Bucket Chemistry 101 Bodie Pennisi, and Paul Thomas Extension Horticulture Specialists The University of Georgia Bucket Chemistry Fertilizer Problems Are Not That Bad ! The Way To Tackle Them Is … Greenhouse Crops and Fertilizer Recommendations Fertilizer Stock Tank PROPORTIONER A device used in a fertigation system to control the rate of fertilizer applied through the system. Fertilizer Injector or Proportioner Stock Fertilizer Tank 1 part stock solution Injector ratio 1 : 100 Water line 100 parts of water Irrigation line to plants Fertilizer Injector or Proportioner Stock Tank 1 part stock solution 5 gal 25 50 100 200 500 etc. To get from ratios to percent: (1/50) x 100 = 2% To get from percent to ratios : 100/2%=1:50 Water line x parts of water Injector ratios 1:50 = 1:100 = 1:200 = 1:500 = 2% 1% 0.5% .01% Fertilizer recommendations for greenhouse crops are given as either ppm of a specific fertilizer nutrient or in pounds and ounces (weight basis) of a fertilizer formulation per 100 gallons of water Parts per million (ppm) One part of a substance into one million parts of another substance Things You Need To Know To Solve ppm Problems: 1. Recommended fertilizer application rate. Example: 8 ounces per 100 gal or 200 ppm nitrogen 2. Fertilizer formulation and analysis. Example: 20-10-20 3. Injection ratio Example: 1:100 4. Size of stock tank in gallons Example: 25 gallons Weight Basis Example: A chrysanthemum grower gets a recommendation to apply 20-20-20 watersoluble formulation to a final concentration of 16 oz per 100 gallons of water. How much fertilizer should be mixed in a 25 gallon stock tank if an injector with a 1:30 injection ratio will be used? Things You Need To Know To Solve This Problem: 1. Recommended fertilizer application rate. 16 ounces per 100 gal 2. Fertilizer formulation and analysis. 20-20-20 3. Injection ratio 1:30 4. Size of stock tank in gallons 25 gallons Solution Step 1: Adjust the rate for the stock tank size using the following equation: Equation 1 oz per 100 gal = oz fertilizer per stock tank 100 / Stock Tank Size (gal) 16.0 oz per 100 gal = 4.0 oz of 20-20-20 100 / 25 gal Solution Step 2: Adjust the rate for the injection ratio: Equation 2 oz per stock tank x injector ratio = oz per stock tank using injector 4.0 oz per 25 gal x 30 = 120.0 oz per 25 gal @1:30 ratio Commercial Fertilizer (ppm) Example: A pansy grower gets a recommendation to apply 150 ppm nitrogen using 20-10-20 watersoluble formulation. How much fertilizer should be mixed in a 25 gallon stock tank if an injector with a 1:100 injection ratio will be used? Things You Need To Know To Solve This Problem: 1. Recommended fertilizer application rate. 150 ppm nitrogen 2. Fertilizer formulation and analysis. 20-10-20 3. Injection ratio 1:100 4. Size of stock tank in gallons 25 gallons The Rule of 75 1 oz / 100 gal = 75 ppm HOW DID WE GET THIS ? One ounce (28 grams) of any pure dry substance that will dissolve 100% in a volume of 100 gal equals 75 ppm 1 oz = 28 g or 28,000 mg 28,000 mg ÷ 379 L = 73.88 ppm ( 1 gal = 3.79 L 100 gal = 379 L ) Solution Step 1: Convert the ppm recommendation to a weight basis using the following equation: Equation 3 desired ppm = oz fertilizer per 100 gal % of fertilizer x 75 150 ppm 20 % x 75 = 10.0 oz of 20-10-20 per 100 gal (final solution) Solution Step 2: Use equation 1 to adjust for a stock tank size of 25 gallons: oz per 100 gal = oz fertilizer per tank 100 / Tank Size (gal) 10.0 oz per 100 gal = 2.5 oz of 20-10-20 per 25 gal 100 / 25 gal Solution Step 3: Use equation 2 to adjust the rate for a 1:100 injection ratio: (In other words, concentrate it! ) oz per stock tank x injector