VAN WATERS AND ROGERS
-- SODIUM HYPOCHLORITE
=======================================================
MSDS Safety Information
=======================================================
FSC: 6810
NIIN: 00-169-5163
MSDS Date: 12/01/1991
MSDS Num: BDFGX
Product ID: SODIUM HYPOCHLORITE
MFN: 01
Responsible Party
Cage: 0AN91
Name: VAN WATERS AND ROGERS
Address: 1600 NORTON
City: SEATTLE WA 98104
Info Phone Number: 408-435-8700
Emergency Phone Number: 800-424-9300
Review Ind: Y
Published: Y
=======================================================
Contractor Summary
=======================================================
Cage: 60777
Name: CHEMICAL COMMODITIES AGENCY, INC.
Address: 27447 PACIFIC STREET
City: HIGHLAND CA 92346-2640
Phone: 909-864-2310
Cage: 0AN91
Name: VAN WATERS AND ROGERS
Address: 2256 JUNCTION AVE
City: SAN JOSE CA 95131
Phone: 408-435-8700/800-424-9300(CHEMTREC)
=======================================================
Item Description Information
=======================================================
Item Manager: S9G
Item Name: SODIUM HYPOCHLORITE SOLUTION
Specification Number: A-A-1427C
Type/Grade/Class: GRADE B
Unit of Issue: CN
Quantitative Expression: 00000000005GL
UI Container Qty: 0
Type of Container: PAIL/CAN
=======================================================
Ingredients
=======================================================
Cas: 7681-52-9
RTECS #: NH3486300
Name: SODIUM HYPOCHLORITE (SARA III)
% Wt: 7-16
Other REC Limits: NOT ESTABLISHED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
EPA Rpt Qty: 100 LBS
DOT Rpt Qty: 100 LBS
-----------------------------Cas: 7647-14-5
RTECS #: VZ4725000
Name: SODIUM CHLORIDE
% Wt: 5-13
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
-----------------------------Cas: 1310-73-2
RTECS #: WB4900000
Name: SODIUM HYDROXIDE (SARA III)
% Wt: .05-0.9
Other REC Limits: NONE SPECIFIED
OSHA PEL: 2 MG/M3
ACGIH TLV: C 2 MG/M3; 9293
EPA Rpt Qty: 1000 LBS
DOT Rpt Qty: 1000 LBS
-----------------------------Cas: 7732-18-5
RTECS #: ZC0110000
Name: WATER
% Wt: NONE
Other REC Limits: NONE SPECIFIED
OSHA PEL: NOT ESTABLISHED
ACGIH TLV: NOT ESTABLISHED
=======================================================
Health Hazards Data
=======================================================
LD50 LC50 Mixture: NO INFORMATION GIVEN ON MSDS BY SUPPLIER
Route Of Entry Inds - Inhalation: YES
Skin: YES
Ingestion: YES
Carcinogenicity Inds - NTP: NO
IARC: NO
OSHA: NO
Effects of Exposure: INHALE FUMES/MISTS CAUSES RESPIRATORY & MUCOUS
MEMBRANE IRRITATION. IF PRODUCT IS MIXED WITH AMMONIA OR OTHER
CHEMICALS,
EVOLUTION OF CHLORINE HYPOCHLORUS ACID RESULTS. THESE GASES CAN
PRODUCE
PULMONA RY EDEMA. CHERONIC: PROLONGED CONDACT MAY PRODUCE DERMATITIS
AND/OR
SENSITIZATION.
Explanation Of Carcinogenicity: SUPPLIER DID NOT INCLUDE THIS FIELD OR
LEFT IT
BLANK.
Signs And Symptions Of Overexposure: EYE CIONTACT:SEVERE IRRITATION.
SKIN:IRRITATION, REDNESS,INFLAMATION. INGESTED:CORROSIVE TO
MOUTH,THROAT,MUCOUS MEMBRANES,AND STOMACH. SEVERE
BURNS,NAUSEA,VOMITING,CIRCULATORY COLLAPSE,CONFUSION,COM A,COLLAPSE.
INGESTION OF LARGE QUANTITIES CAN CAUSE DEATH. EFFECTS OF IRRITATION
INCREASE
WITH STRENGTH OF SOLUTION.
Medical Cond Aggravated By Exposure: NONE SPECIFIED BY MANUFACTURER.
First Aid: EYE:FLUSH W/WATER 15 MIN, HOLD LIDS OPEN. SKIN:WASH WITH
SOAP &
WATER. REMOVE CONTAMINATED CLOTHING AND LAUNDER BEFORE REUSE.
INHALED:REMOVE
TO FRESH AIR. RESTORE BREATHING IF NECESSARY. INGESTED:DO N OT INDUCE
VOMITING. GIVE 2 LARGE GLASSESOF MILK OR WATER AND GET IMMEDIATE
MEDICAL
CARE. DOCTOR TO ORDER VOMITING. NOTHING BY MOUTH IF UNCONSCIOUS. IF
IRRITATION PERSISTS OR IS SEVERE,SEE A DOCTOR.
