ChE 344: CHEMICAL REACTION ENGINEERING Fundamentals of chemical reaction engineering. Rate laws, kinetics, and mechanisms of homogeneous and heterogeneous reactions. Analysis of rate data, multiple reactions, heat effects, bioreactors. Design of industrial reactors. Prerequisite: ChE 330, ChE 342 Winter 2013 Lectures and In-Class Problems: TuTh 9:40 (Sharp) to 11:30 (not so sharp) - 1013 Dow Instructor: Professor H. Scott Fogler 3168 DOW, 763-1361, sfogler@umich.edu Office Hours: TuTh 11:30 to 12:30 Text Required Essentials of Chemical Reaction Engineering, (2011) H. Scott Fogler GSIs Matthew Morabito, Roon 3166 Dow, email: morabitm@umich.edu VJ Tocco, Room, 3094 Dow, email: vjtocco@umich.edu GSI Office Hours: MW 3:00-6:00 Room to be determined Tutor Corey Peterson, cdpet@umich.edu Proctors Chris McMullen, cmcmull@umich.edu Matt Mackey, mdmackey@umich.edu Corey Peterson, cdpet@umich.edu Graders Ben Leung, benleung@umich.edu - Blue Pen Qian Wang, wangzt@umich.edu - Red Pen Chayanin Na Chiangmai, chayanin@umich.edu - Green Pen Recommended Reading List • Problem Solving in Chemical and Biochemical Engineering with POLYMATH, Excel, and MATLAB, 2nd Edition 2008, Cutlip & Shacham • The Elements of Style, Strunk and White • Strategies for Creative Problem Solving, 2nd Edition 2008, Fogler and Leblanc (for OEP’s) 1 Schedule *Note - all ICGs (Interactive Computer Games) are Individual* http://www.umich.edu/~essen/html/byconcept/modules/frames_icm.htm Send your performance numbers to cdpet@umich.edu 1) Thursday, January 10 Topic: Lecture 1- Introduction, POLYMATH, Mole balances Finish Reading: Preface, Prerequisites, Appendix B Study Problems: P1-7A, P1-11B 2) Tuesday, January 15 Topic: Lecture 2 - Design equations, Rate versus X plots, Reactor staging Finish Reading: Chapter 1, P1-9A, Appendix A, from the Web, Chapter 2 Sections 2.1, 2.2, and 2.3 Hand In: Problem Set 1 ICG: Kin Chal 1 (29 10 min) Study Problems: P2-5B(a - d), P2-8B 3) Thursday, January 17 Topic: Lecture 3 - Rate laws Finish Reading: Chapter 2, Chapter 3 Hand In: Problem Set 2 ICG: Staging (35 10 min) Class Problem: 1 Study Problems: P3-2A(a), P3-4A, P3-5B, P3-15B (a), P3-16B Hint: Viewing the YouTube video "The Black Widow" noted in Problem P3-6B may help you with today's in class problem 4) Tuesday, January 22 Topic: Lecture 4 - Stoichiometry Batch Reading: Chapter 4 Hand In: Problem Set 3 Class Problem: 2 - Bring i>clickers - Test Run of System in 1013 Dow Study Problems: P4-2A(c-e) 5) Thursday, January 24 Topic: Lecture 5 - Stoichiometry Flow Reading: Chapter 4, Section 4.1 Hand In: Problem Set 4 Class Problem: 3 Study Problems: P4-8B, P4-10C 6) Tuesday, January 29 Topic: Lecture 6 - Isothermal reactor design (1st hour) Lecture 7 - California Registration Exam Problem (2nd hour) Reading: Chapter 5, Chapter 5 Summary Notes on DVD Hand In: Problem Set 5 ICG: Kin Chal II (36 16 min) 2 Study Problems: P5-2B (b), P5-4A 7) Thursday, January 31 Hand In: Problem Set 6 Study Problems: P5-15B, P5-17B, P5-19A 8) Tuesday, February 5 Topic: Lecture 8 - Pressure drop Finish Reading: Chapter 5, Sections 5.4 and 5.5 Hand In: Problem Set 7 Class Problem: 6 Bring Laptops Study Problems: P5-2B (d,e), 5-7A, 5-5B (d), P5-23B 9) Thursday, February 7 Topic: Lecture 9 - Membrane Reactors Finish Reading: Chapter 6 Hand In: Problem Set 8 ICG: Mystery Theater (32 10 min) Class Problem: 7 Study Problems: P5-9B, P5-10B, P5-11B, P6-2 (a), P6-4B, P6-14B 10) Tuesday, February 12 Topic: Lecture 10 - Semibatch Reactors Finish Reading: Chapter 6 Hand In: Problem Set 9 Class Problem: 8 Study Problems: P6-6B, P6-7B, P6-12B 11) Thursday, February 14 Topic: Lecture 11 - Analysis of Rate Data