2012 Emissions Inventory Workshop 1 2012 Emissions Inventory Workshop 2 The owner or operator of any facility that is a source of air contaminants shall submit a complete emission inventory annually on forms obtained from the Division. The TAD is the form used to report the Emissions Inventory data to Oklahoma DEQ DEQ Form #100-730 (TAD) contains the annual emissions inventory for a particular facility, as well as other relevant information such as the facility location and address, ownership details, operating hours and process rates, etc. Redbud is the preferred method to report emissions inventories and provides a complete printed Turn Around Document for records 2012 Emissions Inventory Workshop 3 Submit by Mail Completed Emission Inventory Submitted to DEQ Submit Electronically Hardcopy TAD Air Permit Data Redbud Webfire & AP-42 Data 2012 Emissions Inventory Workshop Operation & Production Information Other Data Sources 4 2012 Emissions Inventory Workshop 5 2012 Emissions Inventory Workshop 6 2012 Emissions Inventory Workshop 7 2012 Emissions Inventory Workshop 8 2012 Emissions Inventory Workshop 9 2012 Emissions Inventory Workshop 10 2012 Emissions Inventory Workshop 11 2012 Emissions Inventory Workshop 12 2012 Emissions Inventory Workshop 13 2012 Emissions Inventory Workshop 14 2012 Emissions Inventory Workshop 15 I. II. III . IV. V. VI. VII. VIII. FACILITY DESCRIPTION PROCESS DESCRIPTION EQUIPMENT AIR EMISSIONS INSIGNIFICANT ACTIVITIES OKLAHOMA AIR POLLUTION CONTROL RULES FEDERAL REGULATIONS COMPLIANCE IX. SUMMARY 2012 Emissions Inventory Workshop 16 Permit writer includes initial application data Emission calculations and referenced sources Normally lists the acceptable Emission Factors 2012 Emissions Inventory Workshop 17 2012 Emissions Inventory Workshop 18 2012 Emissions Inventory Workshop 19 Emission Units Stack or Emission Release Point Data Emission Processes Fuel Combustion Data Pollutants Emission Factors Controls Emission Limits 2012 Emissions Inventory Workshop 20 Every emission unit must have: An emission release point (stack) At least one process If active, one or more pollutants 2012 Emissions Inventory Workshop 21 2012 Emissions Inventory Workshop 2012 Emissions Inventory Workshop 22 –this emission unit operated all or part of the calendar year (Active at anytime during the year). –this emission unit did not operate at all during the calendar year, but may restart at sometime in the future (no emissions during the calendar year). –select this status if an emission unit has been removed, removed from service, or is permanently shutdown (no emissions during the calendar year). 2012 Emissions Inventory Workshop 23 2012 Emissions Inventory Workshop 24 2012 Emissions Inventory Workshop 25 Stack Fugitive Height above ground level Pipe work Storage Tank 2012 Emissions Inventory Workshop Minerals 26 2012 Emissions Inventory Workshop 27 2012 Emissions Inventory Workshop 28 2012 Emissions Inventory Workshop 29 2012 Emissions Inventory Workshop 30 Description of each process or activity at an emission unit This description is assigned by the SCC A single point may have two or more processes 2012 Emissions Inventory Workshop 31 2012 Emissions Inventory Workshop 32 From Specific Conditions: From Permit Memorandum: 2012 Emissions Inventory Workshop 33 Sulfur %: Mass percentage of the sulfur content in the process fuel Ash %: Mass percentage of the ash content in the process fuel 2012 Emissions Inventory Workshop 34 TANKS: if over 5 tons of emissions – separate breathing, working and flashing losses. Under 5 tons of emissions, losses can be combined using SCC 40400311 ANY EQUIPMENT that utilizes different process material (coal, wood, natural gas) 2012 Emissions Inventory Workshop 35 2012 Emissions Inventory Workshop 36 2012 Emissions Inventory Workshop 37 Contains information on all the pollutants Includes the methods of calculation, emission factors & units (numerator & denominator), and the amount of emissions as calculated from the reported activity, excess emission and control equipment details 2012 Emissions Inventory Workshop 38 Air pollutants for which an ambient air quality standard has been set (health based and/or environmentally-based criteria) Air pollutants for which acceptable levels of exposure can be determined (permissible levels) 2012 Emissions Inventory Workshop 39 Criteria Air Pollutants Carbon monoxide (CO) Nitrogen oxides (NOx) Sulfur dioxide (SO2) Lead (Pb) Particulate matter (PM) Ozone (O3) 2012 Emissions Inventory Workshop 2012 Emissions Inventory Workshop 40 Air Toxics - Hazardous Air Pollutants (HAPs) Section 112b http://www.deq.state.ok.us/aqdnew/toxics/index.htm Mercury (Hg) - Mercury is a HAP in Section 112b list http://www.epa.gov/ttn/atw/orig189.html Ammonia - 40 CFR 51 Subpart A (CERR) http://www.deq.state.ok.us/aqdnew/emissions/Oklahoma EmissionsInventoryRAPreportingList.htm For more information: http://www.deq.state.ok.us/aqdnew/emissions/Oklahoma RegulatedAirPollutants.htm 2012 Emissions Inventory Workshop 41 Two Categories – Dependent on Particle Size PM-10 and PM-2.5 2012 Emissions Inventory Workshop 42 "PM-10" means all particulate matter with an aerodynamic diameter of 10 micrometers or less (fine & coarse particle fractions combined) 2012 Emissions Inventory Workshop 43 "PM-2.5" means particulate having an aerodynamic diameter equal to or less than 2.5 micrometers (i.e., the fine particle fraction) 2012 Emissions Inventory Workshop 44 Amt PM-10 10 0 Amt PM-2.5 0 2.5 10 Size (microns) 2012 Emissions Inventory Workshop 45 2012 Emissions Inventory Workshop 46 An emission factor is a representative value that attempts to relate the quantity of a pollutant released to the atmosphere with an activity associated with the release of that pollutant. Emissions = EF x Process Rate These factors are usually expressed as the weight of pollutant divided by a unit weight, volume, distance, or duration of the activity emitting the pollutant. 2012 Emissions Inventory Workshop 47 2012 Emissions Inventory Workshop 48 2012 Emissions Inventory Workshop 49 Storage Tanks - use the Software TANKS Landfills - use LANDGEM, a gas emissions model Tank Flashing - Vasquez-Beggs equation Glycol Dehydrator Reboiler - GRI-GLYCalc These are models with formulas using multiple variables. There is no single emission factor. 2012 Emissions Inventory Workshop 50 (d) Method of calculation. The best available data at the time the emission inventory is or should have been prepared shall be used to determine emissions 2012 Emissions Inventory Workshop 51 Stack testing plus 25% safety factor AP-42, 7/98, Sec. 1.4 plus 25% safety factor Baghouse manufacturer guarantee plus safety factor 2012 Emissions Inventory Workshop 52 AP 42, Fifth Edition Compilation of Air Pollutant Emission Factors, Volume 1: Stationary Point and Area Sources http://www.epa.gov/ttn/chief/ap42/index.html WebFIRE http://cfpub.epa.gov/webfire/index.cfm Stack Testing 2012 Emissions Inventory Workshop 53 2012 Emissions Inventory Workshop 54 2012 Emissions Inventory Workshop 55 Actual amount (%) of air emissions prevented from being emitted by a control approach 2012 Emissions Inventory Workshop 56 Capture efficiency: The percentage of air emission that is directed to the control equipment If emissions escape prior to the control device, these should be accounted for in the total actual emissions amount. 2012 Emissions Inventory Workshop 57 2012 Emissions Inventory Workshop 58 2012 Emissions Inventory Workshop 59 Allowed Emissions (tpy): The total amount of any regulated air pollutant which is subject to an emissions limiting standard, either by rule or permit condition contained in an enforceable permit or potential to emit, or for grandfathered sources, emission limits based on maximum design capacity and considering all applicable rules. 2012 Emissions Inventory Workshop 60 2012 Emissions Inventory Workshop 61 If a process emits pounds or more of a regulated air pollutant (≥ 0.001 tons) Please Report Them!! Trace (<0.001 TPY): Use the Trace check box to indicate annual emissions have been calculated but are less than 0.001 Tons (2.0 lbs). 2012 Emissions Inventory Workshop 62 What should be reported? All Actual Emissions not Permit limits or Potential to Emit Values 2012 Emissions Inventory Workshop 63 Yes, Report the following: Emissions that are in excess of a permit or other such limit should be reported in the excess emission field However, ALL actual emissions must be reported in the total emissions field 2012 Emissions Inventory Workshop 64 Oklahoma Administrative Code (OAC) 252:100 Subchapter 5 – Emissions Inventory Permit Exempt and De Minimus Facilities not required to submit Subchapter 7 – Minor Permits Subchapter 8 – Major Permits 2012 Emissions Inventory Workshop 65 Remember Air Quality Rules Always Apply http://www.deq.state.ok.us/mainlinks/deqrules.htm 2012 Emissions Inventory Workshop 66 2012 Emissions Inventory Workshop 67