Sadegh Salehzadeh
Professor of Inorganic and Computaional Chemistry
First name:Sadegh
Family name:Salehzadeh
Born: 1966, Hamedan
Nationality: Iranian
Married, My wife have a B.Sc. degree in Chemistry
Children: one daughter and one son
Address:
Dr S. Salehzadeh
Faculty of Chemistry
Bu-Ali Sina University
Hamedan
Iran
E-mails:saleh@basu.ac.ir
Fax: + 98-811-8380709
or
ssalehzadeh@gmail.com
Awards:
1) Distinguished PhD student of the Bu Ali Sina University in year 2000.
2) Distinguished researcher of the chemistry group of the Bu-Ali Sina University in
year 2005.
3) Distinguished researcher of the faculty of chemistry of the Bu-Ali Sina
University in year 2007.
1
4) Distinguished researcher of the faculty of chemistry of the Bu-Ali Sina
University in year 2009.
Areas of research interest:
■ Design, synthesis and charcterization of new polydentate ligands and macrocyclic and
macroacyclic complexes, specially Schiff base complexes.
■ Proton affinity of polybasic ligands and corresponding metal complexes
■ Protonation constants and/or microconstants of polybasic ligands
■ Relative stabilities of different conformers of ligands and different isomeric forms of metal
complexes and designing compounds with special properties or structures
■ Binding energies and the nature of metal-ligand bonds in metal complexes
■ Interaction between the nano size and/or non-nano size molecules
Sabbatical leaves:
a) I have been for four months in UMIST, Manchester, UK, as a member of Prof. Parish’s
research group in year 1999.
b) I have been for six months in University of Shefiiled, Sheffield, UK as a member of Prof.
Ward's research group in year 2007.
Supervision of MSc and PhD students:
a) I have directed 16 MSc and 2 PhD students.
b) At the moment I have 5 MSc and 5 PhD students.
Teaching experience:
BSc level:
• General Chemistry I and II
• Inorganic Chemistry I and II
• Chemical Applications of Group Theory
• Chemical literature
• Scientific English for Chemistry Students
MSc and PhD levels:
• Advanced Inorganic Chemistry
• Inorganic Spectroscopy
• New Subjects in Inorganic Chemistry
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Selected Publications:
(1) H. Keypour, S. Salehzadeh, R. G. Pritchard and R. V. Parish; Synthesis and Crystal
Structure Determination of Some Asymmetrical and Symmetrical CR-type
Macrocyclic Schiff-base Complexes, with a Single Pendant Coordinating 2Aminoethyl Arm. Inorg. Chem., 39, 5787-5790 (2000).
(2) H. Keypour, S. Salehzadeh, R. G. Pritchard and R. V. Parish; Cadmium(II)
complexes of fully condensed Schiff-base Ligands derived from two symmetrical
and asymmetrical tripodal tetraamines and 2-acetylpyridine; the novel observations
for heptadentate mono-capped trigonal antiprismatic Schiff-base complexes,
Polyhedron, 19, 1633-1637 (2000).
(3) H. Keypour, S. Salehzadeh; Nickel(II) and copper(II) complexes of macrocyclic and
acyclic Schiff-base ligands derived from new asymmetrical tripodal tetraamines and
2,6-diacetylpyridine. Transition Met. Chem., 25, 204-208 (2000).
(4) M. A. Zolfigol, M . H. Zabarjadian, G. Chehardoli, H. Keypour, S. Salehzadeh, M.
Shamsipur; N-Nitrosation of Secondary Amines with [NO+•Crown•H(NO3)2-]. J. Org.
Chem., 66, 3619-3620 (2001).
(5) S. Salehzadeh, S.M. Nouri, H. Keypour, M. Bagherzadeh, Synthesis of
gadolinium(III) and samarium(III) complexes of new potentially heptadentate (N4O3)
tripodal Schiff base ligands, and a theoretical study, Polyhedron, 24, 1478-1486
(2005).
(6) S. Salehzadeh, M. Bayat, Three new defined proton affinities for polybasic
molecules in the gas-phase: Proton microaffinity, proton macroaffinity and proton
overallaffinity. Chemical Physics Letters. 427, 455 (2006).
(7) S. Salehzadeh, S.A. Javarsineh, H. Keypour, Metal complexes of a new potentially
heptadentate(N7) tripodal Schiff base ligand. Synthesis, NMR studies and ab initio
calculations, J. Mol. Structure, 785, 54-62 (2006).
(8) S Salehzadeh, M. Bayat, Mehdi Hashemi, Complete gas-phase proton microaffinity
analysis of two bulky polyamine molecules. Journal of Physical Chemistry A. 111,
8188 (2007).
(9) M. A. Zolfigol, G. A. Chehardoli, S. Salehzadeh, H. Adams, M. D. Ward, {[K.18Crown-6]Br3}n: a unique tribromide-type and columnar nanotube-like structure for
the oxidative coupling of thiols and bromination of some aromatic compounds.
Tetraheron letters, 48, 7969, (2007).
(10) S Salehzadeh, M. Bayat, The First Reported Correlation Between the Calculated
Gas-Phase Proton Macroaffinities of some Metal Complexes with their Measured
Formation Constants in Solution; Zn(II) Complexes of a Series of Tripodal Aliphatic
Tetraamines.. Journal of Physical Chemistry A. 112, 4090 (2008).
(11) S Salehzadeh, R. Golbedaghi, I.S. Tidmarsh, N.K. Al-Rasbi, H. Adams, M.D.
