Fall 2010 Program of Study Technology for Teaching Develop chemistry, physics, and biotechnology laboratory modules for schools with limited access to specialty chemicals and supplies. Engineers without Borders Iowa State University Fall 2010 Program of Study Fall 2010 Table of Contents Biology I......................................................................................................................................................... 9 Overall Goal: Biology as a science ............................................................................................................. 9 Specific aims:......................................................................................................................................... 9 Identify the field of study of Biology ......................................................................................... 9 Biology divisions ........................................................................................................................ 9 Relation between Biology and other sciences (i.e., Chemistry, Physics, Mathematics, Geography, and Informatics) ............................................................................................................ 9 Identify the basic characteristics of science ............................................................................. 9 Describe the components of the scientific method applied to Biology.................................... 9 Overall Goal: Identify the main characteristics and components of living beings ................................. 11 Specific aims:....................................................................................................................................... 11 Identify the main characteristics on living beings: structure, organization, metabolism, reproduction, growth, adaptation, etc. .......................................................................................... 11 Identify the main bioelements that form part of living beings: C, H, O, N, P, S, Ca, K, Cl, Fe, I, etc. 11 Recognize the structure and function of the main organic biomolecules: Carbohydrates, Lipids, Proteins, Nucleic Acids ......................................................................................................... 11 Explain DNA replication .......................................................................................................... 11 Explain the synthesis of proteins from DNA ........................................................................... 11 Overall Goal: Recognize the cell as a unit of life ..................................................................................... 11 Specific aims:....................................................................................................................................... 11 Identify cells as a basic component of life .............................................................................. 11 Cellular theory......................................................................................................................... 11 Explain theories about the origin of first cells ........................................................................ 11 Identify the different types of prokaryotic and eukaryotic cells ............................................ 11 Recognize the different components of the cell and their functions: membrane, cytoplasm, etc. 11 Overall Goal: Metabolism of living beings .............................................................................................. 11 Specific aims:....................................................................................................................................... 11 Identify the different energy forms in living beings ............................................................... 11 Page 1 Program of Study Fall 2010 Identify the process for transformation of energy and the endothermic and exothermic reactions in organisms .................................................................................................................... 11 Recognize the function of ATP in living beings ....................................................................... 11 Functions of enzymes in biological processes ........................................................................ 11 Describe the anabolic processes: Quimisynthesis, photosynthesis........................................ 11 Catabolic processes: Respiration, Fermentation .................................................................... 12 Overall Goal: Biodiversity and its preservation ...................................................................................... 12 Specific aims:....................................................................................................................................... 12 Recognize the main characteristics of viruses: chemical composition, replication, classification criteria, examples of diseases ................................................................................... 12 Classification of living beings .................................................................................................. 12 Describe the main characteristics of bacteria: structure, reproduction, respiration, etc. ..... 12 Recognize the importance of biodiversity .............................................................................. 12 Biology II...................................................................................................................................................... 13 Overall Goal: Identify the different types of cell and different organisms reproduction....................... 13 Specific aims:....................................................................................................................................... 13 Recognize DNA as a fundamental structure of a chromosome .............................................. 13 Identify chromosome structure .............................................................................................. 13 Identify the stages of the cellular cycle involved in cancer .................................................... 13 Recognize the scientific advances that improve life quality ................................................... 13 Mitosis as a process of asexual reproduction ......................................................................... 13 Overall Goal: Recognize and apply the principles of heredity ................................................................ 13 Specific aims:....................................................................................................................................... 13 Principles of genetics .............................................................................................................. 13 Identify the main terminology used in genetics: phenotype, genotype, etc. ......................... 13 Identify the principles of heredity .......................................................................................... 13 Identify human diseases related to genetic ............................................................................ 13 Overall Goal: Biotechnology ................................................................................................................... 13 Specific aims:....................................................................................................................................... 13 Biotechnology applications ..................................................................................................... 13 Elaboration processes of wine, beer, bread ........................................................................... 13 Page 2 Program of Study Fall 2010 Selective reproduction of plants and animals ........................................................................ 13 Elaboration processes of hormones, antibiotics, etc. ............................................................. 13 Transgenic organisms.............................................................................................................. 13 Bioremediation ....................................................................................................................... 13 Recognize the role of genetic engineering in biotechnology.................................................. 13 Overall Goal: Recognize the principles of biologic evolution and relate them with biodiversity........... 14 Specific aims:....................................................................................................................................... 14 Identify the causes and objectives of evolution by natural and artificial selection................ 14 Overall Goal: Structural principles and functions of human beings ....................................................... 14 Specific aims:....................................................................................................................................... 14 Recognize the components and functions of the immune system and its relation with the generation of infections and diseases ............................................................................................ 14 Recognize the importance and function of the muscular system .......................................... 14 Recognize the importance and function of the skeletal system ............................................. 14 Identify the components and functions of the digestive system ........................................... 14 Identify the structural components and functions of the circulatory system ........................ 14 Identify the function of blood cells of human beings ............................................................. 14 Recognize the components and functions of the respiratory system .................................... 14 Recognize the functions of the urinary system ...................................................................... 14 Identify the function of the nervous system........................................................................... 14 Neurons as a basic unit of the nervous system ...................................................................... 14 Classification of the nervous system....................................................................................... 14 Recognize the components of the nervous system and their functions ................................ 14 Health problems related with the nervous system ................................................................ 14 Hormones and their functions as regulators of metabolic activity in human beings ............. 14 Recognize the components and functions of the reproductive systems for male and female 14 Diseases related with the reproductive systems .................................................................... 14 Overall Goal: Plants as complex organisms and their importance for living beings............................... 15 Specific aims:....................................................................................................................................... 15 General characteristics of plants: nutrition, organization, transport and reproduction ........ 15 Page 3 Program of Study Fall 2010 Types of cells present in plants ............................................................................................... 15 Parts of a plant ........................................................................................................................ 15 Identify the utility of the different parts of the plan for human beings ................................. 15 Recognize the biological, cultural, social and economic importance of plants ...................... 15 Chemistry I .................................................................................................................................................. 16 Overall Goal: Chemistry as a tool in life .................................................................................................. 16 Specific aims:....................................................................................................................................... 16 Chemical science and technology in life ................................................................................ 16 Scientific method and its applications .................................................................................... 18 Overall Goal: Matter and Energy relationships ...................................................................................... 18 Specific aims:....................................................................................................................................... 18 Matter: Properties and changes ............................................................................................. 18 Energy and its relationship with matter ................................................................................. 18 Overall Goal: Atomic model and its applications .................................................................................... 19 Specific aims:....................................................................................................................................... 19 Atomic models and subatomic particles ................................................................................. 19 Basic concepts (Atomic number, atomic mass, mass number) .............................................. 19 Electronic configurations and quantum numbers .................................................................. 19 Isotopes and its applications ................................................................................................... 19 Overall Goal: Periodic table .................................................................................................................... 19 Specific aims:....................................................................................................................................... 19 Chemical elements .................................................................................................................. 19 Groups, periods and blocks..................................................................................................... 19 Periodic properties and its variation in periodic table............................................................ 19 Importance and use of metal and non metal elements in social and economic life .............. 19 Overall Goal: Chemical bonds and intermolecular interactions ............................................................. 19 Specific aims:....................................................................................................................................... 19 Chemical bond ........................................................................................................................ 19 Ionic bond properties .............................................................................................................. 19 Properties and formation of covalent bonds .......................................................................... 19 Metallic bond .......................................................................................................................... 20 Page 4 Program of Study Fall 2010 Intermolecular forces .............................................................................................................. 20 Overall Goal: Inorganic Chemistry nomenclature................................................................................... 21 Specific aims:....................................................................................................................................... 21 IUPAC rules to name inorganic compounds: Metallic oxides, non metallic oxides, metallic hydrides, hydracids, hydroxides, oxyacids, salts............................................................................. 21 Overall Goal: Chemical reactions ............................................................................................................ 21 Specific aims:....................................................................................................................................... 21 Symbols in chemical equations ............................................................................................... 21 o Decomposition ........................................................................................................................ 