mega Giga Sym N m m c d D H K M G Size Billionth Millionth Thousandth Hundredth Tenth Ten x Hundred x Thousand x Million x Billion x Decimal .000000001 .000001 .001 .01 .1 10 100 1000 1000000 1000000000 Power 10-9 10-6 10-3 10-2 10-1 101 102 103 106 109 Examples of Common Metric Units Metric Unit Liter milliliter Millimeter centimeter Meter kilometer Gram kilogram Common Example 1 L bottle of pop half teaspoon Thickness of dime Width of pinky nail Little more than a yard 2.5 x around track Paperclip, 2 aspirin (500mg) Baseball bat (2.2 pounds) Quiz – Units & Prefixes 1. nanosecond Billionth of a time unit 2. kiloJoule 1000 units of heat 3. Gigameter Billion units of distance 4. Microliter Millionth of a volume unit 5. Centimole Hundredth of a unit of substance Converting k h D d c m how far you have to move on this chart, tells you how far, and which direction to move the decimal place. The box is the base unit, meters, Liters, grams, etc. Conversions k h D Change 5.6 m to millimeters starts at the base unit and move three to the right. move the decimal point three to the right 56 00 d c m Conversions k h D d c convert 25 mg to grams convert 0.45 km to mm convert 35 mL to liters It works because the math works, we are dividing or multiplying by 10 the correct number of times. m Conversion Practice Kilo1000 units To convert to a smaller unit, move the decimal point to the right or multiply. Hecto 100 Dekaunits 10 units Base Unit Deci0.1 units To convert to a larger unit, move the decimal point to the left or divide. Centi0.01 Milliunits 0.001 units Conversions k h D Change 5.6 km to millimeters d c m Metric Units •Convert 98 milligrams to grams. 98 mg 10-3 g 1 mg = 0.098 g 025 Metric Units •Convert 1.025 kilometers to meters. km 103 m 1 km = 1.025 x 103 m .00 Metric Units •Convert 52.00 microliters to liters. µl 10-6 l 1 µl = 5.200 x 10-5 l Metric Units •Convert 0.250 milliliters to microliters. 0.250 ml 10-3 l 1 ml 1 µl 10-6 l = 2.50 x 102 µl Multistep & Dimension Conversions 1. 2. 3. 4. 869ft = ?m 1. 2.5 yd2 = ?m2 0.63tons = ?oz 2. 47.2L = ?cm3 7960oz = ?kg 3. 3.6ft3 = ?m3 427,000in = ?km 4. 83,000ml = ?in3 Unit Conversions Quiz 1. 64 oz = ?g 2. 4,693mm = ?ft 3. 327in3 = ?L Quiz - October 05, 2010 Convert the following metric units. 5.79 centimeters to meters 7.5 Megaliters to liters 8.94 centigrams to kilograms 34.98 milligrams to kilograms 0.093 micrograms to milligrams Uncertainty in Measurement A digit that must be estimated is called uncertain. A measurement always has some degree of uncertainty. Why Is there Uncertainty? Measurements are performed with instruments No instrument can read to an infinite number of decimal places Which of these balances has the greatest uncertainty in measurement? Significant Figures (1 of 6) A. Uncertainty We will assume an uncertainty of +/- 1 of the last significant figure. Industry operates on an assumption of +/- 0.5 of the last significant figure unless otherwise noted. Significant Figures (2 of 6) A. Uncertainty Value Dodge 3.8L F100 351 cu. in. Mazda B2200 (Manual) 2159 cu.in. 21.59 cm 2.159 cm 21,590 cm 215.90 cm 21,590,000 m Uncertainty +/- .1 +/- 1 +/- 100 +/- 1 +/- .01 +/- .001 +/- 10 +/- .01 +/- 10,000 Differences Accuracy can be true of an individual measurement or the average of several. Precision requires several measurements before anything can be said about it. examples Precision and Accuracy Accuracy refers to the agreement of a particular value with the true value. Precision refers to A) the degree of agreement among several measurements made in the same manner. B) the level of detail in a measurement. Neither accurate nor precise Precise but not accurate Precise AND accurate Let’s use a golf anaolgy Accurate? Precise? No Yes Accurate? Yes Precise? Yes Precise? Accurate? No Maybe? Accurate? Precise? Yes We cant say! Types of Error Random Error (Indeterminate Error) measurement has an equal probability of being high or low. Systematic Error (Determinate Error) Occurs in the same direction each time (high or low), often resulting from poor technique or incorrect calibration. Rules for Counting Significant Figures - Details Nonzero integers always count as significant figures. 