Ward, H. Adams, Cd(ΙΙ) and Mn(ΙΙ) complexes of a new hexadentate Schiff base
3
ligand derived from an asymmetric tripodal tetraamine and 2-pyridinecarboxaldehyde.
Polyhedron. 27, 3549 (2008).
(12) S. J. Sabounchei, H. Nemattalab, S. Salehzadeh, M. Bayat, H. R. Khavasi, H.
Adams, New mono and binuclear mercury(II) complexes of phosphorus ylides
containing DMSO as ligand: Spectral and structural characterization, Journal of
Organometallic Chemistry, 693, 1975(2008).
(13) S Salehzadeh, R. Golbedaghi, I.S. Tidmarsh, L. Sorace, H. Adams, M.D. Ward, H.
Adams, Syntheses, crystal structures and magnetic properties of three new binuclear
Ni(II) complexes derived from tripodal tetradentate (N4) ligands. Polyhedron. 28,
162 (2009).
(14) S. Salehzadeh, R. Golbedaghi, H. R. Khavasi, Synthesis, characterization and
crystal structure of Ni(ΙΙ) complex of an acyclic pentadentate Schiff base ligand. An
agreement between the experimental and theoretical results., J. Coord. Chem. (2009)
62, 2532–2539.
(15) S Salehzadeh, M.D. Ward, H. Adams, A Novel chelate assisted C-C bond
formation on a cadmium(II) complex of an asymetric heptadentae tripodal Schiff base
ligand. Inorg. Chem. Comm. 12 (2009) 433–435.
(16) S. Salehzadeh, F. Yaghoobi, M. Bayat, Illustration of all Species and all
Microspecies Involved in Full Protonation Steps of Spermine and determination of
Corresponding Most Abundant and Most Stable Conformers, A Gas Phase
Theoretical Study, Chemical Physics, (2009) 361, 18–26.
(17) S. Salehzadeh, A. Shooshtari, M. Bayat, Theoretical Study on First Proton
Macroaffinity of Cu(II), Zn(II) and Cd(II) Complexes of Four Triazacycloalkanes (
[X] ane N3, X = 9 – 12 ): Good Correlations with Formation Constants in Solution.
Dalton Trans. , (2009) 2865–2870.
(18)
Seyyed Javad Sabounchei, Sepideh Samiee, Sadegh Salehzadeh, Zabihollah Bolboli
Nojini, Elisabeth Irran, Four-coordinate and pseudo five-coordinate Hg(II) complexes of
a new bidentate phosphorus ylide: X-ray crystal structure and spectral characterization.
Journal of Organometallic Chemistry 695 (2010) 1441–1450.
(19) Sadegh Salehzadeh, Reza Golbedaghi and Allan G. Blackman, Synthesis,
characterization, and X-ray crystal structure analysis of Cd(II) and Cu(II) complexes of
an acyclic pentadentate Schiff base. Journal of Coordination Chemistry Vol. 63, No. 4,
20 February 2010, 634–642.
(20) Reza Golbedaghi, Sadegh Salehzadeh, Hassan Keypour, Allan G. Blackman, Mn(II)
and Cd(II) macrocyclic Schiff base complexes with a single pendant coordinating 2pyridylmethyl arm: Synthesis, X-ray crystal structure and NMR studies. Polyhedron 29
(2010) 850–856.
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(21) Sadegh Salehzadeh , Mehdi Bayat, Theoretical Studies on the Structure and
Protonation of Cu(II) Complexes of a Series of Tripodal Aliphatic Tetraamines: Good
Correlations with the Experimental Data. J Comput Chem (2010) 31: 2371–2380.
(22) Mehdi Bayat, Sadegh Salehzadeh, Theoretical studies on the proton affinities of four
different series of nano-size diamines and designing strong superbases based on
fullerene(C60) molecule. Journal of Molecular Structure: THEOCHEM 957 (2010) 120–
125.
(23) Sadegh Salehzadeh, Mehdi Bayat, Computational evidence of preferred energy and
preferred binding energy in the formation of ‘‘1 + 1’’ versus ‘‘2 + 2’’ macrocyclic Schiff
base complexes. Computational and Theoretical Chemistry 965 (2011) 131–136.
(24) Sadegh Salehzadeh, Mehdi Bayat, A theoretical study on the formation of ‘‘1 + 1’’
versus ‘‘2 + 2’’ macrocyclic Schiff base complexes in the absence of coordinated anions,
Computational and Theoretical Chemistry 971 (2011) 30–37.
(25) Sadegh Salehzadeh, Yasin Gholiee, Mehdi Bayat, Prediction of Microscopic
Protonation Constants of Polybasic Molecules Via Computational Methods: A Complete
Microequilibrium Analysis of Spermine, International Journal of Quantum Chemistry,
Vol 111, 3608–3615 (2011).
(26) Mehdi Bayat, Fereshteh Yaghoobi, Sadegh Salehzadeh, Samaneh Hokmi, A
Theoretical study on the interaction of [Al(H2O)6]3+ and [Mg(H2O)6]2+ cations with
fullerene (C60), coronene and benzene π-systems Polyhedron 30 (2011) 2809–2814.
(27) Mehdi Bayat, Moritz von Hopffgarten, Sadegh Salehzadeh, Gernot Frenking, Energy
decomposition analysis of the metal-oxime bond in [M{RC(NOH)C(NO)R}2] (M =
Ni(II), Pd(II), Pt(II), R = CH3, H, F, Cl, Br, Ph, CF3) Journal of Organometallic
Chemistry 696 (2011) 2976-2984.