21 o Simple substitution ................................................................................................................. 21 o Double substitution................................................................................................................. 21 Chemical reaction balance techniques ................................................................................... 21 Overall Goal: Heat and kinetics in chemical reactions............................................................................ 21 Specific aims:....................................................................................................................................... 21 Enthalpy .................................................................................................................................. 21 o Reaction enthalpy ................................................................................................................... 21 o Formation enthalpy................................................................................................................. 21 Exothermic and endothermic reactions.................................................................................. 21 Reaction velocity ..................................................................................................................... 32 Sustainable development ....................................................................................................... 39 Chemistry II ................................................................................................................................................. 40 Overall Goal: Mole as a unit to measure chemical processes ................................................................ 40 Specific aims:....................................................................................................................................... 40 Mole as a basic unit................................................................................................................. 40 Chemical laws of mass, definite proportions, multiple proportions and reciprocal proportions. .................................................................................................................................... 40 Stoichiometric calculus ........................................................................................................... 40 Mole-mole, mass-mass, volume-volume relations ................................................................. 40 Minimal formula ..................................................................................................................... 40 Overall Goal: Reduction of pollution in air, water and soil techniques .................................................. 40 Specific aims:....................................................................................................................................... 40 Page 5 Program of Study Fall 2010 Pollution in soil, water and air ................................................................................................ 40 Primary and secondary contaminants .................................................................................... 40 Chemical reactions related to pollution.................................................................................. 40 Thermal inversion, smog and acid rain ................................................................................... 40 Overall Goal: Disperse systems ............................................................................................................... 40 Specific aims:....................................................................................................................................... 40 Element, compound, mixture: homogeneous, heterogeneous ............................................. 40 Separation techniques ............................................................................................................ 40 Elements, compounds and mixtures’ characteristics. ............................................................ 40 Overall Goal: Carbon compounds in the environment ........................................................................... 41 Specific aims:....................................................................................................................................... 41 Electronic configuration of carbon and its molecular geometry ............................................ 41 Molecular geometry................................................................................................................ 41 Types of isomers and chains ................................................................................................... 41 Physical properties, nomenclature and carbon compounds use............................................ 41 Alkanes, alkenes, alkynes ........................................................................................................ 41 Functional groups: alcohols, ethers, aldehydes, ketones, carboxylic acids. ........................... 41 Overall Goal: Natural and synthetic macromolecules ............................................................................ 41 Specific aims:....................................................................................................................................... 41 Monomers and polymers ........................................................................................................ 41 Lipids, proteins and carbohydrates......................................................................................... 41 Addition and condensation polymers ..................................................................................... 41 Physics I ....................................................................................................................................................... 42 Overall Goal: Relate the scientific knowledge and physic magnitudes, and basic tools to understand natural phenomena ................................................................................................................................ 42 Specific aims:....................................................................................................................................... 42 Identify prefixes used in the International System SI. ............................................................ 42 Identify types or errors in different kinds of measurements.................................................. 42 Analyze the precision of different instruments. ..................................................................... 42 Identify scalar and vector magnitudes.................................................................................... 42 Identify characteristics of a vector.......................................................................................... 42 Page 6 Program of Study Fall 2010 Properties of vectors. .............................................................................................................. 42 Overall Goal: Identify the differences among different types of movement ......................................... 42 Specific aims:....................................................................................................................................... 42 Recognize concepts related to motion (distance, time, position, displacement, speed, velocity, acceleration, reference system). ...................................................................................... 42 Identify characteristics of movements. One dimension: uniform rectilinear, uniform accelerated rectilinear, free fall. Two dimensions: Parabolic, uniform circular motion, accelerated circular motion. ............................................................................................................................... 42 Overall Goal: Understand the utility in practice of Motion Newton Laws ............................................. 42 Specific aims:....................................................................................................................................... 42 Describe historic background in the study of mechanical movement. (Aristotle, Galileo Galilei, Isaac Newton). .................................................................................................................... 42 Define Newton's Law (Inertia, Force=Mass acceleration, action and reaction). Use these laws to solve problems and use them to explain daily situations. ......................................................... 42 Recognize Gravitation Universal Law...................................................................................... 48 Conceptualize velocity and tangential acceleration. .............................................................. 48 Recognize Kepler’s Laws. ........................................................................................................ 48 Overall Goal: Relate work with energy ................................................................................................... 48 Specific aims:....................................................................................................................................... 48 Define the concept of work in the context of physics as the scalar product between force and displacement. ........................................................................................................................... 48 Define concepts of Kinetic Energy, Potential Energy and their relation with work................ 48 Identify the concept of power and its units. ........................................................................... 48 Identify Joules, erg as units of work, kinetic energy and potential energy. ........................... 48 Conservation of Mechanical Energy. ...................................................................................... 48 Recognize heat as a form or energy........................................................................................ 48 Physics II ...................................................................................................................................................... 49 Overall Goal: Describe fluids in motion and stationary state ................................................................. 49 Specific aims:....................................................................................................................................... 49 Identify the different states of matter (liquid, solid, gas). ...................................................... 49 Identify the differences between fluids and solids from their physic properties................... 49 Page 7 Program of Study Fall 2010 Describe different properties of fluids such as: viscosity,_ superficial tension, capillarity, cohesion, adhesion, density, specific weight, pressure, hydrostatic Pressure, gauche pressure, atmospheric pressure, absolute pressure. ..................................................................................... 49 Overall Goal: Differentiate heat and temperature ................................................................................. 56 Specific aims:....................................................................................................................................... 56 Identify different concepts of heat, temperature, kinetic energy. ......................................... 56 Recognize the following scales of temperature and their units: Fahrenheit, Celsius, Kelvin, and Rankine..................................................................................................................................... 56 Identify the different mechanism of heat transfer: radiation, convection, conduction. ....... 56 Recognize absorbed heat vs. dissipated heat and its relation with temperature and mass. . 56 Overall Goal: Understand electricity laws .............................................................................................. 61 Specific aims:....................................................................................................................................... 61 Identify basic electrostatic concepts such as: electrostatic charge, insulators, and conductors. ..................................................................................................................................... 61 Identify concepts as electric field, electric potential energy, and electric potential. ............. 61 Identify characteristics of different kinds of circuits: parallel, series, mixed. ........................ 61 Solve problems using Ohm's Law............................................................................................ 61 Overall Goal: Relate electricity and magnetism ..................................................................................... 62 Specific aims:....................................................................................................................................... 62 Know historic background in the field of electromagnetism. (Hans Cristian Oersted, Michel Faraday, Andre Marie Ampere, George Simon Ohm, James Clerk Maxwell) ................................. 62 Establish the characteristics of magnets and their magnetic interactions. ............................ 62 Explain the concept of magnetic field..................................................................................... 62 Page 8 Program of Study Fall 2010 Biology I Overall Goal: Biology as a science Specific aims: Identify the field of study of Biology Biology divisions Relation between Biology and other sciences (i.e., Chemistry, Physics, Mathematics, Geography, and Informatics) Identify the basic characteristics of science Describe the components of the scientific method applied to Biology Experiment: The M&M Candy Experiment The scientific method can be broken down into the following parts: 1. 2. 3. 4. 5. 6. State the problem. (We want to know how many M&Ms are in the bag. We want to know how much of each color is in the bag.) Gather information on the topic. (We know there are different colors of candy in the bag and we generally know the size of each M&M) Form a hypothesis. (We can create a hypothesis on how many M&Ms and how much of each color is in the bag.) Experiment! (We open the bag and start to count and record the data) Record and analyze data. (With the candy counted, we can find information of the bags and average the different bags.) State a conclusion ( We can state a general conclusion on the bags of the M&M, give average numbers of each bag.) Supplies: One regular sized bag of M&M’s (or other small piece of candy) for every 2 to 3 students. One regular sized bag of M&M’s (or other small piece of candy) for demonstration. Introduction: The teacher holds up a bag of regular sized M&M’s. The teacher asks a question to begin the discussion--What things might we want to know about this bag of M&M’s? Students will respond with a variety of inquiriesHow many M&M’s are in the bag? What color M&M’s are in the bag? How many of each color M&M are in the bag? How much does one M&M weigh? How much does the bag weigh? Page 9 Program of Study Fall 2010 The teacher can choose one question. One question might be How many M&M’s are in the bag? Students guess the number of M&M’s. Using the students’ guesses, the teacher introduces scientific terminology. For instance, during the discussion of answers to the question of how many M&M’s are in the bag, the numbers put forth are hypotheses. At this point, the teacher should write the definition of the new scientific term on the board and have students copy it down. The teacher then will ask the students to volunteer some numbers to write on the board. Afterwards the teacher asks—How do we determine which hypothesis, if any, is correct? The students usually will ask the teacher to open the bag. The teacher then introduces the concept of data collection to determine if one’s hypothesis is correct. The teacher opens the bag, counts the number of M&M’s and writes ‘Data’ under which she writes the number counted in her bag. Now the students will split into groups of 2-3 and given this chart. It is now time for them to collect data. By collecting the data from all of the groups, the teacher introduces the concept of multiple trials. Group # Total Number of M&M’s in bag Number of Green M&M’s Number of Brown M&M’s Number of Yellow M&M’s Number of Orange M&M’s Number of Blue M&M’s 1 2 3 Analyzing the Data: Using the data from the class, the teacher is able to address the idea of variance in data. To follow up the teacher asks—From our data, what would be an accurate way to determine the number of M&M’s in a random bag I pick up at the grocery store? The average of the numbers provides an accurate description of the number of M&M’s in a randomly chosen bag. Also, the average number of each color M&M per bag may be calculated. In addition to the average calculations, the class determines the median and mode for the total number of M&M’s per bag and/or the number of each color of M&M per bag. References: 1. 