Pav 2013 Chapter 7: Ionic Bonding Section 7.1 Ions (pg.187-193) 1. Determine the number of valence electrons of the representative elements using a periodic table 2. Describe the formation of a cation as it relates to the Octet Rule. 3. Describe the formation of an anion as it relates to the Octet Rule. Section 7.2 Ionic Bonds and Ionic Compounds (pg. 194-199) 1. Describe the formation of ionic bonds through electron transfer 2. Interpret the chemical formula of a formula unit. 3. Describe the structure and properties of ionic compounds. Section 7.3 Bonding in Metals (pg. 201-203) 1. 2. 3. 4. Describe the nature of a metallic bond. Describe the crystalline structure of metals Explain the utility of alloys Describe the two main types of alloys Chapter 9: Chemical Names and Formulas Section 9.1 Naming Ions (pg. 253-258) 1. Name the representative element ions and determine their charges from the periodic table. 2. Determine the name of transition metal ions from the number of electrons lost. 3. Recognize and name several polyatomic anions. . Section 9.2 Naming and Writing Formulas for Ionic Compounds (pg. 260-266) 1. Name binary ionic compounds and those containing polyatomic anions given a chemical formula. 2. Write the chemical formula of binary ionic compounds and those containing polyatomic anions given its name. Section 9.3 Naming and Writing Formulas for Molecular Compounds (pg. 268-270) 1. Name binary molecular compounds given chemical formulas 2. Write the chemical formulas for molecular compounds given their names Section 9.4 Naming and Writing Formulas for Acids and Bases (pg. 271-273) 1. Name binary and oxyacids given chemical formulas 2. Write the chemical formulas for binary and oxyacids given their names Section 9.5 The Laws Governing Formulas and Names (pg. 274-279) 1. Explain the Law of Definite Proportions as it relates to formula units 2. Explain the Law of Multiple Proportions as it relates to molecules Written Work Chapter 7: p. 207-210 # 41, 43, 44, 45, 47, 48, 57, 73, 91, 93, 102 p. 211 # 2, 4, 11,12,13 Chapter 9: pg. 281- 284 # 47, 49, 51, 53, 57, 60, 62, 63, 64, 65, 69, 71, 72, 73, 74, 83, 103 Pg. 285 # 12, 14,15 Pav 2013 Chapter 7/9 Supplemental Questions 1. Create a data table to record the physical and chemical properties of sodium chloride and the elements that it is composed of, sodium and chlorine. Use may use any resource that is available (except Mrs. Pav ) a. Write a general statement that compares the compound with the elements it is comprised of. 2. Hard water is water that contains a large quantity of dissolved minerals such as calcium and magnesium which can precipitate out of solution, form scaling in pipes, and ultimately ruin plumbing systems. Many water softeners work by running water through a system that contains a solid substrate (beads) that is coated with sodium ions. The dissolved minerals having a stronger positive charge than sodium and therefore have a greater affinity for the substrate than sodium and will replace sodium on the substrate. a. The hardness of water is defined by the unit GPG (grains per gallon). 1 grain is defined as 64.8mg of calcium carbonate per gallon. The ranges used to classify water as soft or hard are in units of mg/L. Convert 1grain to mg/L using the following conversion factors. 1 grain = 64.8 mg/gal 1 gal = 4 qt 1.06 qt = 1L b. The process of water softening adds about 12.5 mg of salt to 8 fluid ounces of drinking water. If the daily maximum intake of sodium is 2300mg, how many milliliters of processed water could one drink a day and not exceed the maximum sodium intake. (8 ounces = 237 ml) Pav 2013 Writing Ionic Equations Using Lithium Bromide (LiBr) as an example, write the ionic equations for the following formula units. Keep in mind that not every combination of cation and anion is 1:1, so you may need multiples of one or each atom to create a neutral compound. MgF2 K 3P Mg3N2 BaS SnO2 Pav 2013 Molecular Compounds When naming binary molecular compounds, always name the more __________________________ atom first. Naming Rules 1. If there is more than one of the 1st atom, precede the atom