(28) Mehdi Bayat, Sadegh Salehzadeh, Gernot Frenking, Energy decomposition analysis
of the metal-imine bond in [(CO)4M-SB](M = Cr, Mo, W; SB: RHC=N-CH2CH2N=CHR) Journal of Organometallic Chemistry 697 (2012) 74-79.
(29) S. Salehzadeh, M. Khalaj, S. Dehghanpour, A. Mahmoudi. Reaction of ZnCl2 and
HgCl2 metal salts with a bidentate Schiff base ligand in methanol solution, X-ray crystal
structure, and theoretical studies. J IRAN CHEM SOC (2013) DOI 10.1007/s13738-0130229-1.
(30) S. Salehzadeh, M. Bayat, Y. Gholiee, Tetrahedron, A theoretical study on the
importance of steric effects, electronic properties, interaction and solvation energies in the
ʻhost–guestʼ chemistry of protonated azacryptands and halide anions. Tetrahedron (2013)
Accepted.
Full list of publications:
1) H. Keypour, S. Salehzadeh, R. G. Pritchard and R. V. Parish; Nickel(II)
complexes of fully and partially condensed Schiff-base ligands derived from tris(3aminopropyl)amine and acetylpyridine. Transition Met. Chem., 23, 605-607 (1998).
5
2) S. Sabounchi, S. Salehzadeh; Multinuclear variable temperature NMR studies on
cyanide, water and hydroxyl group scrambling on halogenation of K2[Pt(CN)4] and
related reactions. Iran. J. Chem. & Chem. Eng., 17, 61-65 (1998).
3) H. Keypour, S. Salehzadeh, R. G. Pritchard and R. V. Parish; Synthesis and
Crystal Structure Determination of Some Asymmetrical and Symmetrical CR-type
Macrocyclic Schiff-base Complexes, with a Single Pendant Coordinating 2Aminoethyl Arm. Inorg. Chem., 39, 5787-5790 (2000).
4) H. Keypour, S. Salehzadeh, R. G. Pritchard and R. V. Parish; Cadmium(II)
complexes of fully condensed Schiff-base Ligands derived from two symmetrical
and asymmetrical tripodal tetraamines and 2-acetylpyridine; the novel observations
for heptadentate mono-capped trigonal antiprismatic Schiff-base complexes,
Polyhedron, 19, 1633-1637 (2000).
5) H. Keypour, S. Salehzadeh; Nickel(II) and copper(II) complexes of macrocyclic
and
acyclic Schiff-base ligands derived from new asymmetrical tripodal
tetraamines and 2,6-diacetylpyridine. Transition Met. Chem., 25, 204-208 (2000).
6) H. Keypour, S. Salehzadeh; Synthesis of binuclear copper(II) complexes
containing two CR-type macrocyclic rings. Asian Journal of Chemistry, 12, 19-22
(2000).
7) M. A. Zolfigol, F. Shirini, A. G. Choghamarani, A. Taqian-Nasab, H. Keypour,
S. Salehzadeh; Chemoselective N-Nitrosation of secondary Amines
under mild
and Heterogeneous Conditions via in situ generation of NOCl. J. CHEM
RESEARCH (S), 420-22 (2000).
8) H. Keypour, S. Salehzadeh, R. G. Pritchard, and R. V. Parish ; Synthesis and
crystal structure determination of a Nickel(II) complex of an acyclic pentadentate
(N5) mono Schiff base ligand. Molecules, 6, 909-914 (2001).
9) M. A. Zolfigol, M . H. Zabarjadian, G. Chehardoli, H. Keypour, S. Salehzadeh, M.
Shamsipur; N-Nitrosation of Secondary Amines with [NO+•Crown•H(NO3)2-]. J. Org.
Chem., 66, 3619-3620 (2001)
10) M. A. Zolfigol, A. G. Choghamarani, F. Shirini, H. Keypour, S. Salehzadeh,
Chemoselective N-Nitrosation of secondary Amines under mild and Heterogeneous
Conditions. Synthetic Communications, 31, 359-365 (2001).
11) M. A. Zolfigol, M. Bagherzadeh, A. G. Choghamarani, H. Keypour, S.
Salehzadeh; N-Nitrosation of Secondary Amines Under Mild and Heterogeneous
Conditions. Synthetic Communications, 31, 1161-66 (2001).
12) M. A. Zolfigol, F. Shirini, A. G. Choghamarani, A. Shiri, H. Keypour,
S. Salehzadeh; Chemoselective N-Nitrosation of secondary Amines under mild and
Heterogeneous Conditions with ZrCl4/NaNO2. Asian Journal of Chemistry, 13, 849853 (2001).
6
13) H. Keypour, S. Salehzadeh, R. G. Pritchard, and R. V. Parish; Copper(II)
complexes of asymmetrical and symmetrical acyclic pentadentate (N5) mono Schiff
base ligands. The X-ray structure of one complex. Transition Met. Chemistry, 27,
720-723 (2002) .
14) H. Keypour, S. Salehzadeh, and R. V. Parish; Synthesis of two potentially
heptadentae (N4O3) Schiff-base ligands derived from condensation of tris(3aminopropyl)amine and salicylaldehyde or its 4-substituted derivative. Nickel(II) and
copper(II) complexes of the former ligand. Molecules, 7, 140-144 (2002).
