1 Unit 2 Homework Packet-Atomic Theory History of the Atom Write the name of the scientist who is credited with the following experiments or discoveries. 1. Thompson__Discovered the electron 5. __Chadwick_ Discovered neutrons 2. _Rutherford_Discovered the nucleus 6. __Rutherford___ Did the Gold Foil Exp. 3. __DemocritusNamed particles atoms 7. __Dalton________ Said all atoms are same for one element 4. __ThompsonUsed a cathode ray tube 8. __Thompson_________ Plum pudding model State the subatomic particle that is described in each of the following statements. 9. __p_____+1 charge 12. __e_____found outside nucleus 10. __n_____ No Charge 13. ___p & n____found inside nucleus 11. ___e____-1 charge 14. ____e___least massive Answer each of the following questions completely. 15. Draw a model of how we expect atoms to look. Be sure to include the location of subatomic particles. 2 16. How does the mass of an electron compare to a proton and neutron? Electrons are much lighter and smaller in mass then protons and neutrons 17. Put the subatomic particles in order from the most massive to the least massive. P, N, then electrons 18. Why has our idea of what the atom looks like changed so many times? Science is discovering new things everyday! 19. Do you think our view of the atom will every change again? Why or why not? Sure! You never know what the future can hold! **This is an opinion question** What is an Atom? 1. How many protons are found in 12C? __6______ 13C? ___6_____ 13C- ? ___6_______ 2. How many neutrons are founds in 12C? _6______ 13C? ___7______ 13C- ? __7_______ 3. How many electrons are found in 12C? __6______ 13C? ___6______ 13C- ? __7_______ 4. Based on the data presented above, a. What do all carbon atoms (and ions) have in common? same protons b. What do all hydrogen atoms (and ions) have in common? 5. What is the significance of the atomic number? Where will you find it on the periodic table? Number of protons; number found on top of each element 6. How is the mass number determined? Number of protons and neutrons 7. What structural feature is different in isotopes of a particular element? Nucleus (changing the number of neutrons) 8. What feature distinguishes a neutral atom from an ion? The charge next to the element 9. Where is most of the mass of an atom, within the nucleus or outside of the nucleus? Explain your reasoning. Within the nucleus since electrons have the least mass 10. Complete the chart below: 3 Isotope Atomic Number (Z) Mass Number (A) Number of Electrons 31P 15 31 15 18O 8 18 8 39K+ 19 39 18 58Ni2+ 28 58 26 12. What is the mass (in amu) of a. one 1H atom? _______1.008_________________ b. one 12C atom? ______12.01_________________ 14. How many electrons, protons, and neutrons are found in each of the following? Atom or ion Electrons Protons Neutrons 24Mg 12 12 12 23Na+ 10 11 12 35Cl 17 17 18 35Cl- 18 17 18 56Fe3+ 23 26 30 15N 7 7 8 16O2- 10 8 8 27Al3+ 10 13 14 Atomic Emission Spectrum of the Bohr Hydrogen Atom Photon: A particle of electromagnetic radiation with no mass that carries a quantum of energy. Quantum (pl. quanta): “a packet of energy”; the amount of energy absorbed or released when an electron moves between energy levels. Ground State: lowest possible energy of an e-. The principal quantum number (n) = 1. [Energy level = 1] The most energy is released when electrons fall to the n=1 energy level. As wavelength decreases, frequency increases. As frequency increases, the energy of the electromagnetic radiation increases. 1) In which transition is the most energy released? a. n = 3 to n = 2 b. n = 3 to n = 1 2) Which transition required the largest quanta of energy input? c. n = 5 to n = 2 d. n = 1 to n = 3 Name___________________________________________________________________________ Date_____________________ a. n = 2 to n = 4 b. n = 1 to n = 2 c. n = 2 to n = 1 d. n = 4 to n = 1 3) a) What wavelength of light is produced during a transition from n = 5 to n = 2? __________434______ nm = _________4.34x10-7______ m b) What color is the light that is released? Color = _______Blue_______________ 4) a) What wavelength of light is produced during a transition from n = 3 to n = 2? _______656________ nm = ________6.56x10-7______________ m b) What color of light does this correspond to? Color = ____Red__________ 5) If violet light of wavelength 4.1 x 10-7 m is released, what transition did the electron make? n = ___6_______ to n = ____2______ 6) Put in order from lowest to highest frequency: a) Radio waves, gamma rays, IR, X-rays, UV, Microwaves Radio, microwaves, IR, UV, Xrays, Gamma b) Blue, Red, Violet, Orange Red, Orange, Blue, Violet 7) Put in order from lowest energy to highest energy: - Gamma Rays, IR, Radio Waves, UV, Red light, Violet Light Radio, IR, Red, Violet, UV, Gamma Nuclear Chemistry: Name the type of emission: 1. Uranium-234 To Thorium-230 Alpha Alpha 5. Polonium-218 to Lead-214 2. Thorium-230 to Radium-226 Alpha Alpha 6. Lead-214 to Bismuth-214 3. Radium-226 to Radon-222 Beta Alpha 7. Bismuth-214 to Polonium-214 4. Radon-222 to Polonium-218 Beta 4 Name___________________________________________________________________________ Date_____________________ 8. Polonium-214 to Lead-210 Alpha Beta 11. Polonium-210 to Lead-206 9. Lead-210 to Bismuth-210 Beta Alpha 11. Bismuth-210 to Polonium-210 Write an equation for the following elements through the given emission type. Alpha Decay: Beta Decay: 1. Polonium-218 1. Lead-210 218 Po→4 2 He + 214Pb 2. Polonium-210 210 Po→4 2He + 206Pb 3. Radium-224 224 Ra→42He + 220Rn 4. Radon-219 219 Rn→42He + 215Po 210 Pb→0-1e + 210Bi 2. Lead-214 214 Pb→0-1e + 214Bi 3. Bismuth-210 210 Bi→0-1e + 210Po 4. Bismuth-214 214 Bi→0-1e + 214Po Half Lives 1. If gallium-68 has a half-life of 68.3 minutes, how much of a 10mg sample is left after two half-lives? 10/2 = 5/2=2.5 mg 2. If the passing of five half-lives leaves 25.0mg of a strontium-90 sample, how much was present in the beginning? 25 mg x2=50x2=100x2=200x2=400x2= 800 mg 3. Manganese-56 is a beta emitter with a half-life of 2.6hr. What is the mass of manganese-56 in a 1mg sample of the isotope after 10.4hr 2.6x2=5.2x2=10.4 (2 half lives) 1 mg/ 2=.5/2= .25 mg 5 Name___________________________________________________________________________ Date_____________________ 6 Study Guide 1. Compare the mass of an electron, neutron, and proton Protons and neutrons have the same mass, electrons are less mass 2. A neutral atom of Aluminum has how many electrons? What would happen if it gained 2 electrons? What if it lost 3 electrons? Al = 13 electrons Al-2= 15 electrons Al+3= 10 electrons 3. To change the identity of an atom, you have to change the number of __protons_______. 4. What atom is this: 18 Protons, 19 Neutrons, and 18 electrons? Argon-37 5. How many total electrons are in Na+1? 10 6. What is an Ion? Element with a charge (+ or -) 7. If an ion has 7 protons, 90 neutrons, and a +3 charge, what is its atomic number? 7 (atomic number = # of protons) 8. What was the purpose of the flame lab we did in class? When an electron travels back to the ground state, it emits different forms of waves. In the lab, they emitted different forms of color. The red color emits the least amount of energy while violet has the most. By checking the colors of the flame will help identify the different elements on the periodic table. 9. Neutral atoms of the same element can have a different number of __neutrons________. 10. Which atom has 13 protons? Aluminum 11. How many protons are in Au+? 79 12. What is the mass number for Calcium-42? 42 13. The atoms mass is in the ___nucleus______, which is made of __protons______and __neutrons_______. 14. Give the atomic symbol for the atom that has 11 protons, 12 neutrons, and 10 electrons. 23 +1 11Na 15. List the subatomic particles with their charges. Protons (+), neutrons (0), electrons (-) 16. How many electrons are in the following a. B3+ a. 2 b. 10 c.7 d. 4 b. Al3+ c. N d. N3+ 17. What is an isotope? Same element but different mass number (different number of neutrons) Name___________________________________________________________________________ Date_____________________ 18. Who discovered the charge of an electron? JJ Thompson 19. If you change the electrons of an atom you also change the ____charge__________. 20. How many protons, neutrons, and electrons are in 48Cr+2? p=24, n=24, e=22 21. Carbon-14 has more __neutrons_____ than Carbon-12. 22. What is transmutation? Changing the element 23. Describe the two orbitals of 97 nm based on the Bohr diagram. n=4 to n=1 24. If carbon as 15.0% of 12 C, 15.0% of 13C, and 70% of 14C, what is the average atomic mass (amu) of carbon? (15x12) + (15x13) + (70x14) = 13.55 amu 100 25. Label the following diagram with the appropriate decays of each element. Alpha Beta . Alpha Alpha Alpha Alpha Alpha Beta Alpha Beta Alpha 7