Density and Avogadro’s Law V α n Name: Kellie Gentile Class/Subject: Chemistry/Gas Laws Date: November 11, 2013 Content Standards/Performance expectations Overall NGSS: “develop and use models to illustrate that energy at the macroscopic scale can be accounted for as a combination of energy associated with the motions of particles (objects) and energy associated with the relative positions of particles (objects)”. Cause and Effect: In a system of constant temperature and pressure, what is the relationship between volume and molecules of gas? Volume is directly proportional to molecules of gas. Student Objectives: A) Students will derive the relationship between volume and molecules of gas under fixed pressure and temperature. The relationship students deduce is volume directly proportional to mols of gas. B) Students recognize parallels between Avogadro’s Law and density. Avogadro’s Law is a chemistry perspective of density. Assessment Criteria A & B) To assist student’s derivation of the Avogadro’s Gas Law I have created a scaffold worksheet. The questions also connect the similarities between density and Avogadro’s Law as well. The worksheet contains three distinct sections to lead to the derivation of Avogadro’s Law v α n. The first section relates to the introductory demo “Bubbling Lava Lamp”. Students have to explain how the “Bubbling Lava Lamp” or lava lamps in general work. The lamp can function because of varying material densities. Section II builds off section one by asking for examples of density units. Students will create a web model to express possible density units. Now to transition from density to an actual gas law the third section states a real world scenario. The same variable chart from lesson one appears after. Students have to decipher the varying gas law variables and provide evidence to support their claim. The students will write out a predicted gas law for the real world example. Students should begin to recognize density variables comprise Avogadro’s Law. A PowerPoint slide and group discussion will highlight the newly found relationship between mols and volume and how it’s a new perspective on density. Where in the lesson is this addressed? The initial hook for deriving Avogadro’s Law begins with the introductory “Bubbling Lava Lamp” demo. The informal assignment will be the completion of the scaffold worksheet. The worksheet includes a web model for density and a section bridging the parallel relationship between density and Avogadro’s Law. A final group discussion will finalize the correct interpretations and a PowerPoint slide will illustrate a mathematical perspective of Avogadro’s law. Prior Knowledge: Make observations and measurements to identify materials based on their 5-PS1-3. properties. Students should associate density with g/mL or mass/volume. Although not specifically an identifiable property, the concept is discussed at the fifth grade level. Materials/Resources/Technology: Bubbling lava lamp- glass jar, cap, vegetable oil, food coloring, Alka-Seltzer tablets, flashlight, water (Demonstration of Gas Laws PDF) Density/ Avogadro’s Law (note) worksheet Time 50-minute class period. * Before students arrive prep class demonstration ‘Bubbling Lava Lamp’. 5-10 min 5 minutes Start of Class: In replacement of a bellringer we will discuss previous night’s homework. The homework involved students to research real world examples incorporating the Gay Lussac’s Gas Law. Initially ask for volunteers. If no one is volunteering randomly ask an array of students to answer the bellringer. Students need to state their example and explain how the law applies to the situation. Introduction of Lesson: -Before Students arrive, set-up the Bubbling Lava Lamp and turn off lights. Here is a short version procedure. The formal instruction can be found at the website http://www.stevespanglerscience.com/lab/experiments/bubbling-lavalamp 1) Fill the glass jar ¾ full with vegetable oil 2) Fill the rest of the glass jar with water 3) Add about 10 drops of food coloring. Coloring should be fairly dark. Notice the coloring only affects the water 4) Divide Alka-Seltzer into 8 pieces Once students have completed the bell ringer collect their examples written on paper. Then alert the students to focus on the hand-made Lava Lamp. Turn the lights off and place the gas jar on a flashlight. Briefly explain the contents and highlight the fact that only the water is colored. After drop one at a time the eight Alka-Seltzer pieces. Add another one once the bubbling stops. Once the pieces are all dissolved cap the jar and tip the bottle back and forth for the students to see. Tiny drops of liquid join together to make big lava like blob. Pass the jar around the class for the students to examine more. Also, turn on the lights. Announce the introductory question how Does the lava lamp works? The students are to work in lab group pairs. In other words each lab group of 4 will split into 2 individual pairs. Pass out the worksheet and the each pair must fill out their own personal copy. 20-25 Minutes Lesson Instruction: Part I In pairs of two, students address the question how does it work? What is the main identifiable property of matter that allows it to float or sink? As students complete part one, I will conduct an informal assessment. I will travel from group to group reviewing their answers for part one. If they oversaw the identifiable property (density) I may pose the question why the glob of water was able to flow through the oil when tipping the glass back and forth? Also, have the glass jar handy for students to visually see the model. Mark part one with initials to keep tally of which pairs have been checked. Part II Students realize density is a major contributor to the function of the lava lamp. Now students need to start to connect mass to mols and volume to liters. The students will brainstorm various units of density (Web model) 5-10 examples. Walk around and ask groups what were some of their examples. Foster the