2. 3. http://www.scienceteacherprogram.org/genscience/AMeyer05.html http://www.shellyssciencespot.com/Worksheets/ScientificMethod/M&M%20Lab.pdf http://www.nhvweb.net/vhs/science/kluckhardt/cp%20bio/Introduction%20to%20Biology/Unit%201/M &M.pdf Page 10 Program of Study Fall 2010 Overall Goal: Identify the main characteristics and components of living beings Specific aims: Identify the main characteristics on living beings: structure, organization, metabolism, reproduction, growth, adaptation, etc. Identify the main bioelements that form part of living beings: C, H, O, N, P, S, Ca, K, Cl, Fe, I, etc. Recognize the structure and function of the main organic biomolecules: Carbohydrates, Lipids, Proteins, Nucleic Acids o Experiment: Extraction and identification of carbohydrates, lipids and proteins from vegetables and animal fat Explain DNA replication Explain the synthesis of proteins from DNA Overall Goal: Recognize the cell as a unit of life Specific aims: Identify cells as a basic component of life Cellular theory Explain theories about the origin of first cells Identify the different types of prokaryotic and eukaryotic cells Recognize the different components of the cell and their functions: membrane, cytoplasm, etc. o Experiment: Extract and identify the cell structure from an onion Overall Goal: Metabolism of living beings Specific aims: Identify the different energy forms in living beings Identify the process for transformation of energy and the endothermic and exothermic reactions in organisms Recognize the function of ATP in living beings Functions of enzymes in biological processes Describe the anabolic processes: Quimisynthesis, photosynthesis o Experiment: Growing plant under water Page 11 Program of Study Fall 2010 Catabolic processes: Respiration, Fermentation o Experiment: Bug respiration Overall Goal: Biodiversity and its preservation Specific aims: Recognize the main characteristics of viruses: chemical composition, replication, classification criteria, examples of diseases Classification of living beings Describe the main characteristics of bacteria: structure, reproduction, respiration, etc. o Experiment: Bacteria growth Recognize the importance of biodiversity Page 12 Program of Study Biology II Overall Goal: Identify the different types of cell and different organisms reproduction Specific aims: Recognize DNA as a fundamental structure of a chromosome o Experiment: Extraction of DNA from fruits Identify chromosome structure Identify the stages of the cellular cycle involved in cancer Recognize the scientific advances that improve life quality Mitosis as a process of asexual reproduction Overall Goal: Recognize and apply the principles of heredity Specific aims: Principles of genetics Identify the main terminology used in genetics: phenotype, genotype, etc. Identify the principles of heredity Identify human diseases related to genetic Overall Goal: Biotechnology Specific aims: Biotechnology applications Elaboration processes of wine, beer, bread o Experiment: Beer and bread fermentation Selective reproduction of plants and animals Elaboration processes of hormones, antibiotics, etc. Transgenic organisms Bioremediation Recognize the role of genetic engineering in biotechnology Page 13 Fall 2010 Program of Study Overall Goal: Recognize the principles of biologic evolution and relate them with biodiversity Specific aims: Identify the causes and objectives of evolution by natural and artificial selection Overall Goal: Structural principles and functions of human beings Specific aims: Recognize the components and functions of the immune system and its relation with the generation of infections and diseases Recognize the importance and function of the muscular system Recognize the importance and function of the skeletal system Identify the components and functions of the digestive system Identify the structural components and functions of the circulatory system Identify the function of blood cells of human beings Recognize the components and functions of the respiratory system o Artificial lung model Recognize the functions of the urinary system Identify the function of the nervous system Neurons as a basic unit of the nervous system Classification of the nervous system Recognize the components of the nervous system and their functions Health problems related with the nervous system Hormones and their functions as regulators of metabolic activity in human beings Recognize the components and functions of the reproductive systems for male and female Diseases related with the reproductive systems Page 14 Fall 2010 Program of Study Overall Goal: Plants as complex organisms and their importance for living beings Specific aims: General characteristics of plants: nutrition, organization, transport and reproduction Chlorophyll extraction and a plant growing Types of cells present in plants Parts of a plant Identify the utility of the different parts of the plan for human beings Recognize the biological, cultural, social and economic importance of plants Page 15 Fall 2010 Program of Study Fall 2010 Chemistry I Overall Goal: Chemistry as a tool in life Specific aims: Chemical science and technology in life Chemistry Scavenger Hunt: Note: Depending on how many of the following items are included, can make this activity one for beginning chemistry students or an activity for mid-course students. Materials: A worksheet for students with the scavenger hunt list (see below). Procedure: Hand out worksheet to students. Instruct them to find examples of the items on the list around their house, neighborhood, ect., to bring in. Can assign one item to each student or all to each person (having them bring in only one or two in that case). Have students share their findings with the rest of the class. Questions: Were there any surprises in what you found in your house/neighborhood? Which were the most difficult to find? 1. An element 2. A heterogeneous mixture 3. A homogenous mixture 4. A gas-liquid solution 5. A malleable substance 6. A solid-liquid solution 7. A substance which has a volume of 1 cm3 8. An edible example of a physical change 9. An edible example of a chemical change 10. A pure compound which contains ionic bonds 11. A pure compound which contains covalent bonds 12. A mixture that can be separated by filtration 13. A mixture that can be separated by some other method than filtration 14. A substance with a density less than 1g/mL 15. A substance with a density more than one 16. A substance which contains a polyatomic ion 17. An acid 18. A metal 19. A non-metal Page 16 Program of Study Fall 2010 20. An inert gas 21. An alkaline earth metal 22. Immiscible liquids 23. A toy which demonstrates a physical change 24. The result of a chemical change 25. A mole 26. A substance with tetrahedral geometry 27. A base with a pH greater than 9 28. A polymer Possible Answers: 1. An element aluminum foil, copper wire, aluminum can, iron name 2. A heterogeneous mixture sand and water, salt and iron filings 3. A homogenous mixture air, sugar solution 4. A gas-liquid solution soda 5. A malleable substance play-doh. modeling clay 6. A solid-liquid solution maybe an amalgam of silver and mercury? tough one - if you think of a decent example let me know 7. A substance which has a volume of 1 cm3 standard sugar cube, cut a cube of soap the proper size 8. An edible example of a physical change melting ice cream 9. An edible example of a chemical change seltzer tablet (barely edible), candies that fizz or pop when damp 10. A pure compound which contains ionic bonds salt 11. A pure compound which contains covalent bonds sucrose or table sugar 12. A mixture that can be separated by filtration fruit cocktail in syrup 13. A mixture that can be separated by some other method than filtration salt water - salt and water can be separated using reverse osmosis or an ion exchange column 14. A substance with a density less than 1g/mL oil, ice 15. A substance with a density more than one any metal, glass 16. A substance which contains a polyatomic ion gypsum (SO42-), epsom salts Page 17 Program of Study 17. An acid vinegar (dilute acetic acid), solid citric acid 18. A metal iron, aluminum, copper 19. A non-metal sulfur, graphite (carbon) 20. An inert gas helium in a balloon, neon in a glass tube, argon if you have access to a lab 21. An alkaline earth metal calcium, magnesium 22. Immiscible liquids oil and water 23. A toy which demonstrates a physical change a toy steam engine 24. The result of a chemical change ashes 25. A mole 18 g of water, 58.5 g of salt, 55.8 g of iron 26. A substance with tetrahedral geometry silicates (sand, quartz), diamond 27. A base with a pH greater than 9 baking soda 28. A polymer a piece of plastic Reference: http://chemistry.about.com/od/chemistry101/a/scavenger.htm Scientific method and its applications Overall Goal: Matter and Energy relationships Specific aims: Matter: Properties and changes Energy and its relationship with matter Page 18 Fall 2010 Program of Study Fall 2010 Overall Goal: Atomic model and its applications Specific aims: Atomic models and subatomic particles Basic concepts (Atomic number, atomic mass, mass number) Electronic configurations and quantum numbers Isotopes and its applications Overall Goal: Periodic table Specific aims: Chemical elements Groups, periods and blocks Periodic properties and its variation in periodic table Importance and use of metal and non metal elements in social and economic life Overall Goal: Chemical bonds and intermolecular interactions Specific aims: Chemical bond, Ionic bond properties, and Properties and formation of covalent bonds Experiment: Physical Properties of Two Solids Some solids consist of molecules in which the atoms are held together by covalent bonds. These compounds are called molecular solids because they are made of molecules (instead of ions). Other solids consist of an array of positive and negative ions, arranged in such a way that every positive ion has only negative neighbours and vice versa; the solid is held together because of the attractions between ions of opposite charge. These substances are called ionic solids. In this experiment, you will examine the physical properties of the molecular solid “camphor” (in which atoms are joined by covalent bonds) and the ionic solid sodium chloride (in which atoms are held together with ionic bonds). Please note that pure camphor can irritate your skin; handle camphor with forceps at all times. Procedure: 1. Set up your retort stand with a ring clamp and clay triangle. You should also have the fume hood in place. Rest an inverted crucible cover in the clay triangle. The cover should be large enough so that it will not pass through the triangle. If the triangle is too large, get another one. Do not light your Bunsen burner yet. 2. Place a few crystals of NaCl on the inverted crucible lid. Smell the sodium chloride; record your observation. 3. Place one small piece of camphor on the lid beside the NaCl. Smell the camphor; record your observation. 4. Place the crucible lid on a clay triangle attached to a retort stand. Set up your fume hood and position the opening directly over the lid. Use a very low Bunsen burner flame (air valve closed, flame about 5 cm high) Page 19 Program of Study 5. 6. 7. 8. Fall 2010 to gently heat the crucible cover until one of the solids melts. Heat the crucible cover strongly for about one minute. Record which compound melts and boils off (only one will disappear). Turn off the Bunsen burner. Get a watch glass and plastic spoon from the front of the room. Onto the watch glass place a sample of NaCl and a piece of camphor (same sizes as before). Crush each of the chemicals with the back of the spoon (by pushing down on the face of the spoon). In the table below, record the hardness of each solid. Obtain two test tubes. Place a few crystals of NaCl in one tube and a sample of camphor in the other. Fill each tube about ¼ full with distilled water. Mix the contents of the tubes by “flicking” the base of the tubes with your finger for about one minute (“flicking” tubes with your fingernail can hurt – use the pad of your finger instead). Note which compound is soluble in water. Keep the test tubes for the next step. Get a plastic spot plate and a conductivity tester (with battery attached). Using the samples at the front of the room, test the conductivity of a large salt crystal and a large camphor crystal. Record your findings. Next, pour some of the liquid from the test tubes (step 6) into two wells of the spot plate. Measure and record the conductivity of the solutions. Dump the contents of the tubes down the sink (place any pieces of camphor in the trash). Rinse and dry the tubes and the spot plate. Return all equipment. This last step will be done as a demonstration: place a sample of NaCl in one tube and a sample of camphor in the other. Fill each tube about ¼ full with the “non-polar” solvent cyclohexane. Mix the contents of the tubes by “flicking” the base of the tubes. Note which compound is soluble in cyclohexane. Sodium chloride 1. 2. 3. 4. 5. 6. 7. 8. 9. Odour (strong, weak, or nil) Type of bonds between atoms (ionic or covalent) Melting point (high or low) Boiling point (high or low) Hardness (hard/brittle or soft) Solubility in a polar solvent such as water (soluble or insoluble) Electrical conductivity of solid (good or poor) Electrical conductivity when dissolved in water (good or poor) Solubility in a non-polar solvent (soluble or insoluble) References: 1. http://www.chalkbored.com/lessons/chemistry-11/two-solids-lab.pdf Metallic bond Intermolecular forces Page 20 Camphor (C10H16O) Program of Study Fall 2010 Overall Goal: Inorganic Chemistry nomenclature Specific aims: IUPAC rules to name inorganic compounds: Metallic oxides, non metallic oxides, metallic hydrides, hydracids, hydroxides, oxyacids, salts. Overall Goal: Chemical reactions Specific aims: Symbols in chemical equations o Decomposition o Simple substitution o Double substitution Chemical reaction balance techniques Overall Goal: Heat and kinetics in chemical reactions Specific aims: Enthalpy o Reaction enthalpy o Formation enthalpy Exothermic Reaction Experiment: How Do You Get Heat from a Supercooled Solution? Explore the Chemistry Within Hand Warmers Abstract You're at the high school football game and it's getting pretty chilly as the sun goes down. You're determined to keep cheering for your team, but your hands are freezing—have you ever tried hand warmers? The chemistry within these little packets is pretty cool. Hand warmers provide a unique and fun way to study the chemistry of crystal formation and heat generation. By pressing a button in a pouch, which contains a supercooled solution, you start a rapid exothermic (heat-producing) crystallization. In this science fair project, you will determine how the starting temperature affects hand warmer chemistry. Objective Page 21 Program of Study Fall 2010 The objective of this chemistry science fair project is to determine how the starting temperature affects crystal growth and heat generation in a supersaturated sodium acetate solution—the solution used in hand warmers. Introduction Hand warmers are pretty cool devices—they are plastic pouches that contain a clear solution of sodium acetate and a small metal disk. When the disk is pushed, the solution crystallizes and the pouch warms up to 58 degrees Celsius (130 degrees Fahrenheit). It stays warm for 20–30 minutes. The hand warmer can be reused many times by simply putting it in hot water. The crystals dissolve when the temperature rises above 58°C, and they stay in the solution as the hand warmer cools to room temperature. Because the solution stays liquid at room temperature, which is below the temperature at which crystals would normally form, it is called a supercooled solution. The disk is slightly curved, so that when it is pushed or flexed, it snaps. The snap of the disk initiates crystallization