ratio = oz per stock tank using injector 2.5 oz per 25 gal x 100 = 250.0 oz per 25 gal using a 1:100 injection ratio Solution Step 4: Convert ounces to pounds and ounces where: 16 ounces = 1 pound (dry) 250.0 oz per 25 gal = 15 lbs 10 oz 20-10-20 16 oz /lb (. . . .in a 25 gallon stock tank) This will give you 150 ppm with a 1/100 ratio You Are Done ! Not Yet ! How many parts per million of actual phosphorus and potassium will be applied with the 150 ppm N from the 20-10-20 ? Equation 4: Oz fertilizer per 100 gal x 0.75 x percent nutrient = the ppm desired nutrient . Phosphorus 10.0 oz per 100 gal x 0.75 x 10% P2O5 = 75 ppm P2O5 Not Yet ! For actual phosphorus : P2O5 is actually only 44% elemental phosphorus Therefor 75 ppm P2O5 x 0.44 = 33 ppm actual phosphorus Equation 4 – Now lets find the potassium true value! Oz fertilizer per 100 gal x 0.75 x percent nutrient = ppm desired nutrient Potassium 10.0 oz per 100 gal x 0.75 x 20% K 2O = 150 ppm K2O in solution For actual potassium : K2O is 83% elemental potassium 150 ppm K2O x 0.83 = 124.5 ppm actual potassium Final analysis: 150 ppm N : 33 ppm P : 124.5 ppm K A Test ! A poinsettia grower needs to apply 500 ppm nitrogen using ammonium nitrate (33.5-0-0). He also needs to treat his crop with 100 ppm magnesium using Epsom salts (10% magnesium). How much of each fertilizer must be added to a 5 gallon stock tank for delivery through a 0.4% injector? If You Got These Answers You Were Right! 15 lbs 9 oz NH4NO3 and 10 lbs 6 oz MgSO4 Things You Need To Know To Solve This Problem: 1. Recommended fertilizer application rate. 500 ppm nitrogen and 100 ppm magnesium 2. Fertilizer formulation and analysis. 33.5-0-0 and 10% magnesium 3. Injection ratio 0.4% 4. Size of stock tank in gallons 5 gallons Solution Step 1: Convert the recommendation for nitrogen ppm to a weight basis : 500ppm = 19.9 oz of 33.5-0-0 per 100 gal (final solution) 33.5 % x 75 Step 2: Adjust for a stock tank size of 5 gallons: 19.9 oz per 100 gal = 0.995 oz of 33.5-0-0 per 5 gal 100 / 5 gal Step 3: Adjust the rate for a 0.4% injection ratio: 0.4% injection ratio is 1:250 (100/ 0.4 = 250) 0.995 oz per 5 gal x 250 = 248.75 oz per 5 gal using 1:250 Step 4: Convert ounces to pounds and ounces: 248.75 oz per 50 gal = 15 lbs 9 oz 33.5-0-0 per 5 gal for 500 ppm N 16 oz Solution Step 5: Convert the recommendation for magnesium ppm to a weight basis : 100ppm = 13.3 oz of 10% Mg sulfate per 100 gal (final solution) 10 % x 075 Step 6: Adjust for a stock tank size of 5 gallons: 13.3 oz per 100 gal = 0.665 oz of 10% MgSO4 per 5 gal 100 / 5 gal Step 7: Adjust the rate for a 0.4% injection ratio: 0.665 oz per 5 gal x 250 = 166.25 oz per 5 gal using 1:250 injection ratio Step 8: Convert ounces to pounds and ounces: 166.25 oz per 50 gal / 16 oz = 10 lbs 6 oz 10% Epsom salts per 5 gal for 100 ppm Mg Nursery Crops and Fertilizer Recommendations Application of Granular Fertilizer to Container Nursery Crops Recommendation: Apply 3 lbs of nitrogen per cubic yard of medium per growing season. Nursery Response: How much Nutricote (17-6-8) do I apply to each container of my Hollies in Trade 1-size containers ? Things You Need To Know To Solve This Problem: 1. Recommended fertilizer application rate. 3 lbs nitrogen per cubic yard 2. Fertilizer formulation and analysis. 