Upper Division Lab (Physics 341): BLACKBODY RADIATION 1. Introduction In this experiment, the spectrum of an incandescent light bulb is scanned by hand using a prism spectrometer that measures relative light intensity as a function of angle. The spectrum is recorded with the computer using the Data Studio software. A broadband light sensor is used with a prism so the entire spectrum from approximately 400 nm to 2500 nm can be scanned continuously avoiding the problem of overlapping diffraction orders prone to grating spectrometers. The wavelengths corresponding to the angles are calculated using the equations for a prism spectrometer. The relative light intensity can then be plotted as a function of wavelength as the spectrum is scanned, resulting in the characteristic blackbody curve that you have studied in Optics and your Modern Physics courses. Decreasing the intensity of the light bulb reduces the temperature, and the scan is repeated to show how the curves nest with a shift in the peak wavelength (Wien’s Law). The temperature of the filament of the bulb can be estimated indirectly by determining the resistance of the bulb from the measured voltage and current. From the temperature, the theoretical peak wavelength can be calculated and compared to the measured peak wavelength. Moreover, the black body radiation curves can be compared with Planck’s radiation law and the temperature dependence can be compared to StefanBoltzmann’s Law. 2. Theory The spectrum of light waves emitted from a hot, glowing object cannot be explained by the classical theories of radiation and temperature introduced by Rayleigh and Jeans at the end of the 19th century. Their “prediction” was that the intensity of the light emitted at a given wavelength should vary inversely as the fourth power of the wavelength, which means that the highest intensity occurs in the short wavelength or “ultraviolet” region. In fact, the predicted intensity grows without bound as the wavelength goes to zero so all objects should appear to be blue no matter what their temperature, and the total intensity of light emitted is infinite. Both these “predictions” are incorrect and this state of affairs, called the Ultraviolet Catastrophe, persisted until Planck proposed the idea that light waves are not continuous, but their energy is emitted in small “chunks” called quanta. Each quantum has an energy E hf , where h 6.626 1034 J s is a fundamental constant of nature called Planck's constant. Introducing this idea, Planck derived his famous distribution function (Planck’s Radiation Law) with the intensity I of radiation emitted by a black body given by: I 2 c 2 h 1 5 e hc kT , (1) 1 where c is the speed of light in a vacuum, h is Planck's constant, k is Boltzmann's constant, T is the absolute temperature of the body, and is the wavelength of the radiation. This distribution function has the property that the graph of intensity vs. wavelength peaks at a wavelength that is inversely proportional to the absolute temperature of the emitter, which is described by Wien Displacement Law: max const 0.002898 m K , T T (2) 1 where T is the absolute temperature of the body and the constant is called Wien’s constant. The total intensity of the light emitted per m2 of surface area, integrated over all wavelengths, is proportional to the fourth power of the absolute temperature. This relationship is known as Stefan Boltzmann’s Law: I T 4 , (3) where 5.67 108 W . m ×K 4 2 2.1. Determining the Temperature of the Bulb The temperature T of the blackbody light tungsten filament can be calculated (CRC Handbook, 45th edition, page E-110) using the resistance of the filament at room temperature R0 . The resistance R of the bulb is given by R R0 1 0 T T0 . (4) where 0 is the thermal coefficient at room temperature and T0 is room temperature. The bulb filament is made of tungsten, which has a coefficient of 0 4.5 103 / K at room temperature. Solving equation (4) for the hot temperature T gives T T0 R 1 R0 0 , (5) The bulb has an approximate resistance of R0 0.84 at room temperature. For a more exact value, measure it yourself. You cannot measure the resistance of the bulb while it is still in the holder (why not?). Solder wire leads to one bulb to ensure a good contact, and use this bulb to determine the resistance with a multimeter. To find the resistance of the hot bulb, measure the voltage drop across the bulb and the current passing through it. Use Ohm’s law, where V IR . You can read off the current supplied to the bulb directly from the front panel of the Agilent power supply. To measure the voltage you can use a multimeter and measure across the black body source. The final equation for the temperature (in Kelvin) of the bulb becomes V I 1 0.84 T 300 K 4.5 103 / K (6) 2.2 Determining the Wavelength from the Angle The 60-degree prism is mounted so that the back face is perpendicular to the incoming light, as shown in Figure 1. A schematic of the prism and the path of light are shown in Figure 2. 2 Figure 1: Experimental Setup of the Pasco Prism spectrometer. Figure 2: Path of Light through the Prism. 3 To measure the spectrum, we take advantage of the dispersion of the prism. In other words different wavelengths passing through the prism get dispersed at different angles. We need to find which angle corresponds to which wavelength. In the following, we will go through the analysis to find this relationship. From Figure 2, since the prism angle is 60 degrees, it can be shown that 2 3 60o Using Snell’s law at each interface, sin 60o n sin 2 (*) and sin n sin 3 n sin 60o 2 , which becomes using double angle trig identities: sin n sin 60o cos 2 sin 2 cos 60o . This expression can be manipulated to change from cos to sin using trig identities to read 1 1 sin n sin 60o 1 sin 2 2 2 n sin 2 cos 60o sin 60o n2 n2 sin 2 2 2 n sin 2 cos 60o Using (*) we can write this as 1 sin sin 60o n 2 sin 2 60o 2 sin 60o cos 60o Solving for n yields: 2 sin o n cos 60 sin 2 60o , which can be simplified to o sin 60 2 2 1 3 n sin 2 4 3 (7) The dispersion relation (refractive index as a function of wavelength) for glass can be empirically described by the Cauchy equation as n A 2 B, (8) 4 where A and B depend on the type of glass. Experimental data for the glas prism used is given in Table 1. A least squares fit to the data given in Table 1 (verify for extra points) to the Cauchy relation (8) gives the values of A 13900 and B 1.689 . Solving (8) for the wavelength gives A nB (9) Thus the final equation for the wavelength (in nanometers) is given by 13900 2 2 1 3 sin 1.689 2 4 3 (10) Thus measuring the angle with the rotary motion sensor in In DataStudio, lets you calibrate measured angle values into wavelength . There is a way to do this calibration in DataStudio using the Calculator Window. Alternatively, you can calibrate your angle measurements in Origin. 