SCH3U Fall 2012 Unit 3 - Stoichiometry SCH3U Name: ________________ Mass Relationships in a Chemical Reaction Purpose To determine the mass of copper formed when Aluminum reacts with a copper salt. Introduction In this experiment, a piece of aluminum foil will be placed in an aqueous solution of Copper II chloride. The reaction may or may not go to completion. The mass of copper produced when a given mass of the copper compound reacts with a given aluminum will be determined experimentally. This will be compared to a theoretical yield calculated from an analysis (based on a balanced equation) of which reactant is limiting and the expected mass of product. Apparatus 2 150 mL beakers graduated cylinder stirring rod tweezers Materials CuCl2•2H2O Aluminum foil watch glass balance hot plate Procedure Record all experimental results in the data table as soon as you obtain them. a) Mass of first beaker (g) b) Mass of beaker and anhydrous Copper II chloride (g) c) Mass of dry Copper II chloride dihydrate (g) d) Mass of Aluminum foil (g) e) Mass of beaker and Copper (g) f) Mass of Copper (g) g) Mass of unreacted Al (s) if applicable h) Appearance of Copper II Chloride solution i) Appearance of Aluminum j) Appearance of the contents of the beaker after reaction A) Determine the mass of a clean, dry 150 mL beaker. To the beaker add approximately 2.5 g of anhydrous copper II chloride. Determine the mass of the beaker and contents. Add 50 mL of water. Stir to dissolve the copper compound. B) Group 1: Weigh out about 0.50 g of aluminum foil and tear small strips into the beaker with the copper solution. Group 2: Weigh out about 0.25 g of aluminum foil and tear small strips into the beaker with the copper solution. C) There may be some foaming during the early stages of the reaction and heat will be produced. Gently stir the foil with a stirring rod to cause copper to fall off and expose more aluminum. Continue to stir occasionally until all signs of a reaction have stopped. D) Carefully use tweezers to shake any remaining aluminum foil in the beaker to dislodge the copper. Remove the aluminum foil, being careful to leave the copper in the beaker. Rinse and dry this aluminum using filter paper and subtract its mass from the mass of aluminum in the data table. E) Pour the liquid in the beaker into the other beaker, being careful not to lose any copper. When you are sure that no copper has been lost, you may pour the contents of the second beaker into the sink. F) Add 50 mL of water to the beaker. Stir gently to wash the copper and repeat step E. Repeat step F H) If time allows, heat the cooper to drive off the water and weigh once cooled down. If there is not time, leave the copper in the beaker to dry out over a few days and then weigh. Concluding Questions 1) Write a balanced chemical equation for this reaction. 2) Calculate the molar mass of Aluminum: ____________ Copper:___________________ Anhydrous Copper II chloride: ________________________________________________________ 3) a) Determine the limiting reactant from the masses of the reactants and the balanced equation. b) How does your answer to 3a compare to item “h” in the data table? 4) Calculate the theoretical yield of solid copper. 5) Calculate the percent yield. 6) Calculate the percent composition of CuCl2 6) What was the purpose of Step F? What would be the consequences of omitting this step?