1 PM1 ELASTICITY The lion is the king of beasts And husband of the lioness. Gazelles and things on which he feasts Address him as Your Lioness There are those who admire that roar of his In the African jungles and veldts. But I think wherever the lion is I'd rather be somewhere else. OBJECTIVES Aims In this chapter you will see that all elastic deformations can be described in terms of linear, shear and bulk changes. You will be introduced to the concepts of stress, strain and material strength. You will apply these ideas to some real-world deformations. You will learn how to do calculations involving simple situations of deformation. Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1. Explain, interpret and use the terms elastic deformation, plastic flow, permanent set, ductile, brittle, compressive, tensile, linear!extension, uniform compression, shear, pressure, fracture, stress, strain, elastic!modulus, Young's!modulus, shear modulus, bulk modulus, strength, elastic limit. 2. (i) Recall and state Hooke's Law. (ii) Use the relations between the three elastic moduli and stress and strain in simple numerical problems. 3. Recall that the elastic moduli have dimensions of force per area. 4. Use a model of the microscopic structure of materials to explain elastic behaviour. 5. (i) Describe the experimental measurement of elastic moduli by direct determinations. (ii) Use mechanical oscillations to measure elastic moduli indirectly. 6. Describe situations involving strength and/or deformation in the human body and in fibrous materials. PRE-LECTURE 1. In mechanics, forces acting on an extended body are assumed to produce only translational and/or rotational accelerations of the body: the body is assumed to be rigid. However, no body is completely rigid: forces also deform bodies. 2. Remember that pressure is defined as force per area. 3. Refer back to chapter FE3 and/or chapter FE5, where inter-molecular forces are discussed in terms of the distance between molecules. 2 PM1: Elasticity LECTURE 1-1 STRESS, STRAIN AND THE BASIC DEFORMATIONS. The study of elasticity is concerned with how bodies deform under the action of pairs of applied forces. In this study there are two basic concepts: stress and strain. The pairs of forces act in opposite directions along the same line. Thus there is no resulting acceleration (change of motion) but there is a resulting deformation or change in the size or shape of the body. This is described in terms of strain. The strain is the relative change in dimensions of a body resulting from the external forces. As a result of the deformation, internal forces are set up and these give rise to stresses. In many simple cases, these stresses are simply related to the external forces, because when these two are in balance the deformation will be maintained without further change. For these simple cases we make the following definition. The stress is the external force divided by the area over which this force is applied. There are three particular cases we will consider. Linear Extension Demonstration The first type is the linear extension. An oppositely directed pair of forces along a line extend the body in along that line. Write the magnitude of these forces as F , the cross-sectional area at right angles to F as A, the original length as L and the extension as e. The stress and strain are then defined as follows: F Stress = F/A Strain = e/L L A e F Fig 1.1 Definitions of stress and strain (linear extension) 3 PM1: Elasticity Uniform Compression Demonstration If the forces are applied uniformly in all directions, we have a deformation typified by that produced by a uniform hydrostatic pressure. Write the pressure as p, the original volume as V and the change in volume as DV. The stress and strain are then defined as follows: Stress = p Strain = - DV/V (the significance of the minus sign is that the volume decreases as the pressure increases) p Fig 1.2 Definitions of stress and strain (uniform compression) Shear Demonstration In the previous two deformations, either the length or volume of a body was changed. In the shear deformation, only the shape of a body is changed. Shear occurs for example when oppositely directed tangential forces are applied across opposite faces of a rectangular block of material. These forces deform the rectangular block into a parallelogram. Write the force as F, the area across which the force is applied as A and the angle of deformation (specified in the diagram) as q. The stress and strain are then defined as follows. Fig 1.3 Definitions of stress and strain (shear deformation) These three deformations are the three basic types. PM1: Elasticity In general, things are more complicated than this but can be resolved in terms of these basic deformations. Demonstration As an example of the more complicated behaviour one can get, consider a rod under the action of a compressive force in the direction of the rod. Fig 1.4 Buckling of a rod as a result of an applied linear compression If there are no complications, this is merely the opposite of the linear extension. However, if the rod is thin enough, one does not get a linear compression but rather the rod buckles. 1-2 ELASTIC AND NON-ELASTIC BEHAVIOUR Let us now consider what happens to a body under the action of one of these types of deforming force as the force is gradually increased from zero. Demonstration This was done for the case of linear extension using one of the testing machines in the Civil Engineering Department. A sample of mild steel was tested and the stress as a function of strain was recorded on a chart recorder. The complete stress-strain curve was as follows: Fig 1.5 A stress/strain curve As the stress was increased it was at first proportional to the strain; if, in this region, the stress were removed, the strain would return to zero i.e. the body would return to its original length. This region OP is known as the elastic regime and the point P is called the elastic limit. 4 5 PM1: Elasticity As the stress was further increased, a point Y, known as the yield point, at which the stress rapidly dropped, was reached. From J to K the material flowed like a fluid; such behaviour is called plastic flow. After a region K to L of partial elastic behaviour, plastic flow continued from L to M . Eventually (when the point B was reached) the material fractured. It should be noted that once the material was taken out of the elastic regime (into the non-elastic regime, where plastic flow occurred) the body suffered a permanent deformation or permanent set, i.e. removal of the stress did not reduce the strain to zero. The behaviour described above for mild steel is not typical of all materials. Materials that behave approximately like this, showing elastic behaviour and plastic flow, are called ductile. Demonstration Other materials, such as concrete, do not flow plastically; such materials are called brittle. 1-3 HOOKE'S LAW and ELASTIC MODULI As we have seen, when a material is stressed there are basically two different regimes: the elastic and the non-elastic. The latter is difficult to describe in a way which is easily applicable but in the former the stress is proportional to the strain. This proportionality between stress and strain is known as Hooke's law; it applies to all of the three basic deformations. Hence the ratio stress/strain is a constant; this constant is known as the elastic modulus. There are three elastic moduli, one for each of the three basic deformations. Linear Extension Stress F/A = Strain e/L = Y named Young's modulus Uniform Compression Stress Strain = -P DV/V = pV - DV = k named bulk modulus Shear Stress Strain F/A = q = F Aq = n named shear modulus or modulus of rigidity << There is one other parameter which is necessary to describe the elastic behaviour or materials. This is Poisson's ratio. When a body is linearly extended, it contracts in the direction at right angles. Poisson's ratio, s, is the ratio of the lateral strain to the longitudinal strain. Fig 1.6 Poisson effect: Contraction of rod in direction transverse to the direction of the applied stress >> A Microscopic Model The values of the various parameters we have defined must depend on the microscopic structure of the material. In the unstressed state the atoms or molecules are in equilibrium positions, such that if PM1: Elasticity they are pulled apart the forces between them are attractive and if they are pushed together the forces are repulsive. Where these forces as a function of distance between the atoms or molecules are known, one could, in principle, calculate the elastic moduli. Such calculations can and have been made, particularly for crystals, where there is a regular array of atoms. However, the values obtained are always too high, due to the presence, in even the purest crystals, of imperfections such as dislocations and impurity atoms. 