Indirect Gasification of Municipal Solid Waste Team Bravo EleftheriosAvtzis David Garcia Bryan Isles Zack Labaschin Alena Nguyen Mentor Dan Rusinak Che 397 - Team Bravo 1 Overview • • • • • • • Design Basis and Goals RDF Processing Taylor Biomass Energy Process Block Flow Diagrams Economics Plant Layout Recommendations Che 397 - Team Bravo 2 Problem: Municipal Solid Waste Che 397 - Team Bravo 3 Solution: Indirect Gasification • Project Design Goals • Indirect Gasification of Refuse-Derived Fuel using TBE Process • Providing High Quality Synthesis Gas to Team Alpha’s Specifications • Location: Newton County Landfill in Brooke, IN • Environmentally Friendly Process • Economic and Energy Efficient Che 397 - Team Bravo 4 Design Benefits • Turns Garbage into Useful Products • Reduces or Eliminates the Landfill Problem • Provides a Feedstock for Liquid Transportation Fuels • No Air Separation Unit Required • Internally Generated Steam • Environmentally Friendly Process Che 397 - Team Bravo 5 Design Basis •Commercial Scale Production •13,000 tons per day MSW • 6,000+ tons per day Syngas •Ideal Max. Output 7,100 tons per day •Scale-up Available Che 397 - Team Bravo 6 Engineering Specifications Team Bravo Syngas Syngas (tons/day) Max. tons/day from 11,025 tons/day RDF 7,105 Team Alpha Syngas Specification Pressure 725 psi Temperature 518°F Min. tons/day 6,000 H2/CO Ratio 2 Che 397 - Team Bravo 7 RDF Processing Shredder • Hammers running at high speeds to chop and shred waste Trommel Screen • Rotating, tubular vessels for sorting waste by size Mill • Shred material into fine particles Eddy-Current Separator • Ejects non-ferrous metals for recycle Magnetic Separator • Removes ferrous metals for recycle Che 397 - Team Bravo 8 Trommel Screen •Cylinder with screen on the outside •Sorts shredded MSW by size •Rotates to drive the MSW through from one side to the other Che 397 - Team Bravo 9 Eddy-Current Separator •Basic Schematic of Eddy-Current Separator •Non-Ferrous Metals are Ejected Che 397 - Team Bravo 10 Magnetic Separator •For Removal of Ferrous Metals •Uses Magnets to Hold Metals to Roller •Releases Metals into Separate Bin for Return to Landfill Che 397 - Team Bravo 11 Block Flow Diagram Return to Landfill MSW Sulfur Halogens Hazardous Materials Ash to Landfill MSW Processing TBE Gasification RDF Raw SynGas Clean SynGas Steam Electrical Grid Electricity Steam Generation Steam Captured CO2 Team Alpha Gasoline Production SynGas at Spec. CO2 Removal Excess SynGas Che 397 - Team Bravo Cooling & Cleaning Boiler Feed Water Clean SynGas Methane Reforming Steam Clean SynGas Water Gas Shift 12 TBE Gasification Effluent Raw SynGas GasConditioning Unit Dirty Flue Effluent Hot Olivine Raw SynGas Circulating Fluidized Bed Gasification Unit Combustion Unit Hot Olivine RDF Olivine and Char Steam Che 397 - Team Bravo Air 13 Block Flow Diagram Streams Reflect PFD Return to Landfill Ash to Landfill 27,36 5, 11,14 MSW 1 MSW Processing Sulfur Halogens Hazardous Materials TBE Gasificatio n RDF 19 Raw SynGas 28 20 Cooling & Cleaning 42 51 Steam Electrical Grid Electricity 71, A3, A4 Steam Steam Generation Captured CO2 68 Boiler Feed Water 57 Team Alpha Gasoline Production SynGas at Spec. 64 Excess SynGas CO2 Removal 53 Clean SynGas Clean SynGas