24-hour Emergency Phone: 800-424-9300 MATERIAL Page 1 SAFETY Synthetic Labs, Inc 24 Victory Lane Dracut, MA 01826 Telephone: 978-957-2919 DATA SHEET Date : 1/2/2008 Ref.No.: 6423 1. Product Identification: PRODUCT NAME: Synonyms or Description: DECK SHAKE & WOOD CLEANER POWDER MIXTURE HMIS CODES: H 4 F 1 R 1 2. Composition/Information on Ingredients: Chemical Name OXALIC ACID CAS# 6153-56-6 Wt %. 50% to 600% Unless listed immediately above, the product contains no hazardous ingredients as listed on the Massachusetts Hazardous Substance List or under §1910.1200 of Title 29 of the Code of Federal Regulations. 3. Hazards Identification: Emergency Overview ------------------------------------Poison! Danger! May be fatal if swallowed. Corrosive. Causes severe irritation and burns to skin, eyes and respiratory tract. Harmful if inhaled or absorbed through skin. May cause kidney damage. Oxalic acid is corrosive to tissue. When ingested, oxalic acid removes calcium from the blood. Kidney damage can be expected as the calcium is removed from the blood in the form of calcium oxalate. The calcium oxalate then obstructs the kidney tubules. Toxic! May cause burns, nausea, severe gastroenteritis and vomiting, shock and convulsions. May cause renal damage, as evidenced by bloody urine. Estimate fatal dose is 5 to 15 grams. CHRONIC EXPOSURE: May cause inflammation of the upper respiratory tract. Prolonged skin contact can cause dermatitis, cyanosis of the fingers and possible ulceration. May affect kidneys. Potential Health Effects ------------------------------------INHALATION: Inhalation produces damaging effects on the mucous membranes and upper respiratory tract. Symptoms may include irritation of the nose and throat, and labored breathing. May cause pulmonary edema, a medical emergency. Pulmonary edema may be delayed up to 48 hours. INGESTION: Corrosive. Swallowing can cause severe burns of the mouth, throat, and stomach, leading to death. Can cause sore throat, vomiting, diarrhea. SKIN CONTACT: Corrosive. Symptoms of redness, pain, and severe burn can occur. EYE CONTACT: Corrosive. Contact can cause blurred vision, redness, pain and severe tissue burns. Can cause blindness. CHRONIC EXPOSURE: Not known. AGGRAVATION OF PRE-EXISTING CONDITIONS: Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of the substance. C 24-hour Emergency Phone: 800-424-9300 MATERIAL Page 2 SAFETY DATA SHEET 4. First Aid Measures: INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. INGESTION: DO NOT INDUCE VOMITING! Give large quantities of water or milk if available. Never give anything by mouth to an unconscious person. Get medical attention immediately. SKIN CONTACT: Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician, immediately. Wash clothing before reuse. EYE CONTACT: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. 5. Fire Fighting Measures: FIRE: Flash Point: 141 - 200 F Boiling Point: > 95 F Flammable limits in air % by volume: Not established. Material can support combustion. EXPLOSION: Containers may explode in heat or fire. FIRE EXTINGUISHING MEDIA: Dry chemical, foam, water or carbon dioxide. SPECIAL INFORMATION: In the event of a fire, wear full protective clothing and NIOSHapproved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Move exposed containers from fire area, if it can be done without risk. Use water to keep fire-exposed containers cool. 6. Accidental Release Measures: Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment. Isolate hazard area. Keep unprotected personnel from entering. Contain and recover liquid when possible. Use non-sparking tools and equipment. Collect material in an appropriate container. Liquids may be absorbed with an inert material (e.g. vermiculite, dry sand, earth), and place in a chemical waster container. Do not use combustible materials such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray to disperse any vapors, to protect personnel attempting to stop leak and to flush spills away from exposures. 7. Handling and Storage: Keep in a tightly closed original container, stored in a cool, dry, ventilated area. Protect against physical damage. Isolate from incompatible substances. Product may be slippery if spilled. Containers of this material may be hazardous when empty since they retain product residues (dust, solids, liquids). Observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection: Material Name OXALIC ACID PEL (OSHA) 1 mg / m3 TWA (ACGIH) 1 mg/m3 TLV (ACGIH) AIRBORNE EXPOSURE LIMITS: A system of local and/or general exhaust if necessary to keep employee exposures below the above Airborne Exposure Limits. RESPIRATORY PROTECTION: Use with adequate ventilation. Avoid the inhalation of dust and particulates for the application of this product. SKIN PROTECTION: Wear rubber gloves or Neoprene gloves. Chemical resistant apron. EYE PROTECTION: Splash goggles. 9. Physical and Chemical Properties: Appearance: White powder. Odor: No odor unless perfumed. 24-hour Emergency Phone: 800-424-9300 MATERIAL SAFETY Page 3 DATA SHEET Solubility in Water: Completely soluble in water. Specific Gravity: 1.00 pH: Not Applicable. Volatile (% V.O.C. by volume): 0.00 Melting Point: Not Known Vapor Density (Air=1): Not Known Vapor Pressure (mm Hg): Not Known Evaporation Rate (BuAc=1): Not Applicable 10. Stability and Reactivity: STABILITY: Stable under ordinary conditions of use and storage. HAZARDOUS DECOMPOSITION PRODUCTS: Not known. HAZARDOUS POLYMERIZATION: Will not occur. INCOMPATIBILITIES: Avoid mixing with other chemicals unless reactivity is known. CONDITIONS TO AVOID: No information found. 11. Toxicological Information: OXALIC ACID: Oral rat LD50: 375 mg/kg; irritation skin rabbit: 500 mg/24H mild; eye rabbit 250 ug/24H severe; investigated as a reproductive effector. --------\Cancer Lists\--------------------------------------------------------NTP Carcinogen--Ingredient Known Anticipated IARC Category ------------------------------------------------- ----------- ----------------- ------------Oxalic Acid (144-62-7) No No None 12. Ecological Information: Environmental Fate: Not established Environmental Toxicity: Not available 13. Disposal Considerations: Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste facility. Large amounts should be given to a licensed disposal agency. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local regulations. 14. Transport Information: D. O. T. Classification (Domestic, Land): UN 3261, CORROSIVE SOLID, ACIDIC, ORGANIC N.O.S. (CONTAINS OXALIC ACID DIHYDRATE), 8, PG III ERG 154 15. Regulatory Information: Not Known 16. Other Information: DISCLAIMER: See the product label for use directions. The information of this Material Safety Data Sheet reflects the latest information and data that we have on hazards, properties and handling of this product under the recommended conditions of use. Any use of this product or method of application which is not described on the Label or in the Product Data Sheet is the responsibility of the user. 24-hour Emergency Phone: 800-424-9300 MATERIAL SAFETY Page 4 DATA SHEET This Material Safety Data Sheet was prepared to comply with the OSHA Hazard Communications Regulation and Massachusetts Right to Know Law.