/54 Name _________________ Organic Chemistry Unit Test! Making Connections (11 marks) 1. We did two labs involving esters. In the first, we made a series of esters. In the second, we made two polyesters. Describe at least 3 ‘real world’ uses that you could imagine for the products of either of these labs based on your observations and data table. (3 marks) 2. In designing a product, such as a diaper, why is knowledge of organic chemistry essential? In your answer, try to use 2 specific examples or concepts from the course. (4 marks) 3. Explain why your knowledge of organic chemistry can help you to understand the dangers of the real world. Choose either CFCs or trans fats (or both) to use as a specific example. (4 marks) /54 Name _________________ Thinking (18 marks) 1. The following data was collected by a student performing a super-fun lab on alcohols. Unfortunately, this student was careless! He forgot to fill in all the boxes. Name 1-propanol 1-pentanol 1-octanol Boiling point 75OC Solubility in Water Solubility in Hexane Reaction with Litmus Do not fill here a. Use your chemistry know-how to make predictions for each unfilled box. (5 marks) b. Explain your prediction for the solubility columns with reference to key terms and concepts. (4) 2. Write structural formulas to represent the synthesis of the compounds below. Show the structures and names of each reactant and product, show any reaction conditions necessary. a. Chloro-ethane from ethane. (3 marks) b. Ethyl butanoate from ethane and 1-butanol. (6 marks) /54 Name _________________ Knowledge (25 marks) ____ 1. The molecule above is which of the following? a. a saturated fatty acid d. palmitin b. a triglyceride e. a natural oil found in grain c. an unsaturated fatty acid ____ 2. What is the monomer for the polymer Kel-F shown below? a. c. b. d. ____ 3. The primary product of the reaction below which uses excess HBr is which of the following? a. c. b. d. ____ 4. Which compound is most likely to be a gas at room temperature? a. propane c. propanal b. 2-chloropropane d. propanone ____ 5. Which of the following compounds is a secondary alcohol? a. 1-pentanol c. 2-pentanone b. 2-pentanol d. 2-methyl-2-butanol /54 Name _________________ ____ 6. Which of the following compounds is an isomer of the other three identical molecules? a. c. b. d. ____ 7.Ethanoic acid can be prepared from ethene by a. reduction with H2, followed by reaction with a strong oxidizer b. addition of HCl, followed by reaction with H2O c. addition of H2O followed by reaction with a strong oxidizer d. addition of Br2, followed by reduction with H2 8. State ‘Markovnikov’s Rule’ and draw a reaction of an alkene to illustrate it. (3 marks) 9. You can draw a lot of organic molecules that have 4 carbons! a. Draw 5 organic compounds that have only 4 carbons. You need to draw 5 different functional groups, and you can’t use alkanes or alkenes or alkynes! (10 marks) b. Name each of your structures with a proper IUPAC name (5 marks) (write under picture) Extra: You are done! Check your work. Then draw and name 2 amides and 2 amines.