15) H. Keypour, M. Dehdari and S. Salehzadeh, Potentiometric Determination of the
Formation Constants of Complexes of 3,3',2”-Triaminodipropylethylamine with Co(II),
Ni(II), Cu(II), Zn(II) and Cd(II), Asian Journal of Chemistry, 14, 856-866 (2002).
16) M. A. Zolfigol, A. G. Choghamarani, A. Taqian-Nasab H. Keypour, S.
Salehzadeh, Chemoselective N-nitrosation of Secondary Amines under Mild and
Heterogeneous Conditions, BULLETIN OF THE KOREAN CHEMICAL SOCIETY,
638-640 (2003).
17) H. Keypour, M. Dehdari and S. Salehzadeh; Potentiometric Determination of the
Formation Constants of Complexes of 3,2',2”-Triaminopropyldiethylamine with Co(II),
Ni(II), Cu(II), Zn(II) and Cd(II).Transition Metal Chemistry, 28, 425-429 (2003).
(18) M. A. Zolfigol, A. G. Choghamarani, A. Taqian-Nasab H. Keypour,S. Salehzadeh,
Chemoselective N-nitrosation of Secondary Amines under Mild and Heterogeneous
Conditions, Bull Korean Chem. Soc. 24,638-640 (2003).
(19) S. Salehzadeh, S.M. Nouri, H. Keypour, M. Bagherzadeh, Synthesis of
gadolinium(III) and samarium(III) complexes of new potentially heptadentate (N4O3)
tripodal Schiff base ligands, and a theoretical study, Polyhedron, 24, 1478-1486
(2005).
(20) S. Salehzadeh, M. Bayat, Three new defined proton affinities for polybasic
molecules in the gas-phase: Proton microaffinity, proton macroaffinity and proton
overallaffinity. Chemical Physics Letters. 427, 455 (2006).
(21) S. Salehzadeh, S.M. Nouri, H. Keypour, Synthesis and Characterization of two New
Asymmetrical Potentially Heptadentate(N4O3) Tripodal Schiff Base Ligands and a
Theoretical Study. Asian Journal of Chemistry,18, 515-552 (2006).
(22) S. Salehzadeh, S.A. Javarsineh, H. Keypour, Metal complexes of a new potentially
heptadentate(N7) tripodal Schiff base ligand. Synthesis, NMR studies and ab initio
calculations, J. Mol. Structure, 785, 54-62 (2006).
(23) S. Salehzadeh, H. Keypour, Synthesis and characterization of Mn(II), Ni(II), Cu(II),
Zn(II) and Cd(II) complexes of heptadentate asymmetrical tripodal Schiff base.
Asian Journal of Chemistry,18, 1387-1393 (2006).
7
(24) S. Salehzadeh, R. Golbedaghi, Synthesis and Characterization of Zn(II) Complex
of a Tripodal Tetradentate(N4) Ligand, and a Theoretical Study. Asian Journal of
Chemistry, 18, 2211(2006).
(25) S Salehzadeh, M.
Bayat, Mehdi Hashemi,
Complete gas-phase proton
microaffinity analysis of two bulky polyamine molecules. Journal of Physical
Chemistry A. 111, 8188 (2007).
(26) S. Salehzadeh, M. Bayat, Comparison Between the Experimental and Theoretical
Investigations on Carbon-13 Isotropic Shielding Constants of Some Tripodal
Tetraamine Ligands. Journal of The Chinese Chemical Society. 54, 1145 (2007).
(27) S. Salehzadeh, R. Golbedaghi, Synthesis and Characterization of the Cd(ІІ)
Complexes of a hexadenate (N4O2) Schiff base Ligand; IR, NMR and Theoretical
Studies. Journal of Chemical Research. 2, 86 (2007).
(28) V. Izadkhah, S. Salehzadeh, R. Golbedaghi, M. Bayat, L. Davoodi, Synthesis and
Theoretical study of Gadolinium(III) complex of Heptadentate (N4O3) Tripodal
Schiff base L:igand. Asian Journal of Chemistry, 19, 5505 (2007).
(29) S. Sabounchei, A. Dadrass, M. Jafarzadeh, S. Salehzadeh, H. R. Khavasi, Synthesis
of a new carbbenzyloxymethylenetriparatolylphosphorane ylide and study of its
reaction with mercury(II) halides: Spectral and structural characterization. Journal of
Organometallic Chemistry. 692, 2500, (2007).
(30) M. A. Zolfigol, G. A. Chehardoli, S. Salehzadeh, H. Adams, M. D. Ward, {[K.18Crown-6]Br3}n: a unique tribromide-type and columnar nanotube-like structure for
the oxidative coupling of thiols and bromination of some aromatic compounds.
Tetraheron letters, 48, 7969, (2007).
(31) S Salehzadeh, M. Bayat, The First Reported Correlation Between the Calculated
Gas-Phase Proton Macroaffinities of some Metal Complexes with their Measured
Formation Constants in Solution; Zn(II) Complexes of a Series of Tripodal Aliphatic
Tetraamines.. Journal of Physical Chemistry A. 112, 4090 (2008).
(32) S Salehzadeh, R. Golbedaghi, I.S. Tidmarsh, N.K. Al-Rasbi, H. Adams, M.D.
Ward, H. Adams, Cd(ΙΙ) and Mn(ΙΙ) complexes of a new hexadentate Schiff base
ligand derived from an asymmetric tripodal tetraamine and 2-pyridinecarboxaldehyde.