by producing a small amount of solid sodium acetate trihydrate that functions as a nucleation center for further crystal growth. The crystals form because the sodium acetate solution is supersaturated. A supersaturated solution is a solution that contains more of the solute than the liquid would ordinarily dissolve. You can see the crystals form as a wave of white that flows from the disk to the edges of the hand warmer, as shown in the video below. The crystallization process is exothermic, meaning that heat is emitted. Chemical energy that was stored in the solution is converted into heat energy. In thermochemistry, the amount of energy released by a chemical substance during an exothermic change of state from liquid to solid (or solid to liquid) is called the latent heat of fusion. The latent heat of fusion for the formation of the crystal sodium acetate trihydrate in the hand warmer is approximately 264–289 joules/gram (J/g). Joules (J) are units of energy. The value for the latent heat of fusion tells us that for every gram (g) of crystal formed, about 264 J of energy are released. In this chemistry science fair project, you will investigate how the starting temperature affects the growth of sodium acetate trihydrate crystals. You will also track how the starting temperature affects the temperature vs. time profile associated with crystallization. Terms, Concepts and Questions to Start Background Research Sodium acetate Supercooled solution Sodium acetate trihydrate Nucleation center Supersaturated Solute Exothermic Thermochemistry Change of state Latent heat of fusion Metastable Page 22 Program of Study Fall 2010 Questions Why don't the sodium acetate molecules in the supersaturated room-temperature solution precipitate to form crystals? Hint: What is created in the nucleation center by the snap of the metal disk? What is the trihydrate in sodium acetate trihydrate crystals? What does it mean to refer to the supersaturated solution of sodium acetate as metastable? Bibliography HowStuffWorks, Inc. (n.d.). How do sodium-acetate heat pads work? Retrieved May 4, 2009, from http://www.howstuffworks.com/question290.htm/printable Anne Marie Helmenstine, Ph.D., About Chemistry (2009). Exothermic reactions. Retrieved November 25, 2009, from http://chemistry.about.com/cs/generalchemistry/a/aa051903a.htm Wikipedia Contributors (2009). Crystallization. Retrieved November 25, 2009, from http://en.wikipedia.org/w/index.php?title=Crystallization&oldid=326582702 Materials and Equipment Pot and a lid Water Heat pack hand warmers (1 package); available from sporting goods stores. A single hand warmer is sufficient, but the procedure will go faster with two or three hand warmers. Tea kettle Coolers, any size (2) Infrared thermometer, such as the Mastercool IR thermometer, model # 52224-A, available from www.amazon.com StyrofoamTM or paper plates or trays (3) Lab notebook Stopwatch or other timer Optional: Camera or video camera Optional: Ruler Small piece of cloth, about 30 cm (12 inches) square Ice Tongs Helper Graph paper Disclaimer: Science Buddies occasionally provides information (such as part numbers, supplier names, and supplier weblinks) to assist our users in locating specialty items for individual projects. The information is provided solely as a convenience to our users. We do our best to make sure that part numbers and descriptions are accurate when first listed. However, since part numbers do change as items are obsoleted or improved, please send us an email if you run across any parts that are no longer available. We also do our best to make sure that any listed supplier Page 23 Program of Study Fall 2010 provides prompt, courteous service. Science Buddies receives no consideration, financial or otherwise, from suppliers for these listings. (The sole exception is any Amazon.com or Barnes&Noble.com link.) If you have any comments (positive or negative) related to purchases you've made for science fair projects from recommendations on our site, please let us know. Write to us at scibuddy@sciencebuddies.org. Experimental Procedure Important Notes Before You Begin: In this science fair project, you will observe how the starting temperature affects the rate of crystal growth, the size of the crystals, and the temperature in the hand warmer after activation. The procedure calls for varying the starting temperature of the hand warmer. The starting temperatures will be 0°C, 20°C, and 40°C. To get the hand warmers to these temperatures, you will place the hand warmers in water baths. The water bath at 0°C will be just ice water. The other water baths will be made by adding hot water to room temperature water until the proper temperature is obtained. Preparing the Setup 1. Heat water to boiling in the pot with the lid. Keep it boiling as you start your experiment. a. 2. This pot of hot water will be used to melt the crystals and to regenerate the hand warmer. Heat water in the tea kettle to boiling, then remove it from the heat. a. This water will be used to raise the temperature in the water baths. 3. Add room-temperature tap water to one of the coolers so that the water level will cover a hand warmer, but do not place a hand warmer in there yet. 4. Add hot water from the tea kettle to the water in the cooler until the water temperature is 20°C. 5. Place a hand warmer in the 20°C water bath. 6. Allow a few minutes for the hand warmer to come to the same temperature as the water in the cooler. 7. Adjust the temperature with hot or cold water to keep the water bath at 20°. Observing Crystallization Growth Note: In the following steps, be ready with the timer and the infrared thermometer to observe and record the changes that occur after crystallization is initiated. Have your helper assist you in taking readings and writing the data. 1. Remove the hand warmer from the 20° water bath. 2. Record the starting temperature and the time in your lab notebook. 3. Place the hand warmer on the Styrofoam tray. a. This insulates the hand warmer so that heat lost to the surface is minimized. b. You can also use an upside-down paper plate. 4. Snap the metal disk in the hand warmer and start the timer. Start the timer at the same time as you snap the disk. 5. Time how long it takes for the entire hand warmer to crystallize. a. Watch the hand warmer carefully as the crystals form. Page 24 Program of Study 6. b. Use your judgment about when the entire contents of the hand warmer have crystallized. c. Write down your criteria for determining that the entire contents of the hand warmer have crystallized. Record the temperature of the hand warmer every minute for 15 minutes. a. 7. Fall 2010 Feel free to change the time or duration of the measurements if you choose, but be sure to use the same time/duration for each trial. For example, take the temperature every 15 seconds for the first minute and every minute for 30 minutes thereafter. Observe the crystals that are formed. Write all observations in your lab notebook. a. Record their shape. b. Record the maximum length of the crystals. c. i. It will be difficult to obtain precise measurements of the crystals' length in the hand warmer since they break easily and grow into each other. Just do your best to estimate. ii. As an option, photograph or film the hand warmer during crystallization and analyze the images later. Include a ruler in the pictures so you know the scale. Sketch the crystals in your lab notebook, or use photographs. 8. To reactivate the hand warmer, wrap it in a piece of cloth and place it in the pot of boiling water for several minutes. 9. Use tongs to remove the hand warmer from the water. 10. Repeat steps 3–7 of Preparing the Setup and steps 1–9 of this section two more times. Observing the Effect of a Cold Starting Temperature on Crystallization Growth 1. Add ice and water to one of the coolers, enough that it will cover a hand warmer. 2. Place the reactivated hand warmer in the ice water. 3. Allow a few minutes for the hand warmer to cool to the same temperature as the ice water. 4. Remove the hand warmer from the ice water. 5. Record the starting temperature and the time in your lab notebook. 6. Snap the metal disk in the hand warmer. 7. Start the timer. 8. Observe the crystal growth and temperature change, as you did in the previous section. 9. Reactivate the hand warmer and repeat steps 1–8 of this section two more times. Observing the Effect of a Hot Starting Temperature on Crystallization Growth 1. Add enough room-temperature tap water to one of the coolers so that the water level will cover a hand warmer. Do not place the hand warmer inside yet. 2. Add hot water from the kettle to the water in the cooler until the water temperature is 40°C. 3. Place a reactivated hand warmer in the 40°C water bath. 4. Allow a few minutes for the hand warmer to come to the same temperature as the water in the cooler. 5. Remove the hand warmer from the water. 6. Record the starting temperature and the time in your lab notebook. Page 25 Program of Study 7. Snap the metal disk in the hand warmer. 8. Start the timer. 9. Observe the crystal growth and temperature change, as you did in the previous sections. Fall 2010 10. Reactivate the hand warmer and repeat steps 1–8 of this section two more times. Analyzing Your Results 1. For the time it took to complete crystallization: a. 2. For the temperature vs. time data: a. 3. Graph the Time on the x-axis and the Temperature of the Hand Warmer on the y-axis. For the length of the crystals: a. 4. Graph the Starting Temperature on the x-axis vs. the Time to Complete Crystallization on the yaxis. Graph the Starting Temperature on the x-axis and the Maximum Length of the Observed Crystals on the y-axis. Discuss your results. For example, what was the maximum temperature reached for each starting temperature, and how long did it take to reach it? Does the temperature remain constant for any length of time for each of the hand warmers? Why? Which hand warmer had the longest crystals? Variations Repeat the procedure above with additional starting temperatures, such as: minus 10°C (use a freezer), 30°C, and 50°C. Set up a calorimetry apparatus to measure the amount of energy produced by the hand warmer. Calculate the mass of the sodium acetate trihydrate, based on the results. The mechanism by which the metal disk initiates crystallization is not well characterized. Make a hypothesis about what happens when the disk is snapped and devise a procedure to test it. What is the highest temperature at which you can form crystals in the hand warmer? For more science project ideas in this area of science, see Chemistry Project Ideas. Credits David B. Whyte, PhD, Science Buddies Parts of the procedure were inspired by the following NASA project: Donald, J. (n.d.). Rapid Crystallization. Retrieved May 6, 2009, from http://quest.arc.nasa.gov/space/teachers/microgravity/12rapid.html StyrofoamTM is a registered trademark of The Dow Chemical Company. Endothermic reactions Experiment: Cold Pack Chemistry: Where Does the Heat Go? Page 26 Program of Study Fall 2010 Abstract Instant cold packs are popular with coaches and parents for treating minor bumps and bruises. The instant cold packs are not pre-cooled—you just squeeze the cold pack and its starts to get cold. So how does it work? In this chemistry science fair project, you will investigate the chemical reaction that occurs in instant cold packs. Objective The objective of this chemistry science fair project is to determine how the temperature of a mixture of water and ammonium nitrate changes with the amount of ammonium nitrate dissolved in the water. Introduction Have you ever used a hot pack to warm your hands or a cold pack on an injury? How can something produce heat or cold without any microwaving or refrigeration involved? The answer is: chemistry. Chemical reactions that produce heat are called exothermic. The burning of gasoline in a car engine is an example of an exothermic reaction. Reactions that are accompanied by the absorption of heat are called endothermic. As an example of an endothermic reaction, when the chemical ammonium nitrate is dissolved in water, the resulting solution is colder than either of the starting materials. This kind of endothermic process is used in instant cold packs. These cold packs have a strong outer plastic layer that holds a bag of water and a chemical, or mixture of chemicals, that result in an endothermic reaction when dissolved in water. When the cold pack is squeezed, the inner bag of water breaks and the water mixes with the chemicals. The cold pack starts to cool as soon as the inner bag is broken, and stays cold for over an hour. Many instant cold packs contain ammonium nitrate. Ammonium nitrate is a white crystalline substance. When it is dissolved in water, it splits into positive ammonium ions and negative nitrate ions. In the process of dissolving the crystal, the water molecules "donate" some of their energy. As a result, the water cools down. How much heat energy is "lost" when ammonium nitrate dissolves in water? You can measure the amount of heat that is involved using Equation 1. Equation 1: q = c m (T1 -T2) q = energy, measured in joules (J) c = heat capacity, measured in joules per gram per degree Celsius, J/(g°C) m = mass of solution, measured in grams (g) J = joules (J), unit of energy g = grams (g) of water °C = degrees Celsius T1 = starting temperature, in degrees Celsius T2 = lower temperature after ammonium nitrate has dissolved, in degrees Celsius Page 27 Program of Study Fall 2010 Equation 1 states that "the amount of heat energy that is lost when water changes from temperature T1 to the lower temperature, T2, equals the difference in the two temperatures, times the heat capacity, times the mass of the solution." The heat capacity of a substance tells you how much the temperature will change for a given amount of energy exchanged. For water at 25°C, the heat capacity is 4.18 J/(g°C). Equation 2: c (water) = 4.18 J (g°C) c = heat capacity, measured in joules per gram per degrees Celsius, (J/g°C) J = joules (J), unit of energy g = grams (g) of water °C = degrees Celsius Equation 2 says that "the heat capacity of water is 4.18 joules per gram of water per degree Celsius." What this means is that if you add 4.18 J of heat energy to 1 g of water, its temperature will increase by 1.0°C. Substances other than water have different heat capacities. In this chemistry science fair project, you will determine how the amount of ammonium nitrate that is dissolved in water affects the magnitude of the temperature change that occurs. In the procedure, you will dissolve different amounts of ammonium nitrate in water and measure the before and after temperatures, then graph the temperature change vs. grams of ammonium acetate added. Terms, Concepts and Questions to Start Background Research Exothermic Endothermic Ammonium nitrate Ion Heat energy Heat capacity Joule (J) Entropy Questions Based on your research, what are some examples of exothermic and endothermic reactions? What is the chemical formula for ammonium nitrate dissolving in water? Page 28 Program of Study Fall 2010 How does the heat capacity of water compare with the heat capacity of other common materials, such as aluminum, glass, or air? Based on your research, what is the definition of entropy? Does it increase or decrease when ammonium nitrate dissolves in water? Bibliography Wikipedia Contributors. (2009, April 14). Specific Heat Capacity. Wikipedia: The Free Encyclopedia. Retrieved April 30, 2009, from http://en.wikipedia.org/w/index.php?title=Specific_heat_capacity&oldid=283732656 Helmenstine, H.M. (n.d.). Exothermic and Endothermic Reactions. Retrieved April 30, 2009, from http://chemistry.about.com/cs/generalchemistry/a/aa051903a.htm These more-advanced sites discuss the thermodynamics of the ammonium nitrate reaction. The W.W. Norton site has nice Flash tutorials that explain the basic chemistry. Tissue, B.M. (2000). Thermodynamics of Ammonium Nitrate Dissolving in Water. Retrieved April 30, 2009, from http://www.files.chem.vt.edu/chem-ed/thermo/reaction.html W.W. Norton and Company. (2003). Flash Tutorial: Ammonium Nitrate Dissolution.Retrieved April 30, 2009, from http://www.wwnorton.com/college/chemistry/gilbert/overview/ch13.htm Materials and Equipment StyrofoamTM cups, 12-ounce (oz.) (5) Permanent marker Water, distilled Measuring cup, liquid Latex gloves Safety goggles Scissors Instant cold packs containing ammonium nitrate and water (4). Instant cold packs are available at most sporting goods stores. The water is in a separate bag within the cold pack. Plastic bowl, disposable Wax paper, cut into 10-cm squares (15, more as needed) Plastic spoons (5) Newspaper, scrap to cover your work surface Digital scale, accurate to at least 1 g o As an option, use a scale accurate to 0.1 g, such as the American Weigh AMW-100 Digital Pocket Scale with 100-g calibration weight, available from www.amazon.com Digital thermometer, such as the Mastercool IR thermometer from www.amazon.com Lab notebook Digital timer Page 29 Program of Study Helper Graph paper Experimental Procedure Performing the Experiment 1. Label the Styrofoam cups with numbers 1 to 5. 