14/15 Semester 2
Physical Chemistry
(TKK-2446)
Instructor: Rama Oktavian
Email: rama.oktavian86@gmail.com
Office Hr.: M-F 13.00 – 15.00
Introduction
 Find me on:
/rama.oktavian
Rama Oktavian
+6285748298891
Lecturer’s blog
http://oktavianrama.lecture.ub.ac.id/
Introduction
 Based on study guide
 4 credits – compulsory :
- 3 credits class, 1 credit laboratory
– Allowed :
Introduction
– Not Allowed :
Academic misconduct
University Rule:
Come to class minimum 80% during one semester meeting or you will
miss FINAL EXAM
Objectives
– Student will be able to understand physical
chemistry concepts: properties of substances.
– Student will be able to understand basic concept
in 1st law thermodynamics and its application in
chemical reaction.
– Student will be able to understand basic concept
in phase equilibrium
Course Contents
Week
1.
Content
Introduction
Sub content


2-3
4.
5-6
The properties of
gas I

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Solid and liquid
properties



Energy and 1st
law
thermodynamics






Introduction to course rule and
objectives.
Course grading system.
Ideal gas, Boyle, and Charles law
Intensive and extensive properties
Equation of state (brief review)
Ideal gas properties
Gas Mixtures: Dalton’s law and Partial
Pressure
Condensed phase
Properties of liquid
Thermal compressibility and volume
expansivity
Vapor pressure
Thermodynamic terms
Heat and work
1st law thermodynamics basic concept
Maximum and minimum work
Change in energy
Course Contents
Week
5-6
7
Content
Energy and 1st law
thermodynamics
(cont’d)
Sub content




Phase equilibrium 
I: Simple system 




8
Midterm exam
9
Phase equilibrium II: Solution
-
Application of 1st law
thermodynamics
Thermochemistry
Standard enthalpy change
Hess’ law
Equilibrium condition
Phase stability of pure substance
P-T diagram for pure substance
(phase diagram)
The Clayperon equation for vapor
pressure
Phase rule
Course material week 1 - 6
Ideal solution
Binary solution
P-x diagram
T-x diagram
Course Contents
Week
Content
Sub content
10.
Phase equilibrium

II: Solution (cont’d) 

11-12
Phase equilibrium in 
condensed phase


Phase equilibrium in 
condensed phase

(cont’d)


Fractional distillation
Azeotrope
Henry’s law and the solubility of
gases
Liquid-liquid equilibria (2components)
Liquid-liquid equilibria (3components)
Ternary diagrams
Solid-liquid equilibrium
Liquid-solid phase diagram
Eutectic point
Salting out
15
Review

Course review
16
Final exam

Course materials week 9-15
13-14
References
Text book
 Castellan, G.W., 1983. Physical Chemistry, Addison Wesley Publishing
Company
Additional references:
 P. Atkins, J. De Paula. 2006. Physical Chemistry 8th ed. W. H. Freeman and
Company, New York.
 Maron, S. H, and Lando, J. B., Fundamentals of Physical Chemistry, Mac
Millan Publishing Co. Inc., New York., 1975
 Levine, I., Physical Chemistry, Mc Graw Hill, 6th ed., 2008
Laboratory
Content
Introduction to
laboratory
Properties of
substances
1st law
thermodynamics
Sub content







Laboratory apparatus and
instrumentation principle, chemicals
MSDS (material safety datasheets)
Laboratory safety
Density measurement
Molecular mass determination by gas
density measurement
Enthalpy-concentration diagram
Heat of combustion of alcohol chains
Heat of netralization
Grading system
Q1 / T1
Q2 / T2
20 %
Laboratory
40 %
Final Exam
40 %