3456 has 4 sig figs. Significant Figures (3 of 6) B. Atlantic – Pacific Rule (page 26) Pacific Rule If the decimal is present, then count from the Pacific (left) side. Start with the 1st non-zero & every number after is also significant. Atlantic Rule If the decimal is absent, then count from the Atlantic (right) side. Start with the 1st non-zero & every number after is also significant. Sig Fig Practice #1 How many significant figures in each of the following? 1.0070 m 5 sig figs 17.10 kg 4 sig figs 100,890 L 5 sig figs 3.29 x 103 s 3 sig figs 0.0054 cm 2 sig figs 3,200,000 2 sig figs Significant Figures (3 of 4) C. Maximum & Minimum Areas 7.6 cm+/-.1 3.4 cm+/-.1 Area A(max) A(mean) A(min) Area = length x width = 7.7cm x 3.5cm = 26.95cm2 = 7.6cm x 3.4cm = 25.84cm2 = 7.5cm x 3.3cm = 24.75cm2 = 25.84cm2+/-1.11 = 26cm2 Significant Figures (6 of 6) D. Rounding Adding & Subtracting Round to the greatest uncertainty (least precision) used in the problem. Ex1: 29,000 gal + 1.4 gal = 29,000 gal Ex2: 44.76ml – 31.4ml = 13.4ml Multiplying & Dividing Round to the least sig figs used in the problem. Ex1: 2.24g/7ml = 0.3 g/ml Ex2: (4.6m)(3.25m) = 15 m2 Mathematical Operations Multiplication and Division: # sig figs in the result equals the number in the least precise measurement used in the calculation. 6.38m x 2.0m = 12.76m2 13m2 (2 sig figs) Rules for Significant Figures in Mathematical Operations Addition and Subtraction: The number of decimal places in the result equals the number of decimal places in the least precise measurement. 6.8 + 11.934 = 18.734 18.7 (3 sig figs) Sig Fig Practice #2 Calculation Calculator says: Answer 3.24 m x 7.0 m 22.68 m2 100.0 g ÷ 23.7 cm3 4.219409283 g/cm3 0.02 cm x 2.371 cm 0.04742 cm2 0.05 cm2 710 m ÷ 3.0 s 236.6666667 m/s 240 m/s 1818.2 lb x 3.23 ft 5872.786 lb·ft 5870 lb·ft 1.030 g ÷ 2.87 mL 2.9561 g/mL 2.96 g/mL 23 m2 4.22 g/cm3 Sig Fig Practice #3 Calculation Calculator says: Answer 3.24 m + 7.0 m 10.24 m 10.2 m 100.0 g - 23.73 g 76.27 g 76.3 g 0.02 cm + 2.371 cm 2.391 cm 2.39 cm 713.1 L - 3.872 L 709.228 L 709.2 L 1818.2 lb + 3.37 lb 1821.57 lb 1821.6 lb 2.030 mL - 1.870 mL 0.16 mL 0.160 mL Significant Figures Quiz How many sig figs? 1) 720,900kg Round appropriately 5) 3.65g + 3.964g 2) 629.0m 6) 7180m – 62m 3) .00076mg 7) 8.269m/240s 4) .390s 8) (.039m)(4.260m) Significant Figures Quiz 1. 2. 3. 4. How many sig figs? 29.2 m 0.0036g 36,000cm .00740L 1. 2. Solve & round: 720m -84.23m 8.63m/800s Significant Figures Quiz How many sig figs? 1) 720,900kg 4 sf 2) 629.0m 4 sf 3) .00076mg 2 sf 4) .390s 3 sf Round appropriately 5) 3.65g + 3.964g 7.61g 6) 7180m – 62m 7120m 7) 8.269m/240s 0.034m/s 8) (.039m)(4.260m) .17m2 Rules for Counting Significant Figures - Details Zeros Leading zeros do not count as significant figures. - 0.0486 has 3 sig figs. Rules for Counting Significant Figures - Details Zeros - Captive zeros always count as significant figures. 16.07 has 4 sig figs. Rules for Counting Significant Figures - Details Zeros Trailing zeros are significant only if the number contains a decimal point. 9.300 has 4 sig figs. Rules for Counting Significant Figures - Details Exact numbers have an infinite number of significant figures. 1 foot = 12 inches, exactly by definition. Wednesday, September 29, 2010 DMA 1. 2. 3. 4. 5. 6. 7. Convert 5.7 cm to kilometers. Convert 986 µg to grams. Convert 893 kilograms to milligrams. Convert 68.58 dg to megagrams. Convert 986 µl to liters Convert 83 grams to nanograms. Convert 5 gigabytes to kilobytes Thursday, September 30, 2010 DMA 1. 