2. Add 100 mL of distilled water to each of the five cups. 3. Cover the work surface with newspaper. 4. Collect the ammonium nitrate from the instant cold pack, as follows: a. Put on your safety goggles and latex gloves. b. Shake the instant cold pack gently to move the water bag and crystals to the bottom. c. Cut the top of the bag off. d. Pour the ammonium nitrate crystals into the plastic bowl. e. Dispose of the water bag. Figure 1. Ammonium nitrate from an instant cold pack. f. Place one of the wax paper squares on the scale. Page 30 Fall 2010 Program of Study 6. g. Zero the scale. h. Use a plastic spoon to add 10.0 g of ammonium nitrate on the square. Fall 2010 Record the starting temperature of the water in cup # 1 in a data table in your lab notebook. f. Point the digital thermometer at the water's surface and push the "on" button to get the temperature. 7. Add 10.0 g of ammonium nitrate to the water in cup # 1. 8. Start the timer. 9. Stir the contents with a plastic spoon. 10. Record the temperature every 15 seconds (sec) until it stabilizes. . You can record at longer intervals, such as 30 sec, if you choose. a. You might want a helper to write the times and temperatures down as you take the readings. b. Stir the contents of the cup gently between each reading. c. Remove the spoon when taking the temperature, as it may cause an error in the reading. d. Stop taking readings when the temperature stops decreasing. 11. Dispose of the ammonium nitrate solution down the sink. 12. Repeat steps 6–9, with new and clean materials and equipment, adding the following amounts of ammonium nitrate. Note: You may need to divide the ammonium nitrate onto two or more pieces of wax paper if it will not all fit on one piece. Be sure to record the starting temperature, the intermediate temperatures, and the final temperature for each sample. . Cup #2: 20 g a. Cup #3: 30 g b. Cup #4: 40 g c. Cup #5: 50 g 13. Repeat steps 1–11 two more times, so you have at least three trials. This ensures that your results are accurate and repeatable. Create a new data table for each trial. You can reuse the spoons and cups for the new trials, after rinsing them thoroughly with water. 14. Dissolve any leftover ammonium nitrate in water and dispose of it in a sink. Analyzing Your Results 1. Look at your data tables. Subtract the ending temperature from the beginning temperature for each cup. 2. Add the mass of ammonium nitrate to the data table for samples 1–5. 3. Graph the data, with the grams of ammonium nitrate on the x-axis and the temperature difference on the y-axis. 4. How does the final temperature change as more ammonium nitrate is added? 5. Using Equation 1 from the Introduction, calculate the heat energy, q, in joules, that each sample lost. a. Use the heat capacity value from Equation 2 for "c." b. Use the total mass (water plus ammonium nitrate) for "m": 110 g for cup #1, 120 g for cup #2, etc. Page 31 Program of Study c. 6. Fall 2010 Use the temperature change from the table for T1 - T2. Graph the results, with the amount of ammonium nitrate in grams on the x-axis and the heat energy (q) on the y-axis. Variations Use different amounts of ammonium nitrate. What happens when the solution becomes saturated (that is, no more ammonium nitrate can be dissolved)? Graph the temperature vs. time for each sample. Look at the slope of the graphs. Do they all have the same initial rate of change, or does the initial rate of change increase as the amount of crystal increases? Calculate q/gram for each sample. Graph the results. What are some sources of error in the procedure? Devise a new procedure that reduces or eliminates the sources of error you identified. Devise a procedure to determine how varying the starting temperature affects the size of the temperature change. Compare ammonium nitrate with other chemicals, such as ammonium chloride, calcium chloride (exothermic), and sodium chloride. Research the thermodynamics of the ammonium nitrate dissolution and calculate the enthalpy and entropy changes that occur. For more science project ideas in this area of science, see Chemistry Project Ideas. Credits David B. Whyte, PhD, Science Buddies StyrofoamTM is a registered trademark of The Dow Chemical Company. Reaction velocity Experiment: Investigate the Kinetics of the Amazing Iodine Clock Reaction Abstract The iodine clock reaction is a favorite demonstration reaction in chemistry classes. Two clear liquids are mixed, resulting in another clear liquid. After a few seconds, the solution suddenly turns dark blue. The reaction is called a clock reaction because the amount of time that elapses before the solution turns blue depends on the concentrations of the starting chemicals. In this chemistry science fair project, you will explore factors that affect the rate of the iodine clock reaction. Objective Determine how the concentration of hydrogen peroxide affects the rate of the iodine clock reaction and calculate the reaction order. Page 32 Program of Study Fall 2010 Introduction Chemical kinetics is the branch of chemistry that is concerned with the mechanisms and rates of chemical reactions. The mechanism of a chemical reaction is a description of what happens to each molecule at a very detailed level—which bonds are broken, which new bonds are formed, and how the three-dimensional shapes of the chemicals changes during the course of the reaction. The rate of the reaction is a measure of its speed. The rate of a chemical reaction can be measured by how quickly the reactants disappear, or by how quickly the products are generated. The iodine clock reaction is a favorite demonstration in chemistry classes because it has an element of drama. Two clear solutions are mixed, producing a new clear solution. Then, after a period of several seconds, the solution turns dark blue. As mentioned, chemical kinetics measures how fast a reaction is occurring. For most chemical reactions, the rate is so fast that special equipment is needed to measure it. For the iodine clock reaction, on the other hand, the rate can be easily measured with a stopwatch. To perform the iodine clock reaction in this science fair project, you will mix potassium iodide, hydrochloric acid, starch, thiosulfate and hydrogen peroxide. The time it takes for the reaction mix to turn blue will be measured with a stopwatch. For the procedure, you will vary the amount of hydrogen peroxide to see how this affects the time the mixed chemicals stay clear before turning blue. The reactions that form the basis for the iodine clock reaction are shown below. Equation 1: H2O2 + 3 I- + 2 H+ → I3- + 2 H2O H2O2 = Hydrogen peroxide I- = Iodide ion (from potassium iodide) H+ = A proton, from hydrochloric acid (HCL) I3- = Triiodide H2O = Water This equation states that hydrogen peroxide reacts with iodide ions in acid solution to form triiodide and water. Triiodide has the very interesting property of reacting with starch to form a dark blue complex. There is starch in the mix of chemicals, so why doesn't the triiodide react with it? The reason the triiodide doesn't react with the starch is that it is immediately consumed in a reaction with the thiosulfate. Equation 2: I3S- + 2 S2O32- → 3 I- + S4O62 I3S- = Triiodide S2O32- = Thiosulfate ion 3 I- = Iodide ion Page 33 Program of Study Fall 2010 S4O62- = Tetrathionate ion Equation 2 says that triiodide reacts with thiosulfate to form iodide ions and tetrathionate. The reaction in Equation 2 happens so fast that none of the triiodide has time to form a complex with starch, even though the starch is in the reaction mix. The reactions in Equations 1 and 2 are moving along during the lag time between mixing the chemicals and the dramatic appearance of the blue color. Note that iodide ions are regenerated in Equation 2, so they are available to react with the hydrogen peroxide in Equation 1. The thiosulfate, on the other hand, is consumed as it is turned into tetrathionate. The lag period ends when the thiosulfate is all used up. At this time, the triiodide is able to react with the starch. Equation 3: I3- + starch → (I3- starch complex) I3- = Triiodide I3- starch complex, which is blue This equation says that starch reacts with triiodide to form a blue complex. The faster the reaction in Equation 1 goes, the faster the triiodide uses up the thiosulfate and the faster the triiodide is free to react with the starch. What is the rate of the first reaction? The rate of the reaction in Equation 1 is a measure of how the concentration of hydrogen peroxide changes per unit time: Equation 4: Rate = [Change in (H2O2)]/sec (H2O2) = Concentration of hydrogen peroxide Equation 4 indicates that the rate of the reaction is proportional to the reciprocal of the time. The rate of a reaction depends on the concentration of the reactants. In Equation 1, for example, increasing the amount of hydrogen peroxide will increase the rate at which it reacts with iodide. The concentrations of iodide and acid remain the same, so the rate will depend only on the changes in hydrogen peroxide concentration. (The iodide is recycled between Equations 1 and 2, and the concentration of acid is high enough that the change in its concentration is small. Note the concentrations of the reactants in the Materials and Equipment section). The rate actually depends on the concentration of hydrogen peroxide raised to a power, called the "reaction order." Equation 5: Rate = k(H2O2)x Page 34 Program of Study k = Rate constant, in 1/seconds (s) (H2O2) = Concentration of hydrogen peroxide, in moles/liter x = Order of the reaction for hydrogen peroxide, unitless Fall 2010 The good news from Equation 5 is that the rate depends on the concentration of hydrogen peroxide, and you will know what the concentration of hydrogen peroxide is when the reaction starts. You will use the number of hydrogen peroxide drops as a measure of its concentration. There are many ways to explore the chemistry of the iodine clock reaction. The details of the reaction mechanisms can be studied by varying the concentrations of other reactants, in addition to hydrogen peroxide. And it is ideal for investigating the effect of temperature on reaction rates. Some of these areas are touched on in the Variations. Now, let's get started. Terms, Concepts and Questions to Start Background Research Chemical kinetics Chemical reaction Mechanism Rate Reactant Product Iodine clock reaction Solution Potassium iodide Hydrochloric acid Starch Thiosulfate Hydrogen peroxide Complex Questions What would happen to the iodine clock reaction if the reaction shown in Equation 2 were very slow instead of very fast? What is the acid that is used in the reactions described above? Based on your research, what is chemical complex? Page 35 Program of Study Fall 2010 What is the structure of the starch and triiodide complex? Why is it blue? Why does the rate of Equation 2 depend on the rate of Equation 1? How would adding more thiosulfate affect the lag period of the clock reaction? Some sources state that triiodide is not really the form of iodine in the starch complex. What other forms have been proposed and which way does the evidence point (triiodide or not) in your opinion? How can Equations 4 and 5 be combined? Hint: The result should show that the reciprocal of the time is proportional to the hydrogen peroxide concentration raised to the value of x, the rate constant. Bibliography 1. Wikipedia Contributors. (2009, September 28). Iodine clock reaction. Wikipedia: The Free Encyclopedia. Retrieved October 30, 2009, from http://en.wikipedia.org/w/index.php?title=Iodine_clock_reaction&oldid=316671620 2. Division of Chemical Education, Inc., American Chemical Society. (1999). Iodine clock reaction videos. Retrieved October 30, 2009, from http://jchemed.chem.wisc.edu/JCESoft/CCA/CCA3/MVHTM/CLOCKRX/CLOCK1.HTM 3. Brooks, David W. University of Nebraska, Lincoln (n.d.). Iodine Clock Kinetics. Retrieved October 30, 2009, from http://dwb4.unl.edu/chemistry/smallscale/SS055.html 4. Department of Chemistry, The University of North Carolina at Chapel Hill. (2008). Kinetics. Retrieved October 30, 2009, from http://www.shodor.org/unchem/advanced/kin/index.html Materials and Equipment Latex gloves; available at hardware stores Safety goggles Newspaper to protect work area Reaction kinetics kit; available from www.enasco.com o Contact Aldon Sciences for a list of other vendors that supply this kit at 1-800-724-9877 or email them at info@aldon-chem.com o The kit should contain the following solutions and materials: potassium iodide 0.1% solution, hydrogen peroxide 3%, sodium thiosulfate 0.001 M, hydrochloric acid, 0.1M, starch capsules, pipettes Beaker, 50-mL; available from online science supply stores, such as WARD's Natural Science at wardsci.com, item # 18 V 1000 Distilled water (1 gallon); available at grocery stores Micro titer plates; available from online suppliers, such as WARD's Natural Science at wardsci.com, Poyethylene Spot Plate, Item # 18 V 1371 o As an alternative to the micro titer plate, mix the drops on a piece of plastic wrap that is spread over a piece of white printer paper. Toothpicks Stopwatch or other timer White piece of printer paper Page 36 Program of Study Permanent marker Thermometer Lab notebook Fall 2010 Disclaimer: Science Buddies occasionally provides information (such as part numbers, supplier names, and supplier weblinks) to assist our users in locating specialty items for individual projects. The information is provided solely as a convenience to our users. We do our best to make sure that part numbers and descriptions are accurate when first listed. However, since part numbers do change as items are obsoleted or improved, please send us an email if you run across any parts that are no longer available. We also do our best to make sure that any listed supplier provides prompt, courteous service. Science Buddies receives no consideration, financial or otherwise, from suppliers for these listings. (The sole exception is any Amazon.com or Barnes&Noble.com link.) If you have any comments (positive or negative) related to purchases you've made for science fair projects from recommendations on our site, please let us know. Write to us at scibuddy@sciencebuddies.org. Experimental Procedure Performing the Experiment 1. Be sure to wear your safety goggles and latex gloves. 2. Protect the surface on which you are working with newspaper. 3. Prepare a 1% starch solution by dissolving a starch capsule from the reaction kinetics kit in 50 mL of distilled water in the beaker. 4. Set up the micro titer plate for the first set of experiments. 5. a. As an alternative, mix the drops on a flat piece of plastic wrap that is placed over a piece of white printer paper. Separate the drops by 2–3 centimeters (cm). b. Look at the mixed drops against a white background; for example, against a white piece of paper. c. Experiments will be run in duplicates (two wells per test). d. If you do not get reproducible results, run the experiment again. In two adjacent wells, add the following (use the pipettes that came with the kit) to each well: a. 4 drops of the potassium iodide (KI) solution b. 2 drops of water c. 2 drops of hydrochloric acid d. 1 drop of starch solution e. 1 drop of thiosulfate solution f. 8 drops of hydrogen peroxide 6. Mix well with a toothpick. 7. Start the timer. Begin timing as soon as the hydrogen peroxide is added. 8. Record the time that you can first see some blue color developing in your lab notebook. a. Call this the time lag. b. Also record the room temperature. Varying the Hydrogen Peroxide Concentration Page 37 Program of Study Fall 2010 Note: You will now continue the procedure using one less drop of hydrogen peroxide and one more drop of water. The first two sets are detailed below. For 7 drops hydrogen peroxide: 1. In two adjacent wells, add the following to each well: a. 4 drops of the potassium iodide (KI) solution b. 3 drops of water c. 2 drops of hydrochloric acid d. 1 drop of starch solution e. 1 drop of thiosulfate solution f. 7 drops of hydrogen peroxide 2. Mix well with a toothpick. 