Polyhedron. 27, 3549 (2008).
(33) H. Keypour, M. Shayesteh, A. Sharifi-Rad, S. Salehzadeh, H. Khavasi, L. Valencia,
Synthesis and characterization of copper(II) and cobalt(II) complexes with two new
potentially hexadentate Schiff base ligands. X-ray crystal structure determination of
one copper(II) complex, Journal of Organometallic Chemistry, 693, 3179 (2008).
(34) H. Keypour, R. Azadbakht, S. Salehzadeh, H. Khanmohammadi, H.R. Khavasi, H.
Adams, Synthesis, crystal structure and spectroscopic properties of some cadmium(II)
complexes with three polyamine and corresponding macroacyclic Schiff base ligands.
Journal of Organometallic Chemistry, 693, 2273 (2008).
8
(35) S. J. Sabounchei, H. Nemattalab, S. Salehzadeh, S. Khani, M. Bayat, H. R. Khavasi,
Structural, theoretical and multinuclear NMR study of mercury(II) complexes of
phosphorus ylides: Mono and binuclear complexes, Polyhedron. 27, 2051 (2008).
(36) S. J. Sabounchei, H. Nemattalab, S. Salehzadeh, M. Bayat, H. R. Khavasi, H.
Adams, New mono and binuclear mercury(II) complexes of phosphorus ylides
containing DMSO as ligand: Spectral and structural characterization, Journal of
Organometallic Chemistry, 693, 1975(2008).
(37) H. Keypour, R. Azadbakht, S. Salehzadeh, H. Khanmohammadi, H.R. Khavasi, H.
Adams, Synthesis of two new tripodal ligands and their cyclocondensation with 2-[2(2-formylphenoxy)ethoxy]benzaldehyde in the presence of manganese(II) and
cadmium(II) metal ions, Polyhedron. 27,1631 (2008).
(38) H. Keypour A.A. Dehghani-Firouzabadi M. Shayesteh S. Salehzadeh, Synthesis and
characterisation of macrocyclic copper(II) complexes containing N3O4 donor sets, J.
Chem. Research-s, 10,587 (2008).
(39) S Salehzadeh, R. Golbedaghi, I.S. Tidmarsh, L. Sorace, H. Adams, M.D. Ward, H.
Adams, Syntheses, crystal structures and magnetic properties of three new binuclear
Ni(II) complexes derived from tripodal tetradentate (N4) ligands. Polyhedron. 28,
162 (2009).
(40) H. Keypour, R. Azadbakht, S. Salehzadeh, H Amiri Rudbari, H. Adams, Synthesis,
characterization and X-ray structural determination of a stable dication derived
from
symmetrical ortho-aminophenyl diamine and 2pyridinecarboxaldehyde. Tetrahedron lett. 50, 169 (2009).
(41)
Hassan Keypour, Majid Rezaeivala, Laura Valencia, Sadegh Salehzadeh, Paulo
Pe´rez-Lourido, Hamid Reza Khavasi, Synthesis and crystal structure of some new
cadmium (II) macrocyclic Schiff-base complexes containing piperazine moiety.
Polyhedron 28 (2009) 3533–3541.
(42) S. J. Sabounchei, H. Nemattalab, S. Salehzadeh, S. Khani, M. Bayat, H. Adams, M.
D. Ward, Synthesis and characterization of binuclear mercury(II) complexes of
phosphorus ylides, X-ray analysis and multinuclear NMR measurements. Inorg.
Chim. Acta. 362, 105 (2009).
(43) V. Izadkhah, S. Salehzadeh, L. Davoodi, R.Golbedaghi, M. Bayat. La(III) Complex
of An Asymmetrical Heptadentate (N4O3) Schiff Base Ligand. Asian. J. Chem. 21,
787-794, (2009).
(44) S. Salehzadeh, R. Golbedaghi, H. R. Khavasi, Synthesis, characterization and
crystal structure of Ni(ΙΙ) complex of an acyclic pentadentate Schiff base ligand. An
agreement between the experimental and theoretical results., J. Coord. Chem. (2009)
62, 2532–2539.
9
(45) H. Keypour A.A. Dehghani-Firouzabadi M. Rezaeivala, S. Salehzadeh, Synthesis
of a new heteropolytopic cryptand through Schiff bse condensation in presence of
Ba(II) ion. Synth. Comm., (2009.) 39: 1136–1142.
(46) S Salehzadeh, M.D. Ward, H. Adams, A Novel chelate assisted C-C bond
formation on a cadmium(II) complex of an asymetric heptadentae tripodal Schiff base
ligand. Inorg. Chem. Comm. 12 (2009) 433–435.
(47) S. Salehzadeh, F. Yaghoobi, M. Bayat, Illustration of all Species and all
Microspecies Involved in Full Protonation Steps of Spermine and determination of
Corresponding Most Abundant and Most Stable Conformers, A Gas Phase
Theoretical Study, Chemical Physics, 361 (2009) 18–26.
(48) S. Salehzadeh, F. Yaghoobi, M. Bayat, Theoretical studies on proton affinities of
H2N-(CH2)n-NH2 (n=2−10) Diamines at gas phase. Good correlation with protonation
constants in solution. Journal of Molecular Structure: THEOCHEM, 906 (2009) 68–
71.