Methane Reforming 52 A2 Steam Clean SynGas Water Gas Shift 65 Che 397 - Team Bravo 14 Block Flow Diagram Streams Reflect PFD 27, 36 Ash to Landfill 1 MSW 964,512 Ib/hr MSW Processing RDF 19 918,583 Ib/hr 72 lb/hr Olivine 21,954 Ib/hr Ash TBE Gasification 20 5,11,14 Steam Return to Landfill 365,600 Ib/hr Che 397 - Team Bravo Raw SynGas 28 8,301 Ib/hr NH3 740,221 Ib/hr CO2 259,924 Ib/hr CO 7,395 Ib/hr C2H6 39,095 Ib/hr C2H4 55,206 Ib/hr H2 1,616 Ib/hr HCl 3,020 Ib/hr H2S 55,448 Ib/hr CH4 71,381 Ib/hr H2O 15 Block Flow Diagram Streams Reflect PFD Raw SynGas 71,381 lb/hr H2O 740,221 lb/hr CO2 259,924 lb/hr CO 55,448 lb/hr CH4 55,206 lb/hr H2 39,095 lb/hr C2H4 7,395 lb/hr C2H6 3,020 lb/hr H2S 1,616 lb/hr HCl 8,301 lb/hr NH3 28 2,071,381 Ib/hr H2O 264,933 Ib/hr CO2 2,866 Ib/hr H2S 355 Ib/hr SelexolTM Cooling & Cleaning 51 42 Sour Gas 475,288 lb/hr CO2 252,477 lb/hr CO 51,619 lb/hr CH4 55,098 lb/hr H2 25,815 lb/hr C2H4 3,330 lb/hr C2H6 Clean SynGas Che 397 - Team Bravo 16 Block Flow Diagram Streams Reflect PFD Clean SynGas 475,288 252,477 51,619 55,098 25,815 3,330 Ib/hr CO2 Ib/hr CO Ib/hr CH4 Ib/hr H2 Ib/hr C2H4 Ib/hr C2H6 51 Methane Reforming A2 Steam 52 x3 44,970 673,870 62,887 181,112 Ib/hr CO2 Ib/hr CO Ib/hr H2 Ib/hr H2O Water Gas Shift 53 x3 289,758 518,095 74,014 80,972 Ib/hr CO2 Ib/hr CO Ib/hr H2 Ib/hr H2O 99,212 Ib/hr H2O Che 397 - Team Bravo 17 Block Flow Diagram Streams Reflect PFD Captured CO2 57 289,758 Ib/hr CO2 2,000,000 Ib/hr H2O 355 lb/hr SelexolTM SynGas at Spec. Raw SynGas 54 289,758 518,095 74,014 80,972 CO2 Removal 64 437,500 62,500 Ib/hr CO2 Ib/hr CO Ib/hr H2 Ib/hr H2O 65 Excess SynGas 80,595 11,514 Ib/hr CO Ib/hr H2 Che 397 - Team Bravo Ib/hr CO Ib/hr H2 Team Alpha Gasoline Production 18 Economics IRR = 27.96% This table displays the selective economics for year zero, one, five, seven, fifteen, and twenty. The net present value and internal rate of return are also displayed. Che 397 - Team Bravo 19 Economics This table displays the cost for selected processes and units required for Team Bravo’s indirect gasification of municipal solid waste. The capital cost as well as the operations, utilities, salaries, and annual cost in total are also listed. Che 397 - Team Bravo 20 Economics This table displays the revenue for Team Bravo’s indirect gasification of municipal solid waste. Major products and electricity are shown. About 90 kW of electricity are available for consumption outside the facility. Che 397 - Team Bravo 21 Economics This graph displays the ideal estimated profit from operating years one through twenty. The breakeven period is just over six years. Che 397 - Team Bravo 22 Newton County Prevailing Wind This figure represents the one square mile area that Newton County Landfill owns and occupies. The current active landfill covers a quarter mile space, allowing for Team Bravo to build their process on available Newton County land. Team Alpha Team Bravo Flare Current MSW Active Site 711 ft Che 397 - Team Bravo 23 Plot Area County Rd 400 S Office Prevailing Wind CO2 Claus Tank and Storage To Alpha Utility RDF Processing Active Landfill TBE Process Power Generation Flare Che 397 - Team Bravo 328 ft S 300 E Syngas Treatment This figure shows the basic plot area of Team Bravo’s process and supporting