3. Start the timer. 4. Record the time that the solution turned blue. 5. Record the room temperature. For 6 drops hydrogen peroxide: 1. In two adjacent wells, add the following: a. 4 drops of the potassium iodide (KI) solution b. 4 drops of water c. 2 drops of hydrochloric acid d. 1 drop of starch solution e. 1 drop of thiosulfate solution f. 6 drops of hydrogen peroxide 2. Mix well with a toothpick. 3. Start the timer. 4. Record the time that the solution turned blue. 5. Record the room temperature. Completing the Experiment 1. Repeat steps 1–5 for 5, 4, 3, 2, and 1 drop of hydrogen peroxide. Remember, each time, add one drop of water and subtract one drop of hydrogen peroxide. This will keep the total volume of the reaction constant, while changing the concentration of the hydrogen peroxide. 2. Perform the entire procedure two more times with clean materials. This will demonstrate that your results can be repeated. Analyzing Your Results 1. Make a data table that shows the following: Page 38 Program of Study 2. 3. 4. Fall 2010 a. The number of drops of hydrogen peroxide. b. The time lag for each test, in seconds (sec). c. Average of the time lags for similar samples, in seconds. For example, average the three trials for the set with seven drops of hydrogen peroxide. d. The reciprocal of the average time lag for each test, in 1/sec. Graph the number of drops of hydrogen peroxide on the x-axis and the reciprocal of the time lag on the yaxis. a. The reciprocal of the time lag is proportional to the rate, so the y-axis is a measure of the reaction rate. b. Label the y-axis Reaction rate and the x-axis Concentration of hydrogen peroxide. Note the shape of the curve. From Equation 5 in the Introduction, the curve shape depends on "x," the order of the reaction for hydrogen peroxide. a. If x = 1, the curve will be a straight line. (Doubling the hydrogen peroxide will double the reaction rate). b. If x = 2, the curve will look like the curve for y = x2, which is a parabola (doubling the hydrogen peroxide will make the reaction go four times faster). Based on your results, what is the order of the reaction for hydrogen peroxide? Variations Graph the number of drops on the x-axis and the time lag on the y-axis. What does this graph show? Calculate the concentration of hydrogen peroxide for each sample and use this number in your analysis. Vary the concentration of other reagents, such as potassium iodide or thiosulfate. Predict how the changes will affect the rate then design a procedure to test your hypothesis. Devise a procedure to test how the reaction rate changes with temperature. Use a graphing program to determine the value of "x" in your graph of the rate vs. hydrogen peroxide concentration. For more science project ideas in this area of science, see Chemistry Project Ideas. Credits David B. Whyte, PhD, Science Buddies Sustainable development Page 39 Program of Study Chemistry II Overall Goal: Mole as a unit to measure chemical processes Specific aims: Mole as a basic unit Chemical laws of mass, definite proportions, multiple proportions and reciprocal proportions. Stoichiometric calculus Mole-mole, mass-mass, volume-volume relations Minimal formula Overall Goal: Reduction of pollution in air, water and soil techniques Specific aims: Pollution in soil, water and air Primary and secondary contaminants Chemical reactions related to pollution Thermal inversion, smog and acid rain Overall Goal: Disperse systems Specific aims: Element, compound, mixture: homogeneous, heterogeneous Separation techniques Elements, compounds and mixtures’ characteristics. Page 40 Fall 2010 Program of Study Overall Goal: Carbon compounds in the environment Specific aims: Electronic configuration of carbon and its molecular geometry Molecular geometry Types of isomers and chains Physical properties, nomenclature and carbon compounds use Alkanes, alkenes, alkynes Functional groups: alcohols, ethers, aldehydes, ketones, carboxylic acids. Overall Goal: Natural and synthetic macromolecules Specific aims: Monomers and polymers Lipids, proteins and carbohydrates Addition and condensation polymers Page 41 Fall 2010 Program of Study Fall 2010 Physics I Overall Goal: Relate the scientific knowledge and physic magnitudes, and basic tools to understand natural phenomena Specific aims: Identify prefixes used in the International System SI. Identify types or errors in different kinds of measurements. Analyze the precision of different instruments. Identify scalar and vector magnitudes. Identify characteristics of a vector. Properties of vectors. Overall Goal: Identify the differences among different types of movement Specific aims: Recognize concepts related to motion (distance, time, position, displacement, speed, velocity, acceleration, reference system). Identify characteristics of movements. One dimension: uniform rectilinear, uniform accelerated rectilinear, free fall. Two dimensions: Parabolic, uniform circular motion, accelerated circular motion. Overall Goal: Understand the utility in practice of Motion Newton Laws Specific aims: Describe historic background in the study of mechanical movement. (Aristotle, Galileo Galilei, Isaac Newton). Define Newton's Law (Inertia, Force=Mass acceleration, action and reaction). Use these laws to solve problems and use them to explain daily situations. Experiment: Rocketology: Baking Soda + Vinegar = Lift Off! Abstract Watching a space shuttle or a rocket launch is an amazing experience. It is thrilling to see the rocket lift off and escape Earth's gravity. Did you know that it takes a chemical reaction to get a rocket into space? Every time you see a rocket blast off, you are watching chemistry at work. In this chemistry Page 42 Program of Study Fall 2010 science fair project, you'll also get to blast an object into the air. You won't be using the same fuel that NASA uses for their rockets; instead, you will use two simple ingredients—baking soda and vinegar. The interesting part will be to figure out how much you need of each one. If you are interested in becoming a rocket scientist in the future, you should definitely try this science fair project. Objective To determine the correct ratio of baking soda to vinegar that will result in the highest launch of a plastic canister. Introduction Have you ever watched a space shuttle launch on television or seen one live? One question that may have crossed your mind when watching this awesome spectacle is, "How does a space shuttle lift off and get into space?" The simple answer to this question is that the space shuttle has engines that lift it into space. But all of that fire and smoke is not an explosion. All rockets depend on combustion to provide the thrust that is required for a vessel to overcome the force of gravity and climb into space. The space shuttle is made up of the orbiter (which holds the astronauts and different kinds of payload), the dark orange-colored external fuel tank, and two solid rocket boosters. At launch, the two solid rocket boosters, along with three space shuttle main engines, power the liftoff. Contrary to popular belief, it doesn't take an explosion to get a rocket ship off of the earth. Rocket engines function on the principle of combustion. Combustion is a chemical reaction between a fuel and an oxidant where the fuel is burned or oxidized. An oxidant or oxidizer is a chemical that causes another chemical to burn. In the solid rocket boosters, the fuel is aluminum and the oxidant is ammonium perchlorate. The three space shuttle main engines use liquid hydrogen as the fuel and liquid oxygen as the oxidant. Combustion produces great amounts of exhaust gas at high temperatures and pressure. The hot gases are pushed out from the bottom of the rocket and thus, the rocket is thrust upward. This is an example of Isaac Newton's third law of motion, which states that for every action, there is an equal and opposite reaction. The gases exiting from the rocket have a downward force that is equal and opposite to the force with which the rocket moves up. Mixing the fuel and oxidant together correctly is complicated and something that real rocket scientists work hard to perfect. In this chemistry science fair project, you will become a rocket scientist, but instead of using dangerous chemicals, you will use a chemical reaction between baking soda (sodium bicarbonate) and vinegar (acetic acid). This reaction produces water and carbon dioxide. Carbon dioxide is what makes soda fizzy and bubbly, which is why you see lots of bubbling and foaming when you mix baking soda and vinegar together. You will mix baking soda and vinegar in a capped film canister and take advantage of the pressure the carbon dioxide gas creates in the canister to launch your own small-scale rocket, experimenting with how different amounts of baking soda and vinegar affect the launch height. You might not be launching the space shuttle, but you will still have messy fun escaping the force of gravity for a few seconds with your own rocket! Terms, Concepts and Questions to Start Background Research Combustion Thrust Gravity Chemical reaction Page 43 Program of Study Fuel Oxidation Exhaust Pressure Newton's third law of motion Ion Fall 2010 Questions What is a chemical reaction? What is combustion? Can you describe Newton's third law of motion and come up with examples? Describe the chemical reaction between baking soda and vinegar Bibliography Wikipedia Contributors. (2009, September 1). Space Shuttle. Wikipedia: The Free Encyclopedia. Retrieved September 3, 2009, from http://en.wikipedia.org/w/index.php?title=Space_Shuttle&oldid=311180564 The following NASA website has information on everything you have ever wanted to know about rockets. Benson, T. (ed). (2007, October 10). NASA: Rocket Index. Retrieved September 1, 2009, from http://exploration.grc.nasa.gov/education/rocket/shortr.html If you would like to know more about the baking soda and vinegar reaction, take a look at this website. Apple-cider-vinegar-benefits.com. (n.d.). Baking Soda and Vinegar Reaction and Demonstrations. Retrieved September 1, 2009, from http://www.apple-cider-vinegarbenefits.com/baking-soda-and-vinegar.html For help creating graphs, try this website: National Center for Education Statistics. (n.d.). Create a Graph. Retrieved June 2, 2009, from http://nces.ed.gov/nceskids/CreateAGraph/default.aspx Materials and Equipment Plastic Fuji® film canisters with the tops (at least 3) Construction paper, any color, 9 inches (in.) X 12 in. (1 pack) Scotch® tape (1 roll) Scissors Permanent marker Ruler, in inches Page 44 Program of Study Optional: Ladder Baking soda (1 box) White vinegar (1/2 gallon bottle or jug) Measuring spoon, 1/8 teaspoon (tsp.) Measuring spoon, 1 tsp. Bowl Water Spoon Safety goggles Adult volunteer Lab notebook Fall 2010 Experimental Procedure Note: Since this science fair project can be messy, you should perform all tests outside. Your location should be along a tall wall and free from debris. Preparing Your Test Area 1. Start building the body of the rocket. Take a piece of construction paper and wrap it around the film canister. Make sure to wrap along the short side of the paper, about 2 millimeters below the lip of edge of the canister, and make sure that the lid is not enclosed or covered by the tube of paper. Wrap the paper neatly and evenly along the canister and use the scissors to remove the excess paper from the bottom. Secure the paper with a few pieces of Scotch tape. 2. Now tape several pieces of construction paper together to make a very large piece of construction paper. Make the large piece of construction paper three paper pieces wide and as tall as your wall. 3. Starting from the bottom of the large paper, use the ruler and permanent marker to mark off every 6 inches. Next to each mark, write down the length, in feet (such as ½ foot, 1 foot, etc.). Tape the paper to the wall, making sure that the bottom of the paper should be even with the bottom of the wall and the ground. You can ask your adult volunteer to the climb the ladder and help tape the paper to the wall. 4. Create a data table in your lab notebook so that you can keep track of the data that you collect. It should look like the one shown below. Amount of Baking Soda Amount of Vinegar Page 45 Trial Launch Height (Feet) Program of Study Fall 2010 Preparing the Rocket 1. Now prepare the fuel for the rocket. Place 1 tsp. of baking soda in the bowl. Carefully add 1/8 tsp. of water to the baking soda and mix it in. This should wet the baking soda enough so that you can pack it into the depression on the inside of the canister lid. Turn the film canister lid over and pack the inside of the depression. Turn the lid upside-down and make sure that the baking soda doesn't fall out. If the baking soda falls, out then add a little bit more water to the baking soda and mix it in. Try to add only a minimal amount of water to the baking soda in order to make it stick together inside the lid. Record the amount of baking soda that you used in your lab notebook. 2. Have your volunteer hold the wrapped film canister and add 1 tsp. of vinegar to the wrapped canister at a time, filling it almost to the top. You need to add as much vinegar to the canister as possible without the vinegar and the baking soda coming into contact when you eventually snap the lid onto the canister. This might take a little trial and error, but be patient and keep trying. Keep careful track of and record the amount of vinegar in your lab notebook. 3. Go over to the area where you have taped your paper to the wall. Have your volunteer hold the baking soda-packed lid in one hand and the wrapped canister in the other. Put on you safety goggles. Stoop down near the bottom of the paper and quickly snap the lid onto the canister. Turn the canister over so the lid is on the ground, and quickly move away. Wait for the chemical reaction to occur (the time depends on the amount of baking soda and vinegar you are using). 4. When the lid finally pops off, the rocket should overcome gravity and launch. You and your volunteer should watch to see how high it goes and record the launch height in your lab notebook. 5. Carefully rinse out the lid and canister with water. Make sure that the construction paper doesn't get too wet. 6. Repeat steps 1–5 two more times, always recording the launch height in your lab notebook. It is a good idea to perform at least three trials of each experiment so that you know your results are accurate and reproducible. 7. Decrease the amount of vinegar in the canister by 1 tsp. and repeat steps 1–5 three times. Record all of the data in your lab notebook. 8. Once again, reduce the amount of vinegar by 1 more tsp. and repeat steps 1–5 three times. Always record all of the data in your lab notebook. 9. Now that you have investigated the effect of the amount of vinegar on launch height, investigate the amount of baking soda required. Reduce the amount of baking soda to ½ tsp. and repeat steps 1–5 three times, with the original amount of vinegar used for your first vinegar trial. Adjust and use just enough water for the baking soda to stick to the depression in the lid. Record all of your data in your lab notebook. 