7. Fission • Sequence of events – using the reaction with U-235: A. The neutron approaches the nucleus of U-235 B. U-236 nucleus has been formed, in an excited state. C. The excess energy in some interactions may be released as a gamma ray, but more frequently, the energy causes distortions of the nucleus into a dumbbell shape. D. The parts of the nucleus oscillate in a manner analogous to the motion of a drop of liquid. Because of the dominance of electrostatic repulsion over nuclear attraction, the two parts can separate. They r then called fission fragments, bearing most of the mass-energy released. They fly apart at high speeds, carrying some 166 MeV of kinetic energy out of the total of around 200 MeV released in the whole process. The resultant thermal energy is recoverable if the fission takes place in a nuc reactor. 235 + n1 ( U236)* U 92 0 92 • ‘*’ excited state • Mass of (U-236)* = 235.043925 + 1.008665 AMU = 236.052590 Atomic mass unit • Mass of U-236 = 236.045563 AMU [in its ground state] - it is lower by 0.007027 amu or 6.5 MeV - This amount of excess energy is sufficient to cause fission. • Above calc did not include any kinetic energy brought to the reaction by the neutron • For very slow neutrons – by absorption, e.g., – Only 1 natural isotope – U-235 & – 94Pu239 & 92U233 – main artificial isotopes Recall – fast neutron vs. slow neutron • Most other heavy isotopes – need significantly larger excitation energy to bring the compound nucleus to the required energy level – for fission to occur. • This extra energy must be provided by the motion of the incoming neutron. E.g., • neutrons of at least 0.9 MeV r required to cause fission from U-238. • Other isotopes need more energy. • Fissile materials are those giving rise to fission with slow neutrons; • many isotopes are fissionable, if enough energy is supplied. • It is advantageous to use fast neutrons – of the order of 1 MeV energy – to cause fission. Byproducts of fission - Some [ν] neutrons [good for chain reaction!] - ν ranges from 1-7, with an avg in the range of 2-3 – depending on the isotope n the bombarding neutron energy. E.g., - U-235 with slow neutrons avg ν = 2.43 - Prompt neutrons – released instantly - delayed neutrons – [0.65% for U-235] as the result of radioactive decay of certain fission fragments 36 90 Kr 235 + n1 U 92 0 144 1 + 56Ba + 20n + Energy • Fission fragments or products are – Krypton & Barium • These r usually more unstable – as more neutrons than natural main isotope [e.g., barium is mainly – 56Ba137 and a prominent element of mass 144 is – 60Nd144 ] – so decay… … decay down to stable forms. 90 33sec Kr 36 90 2.91min Rb 37 90 27.7yr Sr 38 90 64hr Y 39 90 Zr 40 • With fission – a part is the absorptions of neutrons in U – merely results in radioactive capture, 235 + n1 U236 + γ U 92 0 92 - U-236 is relatively stable - About 14% of the absorptions r of this type - Rest 86% r fission η [eta] = no. of neutrons produced per absorption - η in U-235 is lower than ν, the no. per fission. - avg ν = 2.43 - η = (0.86)(2.42) = 2.07 The effectiveness of any nuclear fuel is essentially dependent on the value of η. So if fast neutrons – fission has larger η.