facilities. Blocks were chosen in order to best take advantage each process 24 Plant Plot This figure represents the plant plot area of both the TBE process and most of the syngas treatment facilities. Placement was based on need of access. The compressors are situated next to a plant maintenance road. Che 397 - Team Bravo 25 Recommendations Move forward with the Indirect Gasification of Municipal Solid Waste Design Project •Environmental Benefits •Lower Landfill Methane Emissions, CO2 Treatment and Little Thermal Pollution •Excellent Location •Newton County Landfill Provides Plenty of Feedstock and Space •High Economic Sensitivity •Increase Annual Expenses and Capital Investment $100MM – IRR = 15.56% •Increase Capital Investment More by $100MM – IRR = 13.04% Che 397 - Team Bravo 26 References • • • • • • • • • Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 1: Availability of Feedstock and Technology (PNNL-18144) Municipal Solid Waste (MSW) to Liquid Fuels Synthesis, Volume 2: A Technoeconomic Evaluation of the Production of Mixed Alcohols (PNNL-18482) www.taylorbiomassenergy.com - TBE www.rentechinc.com – Rentech Engineering Toolbox Heats of formation: http://cccbdb.nist.gov/hf0k.asp Municipal Solid waste Generation, Recycling, and Disposal in the United States: Facts and Figures for 2008 – EPA Higman, Christopher and van derBurgt, Maarten. Gasification 2nd Edition. Gulf Professional Publishing. Oxford, 2008. Paisley, Mark A., Corley, Ralph N. and Dayton, David C. Advanced Biomass Gasification for the Economical Production of Biopower, Fuels, and Hydrogen. Taylor Biomass Energy Che 397 - Team Bravo 27 Aspen Acid Removal Che 397 - Team Bravo 28 Furnace-Boiler Schematic Che 397 - Team Bravo 29 Ash Material Balance wood wood wood leather (treated) (untreated) (demo) PET organic 0.0286 0.8678 0.6878 0.00552 0.3859 0.4137 1.000 ash 3.1614 (tons/day) 95.66 75.82 0.6090 42.54 45.61 263.41 wt % Che 397 - Team Bravo Totals 30 Sample Calculation Gasification Sizing Calculation CO CO2 CH4 H2 C2H4 C2H5 H20 Σ Kmol/Day 127,404 87,616.9 60,950.9 245,726 16,507.5 0 113,551 651,756.3 Sizing of Gasification Unit Inputs MW (Kg/Kmol) WT Frac MW x WT Frac (Kg/Kmol) 28 0.195477972 5.473383226 44 0.134431996 5.915007803 16 0.09351793 1.496286879 2 0.377021288 0.754042577 28 0.025327718 0.709176114 17 0 0 18 0.174223095 3.136015716 153 1 17.48391232 Table 5-1: Calculation of synthesis gas molecular weight for ideal gas density equation. Che 397 - Team Bravo 31 Sample Calculation PV = NRT Gasification Sizing Calculation P= n RT V P !MW = ! RT ! syn = P MWsyn RT g g mol ! syn = = 374.4 3 m3 ² 5 Bar!m 8.314 !10 1123K mol!K 2Bar !17.48 Che 397 - Team Bravo 32 Sample Calculation Gasification Sizing Calculation kmol kg kg w = 651, 756.3 !17.48 = 11, 392, 700.124 day kmol day m3 day hour m3 q = 30, 429, 220.42 ! ! = 352.2 day 24!hour 3600sec sec Assume superficial gas velocity of 7.5 m/s Che 397 - Team Bravo 33 Sample Calculation Gasification Sizing Calculation m3 352.2 q sec = 46.96m 2 A= = m v 7.5 sec d= 4A ! = Che 397 - Team Bravo 4 !46.96m 2 ! = 7.73m 34 Sample Calculation Absorber If !t = 0.6m H » 1.1(0.6m)(35stages) = 23.1m = 75.79 ft lb hr = 63.23 lb = 1012.85 kg rL = 3 ft 3 m3 4 ft 7.32 ×10 hr lb 8.65×10 5 hr = 4.23×10 -2 lb = 0.678 