(49) S. Salehzadeh, A. Shooshtari, M. Bayat, Good correlation between the calculated
gas-phase first proton macroaffinities of some triazacycloalkanes ([X]aneN3, X = 9–
12) with their protonation constants in solution. Journal of Molecular Structure:
THEOCHEM 911 (2009) 88–91.
(50) S. Salehzadeh, A. Shooshtari, M. Bayat, Theoretical Study on First Proton
Macroaffinity of Cu(II), Zn(II) and Cd(II) Complexes of Four Triazacycloalkanes (
[X] ane N3, X = 9 – 12 ): Good Correlations with Formation Constants in Solution.
Dalton Trans. , 2009, 2865–2870.
(51)
Seyyed Javad Sabounchei, Sepideh Samiee, Sadegh Salehzadeh, Zabihollah Bolboli
Nojini,Mehdi Bayat, Elisabeth Irran, Marina Borowski, New mononuclear mercury(II)
complexes of a bifunctionalized ylide containing five-membered chelate ring: Spectral
and structural characterization. Inorg. Chim. Acta 363 (2010) 3654–3661.
(52)
Seyyed Javad Sabounchei, Sepideh Samiee, Sadegh Salehzadeh, Mehdi Bayat,
Zabihollah Bolboli Nojini, David Morales-Morales, Synthesis, characterization, and
structural studies of mercury(II) complexes of new bidentate phosphorus ylide. Inorg.
Chim. Acta 363 (2010) 1254–1261.
(53)
Seyyed Javad Sabounchei, Sepideh Samiee, Sadegh Salehzadeh, Zabihollah Bolboli
Nojini, Elisabeth Irran, Four-coordinate and pseudo five-coordinate Hg(II) complexes of
a new bidentate phosphorus ylide: X-ray crystal structure and spectral characterization.
Journal of Organometallic Chemistry 695 (2010) 1441–1450.
10
(54)
Seyyed Javad Sabounchei, Vida Jodaian, Sadegh Salehzadeh, Sepideh Samiee,
Alireza Dadrass, Mehdi Bayat, and Hamid Reza Khavasi. Synthesis of New
Phosphonium Ylides Containing Thiophene and Furan Rings and Study of Their
Reaction with Mercury(II) Halides: Spectral and Structural Characterization by Seyyed
Helvetica Chimica Acta , Vol. 93 (2010).
(55)
Sadegh Salehzadeh, Mehdi Bayat, Leila Davoodi, Reza Golbedaghi and Vida
Izadkhah SYNTHESIS AND CHARACTERIZATION OF A HEPTADENTATE (N4O3) SCHIFF
BASE LIGAND AND ASSOCIATED La(III), Sm(III) AND Gd(III) COMPLEXES, AND A
THEORETICAL STUDY. Bull.
Chem. Soc. Ethiop. 2010, 24(1), 59-66.
(56) Sadegh Salehzadeh, Reza Golbedaghi and Allan G. Blackman, Synthesis,
characterization, and X-ray crystal structure analysis of Cd(II) and Cu(II) complexes of
an acyclic pentadentate Schiff base. Journal of Coordination Chemistry Vol. 63, No. 4,
20 February 2010, 634–642.
(57) Reza Golbedaghi, Sadegh Salehzadeh, Hassan Keypour, Allan G. Blackman, Mn(II)
and Cd(II) macrocyclic Schiff base complexes with a single pendant coordinating 2pyridylmethyl arm: Synthesis, X-ray crystal structure and NMR studies. Polyhedron 29
(2010) 850–856.
(58) Sadegh Salehzadeh , Mehdi Bayat, Theoretical Studies on the Structure and
Protonation of Cu(II) Complexes of a Series of Tripodal Aliphatic Tetraamines: Good
Correlations with the Experimental Data. J Comput Chem 31: 2371–2380, 2010.
(59) Sadegh Salehzadeh, Yasin Gholi ee, Mehdi Bayat, Complete gas-phase proton
microaffinity analysis of five linear tetraamines containing two ethylenediamine residues.
Journal of Molecular Structure: THEOCHEM 952 (2010) 124–127.
(60) Mehdi Bayat, Sadegh Salehzadeh, Theoretical studies on the proton affinities of four
different series of nano-size diamines and designing strong superbases based on
fullerene(C60) molecule. Journal of Molecular Structure: THEOCHEM 957 (2010) 120–
125.
(61) Sadegh Salehzadeh, Mahsa Mahdavian and Mehdi Khalaj, Zwitterionic form of
tris({[5-(4-methoxyphenylazo)salicylidene]amino}ethyl)amine. Acta Cryst. (2011). E67,
o606.
(62) Sadegh Salehzadeh, Saeed Dehghanpour, Mehdi Khalaj and Mohammad
Rahimishakiba,
Di-μ-chlorido-bis{chlorido[4-nitro-N-(pyridin-2-ylmethylideneκN)aniline-κN]mercury(II)}. Acta Cryst. (2011). E67, m327.
11
(63) Sadegh Salehzadeh, Mehdi Khalaj, Saeed Dehghanpour, Isaac Tarmoradi,
Dibromido{2-[(4-nitrophenyl)iminomethyl] pyridine-k2N,N'}zinc(II) Acta Cryst. (2011).
E67, m1556.
(64) Mehdi Khalaj, Saeed Dehghanpour, Sadegh Salehzadeh, Dichlorido{2-[(3,4dimethylphenyl)iminomethyl]pyridine- 2N,N'}copper(II), Acta Cryst. (2011). E67,
m1624.