3. Equipment PASCO spectrophotometer, IR sensor, Blackbody Light Source with Light Aperture and Lens assemblies, Agilent power supply, Digital Multimeter (DMM), Science Workshop interface with Data Studio software. The equipment should be already assembled for you and your instructor will show you how to make the fine adjustments. Please refer to the Spectroscopy laboratory manual for details, for instance how to calibrate the angular position readout of the sensor into actual angle. 4. Procedure The PASCO prism spectrometer used in this experiment allows for the measurement of the intensity of infrared radiation as a function of its wavelength. The source of the radiation is a light bulb that is heated to a known temperature by adjusting the voltage V across its filament. The temperature can be calculated from the resistance of the filament at room temperature, the voltage across the bulb and the current through the bulb. The wavelength of the light is related to the angle at which it emerges from the prism. However, since the index of refraction of the prism is a function of the wavelength of the light, the relationship between wavelength and angle is somewhat complicated. In this experiment, the corresponding equation has been determined for the spectrometer you are using and has been described in the theory section before. 5 4.1. Determination of Intensity as a Function of Wavelength. The light intensity as a function of angle will be measured using the Data Studio program, for several different voltages across the bulb in the range from 1-7 V. The computer interface has been set up for you. Please also look at the instructions in the Spectroscopy manual for details. The procedure to make a measurement is as follows: Open the Data Studio program and set up the experiment just like you did for the Spectroscopy experiment. Make sure the IR sensor and rotary motion sensors are selected. Carefully rotate the “light sensor” arm on the spectrometer in a counter-clockwise direction until it hits the stop on the angular indicator of the circular table. You will be finding a good position for placing this stop after some experimentation. All data runs will start in this position so they can be compared side by side later on. Set the voltage across the light bulb, using the power supply to a value in the range from 1-7V, and record this value (double check whether you can trust the reading of the power supply or whether you need to use the multimeter) as well as the current through the light bulb. One person will start and stop the data run and view the resulting intensity vs. wavelength plot, while a second person will “tare” the IR sensor and move the arm of the spectrometer to scan the spectrum. Click on the green START button of Data Studio next to the timer at the top of the screen. This will become the red STOP button, at which time the data taking can begin. Tare the IR sensor by pushing its tare button (located on the top front of the sensor) while holding your hand in front of the lens to prevent light from the bulb from reaching the sensor. This establishes the “zero intensity” IR level. Next, uncover the lens and begin to rotate the arm of the spectrometer clockwise, slowly and steadily. At first nothing may seem to be happening, but eventually the intensity level on the Intensity vs. angle plot will begin to rise and then fall. Experiment where to start and stop your scan and place the stop on the angular indicator of the circular table and record the corresponding angle value. You will always start your experiment from that location. This entire wavelength-scan process should take about one minute or so. Repeat the above process for at least four different light-bulb currents and voltages (record the values in your lab notebook and calculate the temperature). After changing the bulb current give the bulb some time to come to a steady temperature. Each lab partner should make at least one scan. If you are happy with your spectra, export the data into Origin for further analysis (look at the Spectroscopy manual to show you how). At this point, data-taking is complete and the remainder of the analysis can be done elsewhere. 5. Analysis In Origin, convert your angular position values into angles, using the calibration procedure described in the Spectroscopy lab. Then calibrate the x- axis to read actual wavelength in nm. It should cover a range between 500-2500nm. The data plots you made will look like the Planck distribution going to zero quickly at short wavelengths and less quickly at long wavelengths. The location of the peak of the distribution should be rather well determined, and the integral from 500-2500 nm should be a reasonably good (though not entirely accurate) measure of the total output of the source. (1) In Origin, compare your data to theory described by Planck’s radiation law. Since you do not know the absolute normalization of your measurements, you will need to normalize your theory curve to 6 one of your data points. Does the shape of your measured curve match the theoretical curve? Can the bulb really be considered a black body? (2) Does the peak shift toward shorter or longer wavelengths as the temperature is lowered? How does the intensity change as the temperature is increased? Determine the constant in the Wien Displacement Law by multiplying the wavelength at maximum IR output by the absolute temperature, for all four runs (use the last graph that you printed, the one with all the curves, to do this). Compare your values with the standard value of 2.898 10-3 mK . To what degree of precision do these values agree? How did the color of the bulb change with temperature? How did the color composition of the spectrum change with temperature? Considering the peak wavelengths, why is a bulb’s filament red at low temperatures and white at high temperatures? At about what wavelength is the peak wavelength of our Sun? What color is our Sun? Why? (3) Check the Stefan-Boltzmann Law by integrating over your spectra from 500-2500 nm and dividing by the fourth power of the measured temperature for each run (it is convenient to express the temperature in units of thousands of degrees K to avoid small numbers). To what degree of accuracy do the data follow the Stefan-Boltzmann Law? 7