Minerals I Elements of the Earth’s crust Properties of minerals Crystal form Cleavage/Fracture Color, streak, luster Hardness, tenacity Specific gravity Acid test, magnetism, etc. http://www.nps.gov/seki/snrm/geology/cave_photos.htm Why Study Minerals? Building blocks of Earth materials Economically important Essential to understanding rock formation Minerals are cool Mineral - A naturally occurring, inorganic, homogeneous solid with a definite chemical composition and an ordered atomic arrangement. naturally occurring - materials synthesized in laboratory do not count, must be formed by natural processes in wild inorganic - not formed by organic chemistry (e.g., sugars, etc.) homogeneous solid - single substance in solid phase which cannot be physically separated into simpler compounds definite chemical composition - composition can be represented as chemical formula (e.g., NaCl), although variation in exact composition is possible (e.g., (Mg, Fe)2SiO4 ) ordered atomic arrangement – repeating structure at the atomic level, which expresses as symmetry in large specimens, i.e., crystalline structure. http://www.uoregon.edu/~jrice/geol311 Mineral Formation Minerals found at the Earth’s surface formed from natural processes both within the Earth and at the Earth’s surface. Environments vary greatly, and include: High temperature and pressure typical of the upper mantle. Evaporation basins Ocean bottoms Volcanic calderas and lava flows A host of stressful environments in mountain building zones And thousands of others! Mineral Properties Crystal Form Cleavage/Fracture Color Streak Color Luster Hardness Tenacity Specific Gravity Acid Test Magnetism Most useful properties for mineral identification Mineral Properties • • • • Crystal Form Cleavage/Fracture Color Streak Color Luster • • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Crystal symmetry is controlled by the atomic structure of mineral 90o 4-fold symmetry (90o) Symmetry 4-fold axes (90o) http://www.a-m.de/englisch/lexikon/mineral/halogenide/halit-bild1.htm http://home.planet.nl/~bartdw/sphalerite.htm 3-fold symmetry (120o) Symmetry 3-fold axes (120o) Crystal Form There are only 6 symmetry classes; each mineral belongs to only ONE symmetry class, and thus all crystals exhibit that symmetry only! isometric tetragonal orthorhombic hexagonal monoclinic triclinic http://members.aol.com/jmichaelh/part1.html Crystal Form Caveat One: Crowding of Caveat Two: other crystals can mask symmetry Crystals are often too small to see Symmetry can always be seen using techniques like X-ray diffraction Mineral Properties • Crystal Form Cleavage/Fracture • Color • Streak Color • Luster • • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Cleavage - tendency to split along planes of weakness corresponding to weaker chemical links in internal structure of crystal A single crystal can display several cleavage directions. 1 direction 2 directions The cleavage directions are not always at right angles to each other. They also are not necessarily parallel to the crystal faces of the mineral. Parallel Cleavage Cleavage Can be parallel to crystal faces, but is often at an angle One Direction of Cleavage Fig. 02.19a One Direction of Cleavage Two Directions of Cleavage Fig. 02.21 Three Directions of Cleavage Fig. 02.22 http://www.geology.sdsu.edu/visualgeology Four Directions of Cleavage Fluorite Crystals http://www.xpsdata.com/ http://www.greatsouth.net/ Mineral Properties • Crystal Form Cleavage/Fracture • Color • Streak Color • Luster • • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Fracture - any breakage that is not cleavage conchoidal fracture Characteristic of quartz, chert and flint conchoidal fracture Fig. 02.23 Mineral Properties • Crystal Form • Cleavage/Fracture Color • Streak Color • Luster • • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Characteristic for some minerals, useless for most One mineral can come in a rainbow of colors Spinel MgAl2O4 Hardness = 8 Quartz Jasper Citrine Rose Quartz Quartz SiO2 Amethyst Hardness = 7 Carnelian Onyx Smokey Quartz One mineral can appear to be different colors under different lighting Chrysoberyl sunlight BeAl2O4 Hardness = 8.5 Alexandrite artificial light Mineral Properties • Crystal Form • Cleavage/Fracture • Color Streak Color • Luster • • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Streak Color - Color of powdered mineral, which may or may not be the color of the crystal hematite streak color Mineral Properties • • • • Crystal Form Cleavage/Fracture Color Streak Color Luster • • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Luster - quality of light reflected from mineral surface Luster - quality of light reflected from mineral surface pyrite metallic gold silver Luster quality of light reflected from mineral surface non-metallic pearly vitreous (glassy) resinous Mineral Properties • • • • • Crystal Form Cleavage/Fracture Color Streak Color Luster • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Hardness - resistance of mineral to scratching or abrasion Mohs Hardness Scale Austrian mineralogist F. Mohs, 1824 hard Higher numbered minerals Based on relative scratch lower numbered minerals hardness of 10 common minerals 10. Diamond C 9. Corundum Al2O3 8. Topaz Al2SiO4(F,OH)2 7. Quartz SiO2 6. Orthoclase KAlSi3O8 glass plate 5. Apatite Ca5(PO4)3(F,Cl,OH) 4. Fluorite CaF2 copper penny 3. Calcite CaCO3 fingernail 2. Gypsum CaSO4 soft 1. Talc Mg3Si4O10(OH)2 Muscovite Hardness < 2 Can scratch with fingernail (H=2.5) Fig. 02.14 Fluorite Hardness =4 Fig. 02.15c Can scratch copper penny (H=3.5), but not glass plate (H=5.5) Apatite Hardness =5 Fig. 02.15b Can scratch copper penny (H<3.5), but not glass plate (H=5.5) Quartz Hardness =7 Fig. 02.15a Scratches glass plate (H=5.5). Hardest of common minerals Mineral Properties • • • • • Crystal Form Cleavage/Fracture Color Streak Color Luster • Hardness Tenacity • Specific Gravity • Acid Test • Magnetism Tenacity - resistance of the mineral to breaking Mineral Properties • • • • • Crystal Form Cleavage/Fracture Color Streak Luster • Hardness • Tenacity Specific Gravity • Acid Test • Magnetism Specific Gravity - density of the material (g/cm3) Specific Gravity Related to both the atomic weight of the contained elements, and how tightly the atoms are packed Orthorhombic Carbonates All minerals have same structure, only cation differs Mineral Formula Cation g/cm3 Aragonite CaCO3 20 2.95 Strontianite SrCO3 38 3.76 Witherite BaCO3 56 4.29 Cerrusite PbCO3 82 6.55 Specific Gravity Related to both the atomic weight of the contained elements, and how tightly the atoms are packed Graphite Diamond http://geology.uvm.edu/vtlandforms/gl_graph.htm Both are minerals composed of the element carbon Ggraphite = 2.23 (loose) Gdiamond = 3.51(tight) Mineral Properties • • • • • Crystal Form Cleavage/Fracture Color Streak Luster • Hardness • Tenacity • Specific Gravity Acid Test • Magnetism Reaction to dilute acid; especially useful in identifying carbonate minerals Minerals like calcite react with weak acid, dissolving the mineral and producing lots of bubbles (effervescence) Mineral Properties • • • • • Crystal Form Cleavage/Fracture Color Streak Luster • • • • Hardness Tenacity Specific Gravity Acid Test Magnetism Some minerals strongly attract magnets. Characteristic of magnetite and some other minerals