Safety data sheet It’s color semipermanent gel 1 Elements identifying the substance or preparation and the company Commercial name: Sales code: packaging: It’s color semipermanent gel from 11020401 to 11020489 bottle 80 ml Manufacturer/supplier: UNICOMPANY S.p.a. Via Pontina vecchia km 33,600 Ardea (Rome) Telephone number for urgent calls to the company and/or to an official consultancy body: UNICOMPANY S.r.l. – Tel. 069145177 Technical person who is responsible for writing MSDS: ntravaglini@unicompany.it 2 Hazard identification Danger classification: R22 Harmful if inhaled R36/38 Irritant for eyes and skin 3 Composition/information on ingredients Description: Mixture of dyes in gel for professional hair care use. Ingredients (according to INCI nomenclature): NEUTRAL / COLOR BASE: AQUA, PEG-4 RAPESEEDAMIDE, HEXYLENE GLYCOL, ETHANOLAMINE, LAURAMIDOPROPYL BETAINE, ISOPROPYL ALCOHOL, CETEARETH-23, SODIUM LAURETH SULFATE, COCAMIDE DEA, PARFUM, PERSEA GRATISSIMA OIL, BUXUS CHINENSIS, LINUM USITATISSIMUM OIL, HELIANTHUS ANNUUS SEED OIL, SODIUM Revision 3 of the 5th june 2008 SULFITE, SODIUM HYDROSULFITE, BENZYL SALICYLATE, HEXYL CINNAMAL, CITRONELLOL, LINALOOL, ALPHA-METHYL IONONE, LIMONENE, COUMARIN, BUTYLPHENYL METHYLPROPIONAL, HYDROXYISOHEXYL 3-CYCLOHEXENE CARBOXALDEHYDE, CITRAL 1N, 2N, 3N, 5N, 6.11, 9.11: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, mAMINOPHENOL, 2-METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, N-PHENYL-pPHENYLENEDIAMINE 4N, 6N, 7N, 7S, 8S,9S, 6.3, 5.01: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, m-AMINOPHENOL; 2-METHYLRESORCINOL 8N, 9N, 7.16, 4.3, 10.3, YELLOW ENHANCER: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, mAMINOPHENOL, 2-METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, N-PHENYL-pPHENYLENEDIAMINE, p-AMINOPHENOL, HC YELLOW 2, HC ORANGE 1 8.3, 8.01, 10.01: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, mAMINOPHENOL, 2-METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, N-PHENYL-pPHENYLENEDIAMINE, p-AMINOPHENOL, HC YELLOW 2 6 SLATE, 11 LIGHTEST SILVER: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, mAMINOPHENOL, 2-METHYLRESORCINOL, N-PHENYL-p-PHENYLENEDIAMINE, N,N-bis-(2-HYDROXYETHYL)-pPHENYLENEDIAMINE, HC YELLOW 2, BASIC RED 51 3.16, 4.65, 6.34, 6.66: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, mAMINOPHENOL, 2-METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, N-PHENYL-pPHENYLENEDIAMINE, p-AMINOPHENOL, 1-NAPHTHOL, 2-AMINO-3-HYDROXY PYRIDINE 4.4, 4.41, 5.41, 5.43, 5.71, 3.7, 4.7, 5.7, 6.7: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, mAMINOPHENOL, 2-METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, N-PHENYL-pPHENYLENEDIAMINE, N,N-bis-(2-HYDROXYETHYL)-p-PHENYLENEDIAMINE, p-AMINOPHENOL, HC YELLOW 2, 1-NAPHTHOL, RESORCINOL, 2-AMINO-3-HYDROXY PYRIDINE 5.62, 6.65, 7.4, 7.40, 7.44, 8.43, 9.44: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, p-AMINOPHENOL 4.6, 6.6, 7.64,: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, p-AMINOPHENOL, HC YELLOW 2, 1-NAPHTHOL, HC ORANGE 1, 2-AMINO-3-HYDROXY PYRIDINE, HC RED 3 RED ENHANCER: p-PHENYLENEDIAMINE, p-AMINOPHENOL, 1-NAPHTHOL, 2-AMINO-3-HYDROXY PYRIDINE, 3-NITRO-pHYDROXYETHYLAMINOPHENOL 5.5, 6.41, 7.41, 7.7: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, mAMINOPHENOL, 2-METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, N-PHENYL-pPHENYLENEDIAMINE, p-AMINOPHENOL 3P: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, DISPERSE VIOLET 1 6F, 7F: BASIC RED 51, BASIC YELLOW 87, ETIDRONIC ACID 6.33, 7.33, 8.33, 9.33: p-PHENYLENEDIAMINE, 4-CHLORORESORCINOL, 2-AMINO-4-HYDROXYETHYLAMINO ANISOLE SULFATE, 2Revision 3 of the 5th june 2008 METHYLRESORCINOL, 4-AMINO-2-HYDROXY TOLUENE, p-AMINOPHENOL, HC YELLOW 2, HC ORANGE 1, 2AMINO-3-HYDROXY PYRIDINE, 4-AMINO-m-CRESOL Dangerous substances: Name/classification CAS - naphtol Xn harmful R21/22 Xi Irritant R37/38 R41 90-15-3 N.67/548/CE EINECS 201-969-4 - 4 First aid measures Inhalation: The product cannot be inhaled Contact with the skin: Washing with running water Contact with the eyes Washing well with large amount of running water Swallowing: Washing out the mouth. Consult immediately a doctor 5 Fire fighting measures Suitable extinguishers: Large amount of water. No type of extinguisher prohibited Combustion risks: None Specific protective equipment: None 6 Accidental release measures Personal protection: None Environmental precautions: Prevent any infiltration into the drains/surface water/phreatic water supply. If the product reaches watercourses and/or drainage system, advise the proper authorities. Cleaning/absorption methods: Collect up the product with suitable medium. Use suitable container to the disposal. 