15 3 The Periodic Table 3 section ● Transition Elements What You’ll Learn ■ properties of some transition elements ■ how to tell lanthanides from actinides Study Coach Make Flash Cards As you read, make flash cards to help you learn the transition elements. On one side of the card, write the name of the element, its symbol, and its atomic number. On the other side of the card, write one important use of the element. Before You Read Name three things you use every day that are made from metals. Read to Learn The Metals in the Middle Groups 3–12 are called the transition elements. All of them are metals. The properties of the transition elements change less as you move across a period than they do for the representative elements. Most transition elements are found combined with other elements in ores. An ore is a mineral that is found naturally on Earth. A few transition elements like gold and silver are found as pure elements. What is the iron triad? D Organize Information ● Make the following Foldable to help you organize information about the iron triad, transition metals, lanthanides, and actinides. The Iron Triad Transition Metals Lanthanides Actinides 232 The Periodic Table Iron, cobalt, and nickel are in Iron Cobalt Nickel period 4 and are known as the 26 27 28 Fe Co Ni iron triad. They are shown in the figure. They have very similar properties. These elements and others have magnetic properties. Large magnets are made from a mixture of nickel, cobalt, and aluminum. The iron triad also has many other uses. Nickel is used in batteries along with cadmium. Iron is a necessary part of hemoglobin, the substance that moves oxygen in your blood. Iron is mixed with other metals and with carbon to create steels with different properties. Bridges and skyscrapers are built with steel because it is strong. Copyright © Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc. chapter How are transition elements used? Look at the figure below. The transition elements are in the middle of the periodic table. They are Groups 3–12. Most transition metals have higher melting points than the representative elements. The filaments of lightbulbs are made with tungsten, element 74. Tungsten has the highest melting point of any metal (3,410°C). Tungsten will not melt when a current passes through it. Picture This 1. Identify How many periods of transition elements are there in the periodic table? 2. Describe Which group Copyright © Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc. Transition Metals Mercury Mercury has the lowest melting point of any metal (–39°C). It is used in thermometers and barometers. It is the only metal that is liquid at room temperature. Like many of the heavy metals, mercury is poisonous to living things. It must be handled carefully. Chromium The name chromium comes from the Greek word chroma. It means color. Chromium is a colorful element. Many other transition elements also combine to make colorful substances. Platinum Group Ruthenium, rhodium, palladium, osmium, iridium, and platinum are sometimes called the platinum group. They have similar properties. They do not combine easily with other elements. So, they can be used as catalysts. What is a catalyst? A catalyst is a substance that can make something happen faster. However, the catalyst is not changed. Other transition elements like nickel, zinc, and cobalt can be used as catalysts. Transition elements are used as catalysts to make electronics, plastics, and medicines. of elements can be used as catalysts? Reading Essentials 233 Lanthanide Series 58 Ce 59 Pr 60 Nd 61 Pm 62 Sm 63 Eu 64 Gd 65 Tb 66 Dy 67 Ho 68 Er 69 Tm 70 Yb 71 Lu Actinide Series 90 Th 91 Pa 92 U 93 Np 94 Pu 95 Am 96 Cm 97 Bk 98 Cf 99 Es 100 Fm 101 Md 102 No 103 Lr Applying Math 3. Calculate How many lanthanide and actinide elements are there altogether? Inner Transition Elements There are two series of inner transition elements. The lanthanides is the name of the first series of inner transition elements. The lanthanides go from cerium to lutetium. The lanthanides also are called the rare earths because at one time people thought they were not common. They are usually found combined with oxygen in Earth’s crust. The actinides is the name of the second series of inner transition elements. The actinides go from thorium to lawrencium. The figure above shows the lanthanides and the actinides. 4. Explain Why are lanthanides in the same ore hard to separate? The lanthanides are soft metals. They can be cut with a knife. The lanthanides often are found in the same ore. They are so much alike that they are hard to separate when they are in the same ore. Lanthanides are not as rare as people once thought. Earth’s crust has more cerium than lead. Cerium makes up 50 percent of a mixture called misch (MIHSH) metal. Flints in lighters are made from misch metal. Lighters are used to start fires. Lanthanum, iron, and neodymium also are in flint. Lanthanides also are used in color TV screens. A blend of some lanthanide elements will give off a bright red light. Other compounds are used to make the other colors for a natural-looking picture on the screen. What are the actinides? All the actinides are radioactive. The nuclei of atoms of radioactive elements are unstable. They break down to make other elements. Thorium, protactinium, and uranium are the only actinides that now are found naturally on Earth. Uranium is found in Earth’s crust. All other actinides are synthetic elements. Synthetic elements are made in laboratories and in nuclear reactors. Synthetic elements have many uses. Plutonium is used as a fuel in nuclear power plants. Americium is used in home smoke detectors. Californium-252 is used to kill cancer cells. 234 The Periodic Table Copyright © Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc. What are the lanthanides? How can scientists make synthetic elements? Scientists can make synthetic elements by using a device called a particle accelerator. In the particle accelerator, the nuclei of atoms are made to crash into each other at high speeds. Some of the nuclei might stick together to make new, heavier elements. Some of the synthetic elements are very unstable. Synthetic elements may only last a fraction of a second before they break down into other elements. What elements do dentists use? 5. Explain What happens to synthetic elements when they break down? 6. Analyze Why do you Copyright © Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc. For over 150 years, dentists have used a substance called amalgam to fill cavities in decayed teeth. Amalgam is a mixture of silver, copper, tin, and mercury. Some people are worried that amalgam is harmful because it contains mercury. Today, dentists can use things other than amalgam to fill cavities. New materials are used to fix decayed, broken, or missing teeth. These new materials are strong. Body fluids will not break them down. They can also be changed to match the natural color of the tooth. Some of the new materials have fluoride in them. Fluoride protects teeth from more decay. Bonding Agents To use these new materials, dentists use new bonding agents. Bonding agents are like glue. They glue the materials to the natural tooth. The bonding agents must be strong and not be broken down by body fluids. Braces Orthodontists, dentists who straighten teeth, use new nickel and titanium alloys for the wires on braces. These wires have shape memory. This means they will always try to keep their shape. The wires are heated to lock in their shapes. The wires are forced out of shape when they are put on crooked teeth. They will try to return to their original shape, straightening the teeth as they do. think wires that hold their shape are useful for fixing crooked teeth? Reading Essentials 235 After You Read Mini Glossary actinides: the name of the second series of inner transition elements catalyst: a substance that can make something happen faster, but not change itself lanthanides: the name of the first series of inner transition elements synthetic elements: elements made in laboratories and in nuclear reactors 1. Review the terms and their definitions in the Mini Glossary. Write a sentence describing why you would add a catalyst to something. 2. Complete the table. In the second column, write whether each element is a regular transition element, a lanthanide, or an actinide. Write a use for the element in the third column. Element Element Group Use Cerium Tungsten Iron 3. You were asked to make flash cards of the transition elements. What is another method you could use to learn the transition elements? End of Section 236 The Periodic Table Visit blue.msscience.com to access your textbook, interactive games, and projects to help you learn more about transition elements. Copyright © Glencoe/McGraw-Hill, a division of The McGraw-Hill Companies, Inc. Plutonium