1-4 EXPERIMENTAL MEASUREMENT OF ELASTIC MODULI The elastic moduli can be determined in two basically different ways. The most direct way is to use one of the engineering-type machines you have seen and to measure the strain appropriate to different stresses. An alternative method is to make use of the fact that the mechanical oscillations of bodies and the characteristics of pressure waves propagating through them depend on the elastic moduli. Demonstration 1. Fig 1.7 Oscillations of a coiled spring: shear modulus The frequency of oscillation of a coiled spring is determined by the shear modulus of the material of which it is made. 2. Fig 1.8 Oscillations of a cantilever: Young's modulus The oscillations of a cantilever are determined by its Young's modulus. 6 PM1: Elasticity 7 3. Fig 1.9 Torsional oscillations: shear modulus The torsional oscillations of a rod are determined by its shear modulus. This alternative method can be particularly useful when it is not possible to obtain a sample suitable for the test machines. Investigations of possible changes in the elasticity of bones in the body with age and disease have been made, for example, by setting the bones into oscillation and measuring the oscillation frequencies. The propagation characteristics of a pressure wave are determined by the bulk modulus of the material in which it is propagating. This will be discussed in more detail in the lecture on sound (chapter PM7). A table of the elastic moduli of various materials is included in the post-lecture material. 1-5 APPLICATIONS Repair of the Human Body Many materials are used in the repair of the body. The prime consideration in these applications is that the materials be strong enough. External to the body there are, for example, artificial limbs, and internal to the body there are, for example, plates used for repairing fractures. In these latter applications the materials must also be bio-compatible as well as strong enough. The strength of a material is defined as that stress which causes the material to break. For some materials this breaking stress will be different under compression (compressive strength) than under tension (tensile strength) or under shear (shear strength). Demonstration An example of a material used for repair of the body is material used for filling teeth. One such material is "composite". This is a polymer mixed with quartz and is quite strong in compression, as it must be, since large compressive stresses are experienced in biting. Its compressive strength is about 2.5 ¥ 108 Pa which compares favourably with that of tooth enamel viz 4 ¥ 108 Pa. Since as well it looks like tooth enamel, it is a very suitable material for anterior fillings. If the strength of a material is exceeded it will fail. It is interesting that a material can fail at stresses much less than this if the stress is applied and removed a large number of times. This phenomenon is known as fatigue. Demonstration Dentures for example can fail by fatigue. Bones etc. as Structural Elements The basic point in designing any element to withstand stress is to properly assess what the stresses are. The element is then designed so as to withstand these stresses without being unnecessarily big. Weight bearing structures which occur in nature are of good design. Of particular interest in this regard are trees. These are basically columns and are in a state of compression due to their own weight. One might think that their heights would be limited only by the requirement that the compressive strength be not exceeded; thus no relationship between height and diameter would be expected. PM1: Elasticity This, however, is not the case. A column fails not by compression but by bending. Failure occurs when the tree's length becomes too great in comparison with its diameter. Demonstration Fig 1.10 Bending of a column To prevent this failure by bending the diameter should increase as the 3/2 power of length. This is observed on average for trees. Demonstration Scaling, with this same relation, is also observed for bones of animals. Scaling is not the only good design feature found in bones. Demonstration For a given weight/unit length, beams of cross-section such as these Fig 1.11 I-shape and tube-shape beams are much stronger against bending than solid beams such as this. Fig 1.12 Solid beams Demonstration Many bones indeed are of tubular shape. In others their good design leads to the bone being arranged differently: it is all a matter of the nature of the stresses. For example, in the top of the femur, the bone is arranged in thin sheets separated by marrow, the sheets being so arranged to give the greatest strength when the bone is experiencing those forces to which it is normally subjected. Demonstration No matter how well-designed bones are, they will fracture when the strength of the bone material is exceeded. This is most likely to happen when the bone is stressed in a direction other than usual i.e. when it is stressed in a way for which it was not designed. 8 9 PM1: Elasticity Fibres The elastic properties of bone and timber are different in different directions. This is so because these materials are fibrous. There are many fibrous materials in nature. One important class of fibres are those used in making textiles: the natural fibres wool and cotton and the various synthetic fibres. The elastic properties of these fibres is obviously important in that they determine the properties of the textiles made from them. Demonstration As an example of these properties, the stress-strain curve for a wool fibre in tension is given. D Stress B O C A Strain Fig 1.13 Stress-strain curve for wool fibre The narrow region OA corresponds to the "crimp" in the fibre being removed. This region is followed by a linear region AB. As the stress is further increased the curve flattens out into the region BC. If the stress is removed in this region the strain returns to zero. Therefore this region does not correspond to a region of plastic flow, as for steel. It results from the long keratin molecules, of which the fibre is composed, changing from a coiled shape to a more extended one. With further stress, the curve again rises and finally the fibre ruptures at the point D. Arteries and the Lung Strong fibrous materials, such as bone, are common in the body. There are other materials in the body where strength is not the important thing but stretchability. The walls of the arteries fall into this category. It is only because they are elastic that the blood flow is smooth. Demonstration As the heart pumps, the pressure in the arteries increases and the artery walls stretch. When the aortic valve shuts and the pressure in the arteries drops, the walls relax maintaining the blood flow. The hardening of the artery walls, which occurs with age, inhibits this process. The elasticity of the lung tissues plays a very significant part in respiration. Muscular effort is required in inspiration to extend the lungs but expiration is mainly due to the relaxing of the stretched tissues. Demonstration The stretching can be shown by measuring the pressure to fill the lungs with air. If the lungs are filled with saline solution, a much lower pressure is required. This difference is because forces associated with surface tension play a large part in the operation of the lung; when the lung is filled with saline solution these forces do not act. If the lung is washed out with kerosene and the experiment of inflation with air is repeated, it is found a much higher pressure is required than before. The kerosene washes out a chemical known as "surfactant" which regulates the surface tension. When surfactant is present it decreases the surface tension during inspiration. (This will become clearer after the surface tension lecture - PM2 - when more details will be given.) 10 PM1: Elasticity Muscle and Skin Demonstration Other tissues in the body where stretchability is important are muscle and skin. decreases noticeably with age. The skin's elasticity POST-LECTURE 1.6 UNITS You will have noticed that in the television lecture, on occasions, units other than SI. units have been used. The correct unit, as agreed by the International Conference on Weights and Measures, for stress (or strength, or any of the elastic moduli) is the pascal (Pa). That unit is used exclusively in these notes. 1.7 TABLES The calculated values are based on microscopic models. The lack of correspondence is the result of dislocations and impurity atoms. TENSILE STRENGTH / 108 Pa MATERIAL THEORETICAL rock salt (NaCl) 2.7 iron 46 cellulose 11 OBSERVED 0.004 1.0 2.0 14.0 1.0 (bulk material) (single crystal) (bulk) (single crystal) (fibre) For liquids and gases the shear modulus is zero; for liquids the bulk modulus is about the same value as for solids but it is much smaller for gases. SUBSTANCE aluminium Y/1010 Pa 7.05 k/1010 Pa n/1010 Pa 7.46 2.67 steel 19 - 21 16.4 - 18.1 7.9 - 8.9 glass (crown) 6.5 - 7.8 4.0 - 5.9 2.6 - 3.2 water 0.2 0 mercury 2.1 0 0 air (atmospheric pressure) 1.4 ¥ 10-5 1.8 TENSILE AND COMPRESSIVE MODULI A crystalline solid exhibits the same stress vs. strain relation whether it is under tension or compression. On the other hand, bone and other biological materials show different behaviour under tension and compression. 