(65) Sadegh Salehzadeh, Mehdi Bayat, Computational evidence of preferred energy and
preferred binding energy in the formation of ‘‘1 + 1’’ versus ‘‘2 + 2’’ macrocyclic Schiff
base complexes. Computational and Theoretical Chemistry 965 (2011) 131–136.
(66) Sadegh Salehzadeh, Mehdi Bayat, A theoretical study on the formation of ‘‘1 + 1’’
versus ‘‘2 + 2’’ macrocyclic Schiff base complexes in the absence of coordinated anions,
Computational and Theoretical Chemistry 971 (2011) 30–37.
(67) Sadegh Salehzadeh, Yasin Gholiee, Mehdi Bayat, Prediction of Microscopic
Protonation Constants of Polybasic Molecules Via Computational Methods: A Complete
Microequilibrium Analysis of Spermine, International Journal of Quantum Chemistry,
Vol 111, 3608–3615 (2011).
(68) M.A. Zolfigol, E. Kolvari, N. Koukabi, S. Salehzadeh, G. Chehardoli, I.S. Tidmarsh
and K. Niknam, A New Crystal Engineering Approach for the Synthesis of {[K.18Crown-6]I3}n as a Nanotube-Like and Recyclable Catalyst for the Chemoselective
Silylation of Alcohols. J. Iran. Chem. Soc., Vol. 8, No. 2, 2011, 484-494.
(69) Seyyed
Javad Sabounchei, Sadegh Salehzadeh, Marjan Hosseinzadeh, Fateme Akhlaghi
Bagherjeri, Hamid Reza Khavasi Structural, theoretical and multinuclear NMR study of
mercury(II) complexes with a new ambidentate phosphorus ylide Polyhedron 30 (2011)
2486–2492.
(70) Mehdi Bayat, Fereshteh Yaghoobi, Sadegh Salehzadeh, Samaneh Hokmi, A
Theoretical study on the interaction of [Al(H2O)6]3+ and [Mg(H2O)6]2+ cations with
fullerene (C60), coronene and benzene π-systems Polyhedron 30 (2011) 2809–2814.
(71) Mehdi Bayat, Moritz von Hopffgarten, Sadegh Salehzadeh, Gernot Frenking, Energy
decomposition analysis of the metal-oxime bond in [M{RC(NOH)C(NO)R}2] (M =
Ni(II), Pd(II), Pt(II), R = CH3, H, F, Cl, Br, Ph, CF3) Journal of Organometallic
Chemistry 696 (2011) 2976-2984.
(72) Mahdi Rezaei Sameti, Mehdi Bayat, Sadegh Salehzadeh, The DFT study of
hydrogen bonding and thermodynamic parameters of (CH3OH)n(H2O)m (n, m = 1–8)
clusters at different temperatures. Arabian Journal of Chemistry, Available online 9
February 2011. http://dx.doi.org/10.1016/j.arabjc.2011.02.003
(73) Mehdi Bayat, Sadegh Salehzadeh, Gernot Frenking, Energy decomposition analysis
of the metal-imine bond in [(CO)4M-SB](M = Cr, Mo, W; SB: RHC=N-CH2CH2N=CHR) Journal of Organometallic Chemistry 697 (2012) 74-79.
12
(74) Sadegh Salehzadeh, Mehdi Khalaj, Mahsa Mahdavian, Aqua[tris(2-{5-[(4methylphenyl)diazenyl]-2-oxidobenzylideneamino}ethyl)amine]samarium(III)
acetonitrile monosolvate, Acta Cryst. (2012). E68, m96.
(75) Reza Golbedaghi, Samira Jafari, Mohammad Reza Yaftian, Reza Azadbakht,
Sadegh Salehzadeh, Babak Jaleh, Determination of cadmium(II) ion by atomic
absorption spectrometry after cloud point extraction. J IRAN CHEM SOC (2012) 9:251–
256
(76) Sadegh Salehzadeh, Mehdi Khalaj, Saeed Dehghanpour, Diiodido{2-[(4methoxyphenyl)iminomethyl]pyridine-κ2N,N_}zinc. Acta Cryst. (2012). E68, m1041.
(77)
Seyyed Javad Sabounche, Mehdi Sarlakifa, Sadegh Salehzadeh, Mehdi Bayat,
Mahbubeh Pourshahbaz, Hamid Reza Khavasi, Structural, theoretical and multinuclear
NMR study of mercury(II) and silver(I)complexes with two new ambidentate phosphorus
ylides. Polyhedron 38 (2012) 131–136.
(78) Sadegh Salehzadeh, Hassan Keypour, Seik Weng Ng, Laura Valencia
Synthesis, characterization and theoretical study of a new asymmetrical tripodal amine
containing morpholine moiety, Arabian Journal of Chemistry, Available online 7 May
2012 http://dx.doi.org/10.1016/j.arabjc.2012.04.024.
(79)
Seyyed Javad Sabounchei, Mehdi Sarlakifar, Mahbubeh Pourshahbaz,
Sadegh Salehzadeh, Mehdi Bayat, Hamid Reza Khavasi, Fatemeh Akhlaghi Bagherjeri,
Collete Boscovic, Structural, Theoretical and Multinuclear NMR Study of a New
Polymeric Mercury(II) Complex with an Ambidentate Phosphorus Ylide. J Inorg
Organomet Polym (2013) 23:401–408.