idea of creating a density unit relatable to chemistry. Ask them to think about mass units and volume units applicable to our subject area. Part III Last students will investigate the relationship between mols of gas and volume. The worksheet presents the following life example; Lungs expand as they fill with air then the longs contract as air is released. Again the gas law variable chart is presented. Students need to identify which gas related variables varied and stayed constant. If students are stuck have them write out before and after states of variables (volume and mols of air should be changing). Once students have identified the manipulative variables, they will propose a predicted gas law for mols of gas and volume. Assessments/Checks for Understanding: As stated in the lesson instruction part one an initial check will be conducted pertaining to the bubbling lava lamp question “how does it work”? Each group should recognize an object’s density determines if it will float or sink. The formal assessment will be worksheet scaffolding the relationship between density and Avogadro’s Law. It will be collected and graded. Another informal assessment will be a class discussion about the worksheet. Reviewing appropriate answers for each of the three sections. A PowerPoint slide will clearly state Avogadro’s Law and illustrate it in a mathematical viewpoint utilizing proportions. Lesson Plan two assessment is alternative because the Avogadro’s Lab presented incorporates the inquiry based 5E model. The lab encourages student communication. Since this lab involves lab partners instead of groups it restricts the appearance of some students working and others messing around. Although there is only one demonstration to explore students now have other aids such as a web model, and a real world scenario. The real world scenario allows students to synthesize similarly to the engineering profession. Again, I will elaborate on the worksheet to clear any misconceptions after each group has finished. The evaluation of the lab is the associated worksheet. 15 minutes Closure/Wrap-Up/Review: Recollect students and review the main idea that density is similar to mols per volume and the number of mols is directly proportional to the volume. A PowerPoint slide will clearly state Avogadro’s Law and illustrate it in a mathematical viewpoint utilizing proportions (V1/n1)=(V2/n2). This is known as Avogadro’s Law Self-Assessment (optional): Rationale for the activity, activity structure, planning etc needs to go here To begin, the students had to research a real world example incorporating the Gay Lussac’s gas law. Therefore, in place of a bell ringer, I will ask students to share their examples. I want student to highlight the changes in pressure and temperature. Again the rationale for this procedure is to see if students can relate these mathematical statements to functioning systems. From and engineering perspective students should recognize how gas laws can relate to a given system. After a few students answer aloud, I will collect their written examples. Moving on, I will introduce Avogadro’s Law informally with a demo titled Bubbling Lava Lamp. Many students have seen a lava lamp before, but few have questioned its workings. In pairs, I want the students to focus on ‘how does it work’? The materials used in the lava lamp include oil, water, and Alka-Seltzer tablets. From these materials, I expect students rationalize density as a plausible explanation. The exhibited water, oil, and the color blobs will float or sink as a result of differing densities. Students will record their thoughts on an accompany worksheet and I will float between groups informally checking their rationales. This activity engages student-student relationships and allows the pairs to question each other’s function explanations. I’m their floating as a guide to redirect pairs if their tangents are not applicable to the given situation. I would scaffold struggling groups to alternative explanations allowing students room to explore why and conclude supporting evidence. I may pose a similar scenario like the lava lamp that students encounter everyday such as, why does ice float in water? It’s essentially the same but what makes ice different then water allowing it to float? Once concluding density, each pair will start to brainstorm various units of (mass/volume) using a web model. Students need to see that density can be defined in other units besides g/mL. Students are encouraged to think about the different mass units incorporated in their chemistry classroom as well. Pairs will be required to write 7-8 units describing density. Then students will read a life example referencing human lungs. The students will have to fill out a similar chart used on the Gay Lussac’s Law worksheet. In this case, the volume and mols of air are changing, but pressure and temperature is held constant. Students will take note of the before and after states of p, v, n, and t. When the groups finish, I will discuss the worksheet, focusing on the Lung example. The lung example illustrated how volume of gas is proportional to mols of gas, which is Avogadro’s Law. In additional, Avogadro’s Law can relate to density because it incorporates mass/volume. Avogadro’s Law is another perspective on the concept of density. The notes are simply and elaboration on their group work. To conclude, the students homework will be to review the Boyle’s, Charles, Gay Lussac’s and Avogadro’s Law because tomorrow we will be working with all four to derive the Ideal Gas Law. Name Date . I. Bubbling Lava Lamp HOW DOES IT WORK? II. Density Web Model Brainstorm different units of density (mass/volume). Specifically think about mass units pertaining to this classroom III. Real Life Example Lungs expand as they fill with air, then the lungs contract as air is released. Variables Held Constant vs. Variables Manipulated Pressure Volume Temperature Mols of Gas Constant Varied Explain: RELATED GAS LAW Discussion) . ( Class