kg rV = 3 ft 3 m3 7 ft 2.04 ×10 0.5 é hr kg ù ê (1012.85 - 0.678) m3 ú 2 m ûv = -0.171( 0.6m) + 0.27× ( 0.6m) - 0.047 ê = 2.06 ú kg s ê ú 0.678 3 ë û m 6.63×10 6 ( ) Che 397 - Team Bravo 35 Sample Calculation Absorber æ lb öæ kg öæ hr ö 4 ç8.65×10 5 ÷ç 0.4536 ÷ç ÷ è ø è ø è hr lb 3600s ø Dc = æ kg öæ mö p ç 0.678 3 ÷ç 2.06 ÷ è m øè sø Dc = 9.95m = 32.7 ft Che 397 - Team Bravo 36 Conceptual Control Scheme The TBE Process Che 397 - Team Bravo 37 Conceptual Control Scheme Acid Cleanup Che 397 - Team Bravo 38 Composition of Syngas Compound H2 CO CH4 C2H4 CO2 C2H6 N2 Percent 45 – 48% 15 – 20% 10 – 13% 1 – 3% 18 –20% 0 – 1% Trace Che 397 - Team Bravo 39 Dioxins • At 800-900°C, dioxins thermally decomposes • SynGas temp. through gas conditioning unit is raised to 1000°C • No copper: which promotes dioxin formation • Dioxins tend to adsorb on char and breakdown in the combustion reactor Che 397 - Team Bravo 40 Carbon Footprint Carbon IN (kmole/day) Carbon OUT (kmole/day) Ratio of OUT/IN 393,142.7 238,659.6 0.607 Environmentally friendly process by removing carbon waste from the environment. Total Carbon Dioxide OUT 6,801 tons/day Che 397 - Team Bravo 41 Design Basis • River Bend Prairie Landfill – 88 Acres – 20 Acres of expansion – Access to MSW of Chicago – Rail and River access – Residential – Limited Expansion Che 397 - Team Bravo 42 Design Basis • Newton County Landfill – 265 Acres – Room for expansion – Access to MSW of South Chicago – Transportation – No river access Che 397 - Team Bravo 43 Design Basis • Environmental Review Positives • Removal of MSW from local landfill (75% of 12000 tonnes per day estimated value enter gasification processing) • Gasification by-products are captured and properly stored (no venting into atmospheres) – Negatives • 400 million lbs of hazardous waste per year (mostly ash) • 100,000 lbs will need relocation (cannot be further utilized) Che 397 - Team Bravo 44 Design Basis Industrial Standard Review • Clean Syngas produced in 2.4-3.0 ratio H2/CO for use by chemical production Clear Statement of Feedstock • MSW from landfills • Return to landfill includes: glass, appliances, paints or oils • Metal will be recycled Che 397 - Team Bravo 45 Methane Emissions in U.S. Top 5 Sources Source Category 2008 (Tg of CO2Equi.) %Total Enteric Fermentation 140.8 24.81 Landfills 126.3 22.26 Natural Gas Systems 96.4 16.99 Coal Mining 67.6 11.91 Manure Management 45.0 7.93 Total for US 567.4 100.00 Che 397 - Team Bravo 46 Municipal Solid Waste • EPA 2008 report on MSW generation – Approximately 250 million tons of MSW generated by Americans in 2008 • ~33.2% is recycled and composited (83 million tons) – Approximately 4.5 pounds of MSW generated per person per day • 1.5 pounds of the 4.5 is recycled and composited. Che 397 - Team Bravo 47 Why MSW? • • • • • Renewable Energy Source Helps the Environment (CH4 emissions) Cost effective Transportation Reduction Located near cities and existing infrastructure Che 397 - Team Bravo 48 Disadvantages of MSW • Preparation of feedstock • A lower heating value than conventional feedstocks • Higher Ash content than conventional feedstocks Che 397 - Team Bravo 49 MSW to RDF • MSW – municipal solid waste in • Sorting – removal of recycle metals and other rejects • Screening