(80) S. Salehzadeh, M. Khalaj, S. Dehghanpour, A. Mahmoudi. Reaction of ZnCl2 and
HgCl2 metal salts with a bidentate Schiff base ligand in methanol solution, X-ray crystal
structure, and theoretical studies. J IRAN CHEM SOC (2013) DOI 10.1007/s13738-0130229-1.
(81) Seyyed Javad Sabounchei, Mohsen Ahmadi, Zahra Nasri, Esmaeil Shams,
Sadegh Salehzadeh, Yasin Gholiee, Roya Karamian, Mostafa Asadbegy, Sepideh
Samiee. Synthesis, characterization, thermal, electrochemical, and DFT studies of
mononuclear cyclopalladated complexes containing bidentate phosphine ligands and their
biological evaluation as antioxidant and antibacterial agents. Comptes Rendus
Chimie, (2013) 16, 159-175.
(82) Seyyed Javad Sabounchei, Parisa Shahriary, Sadegh Salehzadeh, Yasin Gholiee,
Hamid Reza Khavasi Mercury(II) complexes with 5-methyl-5-(4-pyridyl)-2,4imidazolidenedione: Synthesis, structural characterization, and theoretical studies
Journal of Molecular Structure (2013) 1051, 15-22.
(83) Majid Rezaeivala, Hassan Keypour, Sadegh Salehzadeh, Reza Latifi, Firoozeh
Chalabian, Fatemeh Katouzian, Synthesis, characterization and crystal structure of some
new Mn(II) and Zn(II) macroacyclic Schiff base complexes derived from two new
13
asymmetrical (N5) branched amines and pyridine-2-carbaldehyde or O-vaniline and their
antibacterial properties. J IRAN CHEM SOC DOI 10.1007/s13738-013-0315-4
(84) S. Salehzadeh, M. Khalaj, S. Dehghanpour, M. Bayat Synthesis and structure of
[Hg2(L)2(NO3)2] (L 5 (4-nitrophenyl)pyridin-2-ylmethyleneamine); a theoretical study
on Hg–Hg bond in this and in linear Hg2X2 (X 5 F, Cl, Br, I, Ph) complexes. J IRAN
CHEM SOC (2013) DOI 10.1007/s13738-013-0268-7.
(85) S. Salehzadeh, M. Bayat, Y. Gholiee, Tetrahedron, A theoretical study on the
importance of steric effects, electronic properties, interaction and solvation energies in
the ʻhost–guestʼ chemistry of protonated azacryptands and halide anions. Tetrahedron
(2013) Accepted.
Persian Publications:
.24 ‫ مشاره‬7831 ‫ رهيافت‬.‫ مهدي بيات خط فقر در علم کجا و چگونه‬،‫) صادق صاحل زاده‬1
‫ مشاره‬7833 ‫ رهيافت‬.)4223-7993( ‫ مهدي بيات جهش علمی ایران در طی یک دهه‬،‫) صادق صاحل زاده‬2
.22
========================================================
‫دکتر صادق صالح زاده‬
:‫■ تاریخ تولد‬
‫ در شهر همدان‬1155/11/5
:‫■ وضعیت تاهل‬
‫ دارای یک دختر و یک پسر‬،‫متاهل‬
:‫■ روند تحصیل‬
‫دیپلم علوم تجربی از دبیرستان دکتر علی شریعتی‬
1135 ،‫همدان‬
1131 ،‫کارشناسی دبیری شیمی از دانشگاه بوعلی سینا‬
،‫کارشناسی ارشد شیمی معدنی از دانشگاه بوعلی سینا‬
1135
1131 ،‫دکترای شیمی معدنی از دانشگاه بوعلی سینا‬
)1131 ‫(دانشجوی نمونه دانشگاه بوعلی سینا در سال‬
‫شروع به کار در دانشگاه‬
14
■
‫استادیار شیمی معدنی دانشگاه بوعلي سینا‬
‫ازآذر ماه ‪1131‬‬
‫دانشیار شیمي معدني از تیر ماه ‪1135‬‬
‫استاد شیمی معدنی و محاسباتی ازتیر ماه‬
‫‪1131‬‬
‫■ مقاالت علمی‪:‬‬
‫* در حال حاضر ‪ 85‬مقاله علمی اینجانب در ژورنال های‬
‫معتبر بین اللمللی)‪ (ISI‬به چاپ رسیده است‪.‬‬
‫*دو مقاله در مجالت داخلی در زمینه علم سنجی(مجله‬
‫رهیافت)‪.‬‬
‫* بيش از ‪ 121‬مقاله در سمينارهاي داخلي به صورت پوستر يا سخنراني‪.‬‬
‫■ طرح های تحقیقاتی‪:‬‬
‫تا کنون هفت طرح تحقیقاتی به انجام رسیده‬
‫■ هدایت دانشجویان تحصیالت تکمیلی‪:‬‬
‫*استاد راهنماي ‪ 13‬دانش آموخته‬
‫کارشناسي ارشد‬
‫* استاد راهنماي ‪ 2‬دانش آموخته دکتری‬
‫* در حال حاضر استاد راهنماي ‪ 5‬دانشجوي کارشناسي ارشد‬
‫و ‪ 5‬دانشجوي دکتري‪.‬‬
‫■ مسئولیت های اجرایی‪:‬‬
‫* مدیر گروه شیمی معدنی از سال ‪ 1133‬تا کنون‬
‫* معاون ادرای و مالی دانشکده شیمی از سال ‪ 1133‬تا‬
‫کنون‬
‫‪15‬‬