11 PM1: Elasticity 1.10. PROBLEMS Q1.1 The effective cross sectional area of a horse's femur (leg bone) is 7.0 ¥ 10-4 m2 and the Young's modulus of this bone is 8.3 ¥ 109 Pa. Calculate the strain that occurs in the femur when the horse (mass ~ 600 kg) puts its full weight on one leg. Q1.2 0.10 mm 5.0 mm F 500 mm 500 mm F Fig 1.14 Diagram for Q1.2 The square brass plate shown is sheared to the position of the dotted lines by the forces F. The distortion is exaggerated, for clarity, in the diagram. Calculate the magnitude of these forces. The shear modulus of brass is 3.5 ¥ 101 0 Pa. Q1.3 By what fraction does the density of water at a depth where the pressure is 4 ¥ 105 Pa increase over the surface density. The bulk modulus of water is 2 ¥ 109 Pa. 12 PM2 SURFACE TENSION The swan can swim while sitting down, For pure conceit he takes the crown, He looks in the mirror over and over, and claims to have never heard of Pavlova. OBJECTIVES Aims In this chapter you will look at the behaviour of liquid surfaces and the explanation of that behaviour both in terms of forces and in terms of energy. The principle of minimum potential energy can be invoked to explain many surface phenomena Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1. Explain, interpret and use the terms intermolecular forces, capillarity, angle of contact, wetting. 2 (i) Describe an experimental determination of the surface tension of a liquid by the measurement of the force on a glass slide in contact with the liquid. (ii) 3 Perform simple numerical calculations associated with such a determination. (i) Use a model of the microscopic structure of liquids to explain the phenomenon of surface tension in terms of potential energy. (ii) Extend this argument to explain why liquids tend to assume a shape which minimises the surface area of the liquid. (iii) Do simple numerical calculations associated with energy per area. 4 (i) Explain how the surface tension of a liquid can be measured either in terms of force per length or of energy per area. (ii) Demonstrate that these two descriptions are dimensionally equivalent. 5 (i) Explain how the phenomenon of capillarity results from forces between solid (e.g. glass) and liquid (e.g. water) molecules. 2T (ii) Recall, explain and use the relationship h = rgr for capillary rise. 6 Give examples of how the wetting characteristics of surfaces can be altered. 7 Explain, by identifying the relevant forces and using scaling arguments, why insects can walk on water but larger animals cannot. 8 Recall that the surface tension of water has a magnitude of 0.1 N.m-1. PM2: Surface Tension 13 PRE-LECTURE Recall from earlier lectures, particularly chapters FE2 and FE3 the following facts about the general nature of forces. (i) The molecules of any substance - solid, liquid or gas - attract one another if they are far apart; at short distances, the intermolecular force is repulsive. There is a crossover point where the force is zero - neither attractive nor repulsive. (ii) When a system is in equilibrium, then the sum of all the forces acting on the system is zero. In particular, the molecules of a substance tend to come together (pulled by the intermolecular attraction) until on the average their distances apart correspond to the cross over point between attraction and repulsion. This means the normal state of a substance is an average kind of equilibrium. (iii) Equilibrium can be discussed in terms of potential energy. The equilibrium configuration is one in which the potential energy is least. For a simple two body system you can see this by considering the diagrams on pages 17 and 59 of the Forces and Energy book. LECTURE 2-1 PHENOMENON OF SURFACE TENSION The surface of any liquid behaves as though it is covered by a stretched membrane. Small insects can walk on water without getting wet. Demonstration The membrane used is obviously quite strong: it will support dense objects, provided they are small and of the right shape: a needle, a small square of aluminium sheet (weighted), a container made of fine wire gauze. The strength of the membrane varies for different liquids, e.g. it is much less for soapy water than pure water. Demonstration Ducks swim on water without getting very wet. However, they cannot swim on soapy water. [There are cases on record where ducks have drowned in farmyard ponds into which washing water was emptied, or in streams polluted with non degradable detergents.] 2-2 MEASUREMENT AND DEFINITION OF SURFACE TENSION The strength of the surface membrane can be imagined to arise from a set of forces acting on each point of the surface, parallel to the surface, like the skin of a drum. 14 PM2: Surface Tension Demonstration The easiest way to measure these forces is with the following apparatus BALANCE ADJUSTABLE WEIGHT AND SAND GLASS SLIDE FIXED COUNTER WEIGHT WATER Fig 2.1 Experimental measurement of surface tension Note that because the water surface curves up near the glass slide the surface tension forces between the glass and the water are vertical rather than horizontal. SLIDE MENISCUS WATER Fig 2.2 Shape of liquid meniscus A first experiment yielded this result: A certain amount of sand (weight, W) was needed to keep slide just in contact with water; when the water was removed this amount of sand plus a 0.55 g (extra weight 5.4 mN) was needed to have the slide in the same position The difference, 5.4 mN, is a measure of the force due to the pull of the water on the slide. A second experiment tested whether the force depended on the length of the slide (recall that on the surface of a drum, a bigger cut is harder to repair than a smaller one). Length of slide used in first experiment: 38 mm Length of slide used in second experiment: 76 mm Result of second experiment: the force due to the pull of surface increases to 10 mN Deduction: The force which a liquid surface exerts on any body with which it is in intimate contact (as described above) is directly proportional to the length of the line of contact. Force = T ¥ length. The constant of proportionality, T, is called the surface tension of the liquid. PM2: Surface Tension 15 Demonstration In the second experiment the width of the slide was 1 mm, so the total length of the line of contact between the glass and the water was (76 + 1 + 76 + 1)mm. These values give a value for the surface tension of water of 0.06 N.m-1. [Most books of tables quote 0.07 N.m-1.] Other liquids have different surface tensions (see post lecture material). Demonstration A little detergent added to the water lowers it surface tension considerably. As defined here the dimensions of surface tension are force per length. Its units in the S.I. system are N.m-1. 2-3 MICROSCOPIC EXPLANATION AND SURFACE ENERGY To understand why the phenomenon of surface tension arises, you must think of intermolecular attraction as recalled in the pre-lecture material. Molecules of any substance want to pack together so that their average separation is low. In solids, this separation is fixed, whereas in gases, the random motion due to heat predominates. In liquids, there is some random motion but, on the average, the molecular separation is low. Consider a fixed number of liquid molecules. If they are packed so that they have a large surface area, their average intermolecular separation is relatively high. If they have small surface area, the average intermolecular separation is relatively low. Their total potential energy is lower in the latter case. A logical conclusion from this is that energy has to be added in order to increase the surface area of a liquid. The bigger the change in surface area, the more energy has to be put in. Associated with the surface there is a potential energy that depends on the area of the surface. This means that an alternative approach is to consider surface tension as an energy per surface area. Since the equilibrium configuration of any system is that in which the potential energy is least, a liquid left to itself will assume a shape which minimises surface area, thereby minimising the total surface potential energy. Demonstration Drops of water are spherical Loop of thread on water; detergent added inside loop; loop takes a circular shape. LOOP OF THREAD CONTAINER PURE WATER WATER AND DETERGENT Shaded area here is greater than shaded area here Fig 2.3 Effect of placing a drop of detergent inside a loop of string that is floating on the surface of water (Surface tension of detergent and water is much lower than that of water.) PM2: Surface Tension energy force The dimensions of energy are force ¥ length, so area has the same dimensions as length . Sometimes it is easiest to explain surface phenomena in terms of energy considerations, sometimes in terms of force considerations Demonstration Three matches on water: CONTAINER MATCHES DETERGENT ADDED becomes PURE WATER Fig 2.4 Effect of placing a drop of detergent inside a triangle of matches that are floating on the surface of water This is basically the same as the loop of thread demonstration, but it is easier to explain why each match moved in terms of forces as thus for the match at the top of the diagram: larger force (water: higher surface tension) smaller force (detergent: lower surface tension) Fig 2.5 The net force acting on the match pushes it away from the detergent 2-4 CAPILLARITY A consequence of the phenomenon of surface tension is that many liquids will "creep up" tubes, an observation made readily with glass tubes of very narrow bore. h WATER (DYED) Fig 2.6 Capillary rise The height of the water in the capillary above the level of the liquid in the surrounding liquid, as indicated by h in the diagram, is called the capillary rise. 16 17 PM2: Surface Tension Demonstration Glass tube of narrow bore in water. It can be demonstrated that: (i) the capillary rise is larger for liquids of higher surface tension than of lower surface tension (e.g. larger for pure water than for water and detergent) ; (ii) the height increases as the radius of the bore of the tube gets smaller. In fact, the height varies inversely as r. Demonstration Glass wedge in water: ELEVATION PLAN HYPERBOLIC !! !SHAPE TWO GLASS SHEETS WIDE END NARROW END RUBBER BAND WATER (DYED) Fig 2.7 The rise of water in a wedge between two flat glass sheets (iii) We would like to have shown that height decreased with increasing density, but we could not find two common liquids with roughly the same surface tension and vastly different densities. The relation between capillary rise, surface tension and density (see post lecture) is 2T h = rgr The tube used in the demonstration had a bore of radius 0.50 mm and the measured rise was 28!mm. For a tube of this radius, the calculated rise is 2!