10. Repeat steps 1–5 three times using a ¼ tsp. of baking soda, with the original amount of vinegar used for your first vinegar trial. Adjust and use just enough water for the baking soda to stick to the depression in the lid. Record all of your data in your lab notebook. Page 46 Program of Study Fall 2010 Analyzing the Data 1. Average the launch height data for each row of baking soda and vinegar that you recorded in the first table. Record the average data into a data table like the one shown below. Amount of Baking Soda Amount of Vinegar Average Launch Height 2. Plot the data. You can make your plots by hand on graph paper, or if you would like to make your plots online, try the following website: Create a Graph. Label the x-axis Amount of Vinegar and the y-axis Average Launch Height. Plot the average launch height for the varying amounts of baking soda on the same graph. You should now have a set of plots that will allow you to determine the ideal amount of baking soda and vinegar. Which variable affects the launch height the most, vinegar or baking soda? Variations Do you think that adding a cone and fins to your rocket will help it have a greater launch height? Add a cone and see how that affects the launch height using the amount of baking soda and vinegar that previously produced the highest launch. Then design and make fins for your rocket out of construction paper and repeat the experiment using the amount of baking soda and vinegar that previously produced the highest launch. Tape the cone on the opposite end from the canister and the fins on the same end. Do the cone and fins help increase the launch height? Try using different containers instead of Fuji film canisters. For more science project ideas in this area of science, see Chemistry Project Ideas. Credits Michelle Maranowski, PhD, Science Buddies This science fair project is based on the following: PBSKidsGo.org. (n.d.). Film Canister Rocket. Retrieved September 1 , 2009, from http://pbskids.org/zoom/activities/sci/filmcanisterrocket.html Fuji® is a registered trademark of Fuji Photo Film, Inc. Scotch® is a registered trademark of 3M. Page 47 Program of Study Recognize Gravitation Universal Law. Conceptualize velocity and tangential acceleration. Recognize Kepler’s Laws. Fall 2010 Overall Goal: Relate work with energy Specific aims: Define the concept of work in the context of physics as the scalar product between force and displacement and define concepts of Kinetic Energy, Potential Energy and their relation with work. Materials: 1. Meter stick 2. Ball(bouncy, tennis,) Procedure: a. Hold the ball 1 meter in the air next to the meter stick; what is the balls potential energy and kinetic energy? b. Let the ball go, measure how high into the air the ball bounces. c. Calculate the velocity of the ball, and the balls kinetic and potential energy just before it hits the ground. d. Calculate the balls potential energy at the apex of the first bounce. e. Is the potential energy the same? Why or why not. Explain how the law of conservation of energy holds true. How much work is done to bring the ball down, how much to bring it back up? Other Info: 𝑃𝑜𝑡𝑒𝑛𝑡𝑖𝑎𝑙 = 𝑚𝑔ℎ 1 𝐾𝑖𝑛𝑒𝑡𝑖𝑐 = 𝑚𝑣 2 2 1 𝑉𝑒𝑙𝑜𝑐𝑖𝑡𝑦 = (2𝑔ℎ) ⁄2 Created by Andy Hausner Identify the concept of power and its units. Identify Joules, erg as units of work, kinetic energy and potential energy. Conservation of Mechanical Energy. Recognize heat as a form or energy. Page 48 Program of Study Fall 2010 Physics II Overall Goal: Describe fluids in motion and stationary state Specific aims: Identify the different states of matter (liquid, solid, gas). Identify the differences between fluids and solids from their physic properties. Describe different properties of fluids such as: viscosity, superficial tension, capillarity, cohesion, adhesion, density, specific weight, pressure, hydrostatic Pressure, gauche pressure, atmospheric pressure, absolute pressure. Viscosity Experiment: Race Your Marbles to Discover a Liquid's Viscosity Abstract How do you like your mashed potatoes? Thin and whipped smooth? Or thick and mashed into chunks? Your mouth checks out not just the taste of your food, but its viscosity, or how it flows on your tongue, every time you take a bite! In this science fair project, you'll learn what viscosity is, and how to measure it in common liquids around your home. Objective To determine the viscosity of common liquids by measuring the transit time of marbles through the liquids. Introduction On a cold winter morning, have you ever tried to squeeze some honey out of the honey bear onto your toast? It's pretty tough, huh? Honey is one of those liquids that is very sensitive to temperature. As the temperature goes down, the viscosity, or resistance to flow, goes way up and you can squeeze and squeeze all you want, but very little honey comes out. If you set the honey bear in a pan of warm water for a few minutes and try again, what happens? One little squeeze and honey comes gushing out all over your toast. The viscosity, or resistance to flow, goes way down as the temperature goes up. As a measure of a liquid's resistance to flow, viscosity can be thought of as friction inside the liquid. If, for example, you try to ride your bike with the hand brakes on (a form of friction), it is difficult to roll the bike forward. The resistance to motion is high. Likewise, in highly viscous liquids (those with high internal friction), the resistance to flow is high. Viscosity is a very important quality of liquids that scientists, engineers, and even doctors are frequently trying to measure and change. It is difficult, for example, to transport highly viscous crude oil through offshore pipelines, so scientists and engineers use a variety of methods to try and lower the oil's resistance to flow through the pipelines. Likewise, in medicine, doctors try to keep blood viscosity in the correct range. If blood is "too thick," or viscous, a patient can develop blood clots. If blood is "too thin,"or lacks viscosity, however, then the patient is at risk for bruising or bleeding events. Blood viscosity, like most things in medicine, has a happy medium. Page 49 Program of Study Fall 2010 Volcanologists (people who study volcanoes) have a big interest in viscosity, too. The viscosity of molten rock or magma determines how easily a volcano will erupt, and what shape the lava flows and resulting mountains will take on. A very thin and fluid magma erupts more easily and forms gentle mountain slopes, while a very thick magma erupts explosively and forms a fat lava flow and steep mountain slopes. So, if you see a mountain formed from a volcano, you can estimate the viscosity of the magma that formed it just by looking at the angle of its slope! Common liquids around your house (thankfully) don't form mountain slopes though, so to measure their viscosities, you have to use some other method. One of the oldest methods is the dropped-sphere method—a glass marble or sphere of some other material is dropped into a column of a liquid. If the liquid is very viscous (imagine cold honey), it will take a long time for the marble to drop to the bottom of the column. Dropping the marble into a less viscous liquid (like water) will take much less time. Viscosity of a liquid can be calculated from the time elapsed, provided that you know the height of the column and the densities of the sphere and the liquid. Density is a measure of how "compact" something is. It is the ratio of mass to volume, and is a measure of how much matter is packed into a space. Think of a 1-inch cube of bread. Then think of a 1-inch cube of potato. The potato is denser than the bread (there is more "stuff" in the same space). You can calculate density yourself for an object by using a scale to find out the object's mass and then dividing that by the object's volume. You can also look up the densities of many common substances, like glass, stainless steel, water, seawater, oils, etc. in materials tables. Knowing the time it took to travel through the column of liquid, the height of the column, the density of the sphere, and the density of the liquid, you can then calculate the viscosity of the liquid with the viscosity equation: Equation 1: Viscosity = 2(ΔP)ga2 9v where: Viscosity is in newton-seconds per meter squared (Nsec/m2). Delta (Δ) P is the difference in density between the sphere and the liquid, and is in kilograms per meter cubed (kg/m3). g is the acceleration due to gravity and equals 9.81 meters per second squared (m/s2). a is the radius of the sphere in meters (m). v is the average velocity, defined as the distance the sphere falls, divided by the time it takes to fall in meters per second (m/s). So, now it's time to race some marbles and see if common liquids in your home are thick or thin! Terms, Concepts and Questions to Start Background Research Viscosity Friction Density Page 50 Program of Study Terminal velocity Inverse relationship Direct relationship Fall 2010 Questions What is liquid viscosity? How does viscosity change (in general) with temperature? Why is it important to understand viscosity? Bibliography This source discusses what viscosity is, its importance to understanding volcanology, and how to measure viscosity in the laboratory: Hawai'i Space Grant College, Hawai'i Institute of Geophysics and Planetology, University of Hawai'i. (1996). Viscosity Teacher Page. Retrieved September 6, 2008, from http://www.spacegrant.hawaii.edu/class_acts/ViscosityTe.html Materials and Equipment Tall, slender drinking glasses or glass jars with straight sides, equally sized (4) Marker, water soluble (1) Ruler, preferably metric Glass marbles, equally sized (5) Safe liquids to test (4), approximately 1/2 gallon of each, such as o Corn syrup o Honey o Cooking or vegetable oils o Glycerin o Seawater o Milk o Water o Molasses Note: It can be challenging to see the marble in the molasses. We recommend using light molasses. You may also need to experiment with different colored marbles to find which ones are most easy to see. Stopwatch Strainer Liquid dish soap Dish towel Access to sink Page 51 Program of Study Graduated cylinder, at least 1,000-mL size (1); available at science supply stores, such as Carolina Biological: www.carolina.com. Note: the larger the graduated cylinder, the easier it is to do testing. Lab notebook Helper Fall 2010 Experimental Procedure Preparing Your Glasses for the Marble Race 1. Measure down about 2 cm from the top of each glass with the ruler, and mark the 2-cm location with the water-soluble marker. 2. Fill each glass with a different test liquid, all the way up to the 2-cm mark. Racing Your Marbles 1. Have a helper hold two marbles level with the tops of two glasses. You hold two marbles level with the tops of two glasses also. 2. Say, "Ready, Set, Go!" and then you and your helper should drop your marbles at the same time and see which marble hits the bottom first and which one hits the bottom last. Record your observations in your lab notebook. If you have trouble figuring out a clear winner between two liquids, race the marbles with just those liquids a second and third time after first completing the next set of steps: Marble Retrieval and Cleanup. Figure 1. This drawing shows the setup of glasses and example liquids for the marble race. Page 52 Program of Study Fall 2010 Marble Retrieval and Cleanup 1. Place the strainer inside a sink or over a large bowl set inside a sink. 2. Pour the contents of each glass (the liquid and the marble) slowly into the strainer. 3. Retrieve the marbles from the strainer and wash and dry both the marbles and the glasses. Preparing the Graduated Cylinder to Measure the Viscosity of Each Liquid 1. Fill the graduated cylinder up with one of the liquids to a level 5 cm below the top of the cylinder, as shown in Figure 2. 2. Measure down at least 2 cm below the surface of the liquid (as shown in Figure 2) and mark a starting line on the graduated cylinder with the marker. The starting line needs to be lower than the surface of the liquid to allow time for your marble to reach its terminal velocity before you start taking measurements. 3. Measure up from the bottom of the graduated cylinder, approximately 5 cm, and mark an ending line on the graduated cylinder with the marker. You don't want the ending line to be at the bottom of the cylinder because the marble will slow down as it approaches the bottom, due to interactions with this boundary. 4. Measure the distance between the starting point and the ending point. Record this distance in your lab notebook. This is the distance that you will use to calculate the speed of the marble as it travels through the liquid. Remember, the average speed is equal to the distance traveled, divided by the time it took to travel that distance. Now you're ready to test and get some travel times. Figure 2. This drawing shows how to prepare the graduated cylinder for testing. Page 53 Program of Study Fall 2010 Testing Your Liquids 1. You or the helper should hold a marble at the surface of one of the liquids. 2. The other person should zero out the stopwatch. 3. The person holding the stopwatch should say "Go!" and have the other person drop the marble. As the marble passes the starting point, which was marked in the previous section, the person holding the stopwatch should start the stopwatch. As the marble passes the ending point, which was marked in the previous section, the person holding the stopwatch should stop it. 4. Record the time elapsed in a data table. 5. Repeat steps 1-4 of this section, with the same liquid and graduated cylinder, four more times with four other marbles. Measured Time Data Table Liquid name Trial 1 time (sec) Trial 2 time (sec) Trial 3 time (sec) Trial 4 time (sec) Trial 5 time (sec) Average of times (sec) Example: Corn syrup Marble Retrieval and Cleanup 1. Place the strainer inside a sink or over a large bowl set inside a sink. 2. Pour the contents of the graduated cylinder (the liquid and the marbles) slowly into the strainer. 3. Retrieve the marbles from the strainer and wash and dry the marbles and the graduated cylinder. 4. Repeat the experiment up to this step, starting from Preparing the Graduated Cylinder to Measure the Viscosity of Each Liquid, for the remaining test liquids. Analyzing Your Data Chart 1. Calculate the average for the five time trials for each liquid and enter it in your data table. 2. Calculate the average velocity for each liquid by dividing the distance, measured in step 4 of Preparing the Graduated Cylinder to Measure the Viscosity of Each Liquid, by the average time it took to travel that distance. Record your calculation in a second data table. 3. Remember Delta P from the viscosity equation, Equation 1? Calculate Delta P, the difference in densities between the marble and each liquid, by using the table below. Record each Delta P calculation in your data table. Note: If you tested a liquid that is not in this table, you will have to look up its density online, or calculate the density yourself, using a scale. Common Approximate Densities (kg/m3) Water 1000 Page 54 Program of Study Corn syrup 1380 Molasses 1400 Honey (room temperature) 1500 Vegetable or cooking oils Fall 2010 920 Glycerin 1260 Ocean water 1030 Milk 1030 Glass marble 2800 Stainless steel 7800 4. If you know the diameter of your marbles, divide the diameter by 2 to get the radius of the marbles. If you don't know the diameter of your marbles, measure the diameter with a ruler, and then divide by 2 to get the radius. Record the radius of your marbles in your lab notebook. 