Z
Zibo Honors Chemical Co., Ltd
Add: Wutai Industrial Zone, Linzi Dist.Zibo, Shandong,China
Tel: +86-533-7167159
Fax: +86-533-7167159
P.C:255420
Http://www.honors.com.cn
E-mail: honors@honors.com.cn
MATERIAL SAFETY DATA SHEET OF MAC
Section 1 、MANUFACTURE AND PRODUCTS
a) Product
Chemical name: Methallyl Chloride
Synonyms:3-Chloro-2-methylpropene
2-Methylallyl Chloride
b) Manufacturer
Name: Zibo Honors Chemical Co., Ltd
Address: Wutai, Linzi district, Zibo, Shandong, China
Tel: +86-533-7167159
Fax: +86-533-7167159
+86-533-7661437
Contact in emergency: Sales dept. of Zibo Honors Chemical Co., Ltd.
Tel: +86-533-7167159
Fax: +86-533-7167159
Section 2、PRODUCT INFOMATION
Product Name------Methallyl Chloride
Purity----------99.5% min
Chemical Formula -----C4H7CL
Structural Formula -----Molecular Weight-------90.55
CAS NO------563-47-3
Melting Point-----
-80℃
Boiling Point-----72.17℃
Flash Point----
-12℃
UN Hazard Class-----3.2
UN NO.----2554
Section 3、 DANGEROUS GOODS CAUTION
MAC is flammable (class one) and poisonous.
It is fugitive; it is also at risk of burning and explosion to meet fire.
It can burn or explode when reacting with strong oxidant. When burning, it can produce large
quantity of poisonous gas, which will do great harm to environment and creature.
It is harmful to human body and irritant to eyes, nose, throat, especially to lung and kidney.
MOUSE 'S LD50 IS 395MG/KG.
It is irritant to eye and skin; it can be absorbed by skin.
Workers must wear protection clothes to avoid accident.
Section 4、FIRST AID MEASURES
EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, obtain medical
attention.
SKIN: Immediately flush with plenty of water while removing contaminated clothing and/or
shoes, and thoroughly wash with soap and water. See a medical doctor immediately.
INGESTION: Drink 1 or 2 glasses of water and induce vomiting by touching the back of the
throat with a finger or by giving syrup of ipecac. Never induce vomiting or give anything by
mouth to an unconscious person. See a medical doctor.
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists,
obtain medical attention.
NOTES TO MEDICAL DOCTOR: This product has moderate oral toxicity, and low dermal
and inhalation toxicity. It is extremely irritating to the skin and minimally irritating to the eyes.
Inhalation of this product may cause respiratory and mucous membrane irritation.
Section 5、FIRE FIGHTING MEASURES
FLASH POINT AND METHOD: -16°C
FLAMMABLE LIMITS: 3.2% to 8.1%
EXTINGUISH MEDIA: Foam, CO2 or dry chemical. Contain all runoff.
EXPLOSION HAZARDS: Extremely flammable. Severe fire hazard when exposed to heat,
flame or oxidizing material. Vapor may travel to an ignition source and flash back. Explosion
hazard moderate when exposed to heat or flames. Confined vapors may present severe
explosion
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
gear and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
HAZARDOUS DECOMPOSITION PRODUCTS: Vapors of chlorides and allylics.
TO USE POWDER, FOAM, 1211,CARBON DEOXIDE FIRE EXTINGUISHER AND
SAND.
WATER NOT ALLOWED
Section 6、ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal
protective equipment as prescribed in Section 8, "Exposure Controls/Personal Protection".
Keep unprotected persons and animals out of the area. Remove potential ignition sources.
Isolate and post spill area.
Wear protective clothing and respiratory protection as prescribed in Section 8, "Exposure
Controls/Personal Protection". Keep unprotected persons and animals out of the area.
To clean and neutralize spill area, tools and equipment, wash with a solution of soap and water
and add the solution to the drums of waste already collected. Dispose of drummed waste
according to the method outlined in Section 13, "Disposal Considerations".
Section 7、HANDLING AND STORAGE
GENERAL PROCEDURES: Store in a cool, dry well-ventilated place. Do not use or store near
heat, open flame or hot surfaces. Store in original containers only. Do not contaminate other
materials, or allow this material to be contaminated, by improper storage or handling.
Section 8、EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or mist
may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles or a
face shield with safety glasses.
RESPIRATORY: For splash, spray or mist exposure wear, as a minimum, a properly fitted
half-face or full-face air-purifying respirator with organic vapor cartridges (approved by U.S.
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and
selection must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear laminate
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of
spills, wear self contained breathing apparatus and fire protective clothing (turnout gear)
because of the flammability hazard. Leather items - such as shoes, belts and watchbands - that
become contaminated should be removed and decontaminated. Washing all work clothing
before reuse (separately from household laundry).
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of eye
or skin contamination. Wash skin prior to eating, drinking or using tobacco. Shower at the end
of the workday.
GLOVES: Wear chemical protective gloves made of materials such as neoprene or other
impervious material. Thoroughly wash the outside of gloves with soap and water prior to
removal. Inspect regularly for leaks.
Section 9. PHYSICAL AND CHEMICAL PROPERTIES
ODOR: Sweet
APPEARANCE: Colorless liquid
VAPOR PRESSURE: 102 mmHg @ 20°C
BOILING POINT: 72°C (162°F) @ 760 mmHg
SOLUBILITY IN WATER: Insoluble
SPECIFIC GRAVITY: 0.926 @ 20°C (water = 1)
MOLECULAR WEIGHT: 90.55
Section 10、STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Excessive heat and fire.
POLYMERIZATION: Will not occur.
Section 11、PACKING &TRANSPORT INFORMATION
PROPER SHIPPING NAME: Methallyl Chloride
PRIMARY HAZARD CLASS/DIVISION: 3
UN/NA NUMBER: UN2554
PACKING GROUP: II
Handled with care to avoid leakage. And stored in dry, cool place .avoid shining.
To be packaged with 200L PE drum or Iron drum (PVF inside).Net weight to be 180 kgs/drum,
also can be packed in ISO-TANK (20mt net weight)
Section 12、ECOLOGICAL INFORMATION
None
Section 13、DISPOSAL CONSIDERATIONS
This product has moderate oral toxicity, and low dermal and inhalation toxicity. It is extremely
irritating to the skin and minimally irritating to the eyes. Inhalation of this product may cause
respiratory and mucous membrane irritation.
Section 14、TRANSPORT INFORMATION
US DOT
Canada TDG
Shipping Name:
METHALLYL CHLORIDE
METHALLYL CHLORIDE
Hazard Class:
3.2
3.2
UN Number:
UN2554
UN2554
Packing Group:
II
II
Section 15、REGULATORY INFORMATION
None
Section 16、