7 Handling and storage Handling: Product can be handle without problem. Storage: Requirements for the warehouse and containers: Store in a cool place. Store in the original sealed containers Check the state and temperature of containers at frequent intervals. Protect from heat and direct sunlight. 8 Checking individual protection/exposure Precautionary measures: Keep out from food, beverage and forage Respiratory protection: None Hand protection: Use proper gloves Eye protection: None Revision 3 of the 5th june 2008 9 Physical and chemical properties Appearance and colour: Odour: Specific weight pH(1%): Boiling point: Flammability point: Properties supporting combustion: Vapour pressure: Water solubility: Vapour density: Liquid Characteristic of fragrance between 0.90 and 1.10 between 8 and 9 n.a. not inflammable no supports combustion not available soluble not available 10 Stability and reactivity Thermal decomposition /conditions to be avoided: Stable in normal conditions. Avoid heat, heat sources. Dangerous reactions: None 11 Toxicological information The product contains ingredients that might irritate sensitive skin. We suggest a preliminary sensibility test about 48 hours before the first application. Extended (chronic)exposure: The product has not been tested according with “OSHA Hazard communication standard” Target organ: skin Organism entrance way: ingestion and skin General health conditions during the extended exposure will be related with the primary toxic effects of the substances used. The presence of skin irritant might get worse pre-existent dermatitis. 12 Ecological information Use in accordance with normal rules of good practice at work, avoiding any dispersion of the product into the surrounding environment 13 Notes on waste disposal Product: Do not dispose of the product along with normal domestic waste. Dirty packing materials: Dispose of in conformity with current administrative requirements 14 Transport information The product does not contains dangerous substances for the rail/road transport, air transport and marine transport. ADR/RID rail/road transport (outside national boundaries): not classified ICAO-TI and IATA-DGR air transport: not classified IMDG marine transport: not classified Revision 3 of the 5th june 2008 15 Information on regulations Classification according to EEC directives: Product danger code and labelling: not dangerous Dangerous components requiring labelling: none Nature of specific risks (R phrases): R22 R36/38 Harmful if inhaled Irritant for eyes and skin Safety recommendations (S phrases) S2 keep out of reach of children S26 In case of contact with eyes, wash immediately with care and consult a medical center Legislative reference list: Law 11/10/1986, n° 713 and subsequent modifications – cosmetic products D.law 136/83 - biodegradability D. law 5/02/97, n° 22 – classification, packing, labelling of dangerous preparations D. law 277/91 – exposure to chemical agent D. law 626/94 – worker safety D. law 3/02/97, n° 52 – classification of dangerous substances D. law 16/07/98, n° 285 – classification of dangerous preparations D.P.R. 303/56 – sanitary inspections And subsequent modifications and provisions for implementation. 16 Other information The data provided is based on our current knowledge, and in no way guarantees the product characteristics or gives support to any legal contractual relations. DATA SHEET REALIZED BY: UNICOMPANY SRL This data sheet substitutes all previous versions PREVIOUS REVISION: 2 OF THE 12TH JULY 2007 MATERIAL SAFETY DATA SHEET It’s color semipermanent gel Revision 3 of the 5th june 2008