Fire Safety Engineering & Structures in Fire Workshop at Indian Institute of Science 9-13 August, 2010 Bangalore India Fundamentals of Fire Dynamics Session JT3 to JT8 Organisers: CS Manohar and Ananth Ramaswamy Indian Institute of Science Speakers: Jose Torero, Asif Usmani and Martin Gillie The University of Edinburgh Funding and Sponsorship: Evacuation te = tde + tpre+ tmov ♦ ♦ ♦ ♦ te – total egress time tde – detection time tpre – pre-movement time tmov – movement or displacement time Movement ♦ Egress is formulated on the basis of displacement velocities V [m/seg] 1 [m/seg] D [people/m2] Movement time(tmov) ♦ Calculations are based on empirical data (SFPE Handbook of Fire Protection Engineering) Pre-Movement (tpre) ♦ Purely statistical ♦ Large error bars ♦ Could potentially be the longest time Detection time (tde) ♦ Calculated as a function of: – Technology used – Growth of the fire – Compartment geometry Detection ♦ Obvious alarm mechanism ♦ Types of detectors: – Smoke detectors (ionization, photoelectric) – CO Detectors – Temperature detectors – Multiple inputs (Artificial Intelligence) – etc. Movement time ♦ Empirical results are available for: – Doors: (q) Personas/m.seg – Act like valves Q= w.q • Where w is the width of the door and Q the total flow rate – – – – Stairs: (q) Personas/m.seg – Act like pipes Ramps: (q) Personas/m.seg – Act like pipes Corridors: (q) Personas/m.seg – Act like pipes Open spaces: (V) velocity in m/s as a function of the density (N – people/m2) – Etc. Simple Systems ♦ Egress time is the displacement time + time to go through a door: Required Safe Egress Time (RSET) ♦ Untenable conditions give the Available Safe Egress Time (ASET) ♦ Codes transform these times into a maximum displacement distance + a required minimum door width Maximum Egress Distance ♦ Egress Time (te) (RSET) te= td + tp ♦ td=dMax/Ve ♦ tp= W.Ve,p ♦ W, dMax given by codes More Complex Scenarios ♦ Maximum egress distances can not be achieved – Safe areas need to be generated with fire rated walls, doors, etc. – Example: Stairs in high rise buildings – The design of these safe areas has to withstand a fire longer than the RSET ♦ Egress is directed to safe areas Complex Systems Street Level 16.4% ♦ Generally are multiple entry, multiple exit systems ♦ Requires more complex calculations Restaurant + Coffee shop ♦ But the principles are 8.1% the same Waiting Area 37.9% Train Platform 37.6% Complete Problem ♦ To be able to analyze such a system all components must be understood ♦ It is necessary to calculate tf, te y ts ♦ Uncertainty needs to be established The Fire Time (tf) ♦ To calculate the characteristic fire times it is essential to understand compartment fire dynamics Introduction ♦ Smoke inhalation is responsible for most of the deaths in a fire ♦ What do we need to know to determine the amount of smoke produced by a fire? ♦ What is in that smoke? ♦ How is the smoke going to migrate from the room of origin to the rest of the building? ♦ What has to be done to control smoke migration? ♦ How do we use the smoke for warning? - Detection The Pre-flashover Fire ) “The Front Room Fire” (BRE Video) The Pre-flashover Fire ) ) The Pre-flashover Fire ) ) ) The Pre-flashover Fire The Compartment Fire H VS TU VS TS S m a,o m Ta e m e m f m a,i m