2. 3. 4. 5. Convert 6.902 milligrams to grams Convert 890,029 seconds to nanoseconds Convert 9.30 joules to kilojoules. Convert 495 kilopascals to micropascals. Convert 293 Kelvin to Celcius Scientific Notation: A method of representing very large or very small numbers in the form: M x 10n M is a number between 1 and 10 n is an integer 2 500 000 000 . 9 8 7 6 5 4 3 2 1 Step #1: Insert an understood decimal point Step #2: Decide where the decimal must end up so that one number is to its left Step #3: Count how many places you bounce the decimal point Step #4: Re-write in the form M x 10n 2.5 x 9 10 The exponent is the number of places we moved the decimal. 0.0000579 1 2 3 4 5 Step #2: Decide where the decimal must end up so that one number is to its left Step #3: Count how many places you bounce the decimal point Step #4: Re-write in the form M x 10n 5.79 x -5 10 The exponent is negative because the number we started with was less than 1. PERFORMING CALCULATIONS IN SCIENTIFIC NOTATION ADDITION AND SUBTRACTION Review: Scientific notation expresses a number in the form: Mx 1 M < 10 n 10 n is an integer 4 x 106 + 3 x 106 6 7 x 10 IF the exponents are the same, we simply add or subtract the numbers in front and bring the exponent down unchanged. - 6 4 x 10 3 x 106 1 x 106 The same holds true for subtraction in scientific notation. 6 10 4x 5 + 3 x 10 If the exponents are NOT the same, we must move a decimal to make them the same. 5 6 40.0 4.00 x 10 + 3.00 x 5 10 5 10 43.00 x = 4.300 x 6 10 Student A To avoid this NO! problem, move Is this good the decimal on scientific the smaller notation? number! 6 10 4.00 x 6 5 .30xx10 10 + 3.00 4.30 x 6 10 Student B YES! Is this good scientific notation? A Problem for you… -6 10 2.37 x -4 + 3.48 x 10 Solution… -6 -6 -4 002.37 2.37xx10 0.0237 10 x 10 -4 + 3.48 x 10 -4 3.5037 x 10 Which is heavier? it depends Volume and Density Relationship Between Volume and Density for Identical Masses of Common Substances Substance Cube of substance (face shown actual size) Mass (g) Volume (cm3) Density (g.cm3) Lithium 10 19 0.53 Water Aluminum 10 10 1.0 10 3.7 2.7 10 0.58 Lead 11.4 Density of Some Common Substance Density of Some Common Substances Substance Density (g / cm3) Air Lithium Ice Water Aluminum Iron Lead Gold *at 0oC and 1 atm pressure 0.0013* 0.53 0.917 1.00 2.70 7.86 11.4 19.3 Density D = M V M M = DxV ass D ensity V olume V = M D Calculating A piece of wood has a mass of 11.2 g and a volume of 23 mL what is the density? A piece of wood has a density of 0.93 g/mL and a volume of 23 mL what is the mass? Calculating A piece of wood has a density of 0.93 g/mL and a mass of 23 g what is the volume? Floating Lower density floats on higher density. Ice is less dense than water. Most wood is less dense than water. Helium is less dense than air. A ship is less dense than water. Density of water 1 g of water is 1 mL of water. density of water is 1 g/mL at 4ºC otherwise it is less Temperature vs Density (1 of 4) Factor Effect Temperat Increasing ure temperature decreases density Volume expands & contracts Application Hot air & water rise while cold stuff sinks. Convection currents form in the earth, oceans & atmosphere Materials vs Density (2 of 4) Material Each material has its own distinct density Density can be used to ID materials. Materials can be separated by density as they float or sink. Concentration vs Density (3 of 4) Factor Effect Concent Increasing ration concentration increases density Application Salt water sinks below fresh water in oceans & estuaries. Melted ice floats on top of beverages. Polluted waters may sink to bottom. Size vs Density (4 of 4) Size Size has no effect on density Small samples can be used to characterize large quantities. Heat a form of energy