procedures • Shredding and drying • RDF – Refuse Derived Fuel out Che 397 - Team Bravo 50 Current Processes • Batelle • Silva Gas • Montgomery Project Che 397 - Team Bravo 51 Disadvantages of Other Processes • • • • • High pressure/Energy intensive Lower quality raw syngas Air or oxygen requirements Poor scale up Unproven technology Che 397 - Team Bravo 52 Advantages of TBE Process • • • • • Low pressure Relatively low temperature Efficient ash removal Indirect gasification Residence time less than one second Che 397 - Team Bravo 53 Backup Slide: Rough Mass Balance • 2500 TPD Basis • 625 TPD rejected material – 306 TPD Ash (considered rejected material) • 361.8 TPD CO2 • 219.6 TPD CH4 Che 397 - Team Bravo 54 Backup Slide: Reactor Compositions – Carbon • 2500 TPD Basis • Gasifier composition – Carbon • 188767.6 lb-mol per day • Combustion Reactor Carbon – Carbon • TBD Che 397 - Team Bravo 55 Gasification Reactions • C is a carbon containing compound • Char reacts with CO2 and steam (gasifier) C + H2O CO + H2 + 131 MJ/kmol C + CO2 CO + 172 MJ/kmol • Combustion reactor heats sand (olivine) C + ½ O2 CO - 111 MJ/kmol CO + ½ O2 CO2 - 238 MJ/kmol H2 + ½ O2 H2O - 242 MJ/kmol Che 397 - Team Bravo 56 Water-Gas Shift and Methane Rxns CO + H2O CO2 + H2 - 41 MJ/kmol • Slightly exothermic, in Gas-Conditioning Unit • Required to achieve Syn Gas ratio of 2.05 • Methane reforming of raw syngas • CH4 + H2O CO + 3H2 Che 397 - Team Bravo + 206 MJ/kmol 57 TBE Gasification Process Che 397 - Team Bravo 58 TBE Process Steam Gasifier RDF Flue Gas Olivine (Hot) Olivine Combustion Reactor SynGas Tars Gas Conditioning Reactor SynGas Air Char, Ash & Olivine (Cool) Ash Removal Che 397 - Team Bravo 59 Gasifier: Material Balance RDF Steam SynGas Tars Olivine IN tons/day OUT tons/day C 5,205.1 CO 3,933.7 H 681.1 CO2 4,250.5 O 3,443.8 CH4 1,077.9 N 125.4 H2 546.0 S 22.0 C2H4 510.5 Cl 11.5 Char C 1,114.3 H2O in RDF 1,534.1 Char H 0.63 H2O Supplied 2,853.1 Char N 0.22 Char S 0.00026 H2O 2,254.9 H2S 23.4 HCl 11.8 NH3 152.2 Total 13,876.1 Char Olivine Total Che 397 - Team Bravo 13,876.1 60 Gasifier: Energy Balance Reactions RDF Steam SynGas Tars C + H2O CO + H2 + 56,376 BTU/lbmol CO + ½O2 CO2 -1.2 E5 BTU/lbmol Olivine Char Olivine Che 397 - Team Bravo Component CO CO2 CH4 C2H4 C2H6 H2S NH3 HCl Char Total BTU/lbmolRDF 21,460.07 -8,286.88 -1,527.77 -260.37 -14.66 -50.52 -16.47 11,303.4 61 Combustion Reactor: Material Balance Flue Gas Olivine (Hot) Air Char, Ash & Olivine (Cool) IN tons/day OUT tons/day Char C 1,114.3 CO2 4,084.4 Char H 0.63 H2O 5.63 Char N 0.22 NO2 0.72 Char S 0.00026 SO2 0.00052 O2 2,979.1 O2 0 N2 9,811.1 N2 9,814.6 Total 13,905.4 Total 13,905.4 Ash Removal Che 397 - Team Bravo 62 Combustion Reactor: Energy Balance Reactions C + O2 CO2 Flue Gas Olivine (Hot) Air Char, Ash & Olivine (Cool) Ash Removal Che 397 - Team Bravo -1.7 E5 BTU/lbmol Component BTU/lbmolRDF CO - CO2 - CH4 - C2H4 - C2H6 - H2S - NH3 - HCl - Char -11,171.50 Total -11,171.50 63 Gas Conditioning Reactor: Material Balance SynGas SynGas Tars Olivine Olivine IN tons/day OUT tons/day CO 3,933.7 CO 2,917.4 CO2 4,250.4 CO2 5,295.1 CH4 1,077.9 CH4 1,171.6 H2 546.1 H2 519.5 C2H4 510.5 C2H4 436.5 C2H6 0 C2H6 180.0 H2O 2,254.9 H2O 2,053.4 H2S 23.4 H2S 23.4 HCl 11.8 HCl 11.8 NH3 152.2 