The Pre-flashover Fire ) ) Flashover The Fire ♦ Temperatures in Two Zone Fires are controlled by fuel burning rates (Fuel Limited) ♦ Temperatures in fully developed fires are controlled by ventilation (Ventilation Limited) Timeline Ventilation Limited A (Floor Area) H0 A0: Opening Area H0: Opening Height Ventilation ~3 m 12-18.5 m ♦ A~ 3000 m2 ♦ A0~ 100 m2 ♦ H0~ 3 m ♦ Ventilation Factor: A/A0H01/2~20 The Temperatures • Empirical Data can be used to estimate fire temperatures 2 Mass Loss Rate per uint Total Area, g/m ♦ Depending on the average compartment temperature a mass loss rate can be established ♦ Total consumption of the fuel defines the longest possible fire duration -s Duration of the Fire 80 70 60 Wood cribs PU cribs PMMA pools PMMA pools, Vent-lim. 50 40 30 20 10 0 0 200 400 600 800 1000 Compartment Ceiling Gas Temperature ( 1200 o C) f m kg / m .s 2 ♦ Fuel Load M f kg / m 2 ♦ Duration of the fire M f tf f m 2 Mass Loss Rate per uint Total Area, g/m C.I.B. ♦ Fuel consumption per unit area per unit time -s Duration of the Fire 80 70 60 Wood cribs PU cribs PMMA pools PMMA pools, Vent-lim. 50 40 30 20 10 0 0 200 400 600 800 1000 Compartment Ceiling Gas Temperature ( 1200 o C) Simplest Approach Temperature:C.I.B. Slope is defined by losses through the walls (resistance method) 7oC/min (t>60 min) 10oC/min (t<60 min) tf Resistance Method h r 104 725 W / m2K (500 o C 1200 o C) 1/Ahr 1/Ahr Ta Tf 1/Ahk 1/Ahc k h C Nu g H 1/Ahc hK kC 4 t Fuel Limited (Growth-PreFlashover) ♦ Zone Model – Divides the room into two well defined zones – Upper Layer – Hot combustion products – Lower Layer – Cold air ♦ Implies strong simplifications but help understand the dynamics of the problem Initial Stages of a Compartment Fire H VS – Upper Layer The parameters that need to be evaluated are: TU VS TS S m a,o m Ta e m e m f m a,i m • The temperature of the upper layer: Tu • The velocity at which the Upper Layer descends: VS dH dt Initial Stages of a Compartment Fire ♦ These parameters can be obtained from, the ideal gas law and conservation of mass and energy in the Upper Layer P RT u A(Tu )H( t ) m S t SCp TS A(Tu )H( t )Cp Tu m t Conservation of Energy S m f m e m SCp TS A(Tu )H( t )Cp Tu m t ♦ Unknowns: QP f m e m SCp (TS Ta ) Qm P Correlations ♦ The “Energy Release Rate” f Q HCm ♦ Mass of air entrained 1/ 3 g Q1/ 3 (H 0 H( t )) 5 / 3 m e 0.20 C P Ta 2 a ♦ Mass Burning Rate: Generally obtained from empirical correlations f f (D, Q,Fuel ) m References ♦ Different engineering correlations are proposed in the literature – SFPE Handbook of Fire Protection Engineering – NFPA-The Fire Protection Handbook – Karlsson and Quintiere, “Enclosure Fire Dynamics,” CRC Press, 2000. – Drysdale, “An Introduction to Fire Dynamics,” John Wiley and Sons, 1999 – Cox, “Combustion Fundamentals of Fire,” Academic Press, 1995 – etc., etc., etc…. The “Energy Release Rate, Q” Q ♦ The effective energy release rate that will be transferred to the combustion products is unknown. ♦ The effective energy used to gasify the fuel is unknown. P Qr Q QF f m aQ QC QS,r Assumptions ♦ Total Energy: ♦ Feedback is generally assumed to be small ♦ Radiation is assumed to be a fraction of the total energy released Q QP QF Qr QF 0 Qr Q 0.3 QP (1 )Q 0.7Q Simplifications ♦ Under these assumptions we