name by the appropriate prefix (di, tri, tetra, penta, hexa, hepta, octa, nona, deca) Example: C6O2 2. hexacarbon dioxide If there is only one of the first atom, do not precede the atom name by mono. CO2 = monocarbon dioxide 3. CO2 = carbon dioxide Precede the second atom name by the appropriate prefix, including mono if there is only one of that atom. Drop the last syllable (or 2) and add –ide to the element name C2O Dicarbon monoxide Element C N O F P Name Carbide Nitride Oxide Fluoride Phosphide Element S Cl Se Br I Name Sulfide Chloride Selenide Bromide Iodide Provide the name of the following molecular compounds Compound Compound Name P 6O 3 Hexaphosphorus trioxide NS4 Se8O C7Br5 S2F2 Provide the Chemical Formulas given the following names Compound Name Dinitrogen monofluoride Nonaphosphorus decachloride Sulfur hexabromide Tetracarbon pentasulfide Octanitrogen trifluoride Compound Pav 2013 Ionic Compounds Ionic compounds form from the combination of _____________________ and ______________________. Atoms that lose electrons are called ____________________ and have a ___________________ charge. Atoms that gain electrons are called ___________________ and have a ___________________ charge. Naming ionic compounds with metals that only form one ion 1. State the name of the first atom 2. Drop the last syllable (or 2) from the second atom name and add –ide Element C N O F P Name Carbide Nitride Oxide Fluoride Phosphide Element S Cl Se Br I Name Sulfide Chloride Selenide Bromide Iodide Name the following ionic compounds Compound CaBr2 Compound Name Calcium Bromide Na2O Ag2S K3P Al2N3 Given the compound name, identify the ions involved and provide the chemical formula Compound Name Cation Anion Compound Beryllium Chloride Be2+ Cl- BeCl2 Sodium Sulfide Lithium Phosphide Magnesium Nitride Calcium Oxide Pav 2013 Naming Ionic Compounds Using the Stock System (for atoms that have more than one possible charge) Element Copper (Cu) Chromium (Cr) Iron (Fe) Lead (Pb) Tin (Sn) 1+ X 2+ X X X X X 3+ 4+ X X X X Follow the 1st atom name by the Roman numeral that represents its charge in parenthesis Example Copper (I) Chloride = CuCl or Copper (II) Chloride = CuCl2 Name the following ionic compounds using the stock system Compound Cation Anion Name FeCl2 Fe2+ Cl- Iron (II) Chloride PbF4 Sn3P2 CoO CrP Provide the chemical formula give the names of the following ionic compounds Name Cation Anion Copper (II) Nitride Cu2+ N3- Tin (IV) Oxide Lead (II) Iodide Chromium (III) Phosphide Iron (III) Bromide Compound Cu3N2 Pav 2013 Ionic compounds that contain polyatomic cations or anions There is only one polyatomic cation, NH4+ (ammonium ion) When naming polyatomic anions, the charge for each member of a pair is the same. The ions differ by the number of atoms each member contains. Example: SO32- and SO42The name of the member of the pair with the fewer number of atoms ends in –ite, the other ends in –ate. SO32- (sulfite) and SO42- (Sulfate) When forming compounds with polyatomic ions, place parenthesis around the entire ion before attempting to add subscripts (balance the charges) Provide the names of the following compounds which contain polyatomic ions Compound Cation Anion Name Ba(NO3)2 Ba2+ NO3- Barium Nitrate MgSO3 (NH4)3P NaCN Pb(HPO4)2 Form the compound containing polyatomic ions given the names Name Magnesium Phosphate Ammonium Sulfite Calcium Oxalate Lithium Bicarbonate Aluminum Permanganate Cation Anion Compound Mg2+ PO43- Mg3(PO4)2 Pav 2013 Acids An acid is a substance that produces H+ ions in solution. There are two common types of acids – Binary (hydrogen plus a monatomic anion or a polyatomic anion that does not contain oxygen, ex. HCl or HCN) and oxyacids (hydrogen plus a polyatomic anion containing oxygen, ex. HNO 3) Naming Binary Acids 1. Hydro- is the prefix of all binary acids 2. Change the ending of the nonmetal to –ic. Naming Oxyacids 1. There is no prefix for oxyacids 2. –ate anions are –ic acids (ex. H2SO4 = sulfuric acid) 3. –ite anions are –ous acids (ex. H2SO3 = sulfurous acid) Name Phosphoric Acid Cation Anion Compound H+ PO43- H3PO4 H+ Hydroiodic Acid HBr H+ H+ H2SO3