¥ !0.06!N.m-1 h = 1!¥ !103 !kg.m-3!¥ !9.8!m.s-2!¥ !0.50!¥ !10-3!m = 2 cm. Specific Applications: (i) Rise of water through soils. Demonstration Although water rising in a column of soil is not rising through a tube of uniform bore it is moving through spaces roughly the same size as the soil grains. So the same kind of capillarity formula will apply. A consequence is that water rises highest in column with finest grains. [Note water rises fastest in column with largest grains. We return to this in the post lecture of chapter PM4.] (ii) Chromatography. Demonstration This is a method of chemical analysis which can be done by eye. See post lecture material for a more careful description. 18 PM2: Surface Tension 2-5 WETTING A question we have skimmed over is: why is there an attractive force between water and glass causing the rise of water in a glass capillary tube? This is a question about intermolecular forces which only chemists can answer properly. But certainly different liquids are attracted to different solids in different degrees. For example, the level of mercury will fall in a glass capillary tube. Demonstration Drops on solid surfaces. WATER MERCURY WATER GLASS MERCURY LEAD Fig 2.8 Water and mercury drops on glass and lead surfaces Laboratory workers measure the intersurface forces in terms of the angle of contact defined as follows. tangent ANGLE OF f line CONTACT Fig 2.9 Definition of f, the angle of contact between a liquid and a solid surface The concept of angle of contact is treated further in the post lecture. This phenomenon is called wetting. Water is said to wet glass completely (the angle of contact is virtually zero). The wetting characteristics of surfaces can be changed by putting a layer of a different material on the surface. Demonstration Oil on glass will repel water. WATER OIL GLASS Fig 2.10 The presence of oil results in the water forming a drop rather than spreading over the glass surface Demonstration Waterproofing of material (this usually involves coating fibres with oil or polymers). Demonstration Preening of birds. Water birds spread oil on their feathers to make them water resistant. Demonstration Water resistant sands. Some West Australian sands are virtually impervious to water as a result of fibrous material between the grains making them water resistant. This leads to bad run off conditions in vast areas of the state. 19 PM2: Surface Tension Detergents The properties of detergents arise from their complicated molecular structure. This can be illustrated schematically thus: This end is repelled by water molecules [hydrophobic] and is This end is attracted to water attracted to oils, fats [lipiphilic] molecules [hydrophilic] H (i) H H H H H H H H H H H C C C C C C C C C C C H H H H H H H H H H H O C O- Fig 2.11 A detergent molecule When detergent is put into water this happens: Fig 2.12 Detergent molecules in water (schematic) Note that along the surface there are water molecules and hydrophobic ends. The surface tension is lower than that of pure water. It is easier to pull this surface apart than it is to pull a surface of pure water apart (ii) In washing up water the following sequence occurs as the water is stirred up. grease water DETERGENT ADDED Fig 2.13 Stirring of soapy water during "washing up" STIRRED 20 PM2: Surface Tension The particles of organic matter are rendered soluble by being coated with detergent molecules: lipophilic ends stick to the particles and hydrophilic ends point outwards. Emulsification. Many organic substances which are insoluble in water (DDT is a good example) can be mixed into an emulsion with water by the addition of a little detergent. Demonstration Oil and water. POST-LECTURE 2-6 UNITS AND DIMENSIONS A couple of statements were made (or implied) in 2-3 above, which may not be all that obvious. Q2.1 The loop of thread changed its shape to a circle because a circle is the geometrical shape which has maximum area for a fixed circumference. This is not easy to prove in general but consider the following concrete example: assume that the length of thread in the loop was 0.l!m and work out which, of the following possible shapes the loop could have, has the largest area. 2.5 cm 1 cm 2.5 cm 3.3 cm 3.3 cm 4 cm 3.3 cm 3.2 cm Fig 2.14 Diagram for Q2.1 Q2.2 Energy/area is the same as force/length. The following example illustrates this fact. Imagine you are increasing the area of a rectangular soap film; as indicated the original dimensions of the film are a and Ú. The surface tension of the soapy water is T. a Ú F Fig 2.15 Diagram for Q2.2 PM2: Surface Tension 21 Suppose that to stretch the film at a constant speed a uniform force F equal (and opposite) to the force associated with surface tension is applied. Since the film has two surfaces, the relation between F and T is F = 2Ú T . Calculate the total work done in increasing the distance a by an amount b, and show it is proportional to the change in area of the soap film. 2-7 MORE ON CAPILLARITY The law quoted in 2-4 can be derived theoretically as follows. Ask yourself first, why should water rise up inside the tube? It is an effect of the surface tension at the top of the water column, particularly where it meets the glass wall. Glass molecules Water molecules Fig 2.16 Interaction of water and glass molecules Each water surface molecule exerts forces on those near it Since there is equilibrium the last water molecule must also have a force exerted on it by the glass molecule near it. Therefore, all around the top of the water, the glass is exerting a force on the water. Because is so happens that water wets glass so well, this force is a vertical force. So that it why the water rises in the tube: because the glass is pulling it up. The length of the line of contact between the water and the glass is 2p times the radius of tube, so the magnitude of the upward force is: = T ¥ (2p radius of tube) = 2 p rT. The next question is: why does not the water keep rising indefinitely? The answer is that the higher the column the more the weight of the water in the column pulls it back. Thus there is a downward force equal to r (pr2h) g. The two forces are in equilibrium so 2prT = rπr2hg and, therefore, for this situation, where the water wets the glass completely, the final height of the water column can be written 2T h = rgr Q2.3 In the experiment with soil, we found that for the coarse grained soils (radius of soil grains ~ 0.3!mm) after a long time the water finally stopped rising at a height of ~ 150 mm. Although soil is by no means a series of uniform bore capillary tubes, it cannot be too bad an approximation to apply the above relation. Apply the relation and find how much error is in fact introduced. PM2: Surface Tension 2-8 ANGLE OF CONTACT The angle of contact is defined to be the angle between the surface of the liquid and the solid surface at the point of contact. tangent ANGLE OF f line CONTACT Fig 2.17 Angle of contact for a liquid that does not "wet" the solid surface You will observe that for a water-glass contact, as in the next diagram, the angle of contact is much smaller; angle of tangent contact line small f Fig 2.18 Angle of contact for water-glass contact for mercury-glass, as in the next diagram, it is almost 180°. angle of tangent contact line large f Fig 2.19 Angle of contact for mercury-glass contact When the angle of contact is less than 90°, the liquid is said to wet the solid surface, while it is said not to wet the surface if the angle of contact is greater than 90°. When the angle of contact is not 0° or 180°, the angle explicitly enters those equations which directly or indirectly involve the force exerted by a solid on a liquid due to surface tension. 