Plasmaterials, Inc. 2268 Research Drive Livermore, CA 94550 Ph: (925) 447-4030 Fx: (925) 447-4031 http://plasmaterials.com MATERIAL SAFETY DATA SHEET Section 1- PRODUCT IDENTIFICATION COMPOSITION PRODUCT NAME Li Lithium Section 2- HAZARDOUS INGREDIENTS Note: Products under normal conditions do not represent an inhalation, ingestion or contact health hazard. MATERIAL OR COMPONENT CAS NUMBER WT% Li 7439-93-2 0-100 EXPOSURE LIMITS OSHA PEL (Mg/M3) NE ACGIH TLV(MG/M3) NE Section 3- PHYSICAL DATA MATERIAL IS (AT NORMAL CONDITIONS) APPERANCE AND ODOR □ Liquid □ Solid □ Gas □ Other MELTING POINT (BASE METAL) Silver-White. No odor 179°C SPECIFIC GRAVITY 0.53g/cc @ 20°C Section 4- FIRE AND EXPLOSION Flash Point (Method Used) N/A Flammable Limits Flammable Solid LEL N.A. UEL N.A. EXTINGUISHING MEDIA Use special mixtures of dry chemical, soda ash & graphite. Do not use water, sand, carbon tetrachloride or carbon dioxide. SPECIAL FIRED FIGHTING PROCEDURES Wear a self-contained breathing apparatus and full protective clothing to prevent contact with skin and eyes. Fumes from fire are hazardous. Isolate runoff to prevent environmental pollution. UNUSUAL FIRE AND EXPLOSION HAZARDS Dangerous when wet. Reacts violently with water to give off flammable hydrogen gas and corrosive dust. When burned lithium emits toxic fumes of LiO2 and hydroxide. Can react vigorously with oxidizing materials. Section 5- REACTIVITY DATA STABILITY INCOMPATABILITY (MATERIALS TO AVOID) Unstable Air, water & moisture CONDITIONS TO AVOID Water, moisture, acids, oxidizers, oxygen, nitrogen, carbon dioxide, bromine pentafluoride, diazomethane metal chlorides, metal oxides and non-metal oxides. HAZARDOUS DECOMPOISTION PRODUCTS Lithium Hydroxide, oxides of lithium and hydrogen gas. Section 6- HEALTH HAZARD GUIDE MAJOR EXPOSURE HAZARD □Inhalation □Skin □Skin Absorption □Eye Contact □Ingestion EFFECTS OF OVEREXPOSURE: The toxicity of lithium compounds are a functional solubility in water. Lithium ion has central nervous system toxicity. The initial effects of lithium exposure are tremors of the hands, nausea, maturation, slurred speech, sluggishness, sleepiness, vertigo, thirst and increased urine volume. Effects from continual exposure are apathy, anorexia, fatigue, lethargy, muscular weakness and changes in ECG. Long term exposure leads to hypothyroidism, leukocytosis, edema, weight gain, polydipsia/polyurea, memory impairment, seizures, kidney damage, shock, hypotension, cardiac arrhythmias, coma and death. INHALATION: Severe irritant and corrosive. Causes irritation to the respiratory tract and mucous membranes. May cause pulmonary edema and lung damage. SKIN/EYE CONTACT: Irritant and corrosive. INGESTION: Irritant and corrosive. May cause central nervous system effects, circulatory failure and cardiovascular collapse. May cause gastrointestinal irritation, renal dysfunction, derangement of neuromuscular activity, diabetes and kidney damage. EMERGENCY & FIRST AID PROCEDURES INHALATION: Remove from exposed area to fresh air immediately; give oxygen if breathing is difficult. Seek medical attention. INGESTION: Do not induce vomiting; seek medical attention. SKIN CONTACT: Remove contaminated clothing; Brush material off skin and wash affected area with soap and water. EYE CONTACT: Flush eyes with lukewarm water lifting up the upper and lower lids for at least fifteen minutes. Section 7- SPILL OR LEAK PROCEDURES SPILL OR LEAK PROCUDRES Wear appropriate respiratory and protective equipment. Isolate the area where the spill occurred and provide proper ventilation and extinguish. Vacuum the spill using a high efficiency unit and place in a container for proper disposal. WASTE DISPOSAL METHODS Dispose of in accordance with applicable federal, state and local regulations. Section 8- SPECIAL PROTECTION RESPIRATORY Wear NIOSH approved respirator. VENTILATION Local Exhaust: Maintain below TLV. EYE PROTECTION & PROTECTIVE CLOTHING Recommend: vented glasses and impervious gloves. Section 9- SPECIAL PRECAUTIONS WORK/HYGIENIC/MAINTENANCE PRACTICES: Store in tightly closed containers in a cool, dry place. Wash hands and face thoroughly after handling and before meals. Keep material under mineral oil or other liquid free from oxygen or water. Handle and store in a controlled environment and in an inert gas, such as argon. The information in this MSDS was obtained from sources, which we believe are reliable. However, the information is provided without any representation or warranty, express or implied, regarding the accuracy or correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product.