5. Calculate the viscosity of each liquid using Equation 1 from the Introduction. Record the calculations in a data table. Viscosity Data Table Liquid name Calculated average velocity (m/s) Delta P (kg/m3) Viscosity (kg/meter sec) Example: Corn syrup 6. Compare your viscosity test results with the marble race results. Do they match up and make sense? Did the liquids with the lowest viscosities win the race? Plot the viscosity of each liquid on the y-axis and the calculated average velocity on the x-axis. Is the relationship between viscosity and velocity inverse or direct? Variations Choose one liquid and repeat the experiment using different sizes and densities of spheres. For example, try different diameters of glass marbles, stainless steel balls, or BB's. (Note: For your viscosity calculations, the density of a stainless steel ball bearing is 7,800 kg/m3. If the diameter of any of your spheres is more than half the radius of the graduated cylinder, you should purchase a larger-diameter graduated cylinder to avoid having the spheres interact with the sides of the cylinder.) Are the velocities of the different spheres different? What about the measured viscosities from those velocities? Are they the same? Obtain some statistics, such as the standard deviation, on your measured viscosities. Page 55 Program of Study Choose a very temperature-sensitive liquid, such as honey, and evaluate how viscosity changes as a function of temperature. For more science project ideas in this area of science, see Chemistry Project Ideas. Fall 2010 Credits Kristin Strong, Science Buddies Edited by Peter Boretsky, Lockheed Martin This project follows much of the experimental procedure outlined in the following source: Hawai'i Space Grant College, Hawai'i Institute of Geophysics and Planetology, University of Hawai'i. (1996). Viscosity Teacher Page. Retrieved September 6, 2008, from http://www.spacegrant.hawaii.edu/class_acts/Viscosity.html Overall Goal: Differentiate heat and temperature Specific aims: Identify different concepts of heat, temperature, kinetic energy. Recognize the following scales of temperature and their units: Fahrenheit, Celsius, Kelvin, and Rankine. Identify the different mechanism of heat transfer: radiation, convection, conduction. Recognize absorbed heat vs. dissipated heat and its relation with temperature and mass. Experiment: Just Keep Cool—How Evaporation Affects Heating and Cooling Abstract When we get hot, we sweat. The physiological role of sweat is to cool us down. When the water evaporates, it removes energy from our bodies. This sort of evaporative cooling can also be used to cool homes, using what are referred to as swamp coolers. Evaporative cooling is also a potential source of energy waste in the kitchen because it increases the time it takes to heat water. In this chemistry science fair project, you will study how a variety of things cool down, whether for better or worse, using the process of evaporation. Objective The objective of this chemistry science fair project is to investigate several aspects of evaporative cooling. Introduction Page 56 Program of Study Fall 2010 Evaporation is the process by which molecules in a liquid escape into the gas phase. In any liquid, such as a glass of water at room temperature, the molecules in the liquid are moving. They bump into each other as they meander about the liquid. The speed with which they move depends on the temperature—in hotter liquids, the molecules move faster. The average speed depends on temperature, but around this average speed, there will be some molecules moving faster (more energetically), and some moving slower. When the more-energetic molecules are near the liquid's surface, they can escape into the gas above. As more and more of the most energetic molecules evaporate into the gas, the average energy of the molecules left behind decreases, so the liquid cools. The rate of cooling caused by evaporation depends on the rate at which molecules can escape from the liquid. You might have noticed that when you pour rubbing alcohol on your skin, it cools your skin more than when you pour water on it. This reflects the greater volatility, or tendency to evaporate, of the rubbing alcohol. The Experimental Procedure for this science fair project has three sections. They might seem unconnected at first, but each is related by the underlying concept of evaporative cooling. In the first section of the Experimental Procedure, you will compare evaporative cooling caused by water, rubbing alcohol, and cooking oil. The cooling effect studied in this part of the procedure is the basis for swamp coolers. In these cooling devices, outside air is blown over a wet surface and then into the home. You are familiar with the principle if you have ever had wet clothes on with a breeze blowing— the evaporation of water cools you off, just as it cools the wet surface in the swamp cooler. Thermal energy in the hot air is "extracted" and used to convert some of the liquid water into water vapor. Because energy is used to evaporate water, the air is cooled after passing over the wet surface. The cool air is then circulated around the interior of the building. In the second section of the procedure, you will look at the temperature change that occurs when water (sweat) evaporates off of skin. Sweating is a physiological response that uses evaporative cooling as a mechanism to remove excess heat. In the third section, you will look at evaporative cooling in the kitchen. When heat is applied to water to make it boil, some of the energy can be lost to evaporative cooling. You will investigate how evaporative cooling affects boiling time by comparing how long it takes to boil a pot of water both with and without a lid. Terms, Concepts and Questions to Start Background Research Evaporation Volatility Evaporative cooling Swamp cooler Energy Questions Why are some liquids more volatile than others? Swamp coolers are most often used in areas that are hot and dry. Would a swamp cooler work in hot, muggy conditions? Dogs do not sweat, but is their cooling mechanism similar to that of humans? Bibliography Page 57 Program of Study Fall 2010 Chem4kids.com. (2007). Evaporation of Liquids. Retrieved October 23, 2008, from http://www.chem4kids.com/files/matter_evap.html Air & Water, Inc. (2007). Swamp Cooling—Not Just for Swamps. Retrieved November 4, 2008, from http://www.air-n-water.com/faq_swamp.htm Materials and Equipment Measuring cup Water Rubbing alcohol Cooking oil, such as olive oil Plastic plates, disposable (4) Paper towels (12) Clear tape Ballpoint pen Infrared thermometer; available online, from websites like www.amazon.com Stopwatch Small fan; if you do not have a small fan, you will need an extra plate. Pots to boil water, identical, 2-qt. size or larger, with lids (2); you can use one pot repeatedly if you do not have identical pots. Stovetop A helper Lab notebook Graph paper Disclaimer: Science Buddies occasionally provides information (such as part numbers, supplier names, and supplier weblinks) to assist our users in locating specialty items for individual projects. The information is provided solely as a convenience to our users. We do our best to make sure that part numbers and descriptions are accurate when first listed. However, since part numbers do change as items are obsoleted or improved, please send us an email if you run across any parts that are no longer available. We also do our best to make sure that any listed supplier provides prompt, courteous service. Science Buddies receives no consideration, financial or otherwise, from suppliers for these listings. (The sole exception is any Amazon.com or Barnes&Noble.com link.) If you have any comments (positive or negative) related to purchases you've made for science fair projects from recommendations on our site, please let us know. Write to us at scibuddy@sciencebuddies.org. Experimental Procedure Evaporative Cooling in Buildings 1. Fill a measuring cup with tap water and allow it to come to room temperature. a. The rubbing alcohol and the oil should also be at room temperature. b. This step is just to ensure that the liquids are at the same temperature at the start of the experiment. 2. Place four disposable plastic plates, with the up sides down, on a work surface. Page 58 Program of Study a. Fall 2010 Use a waterproof surface (such as tile or laminate) since you will be using alcohol that could damage wood finish. 3. Fold each paper towel in half twice, so that each has four layers. 4. Place a folded paper towel on top of each plate. a. The plates keep the towels from being in contact with the work surface, which would affect their temperature. You could also use StyrofoamTM or other insulating material. 5. Tape the edges of the paper towels to the plates. 6. Label the paper towels 1–4. a. In the next step, the paper towels will be treated as follows: 1: no liquid 2: water 3: rubbing alcohol 4: oil 7. Start the stopwatch. 8. Take the temperature of the paper towels with the infrared thermometer. a. Take three readings of each paper towel. b. Keep the direction and distance between the thermometer and each plate the same. c. Record the temperatures and times in a data table in your lab notebook. 9. Pour water on paper towel #2, just enough to wet it. 10. Pour rubbing alcohol on paper towel #3, just enough to wet it. 11. Pour oil on paper towel #4, just enough to wet it. 12. Take the temperature of each paper towel, and record the temperature and time in your lab notebook. 13. Repeat the temperature readings three more times, at 2-minute intervals. 14. Which paper towel has the lowest temperature? What was the largest temperature difference between two paper towels that you noted? Record all observations in your lab notebook. 15. Repeat steps 1-14 two more times, with fresh paper towels, but you can rinse and reuse the plates. Average the results in your final report. 16. Repeat steps 1-15 three more times, only for these trials, with the fan gently blowing over the paper towels. If you do not have a fan, use a paper plate as a fan. Your helper can fan as you take and record the temperature at 2-minute intervals. Did the fan change the results? Why? Evaporative Cooling on Skin In this section, you will look at the cooling effect of evaporation on human skin. 1. Mark a small spot on your arm with a ballpoint pen. 2. Measure the temperature of the skin on your forearm near the pen mark. a. As in the section before, take two more readings and average them. 3. Pour some room-temperature water on your arm. 4. Take the temperature of your skin near the mark. Record all data in your lab notebook. 5. Take a temperature reading every minute until your arm dries. 6. Repeat steps 1-5 two more times. Page 59 Program of Study Fall 2010 7. Now repeat steps 1-6 of this section three times, this time using the fan or helper with the paper plate to blow air on your arm. Average all the results. 8. Graph your results. 9. What temperature change did you see? 10. Repeat steps 1-9 of this section using rubbing alcohol. What is the difference in the temperatures between water and alcohol? Evaporative Cooling When Boiling Water You have looked at two beneficial aspects of evaporative cooling—one used to cool buildings and one used to cool people. In this section, you will look at a situation where evaporative cooling is a source of energy waste and thus, something to avoid. 1. Add 2 qt. (8 cups) of tap water to each pot. 2. Check the starting temperature of the water with the infrared thermometer. Record the time and temperatures in your lab notebook. 3. Start two burners on your stovetop. They should be set to the same setting. 4. Cover one of the pots with a lid, but not the other. 5. Put the pots on the burners. 6. Use the infrared thermometer to record the temperature of the water every 3 minutes. o Measure the temperature of the open pot by pointing the thermometer at the surface of the water. o Measure the temperature of the covered pot by briefly removing the lid and pointing the thermometer at the surface of the water. 7. Determine how long it takes for the water in each pot to come to a boil. 8. Stop taking the temperature of a pot when it is at a full boil. Use your judgment as to when this point is reached. 9. Repeat two more times and average your results. 10. Graph your results. Put "Covered" and "Uncovered" on the x-axis, and "Time to boil" on the yaxis. What was the time-to-boil difference between the two pots, in minutes and in percent change? Variations Try other liquids for the first section, such as sugar or salt solutions, nail polish remover, etc. If you have access to a sensitive scale, weigh the paper towel with the alcohol during the course of the procedure. Find a relationship between weight change and temperature. For example, "on average, 1 gram (g) of alcohol was evaporated every minute to keep the paper towel 3 degrees cooler than room temperature." Demonstrate how a swamp cooler works in a model house made out of cardboard. Look up some design ideas online. Remember, the air coming in from the fan needs an open window or door to escape out of. This is a consideration for real houses with swamp coolers. Do some research on the energy used by your stove and calculate how much energy you used to boil the water on your stovetop with and without the lid. You might look at the gas meter to estimate how much gas is used. Make some rough guesses to come up with an estimate of how much energy could be saved nationally if everyone used a lid on a pot of water set to boil. Devise a method for reliably measuring small changes in temperature due to evaporation of low-volatility liquids, such as oil. Page 60 Program of Study Fall 2010 For more science project ideas in this area of science, see Chemistry Project Ideas. Credits David Whyte, PhD, Science Buddies StyrofoamTM is a registered trademark of The Dow Chemical Company. Overall Goal: Understand electricity laws Specific aims: Identify basic electrostatic concepts such as: electrostatic charge, insulators, and conductors. Identify concepts as electric field, electric potential energy, and electric potential. Identify characteristics of different kinds of circuits: parallel, series, mixed. Solve problems using Ohm's Law. Understanding Circuits and Ohm’s Law Introduction: Electricity flows through circuits. An electrical circuit is a closed loop that consists of an electric source and an electrical load such as a light bulb that are connected by a conductor such as a wire. The circuit can be opened or closed with the help of a switch. Circuits can be used in science fair experiments to demonstrate the behavior of electricity. It is important to note that some circuits are designed to allow electricity to flow freely whereas some are deliberately designed so that the flow is slowed down or hindered. This hindrance is called resistance. There are loads of science fair experiments that can be based on the concept of electrical resistance. Circuits that are designed for a limited flow or electricity are fitted with an electronic unit called a resistor. A resistor slows down the flow of electricity according to Ohm's law. Ohm's law defines the relationship between resistance (R), electrical current (I) and voltage (V). It is named in honor of Georg Simon Ohm who formulated it. If the current is too strong then it can damage the LED or the bulb filament. Therefore resistors are useful in limiting the current so that just the right amount of current flows through an LED or a bulb to light it up. Resistors are also used to control the quantity of electricity moving through a circuit. Did you know that resistors are used in dimmer switches and fan regulators? In this experiment, I will teach you how to use a pencil as a resistor. More importantly, this experiment will help you understand how changing the length of the pencil affects the amount of current flowing through a circuit and results in the dimming or brightening of a light bulb. Materials: You will require a few pencils, a 9 V battery, a 9 V light bulb, insulated wire, a few alligator clips, an extra length of wire, a popsicle stick and a ruler. You will also require a coping saw and a pencil sharpener. Page 61 Program of Study Fall 2010 Procedure: 1. Connect the battery to the bulb in series with the help of wires and set up a circuit on a flat wooden board. Do not complete the circuit, but leave two tips of the wire free. Attach alligator clips to these free ends. You must always use insulated alligator clips during science fair experiments. Now you can complete this circuit by touching both the alligator clips. Go ahead, try it. If the bulb lights, your circuit is working. 2. Next, you must cut the pencils into pieces of different sizes; say 3 inches, 5 inches and 7 inches. Sharpen these pieces at both ends. These are your pencil resistors. 3. Now, make a neat table with two rows, and as many columns as pencil pieces. The row headers can be 'Pencil Length' and 'Bulb Brightness.' 4. Measure each pencil piece from one tip to the other and write down the lengths in the 'Pencil Length' row. 5. Next, clamp each pencil piece between the two alligator clips. Note that the alligator clips need to be clamped to the pencil lead only. 6. Observe the brightness of the lit up bulb for each pencil piece and rate the brightness from 1 to 5 such that 1 could stand for dark and 5 for bright. Write your ratings in the 'Bulb Brightness' row under the respective lengths. 7. Now rate the extra wire and the popsicle stick, which are your positive control and negative control respectively. Reference: http://www.squidoo.com/Easy-Science-fair-experiments-that-get-good-grades-Project-6-Circuits Overall Goal: Relate electricity and magnetism Specific aims: Know historic background in the field of electromagnetism. (Hans Cristian Oersted, Michel Faraday, Andre Marie Ampere, George Simon Ohm, James Clerk Maxwell) Establish the characteristics of magnets and their magnetic interactions and explain the concept of magnetic field. Materials: 1. Insulated copper wire (1 meter) 2. Iron rod (nail, screwdriver, any magnetic metal) 3. Battery (D, maybe 9v) 4. Scissors or wire strippers Procedure: Tightly wrap the wire around the metal rod, leaving several inches at either end to connect to the battery. Attaching the battery runs a current through the wire which creates an magnetic field down the center of the metal rod. Other info: a) The more tight the turns are, the stronger the magnetic field will be. Page 62 Program of Study b) Heat produced is proportional to the voltage squared. c) For low voltage (1.5) an uninsulated wire may be used for short time periods go get a tighter wrapping and stronger magnetic field. d) This experiment relates electric current to magnetic fields, the right hand rule can be applied to determine the direction of the magnetic field. Refrences: 1. http://education.jlab.org/qa/electromagnet.html Page 63 Fall 2010