22 PM2: Surface Tension 23 Forces associated with surface tension Angle f Fig 2.20 Close up of part of Fig 2.16 Redrawing an earlier diagram in a more general way, we note that the force the liquid exerts on the wall (and vice versa) is not vertical. There is a horizontal component, T sin f (which for f equal to 0˚ or 180˚ is zero), which results in a usually imperceptible distortion of the wall. There is a vertical component, T cos f (which for f equal to 0˚ or 180˚ is T), which causes the liquid in a capillary tube to rise. So the equation for capillary rise that we wrote is not complete. The general form is 2Tcosf h = rgr For clean glass-water contacts f ª 0 and cos f ª 1. So the equation was suitable for water in a clean glass tube. Q2.4 For mercury-glass we saw f ª 180° and we know that cos 180° = -1. The formula for capillary height will therefore have a minus sign in it. Does this mean that if you put a glass tube in mercury the level of the surface would be lower inside the tube? PM2: Surface Tension 2-9 SCALING QUESTIONS Q2.5 Why can insects walk on water, but larger animals (no matter how much water repellent material they put on themselves) cannot? Similarly, why will a needle float on water, but a much larger piece of metal of exactly the same shape will not? Try to answer this question as follows: (i) Consider a nice simple geometric shape for the needle, say a rectangular bar. Take the length to be 40 mm and the width 0.50 mm. (ii) Calculate its weight (the density of iron is 7.8 ¥ 103 kg.m-3). (iii) Now assume it is on top of the water with an angle, f, as shown. Needle f Fig 2.21 Needle "floating" on water Calculate the total upward force (remember the force associated with surface tension acts right around the contact line between the needle and the water). (iv) Can the weight of the needle be supported? (v) How does the angle of contact depend on the weight? (vi) Now assume the "needle" is 4 m in length and 5 cm thick. Will its weight be supported by surface tension? (vii) See if you can use the kind of scaling argument which was employed in chapter FE8 to answer the original question succinctly. 24 25 PM2: Surface Tension << 2-10 CHROMATOGRAPHY Chromatography is a technique for separating out the chemical constituents of mixtures. useful in biological contexts. There are two commonly used forms. It is particularly Paper Chromatography: Here a few drops of the chemical mixture are put onto a piece of filter paper and allowed to dry. Next the paper is touched to a reservoir of some solvent which will dissolve the chemical substance you hope to detect. The solvent is sucked up into the filter paper (by capillary action), and as it flows past the dried mixture, it dissolves out the chemical constituents and carries them along. However, different chemical substances adhere more or less strongly to the paper (i.e. the surface tension between the surface of the solution and the fibres of the paper differs) and so different chemical substances are carried along at different rates. So if you remove the paper from the solvent after a while the various chemical constituents of the original mixture will be at different positions on the filter paper. Colour Chromatography (This is the experiment we filmed.) Here the solvent is put on top of the mixture, and allowed to flow through a plug composed of grains of cellulose. Again, the adhesion between the chemical constituents of the sample (spinach leaf) and the cellulose grains is different and they all sink at different rates. In our experiment (which we filmed in the Department of Agricultural Chemistry with the help of Dr Bob Caldwell) the final order of chemical constituents is TOP: Flavonoid (Yellow) Chlorophyll B (Green) Xanthophyll (Yellow) Chlorophyll S (Green) Pheophytin (Purple) BOTTOM Carotenoids (Yellow) Only the two chlorophyll bands show up well on the TV screen. >> 2-11 VALUES OF SURFACE TENSION Here are the values of surface tension of some common liquids. They are listed here merely for the purpose of showing you what range the values of surface tension can have . Liquid Surface Tension/N.m-1 water (20°C) 0.073 water (100°C) 0.059 alcohol 0.022 glycerine 0.063 turpentine 0.027 mercury 0.513 2-12 REFERENCES "Surface tension in the lungs" Scientific American, p 120, Dec 1962. "Synthetic detergents" Kushner & Hoffman, Scientific American, p 26, Oct 1951. 26 PM3 HYDRODYNAMICS Some fish are minnows Some are whales. People like dimples. Fish like scales. Some fish are slim, And some are round. They don't get cold, They don't get drowned But every fish wife Fears for her fish. What we call mermaids and they call merfish. OBJECTIVES Aims In this chapter you will look at the behaviour of fluids in motion and the explanation of that behaviour both in terms of forces, energy and the continuity of the fluid. The distinction between smooth and turbulent flow is investigated. Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1. Explain, interpret and use the terms: thrust force, lift force, streamline, turbulence. 2. (i) Explain why the description of mutual forces between a moving fluid and a stationary object is identical to that for a stationary fluid and a moving object. (ii) Draw a diagram showing the origin of thrust and lift forces in such situations. (iii) Explain why it is preferable in discussing liquid flow, to consider the liquid as a continuous substance rather than individual molecules. 3. Describe how energy is dissipated in turbulent motion. 4. (i) Recall the definition of Reynolds number vLr R= h and state how L is determined in different situations. (ii) Recall that it is experimentally found that turbulent flow occurs if R ≥ 2000. (iii) Do simple calculations and interpretations involving Reynolds number. 5. (i) Explain how, for streamline motion in a tube (or channel) of variable cross-section, the flow speed depends on the cross-sectional area. (Equation of continuity.) (ii) Give a quantitative description of the branching effect at pipe junctions. (iii) Explain why flow speed must increase where streamlines are crowded together. 6. (i) Use an energy argument to explain why, for constricted streamline flow, the fluid pressure decreases as the flow speed increases. (Bernoulli's Principle.) (ii) Describe and explain the following phenomena : the venturi effect, the chimney effect, the working of an atomiser. PM3: Hydrodynamics 27 PRE-LECTURE Recall the following background information from earlier chapters, particularly chapters FE3, FE4 and FE5. (i) All fluids (liquids and gases) exert a pressure on the walls of any container which contains them - pressure being defined as force per unit area. This same pressure is exerted by each part of the fluid on neighbouring parts. The kinetic theory is a school of thought which seeks to understand how this pressure arises through the collision of individual molecules of the fluid with the walls and with each other. We will not in fact pursue kinetic theory any further - but concentrate on experimentally observable laws concerning fluid pressure and its effects. (ii) The simply established laws concerning fluid pressure are these: (a) The pressure at any point in a fluid is the same in all directions (Pascal's Principle). (b) The pressure within a fluid can vary from point to point; in a fluid at rest the pressure varies with vertical height according to the law. p = constant + rgh. It will be the concern of this lecture to establish how the pressure varies inside a fluid which is in motion. (iii) In general, mechanical forces can be classified as either dissipative or conservative forces, according to whether or not they result in the dissipation of energy (usually as conversion into thermal energy). Typically forces such as electromagnetic or gravitational are conservative and frictional forces are dissipative. Workers in hydrodynamics (or aerodynamics) try to classify pressures and fluid forces similarly. However since the origin of these effects has a more complicated microscopic explanation, this classification is not always so straightforward. The basic criterion employed is whether or not the equation of conservation of mechanical energy is obeyed. LECTURE 3-1 THRUST AND LIFT FORCES The study of hydrodynamics involves the study of the interaction of fluids and solid bodies. Three apparently different kinds of interaction can be distinguished: (a) moving fluids with stationary objects (b) stationary fluids with moving objects and (c) moving fluids with moving objects From work you have done already you can understand in a general way where the forces of interaction come from. (a) A moving fluid exerts a force on a stationary object because each molecule of the fluid, on bouncing, is accelerated by the solid. The solid exerts a force on the fluid. Before collision After collision Force exerted on molecule Figure 3.1 Collision of fluid molecules with a solid surface 28 PM3: Hydrodynamics and, by the fact that forces occur in pairs, the fluid exerts an equal and oppositely directed force on the solid. Force exerted on solid Figure 3.2 Force exerted by fluid molecules on solid surface Wind direction !WING RESULTANT LIFT FORCE Deflected air stream Figure 3.3 Lift force exerted by horizontal wind on an inclined wing Examples: Hovering birds, gliders, kites. (b) A moving solid exerts a force on a stationary fluid by exactly the same mechanism, by giving a velocity to (i.e. accelerating) each molecule of the fluid. Example : Fish tails. Tail Motion of tail Wake direction ! RESULTANT THRUST FORCE Pivot Figure 3.4 Thrust force on flipping fish tail (This example is in fact too complicated to worry about too much for now; suffice it to say that the backward and forward motion of the tail results in an average forward thrust.) From all this we want to draw two simple conclusions: (1) This way of analysing things is too simplistic. Yet the main conclusion is correct: if you want to move up through a fluid, you must push the fluid down; if you want to move forward, you must push the fluid backwards. (2) The physics of what happens is the same whether it is the fluid or the solid or both which is moving. Application Aeronautical engineers can predict how an aeroplane will behave in flight by observing it at rest in a wind tunnel (or even in a water tank). PM3: Hydrodynamics 29 3-2 STREAM LINES AND TURBULENCE The preceding analysis is obviously too simplistic as can be seen from a very easy observation. When a stream of (gently) flowing fluid is diverted by the presence of a wall, the particles of fluid do not all bounce off the wall, most bounce off other fluid particles. Demonstration Glycerine solution flowing in a flow tank. Figure 3.5 Streamlines for fluid flowing past a solid obstacle Since the stream is diverted (accelerated) the wall must be exerting a force on the fluid, and the fluid on the wall. The origin of this force must be that the fluid molecules bounce off one another, causing those next to the wall to bounce off it more violently. That means the fluid pressure must increase near the corner. More of this later. Whatever the means whereby force is exerted on the wall, it is clear that for some parts of their motion particles of the fluid do not travel in straight lines but in curved paths. It turns out that it is more helpful in describing fluid flow to think of the fluid as a continuous substance rather than to concentrate on the motion of individual molecules. Particles of this continuous fluid can be considered to travel along these smooth continuous paths which are given the name streamlines. These stream lines can of course be curved or straight, depending on the flow of the fluid. This continuous substance can be regarded as being made up of bundles or tubes of streamlines. The tubes have elastic properties: (a) A tensile strength, which means that the parts of the fluid along a particular streamline stick together and do not separate from one another, (b) zero shear modulus, which means that each streamline moves independently of any other. Streamline motion is not the only possible kind of fluid motion. When the motion becomes too violent, eddies and vortices occur. The motion becomes turbulent. Demonstrations Wakes of boats Liquid tank demonstration. Turbulence is important because it is a means whereby energy gets dissipated. When a body is moved through a stationary fluid in streamline motion some kinetic energy is given to the fluid, but only temporarily. When the body has passed, the fluid is still again; no net energy has been given to it. But when turbulence is established, a net amount of kinetic energy is left in the fluid after the body has passed. Application This is very important in aeronautical engineering. Air turbulence means increased fuel consumption in aircraft, and many cunning and intricate devices are used to reduce turbulence. The shape of a body will, to some extent, decide whether it will move through a fluid in streamline or turbulent motion. Demonstration Shapes of marine animals, specially shaped corks. 30 PM3: Hydrodynamics 3-3 REYNOLDS NUMBER What factors determine whether a fluid will flow in streamlined or in turbulent motion? You could guess some of these more or less easily. (i) Speed of flow - faster flow gets turbulent more easily. (ii) Stickiness of fluid - thick, sticky liquids like glycerine become turbulent less easily than thin liquids like water. [Just what physical quantity is involved here is not obvious. It is called the kinematic viscosity and we cannot say anything about it till next lecture. The symbol for it is h/r (see post lecture).] (iii) A more unexpected result which turns up is that the size of the system is important. For water flowing at the same speed through narrow pipes, the flow becomes turbulent more easily in the tube of larger radius. More thorough experimental investigation will collect all these results thus. We define for any system a number R, called the Reynolds number vLr R ≡ h where v is a typical flow speed of the fluid, L is a typical length scale and h/r the kinematic viscosity of the fluid. Then it is found experimentally that if this number is not too large (smaller than about 2000) the motion will be streamline; whereas if R ≥ 2000 then turbulence can set in. There is no theoretical explanation of this value of 2000, it is just found to be the case. 3-4 THE EQUATION OF CONTINUITY For fluids which are flowing in streamlined motion, what laws do they obey? Firstly there is the so called equation of continuity: for an incompressible fluid moving in streamline motion in a tube of variable cross-section, the flow speed at any point in inversely proportional to the cross sectional area 1 Speed µ area . The reason behind this is very easy to grasp. If you want a more rigorous statement, see the post-lecture material. One sees many applications of this. Four examples follow. Demonstrations (i) In flowing rivers, when going from deep to shallow, the flow speed increases (often becoming turbulent). (ii) In the circulatory system of the blood there is a branching effect. When a fluid flows past a Y-junction made up of pipes of the same diameter, the total crosssectional area after the branch is twice that before the branch, so the flow speed must fall to half. Low Speed High Speed Figure 3.6 Y-junction with pipes of same diameter Conversely, if it is important to keep the flow speed up, the pipes after the branch must have half the cross-sectional area of those before. 31 PM3: Hydrodynamics Same Speed High Speed Figure 3.7 Y-junction with pipes of half the original cross-section (Note: blood will clot if its speed falls too low.) Most gases behave like incompressible fluids provided their flow speed is less than the speed of sound. The bulk modulus of a gas, while lower than that of a solid, is still large enough for the equation of continuity to describe its motion. Demonstrations Air conditioning systems must also be built with consideration for the branch effect. Also the tube structure of the respiratory system is remarkably similar to that of the circulatory system. In complicated patterns of streamline flow, the stream lines effectively define flow tubes. So the equation of continuity says that where streamlines crowd together the flow speed must increase. Streamlines close together: speed high Aerofoil Streamlines spread out: speed low Fig 3.8 Streamline pattern around an aerofoil PM3: Hydrodynamics 3-5 BERNOULLI'S PRINCIPLE Demonstration An interesting effect which is easy to show is that, for a fluid (e.g. air) flowing through a pipe with a constriction in it, the fluid pressure is lowest at the constriction. In terms of the equation of continuity, the fluid pressure falls as the flow speed increases. The reason is easy to understand. The fluid has different speeds and hence different kinetic energies at different parts of the tube. The changes in energy must result from work being done on the fluid and the only forces in the tube that might do work on the fluid are the driving forces associated with changes in pressure from place to place. higher speed higher kinetic energy lower pressure lower speed lower speed lower kinetic energy lower kinetic energy higher pressure higher pressure Figure 3.9 Application of Bernoulli's Principle The units of pressure, N.m-2, might be rewritten as J.m-3; that is, pressure is dimensionally equivalent to work/volume. Since the fluid is driven from regions of high pressure to those of low pressure and thus increases its kinetic energy, we can write kinetic energy/volume + work/volume is constant, l i.e. 2 rv2 + p = constant. In cases where the flow is not horizontal, we should add in the gravitational potential energy/volume l also: 2 rv2 + p + rgh = constant. This is known as Bernoulli's equation. For the very simple cases it says what we had before the fluid pressure is lowest where the flow speed is highest. Demonstrations The venturi effect: a fast jet of air emerging from a small nozzle will have a lower pressure than the surrounding atmospheric pressure. You can support a weight this way: Nozzle Air low pressure high pressure Figure 3.10 Example of the Venturi Effect The chimney effect: just the venturi effect being used to suck material up. [Note in most automobiles, petrol is sucked into the carburettor in this way.] 32 PM3: Hydrodynamics 33 Atomiser: This same effect makes atomisers and spray guns work. Nozzle: low pressure High pressure (Atmospheric) Figure 3.11 An "Atomiser" It is most important that the free surface of the liquid should be open to the atmosphere, else the high pressure outside the container and the low pressure inside will result in the container being crushed. {Fly sprays always have a small