NH3 152.2 Total 12,760.9 Total 12,760.9 Che 397 - Team Bravo 64 Gas Conditioning Reactor: Energy Balance Water Gas Shift reaction reaches thermal equilibrium. SynGas SynGas Tars Olivine Olivine Che 397 - Team Bravo Component BTU/lbmolRDF CO -451.03 CO2 - CH4 - C2H4 - C2H6 - H2S - NH3 - HCl - Char - Total -451.03 65 Gas Clean Up: Scrubber Material Balance Sulfur Halogens Raw SynGas Hazardous Materials Raw SynGas IN tons/day OUT tons/day H2S 23.429 H2S 23.429 HCl 11.847 HCl 11.847 NH3 152.184 NH3 152.184 Total 187.46 Total 187.46 Basically all incoming volatiles will be treated (place holder). Che 397 - Team Bravo 66 Gas Clean Up: Reformer Material Balance Raw SynGas SynGas Steam IN tons/day OUT tons/day CO 2,917.4 CO 4,711.5 CO2 5,295.1 CO2 7,586.9 CH4 1,171.6 CH4 0 H2 519.5 H2 1,251.9 C2H4 436.6 C2H4 0 C2H6 180.0 C2H6 0 H2O 2,053.4 H2O 0 H2O Supplied 2,092.0 H2O Supplied 1,115.3 Total 14,665.6 Total 14665.6 Che 397 - Team Bravo 67 Reverse Water Gas Shift: Material Balance Reactions CO2 + H2 CO + H2O SynGas SynGas At spec. +17,644 BTU/lbmol IN tons/day OUT tons/day CO 4,711.5 CO 7,368.8 H2 1,251.9 H2 1,060.7 CO2 7,586.9 CO2 3,411.7 H2O 1,115.3 H2O 2,824.3 Total 14,665.6 Total 14,665.6 Che 397 - Team Bravo 68 TBE: Total Energy Balance Gasifier G.C.R. C.R. BTU/lbmolRDF BTU/lbmolRDF BTU/lbmolRDF CO 21,460.07 -451.03 - CO2 -8,286.88 - - CH4 -1,527.77 - - C2H4 -260.37 - - C2H6 - - - H2S -14.66 - - NH3 -50.52 - - HCl -16.47 - - Char - - -11,171.50 TOTAL Total 11,303.4 -11,171.50 -319.13 Che-451.03 397 - Team Bravo 69 Investment Trend ~ 595 tons/hour --> ~335 millions $ Che 397 - Team Bravo 70 TIC RDF Processing Total Installed Cost of Some RDF Processing Equipment Processing Unit Non-Ferrous Material Removal Gravity Separation Size Reduction Thermal Drying Total TIC 2011 Dollars at 5% interest Lower Upper Avg -- -- $465,390.00 $142,719.60 $1,213,116.60 $2,295,924.00 $465,390.00 $2,606,184.00 $5,832,888.00 $304,054.80 $3,819,300.60 $4,064,406.00 -- -- $8,653,151.40 Che 397 - Team Bravo 71 Costs Total Installed Cost Equipment Cost Heat Exchangers $ 2,970,000 $ 1,230,000 Compressor $ 95,000,000 $ 91,700,000 Absorbers $ 949,000 $ 417,000 Strippers $ 695,000 $ 198,000 TBE Process $ 347,000,000 $ 182,000,000 Total $ 447,000,000 $ 276,000,000 Che 397 - Team Bravo 72 Capital Costs Million $ (+/- 45%) % of Total (+/- 45%) $58 - $153 13% - 35% Feedstock $22 - $58 5% - 15% Gasification, Tar Reforming, Scrubbing $36 - $98 9% - 23% $90 - $238 21% - 57% $18 - $50 6% - 16% Year 2008 RDF Processing SynGas Conditioning Steam System and Power Generation Total Capital Investment Che 397 - Team Bravo $224 - $597 Million 73 TIC Assumptions • TIC breakdown – Purchased Equipment – Installation – Instrumentation and Controls – Piping – Electrical Systems – Buildings (including services) – Yard Improvements • Indirect Costs – Engineering – Construction – Legal and Contractors Fees – Project Contingency Che 397 - Team Bravo 74 Operating Costs Operating Costs Raw materials Feedstock Catalysts & Chemicals By-product credits Scrap Aluminum Scrap Iron Electricity sold to grid Waste treatment or Disposal Gasifier ash MSW rejects Spent carbon Waste water treatment Che 397 - Team Bravo $/operating unit 0.00 0.10 -0.86 -0.58 -0.17 0.00 0.00 0.0001 0.026 75