can correlate everything with “Q” ♦ There is no need to “calculate” QP directly ♦ How do we calculate “Q”? f Q HCm 1/ 3 g Q1/ 3 (H 0 H( t )) 5 / 3 m e 0.20 C P Ta 2 a f f (D, Q,Fuel ) m The Energy Release Rate f Q HCm Can be found in tables but generally only for simple materials, i.e. liquid fuels Can be found for some particular conditions, generally difficult to generalize to real scenarios ♦ Generally “Q” is evaluated empirically Standard Test Methods ♦ The Cone Calorimeter Energy Release Rate obtained from Oxygen Consumption – ASTM E 1354 Standard Test Method for Heat and Visible Smoke Release Rates for Materials and Products Using an Oxygen Consumption Calorimeter – NFPA 264 Standard Method of Test for Heat and Visible Smoke Release Rates for Materials and Products Using an Oxygen Consumption Calorimeter – ISO 5660 Rate of Heat Release of Building Products (Cone Calorimeter) ♦ Ohio State University Calorimeter (OSUCalorimeter) • Energy Release Rate obtained from temperature measurements of the combustion products – ASTM E906 Standard Test Method for Heat and Visible Smoke Release Rates for Materials and Products The Cone Calorimeter (ASTM E 1354 ) Fundamental Issues ♦ Heat Release Rate is obtained indirectly by measuring O2 consumption ♦ Mass is obtained real-time allowing a true mass loss rate to be obtained ♦ External Heat Fluxes of 0 to 100 kW/m2 may be achieved simulating conditions from incipient stages of a fire to post-flashover conditions O2 Consumption COMPLETE COMBUSTION ♦ Main simplifying assumptions: – Energy release per unit mass of O2,constant E = 13.1 MJ/kg of O2 consumed – Ideal gas law applies – O2 depletion factor assumes each mole of air required for complete combustion is replaced by 1.105 moles of products nf nair np 1.105nair Energy Released/kg of O2 [MJ/kg] Energy Released per kg of O2 18 16 14 12 10 8 6 4 2 0 0 5 10 Carbon Atoms 15 Example CH4 2(O2 3.76N2 ) CO2 2H2O 7.52N2 2 7.52 1 2 7.52 1.105nair nP ♦ The assumption is reasonable but can be improved by measuring CO, CO2, soot concentration and reconstructing the chemical reaction O2 Consumption To Blower ex m Exhaust Duct = control volume in m Plenum Hood f m Calculations ♦ Oxygen concentration is measured at the exhaust ♦ Incoming oxygen concentration is that of air ♦ Therefore oxygen consumed is given by: O m O .in m O .ex m 2 2 2 Calculations ♦ Using this information, the energy release rate can be calculated as: O Q 13.1 m 2 MJ Calculations 2P mex cA o To Texh P Density of the exhaust gas Pressure differential across the exhaust orifice A Cross sectional area of the exhaust stack c Orifice coefficient Solution ♦ How much smoke? ♦ How much time does it take? H(tO)=HO ♦ The following equations need to be solved: P RT u A(Tu )H( t ) m S t SCp TS A(Tu )H( t )Cp Tu m t Solution 1/ 3 g Q1/ 3 (H 0 H( t )) 5 / 3 m e 0.20 C P Ta P RT u 2 a A(Tu )H( t ) m S t 1.105nair np S f (m e) m SCp TS A(Tu )H( t )Cp Tu m t SCp (TS Ta ) 0.7Q QP m Q comes from experimental data – Calorimetry Experimental Results ♦ Ideal Scenario: Q m f f m t t Kerosene 600 500 2 HRR (kW/m ) 400 Series1 Series2 Series3 300 200 100 0 0 25 50 75 100 125 Time (s) 150 175 200 225 Gasoline 800 700 600 2 HRR (kW/m ) 500 Series1 Series2 Series3 400 300 200 100 0 0 25 50 75 Time (s) 100 125 150 