air hole.] A spinning ball or cylinder moving through a fluid experiences a sideways force. There is a high pressure on one side (so a big force) and low pressure (small force) on the other. The ball experiences a net sideways thrust. This is one of the ways players can get cricket or ping pong balls to swerve. Demonstration Spinning cylinder. POST-LECTURE 3-6 MORE ON REYNOLDS NUMBER There are several points to note about the definition of the Reynolds Number. (a) It is not a precise physical quantity. The quantities L and v are only typical values of size and speed. It is often not possible even to say which length you are talking about. For a body moving through a fluid it might be either length or breadth or thickness - or any other dimension you might think of. For a fluid flowing through a channel or a tube, it turns out that it is the diameter of the tube which enters. It is not until you learn more about the Reynolds Number that you can really hazard an intelligent guess at which one you should use. This imprecision in its definition reflects the fact that the basic physical law is itself rather vague - indeed it can often only be stated as we did: "The flow of fluid in a system is more likely to be turbulent if the system is large, than if it is small". It is not surprising then that the magic number of 2000 is also only rough. b) The "stickiness" index, the kinematic viscosity, is given the strange symbol h/r for the following reason. There are many ways in which this "stickiness" or viscosity manifests itself. Basically, how fast the fluid flows determines one measure of stickiness known as the coefficient of viscosity (h) - see next lecture. How easily the fluid becomes turbulent is related to this but to the density (r) as well - or if you like, it defines a different measure of stickiness. It is pointless to say any more at this stage, except to give units. h is measured in units of Pa.s; to give you a feeling for what numbers occur, for water h ~ 103 Pa.s. (c) The Reynolds number is a dimensionless number as you can see from its definition: [R] = [m.s-1][m][kg.m-3] [Pa.s] This will be understood when you come to see where the Reynolds Number comes from. It is a ratio of two quantities - essentially a scaling number. 34 PM3: Hydrodynamics Q3.1: Work out the Reynolds Number for the following flow systems, and say in which ones you might expect there to be a lot of energy dissipated through turbulence. (i) A Sydney Harbour ferry (ii) Household plumbing pipes (iii) The circulatory system. [Take an average sort of figure for the flow speed of blood to be 0.2 m.s-1 the diameter of the largest blood vessel, the aorta, to be ~ 10 mm; and guess that the viscosity of blood probably is not very different from that of water.] (iv) Spermatozoa swimming. [They are typically about 10 µm in length with speeds of about 10-5m.s-1.] 3-7 CONTINUITY A careful derivation of the equation of continuity goes like this. Consider a fluid flowing through an irregular tube like this Speed = v 2 B Speed = v 1 A Area = A Area = A 2 1 Figure 3.12 Figure for derivation of Equation of Continuity The volume of fluid flowing past A in a very small time ∆t = A1v1Dt. So the mass which flows past A is r1 A1v1Dt . Similarly the mass of fluid flowing past B in time ∆t is r2 A2v2∆t . Now, when the flow is steady all the material which goes past A must go past B in the same time (or else it will continually piling up somewhere) so r 1 A1v1Dt . = r 2 A2v2Dt . r 1 A1v1 = r 2 A2v2 Then if the fluid is incompressible, its density does not change, so A1v1 = A2v2 which is the result stated earlier. Notice that for the final statement to be true, incompressibility is important. But notice also that if the fluid is approximately incompressible, i.e. if its density never changes by very much, then the equation of continuity, as we quoted it, is approximately true. The quantity appearing in this equation, Av, measures the volume of the fluid which flows past any point of the tube divided by time. It is given the name volume rate of flow, and is usually denoted by the symbol q. See, for example, Poiseuille's law on page 43. Q3.2 From observations you have made, either from the TV screen or in the real world, draw in the stream lines for a liquid flowing in streamline motion through a drain with a corner in it. PM3: Hydrodynamics 35 Figure 3.13 A drain with a corner in it! Use continuity to decide where the flow speeds up, and when it slows down. You cannot apply this to water flowing around a bend in the river. A Reynolds number calculation shows that the situation is quite different. 3-8 BERNOULLI'S EQUATION If you really want a more careful derivation of Bernoulli's equation, you can look it up in another book. It goes along the same lines as the proof of the equation of continuity. Just remember that, because you are using the equation of conservation of energy, it is important that there should be no energy dissipation through turbulence. Bernoulli's equation only really applies when the motion is strictly streamline. Nonetheless, provided there is not too much turbulence, the law will approximately apply. Certainly, in all of the experiments we did on screen the flow must have been pretty turbulent, yet they all showed the characteristic effect of pressure drop. Q 3.3 Medical textbooks often quote Bernoulli's equation simply as p + rgh = constant l implying that the kinetic energy term ( rv2 ) is not important but the gravitational potential energy term is. 2 Use the average speed for blood flow quoted above and a typical human blood pressure of 104 Pa to explain why this is so. Q 3.4 In section 2 above, you analysed streamlined flow round a corner. Using the result of that analysis show how the pressure changes as the liquid goes round the corner. Can you reconcile this with the kind of simple minded diagrams drawn for the lift force on wings drawn in figure 3.3 above? Q 3.5 When you are in the dentist's chair, the dentist uses a device based on the venturi effect to suck saliva out of your mouth. Discuss. 36 PM4 VISCOSITY Come crown my brow tin leaves of myrtle I know the tortoise is a turtle. Come carve my name in stone immortal, I know the turtoise is a tortle. I know to my profound despair I bet on one to beat a hare. I also know I'm now a pauper Because of its tortley turtley torpor. OBJECTIVES Aims In this chapter you will look at the effect of the application of shear stresses to fluids and the associated phenomenon of fluid viscosity. The coefficient of viscosity will be defined. Poiseuille's equation, which describes the flow rate of viscous liquids through pipes is presented, discussed and applied to a number of situations Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1. Explain and use the following terms: shear stress, velocity gradient, viscosity, newtonian liquid. 2. (i) Describe an experiment that shows qualitatively a relationship between shear stress and velocity gradient. (ii) Define the coefficient of viscosity in terms of this relationship (Newton's Law of viscosity). 3. 4. (i) Identify the unit of viscosity as 1 Pa.s. (ii) Recall that the coefficient of viscosity for water is about 1 ¥ 10- 3 !Pa.s. (i) Describe the different response of liquids and solids to an applied shear stress. (ii) State Newton's law of viscosity in terms of shear stress and the rate of shear deformation. 5. (i) Explain qualitatively the dependence of the rate of streamline flow of liquid in a pipe on pressure difference, pipe length, pipe radius and the coefficient of viscosity of the liquid. (Poiseuille's equation.) (ii) Use Poiseuille's equation, when quoted, to do simple calculations. (iii) Describe three phenomena, including both water pipes and the human body, which relate to Poiseuille's equation. 6. Present the analogy between current in an electric circuit and fluid flow in a pipe system and explain what is meant by resistance in fluid flow. 7. (i) Explain how energy is dissipated by viscosity. (ii) Use the Reynolds number to determine whether or not viscous dissipation of energy is important in simple systems. PM4: Viscosity 37 PRE-LECTURE Keep in mind two particular points that have been made so far in these Properties of Matter lectures. (i) The definition of the Reynolds number, and its importance essentially as a scaling number. In last lecture we pointed out that this number told you whether or not a particular flow system was likely to be turbulent or streamline. The same number will turn up again to decide whether or not the flow is viscous. The basic reason for the existence of this number and why it takes the form it does is perhaps one of the most important questions in the whole study of fluid flow. (ii) The definition of the shear deformation and Hooke's Law as it applies to bodies which behave elastically under shear stresses. As we have pointed out it is the behaviour of a substance under shear which essentially distinguishes between a solid and a liquid . A solid (usually) has a large shear modulus, i.e. if you try to deform it (in shear) it will deform, but then return to its original shape afterwards. A liquid has a very, very small shear modulus. You can slide one bit of a liquid past another