17-6-8 3. Container size Trade 1 4. Number of containers per cubic yard 300 Useful Conversions Pounds Nitrogen/Acre/Year are converted to lbs fertilizer/A/Yr by the following formula: lbs N/A/Yr x 100 constant = lbs fertilizer/A/Yr % fertilizer Pounds Nitrogen/cubic yard/Year are converted to lbs fertilizer/ cubic yard /Yr by the same formula: lbs N/cu yd/Yr x 100 constant = lbs fertilizer/cu yd/Yr % fertilizer Solution Step 1: Convert the pounds nitrogen recommended to pounds of Nutricote (17-6-8): 3 lbs N/cubic yard x 100 = 17.65 lbs Nutricote per cubic yard 17 Step 2: Calculate pounds of Nutricote per #1 container. Remember that there one cubic yard of medium can fill up 300 Trade 1 containers: 17.65 lbs = 0.0588 lbs Nutricote per Trade 1 container 300 Step 3: Convert pounds to grams and grams to tablespoons: 1 lb = 453.6 grams 1 tbs = 15 grams 0.0588 lbs x 453.6 = 26.69 grams 26.69 grams / 15 = 1.78 tbs Nutricote Final answer: 2 tbs of Nutricote per Trade 1 Holly per season Other Useful Conversions Milligrams per liter equal ppm mg/L = ppm 1 gram = 1,000 ppm 1 % = 10,000 ppm Tank Mixes Tank Mixes Example: A grower wants to prepare a tank mix containing 200 ppm actual nitrogen and 200 ppm actual potassium using calcium nitrate (15.5-0-0) and potassium nitrate (13-0-44). How much of each fertilizer must be added to a 50 gallon stock tank for delivery through a 1:100 injector? Things You Need To Know To Solve This Problem: 1. Recommended fertilizer application rate. 200 ppm nitrogen and 200 ppm potassium 2. Fertilizer formulation and analysis. calcium nitrate (15.5-0-0) potassium nitrate (13-0-44) 3. Elemental nutrient analysis. 4. Injection ratio 1:100 5. Size of stock tank in gallons 50 gallons Note: When combining two or three fertilizers to formulate a tank mix, it is usually easiest to start with a fertilizer containing two nutrients of interest, usually phosphorus or potassium, and do the calculation for nitrogen last. Solution Start with the potassium nitrate because it contains both nitrogen and potassium. Since K2NO3 contains 13% actual nitrogen and 44% K2O, first calculate the amount of K2NO3 to add to 100 gallons to get 200 ppm actual potassium. However, 44% is not actual K, it is K2O. Step 1: Convert 44% K2O to actual K. Contains 83% actual K : 44 % K2O potassium nitrate x 0.83 = 36.52% actual K Solution Step 2: Determine ounces per 100 gallons of K2NO3 for 200 ppm actual potassium using equation 3: 200 ppm = 7.3 oz of 13-0-44 per 100 gal 36.52 % x 0.75 (final solution) Solution Step 3: But wait … how much nitrogen was added? Calculate by using equation 4. 7.3 oz per 100 gal x 0.75 x 13% N = 71 . 175 ppm actual N So a solution containing 7.3 ounces potassium nitrate per 100 gallons is 200 ppm potassium and 71.175 ppm nitrogen. Solution Now adjust the amount of potassium nitrate for the stock tank size and injector ratio. Step 4: Using equation 1 to adjust for a stock tank size of 50 gallons: 7.3 oz per 100 gal = 3.65 oz of 13-0-44 per 50 gal 100 / 50 gal Step 5: Using equation 2 to adjust the rate for a 1:100 injection ratio: 3.65 oz per 50 gal x 100 = 365.0 oz per 50 gal @ 1:100 injection ratio Solution Step 6: Convert ounces to pounds and ounces: 365.0 oz per 50 gal = 22 lbs 13 oz 13-0-44 per 50 gal for 200 ppm K 16 oz Solution Step 7: Calcium nitrate (15.5-0-0) contains 15.5% nitrogen and 200 ppm total nitrogen is required. However, the potassium nitrate supplied 71.175 ppm N. Therefore, subtract 71.175 from 200 and apply equation 3: 200 – 71.175 ppm = 11.1 oz of 15.5-0-0 per 100 gal 15.5% x 0.75 (final solution) Step 8: Use equation 1 to adjust for a stock tank size of 50 gallons: 11.1 oz per 100 gal = 5.55 oz of 15.5-0-0 per 50 gal 100 / 50 gal Solution Step 9: Using equation 2 to adjust the rate for a 1:100 injection ratio: 5.5 oz per 50 gal x 100 = 555.0 oz per 50 gal using 1:100 injection ratio Step 10: Convert ounces to pounds and ounces: 555.0 oz per 50 gal / 16 oz = 34 lbs 11 oz 15.5-0-0 per 50 gal for 200 ppm N Now You Are Really Done !