Naphthalene 1200 1000 2 HRR (kW/m ) 800 Series1 Series2 Series3 600 400 200 0 0 25 50 75 Time (s) 100 125 The Real Scale Application ♦ Large Scale Calorimeters – Factory Mutual – Underwriters Laboratories – BRE Design Fire ♦ Simple representation of the HRR H m Q H A m C f C B f A B r 2 (Vf t ) 2 (Vf2 ) t 2 2 2 2 f H C (Vf )m f t at Q H C A B m t2 parameters Incipient heat release rate (Q*i) Incipient period (to) Growth time (tg) Growth HRR(Q*o) Peak HRR (Q*max) Total HR (Q) Burnout time (tbo) RELEASE RATE ♦ ♦ ♦ ♦ ♦ ♦ ♦ 1 2 3 4 Q max tg Q o Q Q i to tbo TIME Fire growth characterization Q=at2 Loveseat Loveseat Qmax Q=at2 Bunk bed ♦ Corner ignition of lower bunk ♦ Data from “Fire on the Web” (www.bfrl.nist.gov) Mattress HRR data resources ♦ BFRL / NIST - Fire on the Web – www.bfrl.nist.gov ♦ Lund University - Report on initial fires – www.brand.lth.se ♦ Many other scattered reports ♦ Some data included in fire model suites – CFAST; FPETool Initial Stages of a Compartment Fire ♦ With “Q” and the empirical correlations we can come back and evaluate: P RT u A(Tu )H( t ) m S t SCp TS A(Tu )H( t )Cp Tu m t The Solution ♦ For most cases the solution to those three simultaneous equations has to be achieved numerically ♦ Several “codes” are available that will solve the equations ♦ Always remember what the assumptions are and where correlations were included ♦ Make sure that the assumptions and correlations apply to your particular scenario Smoke Movement H VS TU VS TS S m a,o m Ta e m e m f m a,i m Objectives ♦ How much smoke? ♦ How much time will it take for the smoke to come out of the room of origin? ♦ What is in the smoke? Solution ♦ How much smoke? ♦ How much time does it take? H(tO)=HO ♦ The following equations need to be solved: P RT u A(Tu )H( t ) m S t SCp TS A(Tu )H( t )Cp Tu m t Solution 1/ 3 g Q1/ 3 (H 0 H( t )) 5 / 3 m e 0.20 C P Ta P RT u 2 a A(Tu )H( t ) m S t 1.105nair np S f (m e) m SCp TS A(Tu )H( t )Cp Tu m t SCp (TS Ta ) 0.7Q QP m Q comes from experimental data – Calorimetry Design Fire ♦ Simple representation of the HRR H m Q H A m C f C B f A B r 2 (Vf t ) 2 (Vf2 ) t 2 2 2 2 f H C (Vf )m f t at Q H C A B m How do we calculate the area? A B r (Vf t ) (V ) t 2 2 2 f ♦ A function of the flame spread – Flame spread is a function of ignition 2 Ignition q e q ( L) x x=0 L ♦ Simplest case – 1-D – Constant heat flux Ignition Events F m q e TFP TfP TP 0 ♦ ♦ ♦ ♦ Flash Point Fire Point Auto-Ignition Piloted Ignition ♦ Piloted ignition minimizes environmental variables-preferred to study the solid phase! x Standard Protocols to Assess the Solid ♦ Introduce many simplifications ♦ A standard methodology will be described and all simplifications and assumptions studied The Lateral Ignition Flame Test (LIFT-ASTM-1321) Ignition Test Flame Spread Test The Lateral Ignition and Flame Spread Test (LIFT) t ig t p t m t i t ig t p t m t i t ig t p TP T(x,t>tP) F (t t P ) m x T(x,tP) Ignition Delay Time Ignition Delay Time [s] 1400 1200 1000 800 600 Critical Heat Flux for Ignition 400 200 0 0 5 10 15 20 25 30 2 External Heat Flux [kW/m ] 35 40 45 Results ♦ The experimental data is fitted to the theoretical predictions and all characteristic values are extracted ♦ The total heat transfer coefficient is evaluated (hT) ♦ Material properties are evaluated (kC, Tig) Assumptions ♦ Semi-Infinite Solid ♦ Linearized Total Heat Transfer Coefficient: hT=hC+hS,r ♦ Solid remains inert until ignition Summary 2500 " q time [sec] 2000 0 ,ig h T (Tig T ) 1500 " 1 1000 t ig 500 0 0 10 Critical Heat Flux for Ignition q e 20 30 2 [kW/m ] 40 2 1 q kc Tig T i Ignition Properties 1 t ig Material Tig [oC] q " 2 1 kc Tig T e kC [s.kW2/m4K2] Douglas Fir Cedar Iroko Polyisocianurate Polyurethane PMMA Acrilic 382 402 410 445 390 378 300 0.94 1.22 1.30 0.02 0.30 1.02 0.42 Critical Heat Flux [kW/m2] 16 18 17 21 16 15 10 Flame Spread ♦ Propagation Rates are controlled by orientation ♦ Propagation defines the evolution in size with time of the fire Forward Propagation Flame Opposed Propagation Lateral Propagation Opposed Flame Spread T g Cp,g lg VF TF S C P ,S Vf (TP T ) d T q g d S U Vf T -x dg q g d S S C P ,S (TP T ) d T e x T S Cp,S lS dT L Thermally Thick dT TP l S (TP T ) q g Thermally Thin T dS x dT L Thermally Thick ♦ Solution Vf q g S l SS C P ,S (TP T ) 2 ♦ Flame Spread Parameter ♦ Solution d 2 q g d S Vf l SS C P,S (TP T ) 2 2 LIFT Test - Flammability Diagram 1400 0.0045 0.004 1200 F* Vf [ q 0,ig q e ] 2 0.003 800 tig (s) 0.0025 Flame Spread Data 600 0.002 Ignition Data 0.0015 400 q "o ,ig 11 kW m2 0.001 200 0.0005 0 0 0 10 20 30 40 50 Incident Heat Flux (kW/m2) 60 70 Vf (m/s) 1000 0.0035 Flame Spread Properties F* Vf [ q 0,ig q e ] 2 Material Minimum Flux [kW/m2] Douglas Fir Cedar Particle Board Polyurethane Acrilic PMMA 6.0 9.0 5.7 0.0 2.0 0.0 F* [kW2/s.m3] 2.3 1.2 2.1 11.7 9.9 14.4 Design Fire ♦ Simple representation of the HRR H m Q H A m C f C B f A B r 2 (Vf t ) 2 (Vf2 ) t 2 2 2 2 f H C (Vf )m f t at Q H C A B m Smouldering ♦ Smouldering leads to propagation rates 100 times slower than flaming fires ♦ Therefore is important to establish if the fire originated in smouldering Smouldering Limits 1600 Exposure Time (s) 1400 1200 1000 800 600 400 ignition no ignition 200 0 5.9 6 6.1 6.2 6.3 6.4 6.5 6.6 6.7 6.8 6.9 kW/m2 What is inside the smoke? ♦ Generally defined by yields (Yp) ♦ A yield is the fraction of the total mass that corresponds to the specific product ♦ The mass of the specific product is given by: CO YCOm S m Typical Yields Irritants Compound Formaldehyde Acetaldehyde Acetone Phenol Xylene Styrene Pyrolysis Yield (%) 0 0 0 0 0.61 0.56 Oxidation Yield (%) 3.32 3.50 3.84 1.16 0.02 0.40 Threshold Value (ppm) 2 100 750 5 From Purser, SFPE Handbook, 1995 These values vary from fuel to fuel and from burning conditions to burning condition Carbon Monoxide (I) Flaming Combustion Material PVC Methane Propane Polyester Rayon Polyurethane Paper Wood (red oak) CO Yield (%) Well Ventilated 11 0.1 0.1 1.5 4.3 1 0.3 0.4 CO Yield (%) Under-Ventilated 42 10 12 From Tewarson, SFPE Handbook, 1995 ♦ CO yields for smoldering tend to be much higher, i.e. 6% for polyurethane foam Carbon Monoxide (II) 3 Heavy Work Light Work Sitting 2.5 %CO2 2 1.5 1 0.5 0 0 10 20 minutes 30 40 From Purser, SFPE Handbook, 1995 ♦ Time to incapacitation because of CO inhalation Carbon Monoxide (III) ♦ It is necessary to know the concentration of CO within the smoke ♦ An additional differential equation has to be incorporated for each species AYCO, u(Tu )H( t ) m CO YCOm S t ♦ The CO concentration is a direct function of the fire size