=======================================================
Handling and Disposal
=======================================================
Spill Release Procedures: WEAR FU7LL PROTECTIVE EQUIPMENT. SMALL SPILL:
MOP OR
WIPE UP AND PLACE IN DOT WASTE CONTAINERS. LARGE SPILLS: CONTAIN BY
DIKING
WITH INERT MATERIAL AND CAREFULLY NEUTRALIZE. KEEP NON-NEUTRALIZED
MATER IAL
OUT OS SEWERS, STORM DRAINS, SURFACEWATERS, .
Neutralizing Agent: DILUTE HYDROCHLORIC ACID.
Waste Disposal Methods: THIS PRODUCT IS TOXIC TO AQUATIC LIFE. CONTACT
ETHE
DISTRICT DIRECTOR OF THE EPA FOR PROPER DISPOSAL INFORMATION.
Handling And Storage Precautions: STORE IN A COOL, DRY WELL-VENTILATED
AREA
AWAY FROM INCOMPATIBLE MATERIALS. STORE @ TEMPERATURES BELOW 85F. DO
NOT
STORE ON OR NEAR WOOD OF ANY KIND.
Other Precautions: DO NOT MIX THIS PRODUCT WITH OTHER CLEANING AGENTS.
THAT MAY
LIBERATE GAS VAPORS. IT IS A VIOLATION OF FEDERAL LAW TO USE THIS
PRODUCT IN
A MANNER INCONSSISTANT WITH ITS LABELING.
=======================================================
Fire and Explosion Hazard Information
=======================================================
Flash Point Text: NON-FLAMMABLE
Autoignition Temp Text: NONE
Extinguishing Media: PRODUCT IS NON FLAMMABLE.
EXTINGUISH FIRE
WITH MEDIA
APPROPRIATE FOR SOURCE OF FIRE.
Fire Fighting Procedures: FIRE FIGHTERS SHOULD USE NIOSH APPROVED SCBA
&
FULL PROTECTIVE EQUIPMENT WHEN FIGHTING CHEMICAL FIRE. USE WATER
SPRAY TO
COOL NEARBY CONTAINERS EXPOSED TO FIRE.
Unusual Fire/Explosion Hazard: CONTAINERS CAN EXPLODE UNDER FIRE
CONDITIONS.
OXYGEN MAY BE LIBERATED UPON CONTACT W/CERTAIN METALS. TOXIC FUMES
ARE
LIBERATED BY ACIDS OR HEAT.
=======================================================
Control Measures
=======================================================
Respiratory Protection: WEAR A NIOSH AAPPROVED RESPIRAATOR APPROPRIATE
FOR THE
VAPOR OR MIST CONCENTARATION AT THE POINT OF USE.
Ventilation: LOCAL MECHANICAL EXHAUST VENTILATION
Protective Gloves: RUBBER
Eye Protection: CHEMICAL GOGGLES
Other Protective Equipment: EYE WASH STATION AND SAFETY SHOWER,
IMPERVIOUS
CLOTHING, LONG SLEEVED SHIRT, TROUSERS, RUBBER APRON.
Work Hygienic Practices: NO INFORMATION GIVEN ON MSDS BY SUPPLIER
Supplemental Safety and Health: HIGHLY EXOTHERMIC REACTIONS WITH
ORGANIC
MATERIAL AND OXIDIZABLE MATERIALS MAY CAUSE FIRE.
=======================================================
Physical/Chemical Properties
=======================================================
HCC: B1
B.P. Text: DECOMPOSES
M.P/F.P Text: 10F,-12C
Decomp Text: UNKNOWN
Vapor Pres: 100F
Vapor Density: 0.9
Spec Gravity: 1.1-1.3
Viscosity: UNKNOWN
Evaporation Rate & Reference: AS WATER
Solubility in Water: 100%
Appearance and Odor: LIGHT YELLOW TO GREEN CLEAR LIQUID;CHLORINE ODOR
Corrosion Rate: UNKNOWN
=======================================================
Reactivity Data
=======================================================
Stability Indicator: YES
Stability Condition To Avoid: EXCESSIVE HEAT, EXPOSURE TO LIGHT, EXCESS
ALKALINITY AND CONTAMINATION OF ANY KIND.
Materials To Avoid: ETHER,AMMONIA ACIDS,REDUCING AGENTS,OXIDIZERS,WOOD,
ORGANIC
MATERIALS,HEAVY METALS AS CU,FE,MG,AL,SN.