Definitions Temperature is a measure of the average kinetic energy of the particles in a sample of matter. A joule is the SI unit of heat as well as all other forms of energy. Heat can be thought of as the energy transferred between sample of matter because of a difference in their temperatures. Units for Measuring Heat The Joule is the SI system unit for measuring heat: kg m 1 J N m 2 s 2 The calorie is the heat required to raise the temperature of 1 gram of water by 1 Celsius degree 1 calorie 4.18 Joules A calorimeter is a instrument that measures the energy absorbed or released as heat in a chemical or physical reaction. Specific Heat The amount of heat required to raise the temperature of one gram of substance by one degree Celsius. Calculations involving Specific Heat cp = ___q__ m x T OR q = cp x m x T cp = Specific Heat q = Heat lost or gained T = Temperature change Table of Specific Heats Simple Problems What is the specific heat of a substance that absorbs 2.5 x 103 joules of heat when a sample of 1.0 x 104 g of the substance increases in temperature from 10.0C to 70.0C? Problems It takes 24.3 calories to heat 15.4 g of a metal from 22 ºC to 33ºC. What is the specific heat of the metal? Iron has a specific heat of 0.11 cal/gºC. How much heat will it take to change the temperature of 48.3 g of iron by 32.4ºC? A 1.0 kg sample of metal with a specific heat of 0.50 KJ/KgC is heated to 100.0C and then placed in a 50.0 g sample of water at 20.0C. What is the final temperature of the metal and the water? 3) A 2.8 kg sample of a metal with a specific heat of 0.43KJ/KgC is heated to 100.0C then placed in a 50.0 g sample of water at 30.0C. What is the final temperature of the metal and the water? Graphs Circle graphs – compare parts in a whole Bar graphs – compare quantities Line graphs – compare sets of data, show change and patterns over time. 100 80 East 60 West 40 North 20 0 1st Qtr 2nd Qtr 3rd Qtr 4th Qtr Proportions Direct Proportion y x y x Inverse Proportion 1 y x y x Direct Proportions The quotient of two variables is a constant As the value of one variable increases, the other must also increase As the value of one variable decreases, the other must also decrease The graph of a direct proportion is a straight line Inverse Proportions The product of two variables is a constant As the value of one variable increases, the other must decrease As the value of one variable decreases, the other must increase The graph of an inverse proportion is a hyperbola High Quality Graphing Make each graph at least ½ page large. Use a ruler or straight edge to make it neat. Place the manipulated variable on the x-axis. Spread the range of data as far as possible. Use logical spacing between numbers on axis. Use hashmarks to clearly locate numbers. Title the axis with quantity measured and (units in parentheses) Accurately place each data point. Use a best fit line or curve to show trend. Title the graph with Responding vs Manipulated in Context Features of Quality Graphs Fills at least half of a page. Manipulated variable on X & responding on Y axis. Neatly constructed with straight edges. Hash marks are evenly spaced. Hash marks use round numbers and are spaced logically for easy estimation in between. X & Y Axes labeled with quantities and units in parentheses. Title written as RV(Y) vs. MV(X) in the appropriate context. Data points are accurately plotted. Best fit line or curve is used to characterize pattern of data. Joke of the Day A group of organic molecules were having a party, when a group of robbers broke into the room and stole all of the guest's joules. A tall, strong man, armed with a machine gun came into the room and killed the robbers one by one. The guests were very grateful to this man, and they wanted to know who he was. He replied: My name is BOND, Covalent Bond.