Finish Reading: Chapter 7 Hand In: Problem Set 10 ICG: Tic Tac (33 9 min) Class Problem: 9 Bring Laptops to carry out Polymath Regression Study Problems: P7-5B, P7-7B, P7-8B, P7-10B 12) Tuesday, February 19 Topic: Lecture 12 - Multiple Reactions Finish Reading: Chapter 8, Sections 8.1, 8.2, 8.3 and 8.4; Hand In: Problem Set 11 Class Problem: 10 Study Problems P8-2B (d), P8-5B Wednesday Evening, February 20 or Thursday, February 21 during class (if rooms are available) – MIDTERM EXAM I (*W13) Closed book, notes, and web 13) Tuesday, February 26 Topic: Lecture 13 - Chapter 8: Multiple Reactions Finish Reading: Chapter 8, Sections 8.5, 8.6, 8.7 and 8.8 Hand In: Problem Set 12 Class Problem: 11 Bring Laptops 3 Study Problems: P8-10B, P8-11B, P8-17B 14) Thursday, February 28 Topic: Lecture 14 - Chapter 8: Multiple Reactions, Chapter 9: PSSH Finish Reading: Chapter 9, Section 9.1 and the cobra web module Hand In: Problem Set 13 ICG: Great Race (30 10 min) Class Problem: 12 Bring i>clickers Study Problems: P8-15B, P8-18B, P8-20B SPRING BREAK: March 2, 2012 – March 9, 2012 15) Tuesday, March 12 Topic: Lecture 15 - Energy Balance and Adiabatic Reactions Finish Reading: Sections 11.1, 11.2 and 11.3, also equilibrium conversion appendix Hand In: Problem Set 14 Class Problem: 13 Study Problems P11-5B, P11-10B 16) Thursday, March 14 Topic: Lectures 16A and 16B - Reactors with Heat Exchange Finish Reading: Chapter 12, Sections 12.1 through 12.3 Hand In: Problem Set 15 ICG Review: Just go through only the Review sections of P12-4A Study Problem: P12-21B (a,f) 17) Tuesday, March 19 Topic: Lecture 17 - Applications of the Energy Balance to PFRs Finish Reading: Chapter 12, Section 12.4 Hand In: Problem Set 16 Class Problem: 14 Bring Laptops Study Problems: P12-6B 18) Thursday, March 21 Topic: Lecture 18 - Multiple Reactions with Heat Effects Finish Reading: Section 12.5 Hand In: Problem Set 17 ICG: Heat Effects II (only the first 3 reactors) (30 10 min) Class Problem: 15 Bring Laptops Study Problems: P12-23C 19) Tuesday, March 26 Topic: Lecture 19 - CSTR with Heat Effects Finish Reading: Sections 12.6 and 12.7 Hand In: Problem Set 18 Class Problem: 16 Bring Laptops Study Problems: P12-17B, P12-18C 4 20) Thursday, March 28 Topic: Lecture 20 - Reactor Safety Finish Reading: Chapter 13 Hand In: Problem Set 19 ICG: Heat Effects I (36 14 min) Class Problem: 17 Bring Laptops and DVDROM Study Problems: P13-4B, P13-5B, P13-8B 21) Tuesday, April 2 Topic: Lecture 21 - Safety Finish Reading: Chapter 13, Sections 13.3 and 13.4 and Chapter 10, Sections 10.1 through 10.2.2 Hand In: Problem Set 20 [Comprehensive Exam] Class Problem: 18 Study Problems: P10-4A 22) Thursday, April 4 Topic: Lecture 22 - Catalysis Finish Reading: Sections 10.2.2 through 10.4.4 Hand In: Problem Set 21 Class Problem: 19 Study Problems: P10-7B, P10-9B 23) Tuesday, April 9 Topic: Lecture 22 Hand In: Problem Set 22 ICG: Catalysis I (33 13 min) Study Problems: P10-17D Wednesday, April 10 – MIDTERM EXAM II (*W13) Evening Exam Thursday, April 11 – No Class 25) Tuesday, April 16 Topic: Lecture 23 - chemical vapor deposition (CVD) Finish Reading: Chapter 10 Hand In: Problem Set 23 ICG: Enzymeman (30 10 min) Class Problem: 20 Study Problems: P10-14B, P10-15A 26) Thursday, April 18 Topic: Lecture 24 - Enzyme Kinetics Reading: Section 9.2 Hand In: Problem Set 24 Study Problems: P9-4B, P9-6C (a-c), P9-7A (a, b, c) 5 27) Tuesday, April 23 Topic: Lecture 25 - Enzyme Kinetics, Inhibition, Bioreactors Finish Reading: Section 9.3 and 9.4 Hand In: Problem Set 25 Class Problem: 21 Study Problems: P9-2A (b), P9-8B (a-c), P9-9B, P9-11B, P9-19B 28) Monday, April 25 – Final Exam (1:30-3:30) 6