3/4/2009 S20 Unit A: Chemistry Organic ChemAssignment Name: ____________ Date: ____________ 1. Complete the following table. (0.5 marks for each space) IUPAC name molecular formula condensed structural formula propane CH3CH2CH3 1-butene CH2CHCH2CH3 2,4-dimethylpentane C7H16 CH3CCCH2CH2CH3 LD Industries line diagram 3/4/2009 2. Define the following terms: (0.5 marks each) a) Aliphatic hydrocarbon: b) Alkyne: c) Alkane: d) Alkene: 3. Explain the difference between a saturated and unsaturated hydrocarbon. Draw an example of a structural diagram of each type of hydrocarbon. (4 marks) Saturated: structure Unsaturated: structure 4. An unknown straight-chain hydrocarbon contains 27 carbon atoms. Determine how many hydrogen atoms would be present if the hydrocarbon is a: (3 marks) a) alkane b) alkene c) alkyne LD Industries Hint: Remember Alkane - CnHn+2 Alkene - CnHn Alkyne - CnHn-2 3/4/2009 5. The following compounds are named incorrectly. Draw a complete structural diagram of the compound, then name it correctly. (2 marks each) a) 2-ethyl-pentane Correct name: _______________________ b) 4-butyl-2-methyl-hexane Correct name: _______________________ c) 3-ethyl-2-propyl-5-hexyne Correct name: _______________________ 6. In the combustion of octane in a car engine, 6.5 moles of octane are used up. a) Determine the balanced chemical formula for the combustion of octane. (1 mark) b) Determine the number of moles of carbon dioxide produced in this reaction. (1 mark) LD Industries 3/4/2009 7. In order to produce plastics, the organic molecule ethene is needed. This compound is created by refining crude petroleum from a fractional distillation tower in a cracking container. In this container, long chain hydrocarbons such as octane are cracked to form ethene and other compounds according to the balanced chemical formula below: C8H18(l) 2 C2H4(g) + _________ octane ethene + unknown hydrocarbon + CH4(g) + methane Determine the identity of the unknown hydrocarbon. Give both it’s IUPAC name and condensed structural formula. (2 marks) Name: ___________________________ structure 8. Draw a diagram of a fractional distillation column. Include in your diagram labels showing the size of each hydrocarbon produced and the common use for each hydrocarbon. (Hint: use your worksheet from the computer lab or your textbook). (4 marks) LD Industries 3/4/2009 9. Write the balanced chemical equation for the following reactions: (2 marks each) a) The combustion of 5,5-diethyl-2,2-dimethyl-octane b) The hydrogenation of 2-butene c) The hydrogenation of 2-methyl-3-hexyne d) The cracking of hexane into two three-carbon molecules 10. Starting with propene (shown below), show the polymerization of polypropene. (2 marks) Bonus Questions: Answer only ONE!!! Fair Bonus Question: Name the organic molecule shown in the title of this assignment. Unfair Bonus Question: Science fiction tells us that some space-creatures may not be carbon-based life-forms, like we are. What element are these alien’s based on? LD Industries