Hazardous Decomposition Products: CHLORINE GAS
Hazardous Polymerization Indicator: NO
=======================================================
Toxicological Information
=======================================================
=======================================================
Ecological Information
=======================================================
=======================================================
MSDS Transport Information
=======================================================
=======================================================
Regulatory Information
=======================================================
=======================================================
Other Information
=======================================================
=======================================================
Transportation Information
=======================================================
Responsible Party Cage: 0AN91
Trans ID NO: 53214
Product ID: SODIUM HYPOCHLORITE
MSDS Prepared Date: 12/01/1991
Review Date: 01/27/1998
MFN: 1
Net Unit Weight: 50.0 LBS
Multiple KIT Number: 0
Review IND: Y
Unit Of Issue: CN
Container QTY: 0
Type Of Container: PAIL/CAN
=======================================================
Detail DOT Information
=======================================================
DOT PSN Code: HNU
DOT Proper Shipping Name: HYPOCHLORITE SOLUTION
Hazard Class: 8
UN ID Num: UN1791
DOT Packaging Group: III
Label: 8
Special Provision: B104,N34,T7
Packaging Exception: 154
Non Bulk Pack: 203
Bulk Pack: 241
Max Qty Pass: 5 L
Max Qty Cargo: 60 L
Vessel Stow Req: B
Water/Ship/Other Req: 26
=======================================================
Detail IMO Information
=======================================================
IMO PSN Code: IKL
IMO Proper Shipping Name: HYPOCHLORITE SOLUTION
IMDG Page Number: 8186
UN Number: 1791
UN Hazard Class: 8
IMO Packaging Group: II/III
Subsidiary Risk Label: EMS Number: 8-08
MED First Aid Guide NUM: 741
=======================================================
Detail IATA Information
=======================================================
IATA PSN Code: NYC
IATA UN ID Num: 1791
IATA Proper Shipping Name: HYPOCHLORITE SOLUTION +
IATA UN Class: 8
IATA Label: CORROSIVE
UN Packing Group: III
Packing Note Passenger: 819
Max Quant Pass: 5L
Max Quant Cargo: 60L
Packaging Note Cargo: 821
=======================================================
Detail AFI Information
=======================================================
AFI PSN Code: NYC
AFI Proper Shipping Name: HYPOCHLORITE SOLUTIONS
AFI PSN Modifier: WITH MORE THAN 5% BUT LESS THAN 16% AVAILABLE
CHLORINE
AFI Hazard Class: 8
AFI UN ID NUM: UN1791
AFI Packing Group: III
Special Provisions: P5, N34
Back Pack Reference: A12.3
=======================================================
HAZCOM Label
=======================================================
Product ID: SODIUM HYPOCHLORITE
Cage: 0AN91
Company Name: VAN WATERS AND ROGERS
Street: 2256 JUNCTION AVE
City: SAN JOSE CA
Zipcode: 95131
Health Emergency Phone: 800-424-9300
Label Required IND: Y
Date Of Label Review: 07/13/1992
Status Code: C
MFG Label NO: NONE
Label Date: 07/13/1992
Year Procured: 1992
Origination Code: F
Eye Protection IND: YES
Skin Protection IND: YES
Signal Word: WARNING
Respiratory Protection IND: YES
Health Hazard: Moderate
Contact Hazard: Moderate
Fire Hazard: None
Reactivity Hazard: None
Hazard And Precautions: CORROSIVE, MAY CAUSE SEVERE SKIN IRRITATION OR
CHEMICAL
BURNS TO BROKEN SKIN. CAUSES EYE DAMAGE. MAY BE FATAL IF SWALLOWED.
AVOID
BREATHING VAPORS. DO NOT GET IN EYES, ON SKIN OR CLOTHING. WEAR
GOGGLE S WITH
FACE SHIELD AND RUBBER GLOVES WHEN HANDLING THIS PRODUCT. WASH HANDS
AFTER
HANDLING. VACATE POORLY VENTILATED AREA AS SOON AS POSSIBLE. DO NOT
RETURN
UNTIL ODORS HAVE DISSIPATED. SRTONG OXIDIZI NG AGENT. MIX ONLY WITH
WATER
ACCORDING TO LABEL DIRECTIONS. STORE IN A COOL, DRY WELL-VENTILATED
AREA AWAY
FROM INCOMPATIBLE MATERIALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT
IN USE.
USE AS SOON AS P OSSIBLE. KEEP OUT OF WATER SOURCES. TOXIC TO FISH.
=======================================================
Disclaimer (provided with this information by the compiling agencies):
This
information is formulated for use by elements of the Department of
Defense.
The United States of America in no manner whatsoever expressly or
implied
warrants, states, or intends said information to have any
application, use or
viability by or to any person or persons outside the Department of
Defense
nor any person or persons contracting with any instrumentality of the
United
States of America and disclaims all liability for such use. Any
person
utilizing this instruction who is not a military or civilian employee
of the
United States of America should seek competent professional advice to
verify
and assume responsibility for the suitability of this information to
their
particular situation regardless of similarity to a corresponding
Department
of Defense or other government situation.