Memorized Mole Triangle Conversions Limiting Reactant Problem Process Empirical/Molecular Problem Process Unit 5 Practice Test Format No Multiple Choice or Short answer responses! All problem-based! Provided Periodic Table Activity Series Part I 1. When the following equation is balanced, the coefficients are _______________. Al(NO3)3 + Na2S Al2S3 + NaNO3 A) 2, 3,1,6 B) 2, 1, 3, 2 C) 1, 1, 1, 1 D) 4, 6, 3, 2 E) 2, 3, 2, 3 2. There are _______ sulfur atoms in 25 molecules of C4H4S2. A) 1.5 x 1025 B) 4.8 x 1025 C) 3.0 x 1025 23 D) 50 E) 6.02 x 10 Coverage Unit 5, Lessons 1-5 Chemical Equation Terminology, Balancing Chemical Equations, Identifying Types of Reactions (Synthesis, Decomposition, Single Replacement, Double Replacement, Combustion), Predicting Products, Calculating Formula Weight, Determining Percent Composition, Hydrates, Converting between Moles, Grams, Liters, and Representative Particles, Converting between Moles and Moles, Theoretical Yield vs. Actual Yield, Limiting Reactant Problems, Empirical vs. Molecular Formulas, Determining/Deriving Empirical/Molecular Formulas. 3. A compound that is composed of only carbon and hydrogen contains 80.0% C and 20.0% H by mass. What is the empirical formula of the compound? A) C20H60 B) C7H20 C) CH3 D) C2H6 E) CH4 4. The formula weight of magnesium fluoride (MgF2) is __________ amu. A) 86.6 B) 43.3 C) 62.3 D) 67.6 5. The mass % (percentage composition) of F in the binary compound KrF2 is __________. A) 18.48 B) 45.38 C) 68.80 D) 81.52 E) 92.9 E) 31.20 Part II Write balanced chemical equations and identify the type of reaction for each of the following: 1. zinc metal reacts with copper (II) bromide to yield zinc bromide and copper metal 2. potassium chlorate decomposes to produce potassium chloride and oxygen gas 3. indium metal reacts with oxygen gas to yield indium (III) oxide 4. potassium metal reacts with fluorine gas to yield potassium fluoride 5. lithium hydroxide reacts with carbon dioxide to produce lithium carbonate and water Part III Identify the type of reaction if it is not provided, then predict the products for the following equations. You will need to use the metal activity series for some equations. 1. Synthesis: Mg + I2 2. Double displacement: CuCl2 + H2S 3. Double displacement: NaOH + HClO4 4. Decomposition: ZnCO3 + heat 5. Single replacement: HCl Zn + 6. Combustion: C6H12 + O2 7. Combustion: C4H6 + O2 8. Combustion: C6H10O3 + O2 9. ________________ Na + MgCl2 10. ________________ CaCl2 + K2CO3 11. ________________ BaCl2 + K3PO4 12. ________________ Pb(NO3)2 + KOH 13. ________________ H2SO4 + BaCl2 14. ________________ Ca + AgCl 15. ________________ H3PO4 + FeBr3 Part III 1. Copper can be extracted from copper (II) oxide by reduction with methane. The unbalanced reaction is: CuO + CH4 Cu + CO2 + H2O. Calculate the amount of copper in particles than can be produced from 100.0 grams of Copper (II) oxide. 2. When nitrogen gas reacts with hydrogen gas, liquid ammonia is formed: N2 + H2 NH3. How many liters of ammonia could be collected from the reaction of 12.5 grams of nitrogen with 14.3 grams of hydrogen? 3. Silver nitrate solution reacts with calcium chloride solution to produce aqueous calcium nitrate and silver chloride precipitate, AgNO3 + CaCl2 Ca(NO3)2 + AgCl (a) Suppose we mix together a solution containing 6.30 g of silver nitrate and one containing 4.20 g of calcium chloride. What mass of silver chloride should we expect to produce? (b) If only 0.05 moles of silver chloride were actually obtained, what is the percent yield? 4. When iron (III) oxide reacts with solid aluminum metal, a highly energetic reaction occurs that produces solid iron metal and aluminum oxide, Fe2O3 + 2 Al 2 Fe + Al2O3 (a) If 500 grams of iron (III) oxide reacts with 500 grams of aluminum, what is the theoretical yield of iron? (b) How much excess reagent will remain when the reaction is finished? (c) If this explosive thermite reaction only produced 166.5 grams of iron metal, what is the reaction’s percent yield? 5. Solutions of sodium sulfate, Na2SO4 and lead(II)chloride, PbCl2, are combined to produce solid lead(II) sulfate, PbSO4, and sodium chloride, NaCl solution. (a) Write a balanced equation for the reaction described above. (b) If the solutions contained 7.50 grams of sodium sulfate and 11.30 grams of lead(II)chloride, what is the limiting reagent? (c) What amount, in grams, of the excess reagent is left over? (d) If the reaction described above was performed experimentally and the % yield of lead (II) sulfate was 87.3%, what mass, in grams, of the solid was recovered? 6. The empirical formula for caffeine, a natural stimulant in coffee and tea, is C4H5N2O. The molar mass of caffeine is 194.2g . (a) What is the molecular formula for caffeine? (b) Calculate the percent composition of nitrogen in caffeine. (c) If there are 50 mg of caffeine in a cup of coffee, how many molecules is that? 7. An active ingredient in photographic fixer contains 29.2% sodium, 40.5% sulfur, and 30.3% oxygen. What is the empirical formula of this substance? 8. Calculate the number of C, H, and O atoms in 1.50 g of glucose (C6H12O6). 9. Cinnamic alcohol is used mainly in perfumery, particularly in soaps and cosmetics. Its molecular formula is C9H10O. Calculate the percent composition by mass of C, H, and O in cinnamic alcohol. 10. Perform each of the following conversions: a. 26.5 g of MgCl2 to moles of MgCl2 b. 2.22 mol of O2 of molecules O2 c. 6.57 x 1018 atoms of Fe to grams of Fe d. 3.456 mol of CH4 to grams of CH4 e. moles of nitrogen in 6.50 mol ammonium phosphate, (NH4)3PO4 11. How many moles of water will be formed in the complete combustion of 2.50 mol of methane, CH4? 12. When 100 g of FeCl3 reacted with 50.0 g of H2S, how many grams of which reactant will be left over when the reaction is complete? 13. In the lab, you decide to combine 125.2 g of aqueous calcium chloride with 20.g of solid sodium. A. Write and balance the equation for the reaction described above. B. If the percent yield for calcium was 92%, calculate the actual yield for calcium. C. Calculate the remaining amounts of each reactant after the reaction finishes. 14. DDT, an insecticide harmful to fish, birds, and humans is produced by the following reaction: C6H5Cl + C2HOCl3 C14H9Cl5 + H2O chlorobenzene chloral DDT In a government lab, 1142g of chlorobenzene is reacted with 485g of chloral. A. Which reactant is the limiting reactant? B. What mass of DDT is formed? C. What mass of the excess reactant is left over? (4 points) D. If the actual yield of DDT is 200.0g, what is the percent yield? E. What might have gone wrong?