Chemistry 11 Final Exam Review Unit 6 Chemical Reactions 1. How can you tell that a chemical reaction has occurred? ________________________________________________________________________ ________________________________________________________________________ 2. What is the Law of Conservation of Mass? ________________________________________________________________________ ________________________________________________________________________ 4. How can you tell that a chemical equation is balanced? ________________________________________________________________________ ________________________________________________________________________ 3. 4. Balance the following chemical reactions: A. ___ Si4H10 + ___ O2 ___ SiO2 + ___ H2O B. ___ Ca3(PO4)2 + ___ SiO2 + ___ C C. ___ C3H7N2O7 + ___ O2 ___ CaSiO3 + ___ CO + ___ P4 ___ CO2 + ___ H2O + ___ N2 Write and balance the following word equations: A. Aluminum + Copper (II) sulphate Aluminum sulphate + Copper __________________________________________________________________ B. Magnesium nitride + Water Magnesium hydroxide + Ammonia (NH3) __________________________________________________________________ C. Calcium hydroxide + Ammonium chloride Water Ammonia + Calcium chloride + __________________________________________________________________ Final Exam Review.doc 1 Chemistry 11 5. 6. Final Exam Review Complete and balance the following reactions and classify each equation as one of: synthesis, decomposition, single replacement, double replacement, neutralization or combustion. A. ___ HF + ___ Fe(OH)3 B. ___ FeCl2 + ___ K2S C. ___ Al + ___ S8 D. ___ N2O E. ___ C3H6OS2 + ___ O2 F. ___ Mg + ___ HCl ____________________________________________ ______________________________________________ __________________________________________________ _______________________________________________________ ____________________________________________ _______________________________________________ Define the terms: A. Exothermic __________________________________________________________________ __________________________________________________________________ B. Endothermic __________________________________________________________________ __________________________________________________________________ 7. Classify the following is exothermic or endothermic: A. 2Na + 2H2O B. KClO3 + 41.4 kJ C. C2H6 + O2 D. 12CO2 + 11H2O Final Exam Review.doc 2NaOH + H2 + 283 kJ K+ + ClO3– CO2 + H2O ∆H = – 3718 kJ C12H22O11 + 12O2 ∆H = +5638 kJ 2 Chemistry 11 Final Exam Review Unit 7 Stoichiometry 1. Whst are are limiting and excess reactants? ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ ________________________________________________________________________ 2. Consider the reaction: 4C4H9SO2 + 25O2 A. 16CO2 + 18H2O + 4SO2 How many oxygen molecules react with 20 molecules of C4H9SO2? __________________________________________________________________ B. How many moles of C4H9SO2 are required to produce 100 moles of water? __________________________________________________________________ C. What mass of SO2 is formed when 50.0 g of C4H9SO2 is reacted? __________________________________________________________________ 3. A 25.0 mL sample of Al(OH)3 is titrated with 67.8 mL of 0.450 M HCl according to the reaction Al(OH)3 + 3HCl AlCl3 + 3H2O What is the concentration of the original Al(OH)3 solution? Final Exam Review.doc 3 Chemistry 11 4. Final Exam Review What mass of CS2 is produced when 25.8 g of C are reacted with 54.2 g of SO2 according to the equation 5C + 2SO2 5. CS2 + 4CO A. What mass of CS2 is produced? B. What mass of the excess reactant will be left over? Consider the reaction K2Cr2O7 + 6NaI + 7H2SO4 Cr2(SO4)3 + 3I2 + 7H2O + 3Na2SO4 + K2SO4 A 35.0 g sample of pure K2Cr2O7 produces 9.67 g of H2O. What is the percentage yield? Final Exam Review.doc 4 Chemistry 11 Final Exam Review Unit 8 Atoms, Periodic Table, and Bonding 1. 2. Which model of the atom is described by the following: A. Dense positively charged nucleus with electrons orbiting like planets around the sun. B. Correctly predicts the spectrum of hydrogen. C. Plum pudding model. D. Atoms are like small spherical balls of matter. Fill in the following table: SYMBOL PROTONS NEUTRON ELECTRONS Rh 107 Pd2+ 123 3. 4. Sb3– 93 89 50 46 Write the electron configurations for the following: (a) Mo (b) Bi (c) Bk (d) Ag+ (e) As3– (f) Pb4+ State the chemical family or group to which each of the following elements belongs. (a) silver (d) xenon (g) silicon (b) calcium (e) potassium (h) promethium (c) iodine (f) californium (i) tungsten Final Exam Review.doc 5 Chemistry 11 5. 6. Consider the two atoms Sn and I. (a) Which atom has the larger atomic radius? (b) Which atom has the larger ionization energy? (c) Which atom has more shells? (d) How many valence electrons each atom have? (e) What is the valence of each atom? (f) Which atom has a greater electrostatic attraction between its nucleus and outermost electrons? Which of the following pairs would you expect to form ionic bonds and which would you expect to form covalent bonds? (a) 7. Na and O (b) H and C (c) N and F Which member of each following pair would you expect to have the higher melting point? (a) 8. Final Exam Review MgO and CsCl (b) LiF and BeO (c) MgS and BaS (c) PF5 Predict the shape of the following molecules. (a) NCl3 Final Exam Review.doc (b) H2O 6 Chemistry 11 Final Exam Review Unit 10 Organic Chemistry 1. Name the following compounds: A. C—C—C—C—C—C—C—C | C—C—C—C B. C—C | C—C C—C—C—C—C—C | | C—C—C C—C __________________________________ __________________________________ C. D. Br F C—C—C | | | C—C—C—C—C—C—C—C | | | Br F C—C F F | | C—C—C—C—C—C | F C—C __________________________________ __________________________________ E. F. C—C—C—C | Br \ C—C—C—C—C—C / —C—C—C—C \ C—C—C __________________________________ 2. | Br __________________________________ Draw the following compounds (draw carbon skeletons only). A. 2,2,4,4–tetramethylheptane B. 3,4–diethyl–3–methyl–1–heptyne Final Exam Review.doc 7 Chemistry 11 3. 2. 3. Final Exam Review Draw the following compounds (draw carbon skeletons only). A. 1,3–dipropylcyclopentane B. 1,1,1–trifluoro–2–methylpentane Draw the following compounds A. 3–methyl–1–hexanol B. 4,4–dimethylheptanoic acid C. methyl pentanoate D. 2–methylbutanal Name the following geometric isomers (remember to include cis or trans as appropriate) A. C—C—C C—C \ / C=C / \ C C—C—C __________________________________ Final Exam Review.doc B. C—C—C \ C=C C—C / \ | C C—C—C—C __________________________________ 8 Chemistry 11 4. Final Exam Review (A) Name the functional groups and (B) Name the compounds: Carboxyllic acid Ester Aromatic ring Halide Alcohol Aldehyde Ketone Ether Amine Amide A. C–C–C–C–C–C–O–C–C B. O || / C \ C–C–C ________________________________ ________________________________ C. D. F–C–C = C–C–C–C–F | C F C | | C–C–C–C–C–C–CO–C–C | | C C ________________________________ ________________________________ E. F. –CHO C C O | | || C–C–C–C–C–C–C–C–C | | C C–C–C ________________________________ ________________________________ G. H. C–C–C–C–C–COO–C C–C–C–C–C–C–C–NH2 | | NH2 NH2 ________________________________ ________________________________ I. J F | C–C–C–C–C–C–C–COOH | | F C ________________________________ Final Exam Review.doc OH | | C | C ________________________________ 9