How are the volume, temperature, and pressure of a gas related? o What happens if there is too much air in this balloon? o How did the air get out of the balloon? Science Standard 8.3.d: Students know the states of mater depend on molecular motion. Science Standard 8.9.e: Construct appropriate graphs from data and develop quantitative statements about the relationship between variables. pressure: the force of its outward push divided by the area of the walls of the container. directly proportional: a term used to describe the relationship between two variables whose graph is a straight line passing through the point (0,0). inversely proportional: a term used to describe the relationship between two variables whose product is constant. Measuring Gases When working with a gas, it is helpful to know its volume, temperature, and pressure. Volume: Because gas particles move and fill the space available, the volume of a gas is the same as the volume of its container. Measuring Gases When working with a gas, it is helpful to know its volume, temperature, and pressure. Temperature: a measure of the average energy of motion of the particles of matter. The faster the particles are moving, the greater their energy and the higher the temperature. Measuring Gases When working with a gas, it is helpful to know its volume, temperature, and pressure. Pressure: the force of its outward push divided by the area of the walls of the container. Pressure is often measured in units of pascals (Pa) or kilopascals (kPa). It can also be measured in atmospheres (atm) or millimeters of Mercury (mm Hg). A Change in Pressure A punctured basketball deflates as gas particles begin to escape. Temperature & Volume – Charles’s Law When the temperature of a gas increases at constant pressure, its volume increases. The variables are directly proportional to each other, forming a straight line that passes through the origin. Temperature & Volume – Charles’s Law When the temperature of a gas is decreased at constant pressure, the volume decreases. Algebra & Science Directly Proportional: linear Inversely Proportional: nonlinear Temperature & Volume – Charles’s Law Temperature Conversion: Kelvin (K) = °C + 273 Example: 0 °C = 273 K 20 °C = 293 K Equation: V1/T1 = V2/T2 V1 = Volume 1 T1 = Temperature 1 V2 = Volume 2 T2 = Temperature 2 • Charles’ Example 1: Calculate the decrease in temperature when 2.00 Liters of gas at a temperature of 20 °C is compressed to 1.00 Liters. V1/T1 = V2/T2 20 °C = 293 Kelvin 2 L = 1L 293 K x 2x = 293 x = 146.5 Kelvin • Charles’ Example 2: Calculate the increase in volume when 600 mL of air at a temperature of 20 °C is heated to 60 °C. V1/T1 = V2/T2 20 °C = 293 Kelvin 60 °C = 333 Kelvin 600 mL = x 293 K 333 K 293x = (600)(333) 293x = 199,800 x = 682 mL Pressure & Volume – Boyle’s Law When the pressure of a gas at constant temperature is increased, the volume of the gas decreases. Pressure & Volume – Boyle’s Law When the pressure is decreased, the volume increases. Gas pressure is inversely proportional to volume at constant temperature. The product of the two variables is a constant. Pressure & Volume – Boyle’s Law Pressure Conversion: 1 atm = 760 mm Hg = 101,325 Pa Example: 2 atm = 1,520 mm Hg 2 atm = 202,650 Pa Equation: (P1)(V1) = (P2)(V2) P1 = Pressure 1 V1 = Volume 1 P2 = Pressure 2 V2 = Volume 2 • Boyle’s Example 1: A gas occupies 12.3 liters at a pressure of 40 mm Hg. What is the volume when the pressure is increased to 60 mm Hg? (P1)(V1) = (P2)(V2) (40)(12.3) = (60)(x) 492 = 60x x = 8.2 liters • Boyle’s Example 2: If a gas occupies 3.60 liters at a pressure of 1 atm, what will its volume be at a pressure of 2.50 atm? (P1)(V1) = (P2)(V2) (1)(3.60) = (2.50)(x) 3.60 = 2.50x x = 1.44 liters Pressure & Temperature When a gas is heated, the particles move faster and collide more often with each other and with the walls of their container. The pressure of the gas increases. Charles’ Law A gas occupies 900 mL at a temperature of 27 °C. What is the volume at 132 °C? Charles’ Law A gas occupies 900 mL at a temperature of 27 °C. What is the volume at 132 °C? V1/T1 = V2/T2 27 °C = 300 Kelvin 132 °C = 405 Kelvin 900 mL = x 300 K 405 K 300x = (900)(405) 300x = 364,500 x = 1,215 mL Charles’ Law What change in volume results if 60 mL of gas is cooled from 33 °C to 5 °C? Charles’ Law What change in volume results if 60 mL of gas is cooled from 33 °C to 5 °C? V1/T1 = V2/T2 33 °C = 306 Kelvin 5 °C = 278 Kelvin 60 mL = x 306 K 278 K 306x = (60)(278) 306x = 16,680 x = 54.5 mL Boyle’s Law If a gas occupies 1.56 liters at a pressure of 1 atm, what will its volume be at a pressure of 3 atm? Boyle’s Law If a gas occupies 1.56 liters at a pressure of 1 atm, what will its volume be at a pressure of 3 atm? (P1)(V1) = (P2)(V2) (1)(1.56) = (3)(x) 1.56 = 3x x = .52 liters #1 & 2 on each side of the Gas Law Problems worksheet Finish the worksheet. HOMEWORK EXTENSION Write a detailed SUMMARY of the section and complete the UNANSWERED QUESTIONS section of your notes. Choose two of the remaining Depth & Complexity ICONS in your notes and explain how they relate to this section. HOMEWORK EXTENSION Write a detailed SUMMARY of the section and complete the UNANSWERED QUESTIONS section of your notes. Choose two of the remaining Depth & Complexity ICONS in your notes and explain how they relate to this section.