bit, and there will be no noticeable tendency for the two to regain their original shape when you shop pushing. Nonetheless the sliding of one bit does have an influence on the other, and this is what viscosity is all about. (iii) Also you should recall discussion of electrical resistance and the various mathematical techniques of working with it (like Ohm's Law and Kirchhoff's Theorem). The flow of water through pipes is an important part of this lecture - and obviously much the same kind of mathematical reasoning can be used to talk about it, as was used to discuss D.C. circuits. (iv) Recall also the meaning of the word gradient. If some quantity (say pressure) varies with distance (x), being big at some point and small at another, we say a pressure gradient exists. dp A measure of this is the derivative dx ; or, more crudely, the ratio: difference!in!pressure!at!2!points distance!between!those!2!points . In a fluid we might expect the flow speed to change from point to point, and we could describe this variation by measuring the velocity gradient. LECTURE 4-1 VISCOSITY A feature which distinguishes one liquid from another is their "thickness" or the ease with which they pour. Demonstration Observe the flow of water, glycerine, oil, treacle, lava, pitch. << This last experiment is on show in the Physics Department, University of Queensland. experimental record is: 1920 Pitch poured in funnel 1938 (Dec.) First drop fell 1947 (Feb.) Second drop fell 1954 (Aug.) Third drop fell 1962 (May)` Fourth drop fell 1970 (Aug.) Fifth drop fell. >> The The physical property which distinguishes these liquids from one another is something to do with how well the liquid molecules adhere to one another; and this molecular adhesion leads to a host of rather complicated effects. 38 PM4: Viscosity Demonstration (i) The rate at which solids fall through liquids (this has already been discussed in chapter FE4). (ii) The spin-down effect, tea leaves in the bottom of a stirred cup migrate to the centre (not the outside as you might expect). (iii) Smoke rings. (iv) Vortex rings in liquids. These are all traceable (in the end) to molecular adhesion, but their explanation and connection with one another is very complicated. However, we have to start somewhere. We must select one physical effect to measure, and try to understand the others in terms of it. We choose to concentrate on the existence of a velocity gradient. When a fluid (e.g. air) flows past a stationary wall (e.g. table top), the fluid right close to the wall does not move. However, away from the wall the flow speed is not zero. So a velocity gradient exists. High speed Fluid Flow Low speed Stationary Wall Fig 4.1 Velocity gradient in a stream of fluid moving past a stationary wall We will find that the magnitude of this gradient (how fast the speed changes with distance) is characteristic of the fluid. We will use this fact to define viscosity. Demonstration Observe the velocity gradient in a tank of treacle. 4-2 THE COEFFICIENT OF VISCOSITY A simple experiment set-up capable of demonstrating the law of viscosity involves a small metal plate suspended in a tank of liquid. Before the experiment starts the weight of an attached pan is adjusted so that the plate is neutrally buoyant - i.e. it does not tend to sink in the liquid or to rise. Applied Force Liquid F A D H Metal plate (side view) E B C G Fig 4.2 Experiment to measure coefficient of viscosity: static situation 39 PM4: Viscosity An extra force is now applied to cause the plate to move through the liquid. When the plate is moving with speed v through the liquid, there will be a velocity gradient between AB and FE; also between DC and HG. The complete apparatus is Pointer Scale Weights (to provide known force) Glycerine Plate (of known size) Fig 4.3 Experiment to measure coefficient of viscosity: complete apparatus Demonstration (i) The speed with which the plate rises, increases as the force pulling it increases: Mass on pan/g Time to go 100 mm/s 2 8 5 2.6 (ii) For the same force, the speed of the plate decreases as the area of the plate increases. For a plate of twice the surface area Mass on pan/g Time to go 100 mm/s 2 13.5 5 5 7 3 We interpret these two sets of results as indicating that the speed of the plate increases with the shearing stress (recall the definition of stress given in chapter PM1) (iii) For a given speed, we change the velocity gradient by moving the plate closer to the wall. velocity gradient = v/d ! distance between wall and plate = d v Fig 4.4 Increased velocity gradient when the plate is closer to the wall Mass on pan 7g Time (close to wall) 4.2 s We interpret this result as saying that a given shearing stress sets up a velocity gradient in the fluid. 40 PM4: Viscosity More careful experimentation, or more detailed theoretical analysis, will clarify these conclusions into Newton's law of viscosity which says: When a shearing stress acts within a fluid moving in a streamlined motion, it sets up in the liquid a velocity gradient which is proportional to the stress. dv s = h dx (stress) = (constant) ¥ (velocity gradient) The constant h is called the coefficient of viscosity, and is different for different liquids. Water is obviously a lot less viscous than glycerine. Though this equipment can roughly show Newton's Law to be plausible, it cannot be used for accurate measurement of viscosity. Some common measuring devices are: Demonstrations (i) Commercial oil companies use simpler viscometers. These essentially measure how fast the oil pours. The "grade" of an oil is the number of seconds it takes to pour a measured amount through a certain tap. (ii) If not much liquid is available, or cannot be removed (e.g. protoplasm in a cell, or sap in a plant) you can observe how fast bubbles rise or particles sink in the liquid. (iii) Laboratories usually use a torsional viscometer, which is really a very refined version of the apparatus we used above. ELEVATION Weights Outer cylinder (fixed) Liquid under test Axle Inner cylinder (rotates) PLAN Liquid velocity gradient set up here Fig 4.5 A torsional viscometer Of course the viscosity of a liquid can change. Demonstration The viscosity depends on temperature, usually increasing as the temperature decreases (which is why automobiles need different oils in hot countries than in cold countries and indeed why the engine runs more freely as it heats up). However, this kind of detail you can catch up on later, when you come to talk about viscous effects in your own discipline. 41 PM4: Viscosity 4-3 ALTERNATIVE STATEMENT OF NEWTON'S LAW Since there are many manifestations of viscosity, there are many different statements of the basic law. We have given Newton's statement, relating velocity gradient to shear stress (pressure). Another statement, which research workers use, specifically points up the difference between solids and liquids. Solids When a shearing stress is applied to a solid it suffers a shear (i.e. a shear deformation) x A C y B Fig 4.6 Shearing of a solid (side view) A solid deforms instantaneously and then stops deforming. When the shearing stress is removed, if the solid is elastic the deformation recovers. Liquids When a shearing stress is applied to a liquid it suffers a shear deformation also, sometimes slowly sometimes fast. However, so long as the shear is applied it continues to shear. When the stress is removed, the shearing stops, but does not recover. The basic law of behaviour of elastic solids and viscous liquids are: Elastic solids obey Hooke's law which says shear stress µ shear deformation {Remember: shear = Viscous liquids obey Newton's law which says shear stress µ length!AC length!AB } velocity gradient. However the velocity gradient is the same thing as time rate of change of shear deformation.. This can be seen as follows, with reference to figure 4.6: speed velocity gradient = transverse!length !dx dt = y rate of shear = d/dt (x/y) = 1/y (dx/dt) provided y is constant, as it is. So, Newton's law can be restated shear stress µ rate of shear deformation. 42 PM4: Viscosity 4-4 POISEUILLE'S LAW We want to find out what effect viscosity has when fluids flow in more relevant situations. The most important one, which is the only one we will consider is flow through a long pipe. We could go through a mathematical analysis and apply Newton's law (of viscosity) to this problem, but we will not. One thing however is obvious. Because viscosity puts restrictions on velocity gradients, it must be true that liquid will flow faster through a wide pipe than a narrow one. Demonstration Polystyrene chips on surface of a treacle tank. Start Later Fig 4.7 Velocity profile for moving treacle [This technique of showing the velocity profile of the flow will become important later.] In trying to find out what other factors control how fast fluids can flow through pipes, the following factors are easy to isolate: (i) the pressure difference between the ends of the pipe. The bigger the pressure difference, the faster will be the flow; (ii) the length of the pipe. More liquid will flow through a shorter than a longer pipe in the same time. (iii) the radius of the pipe. More liquid will flow through a wide than a narrow pipe in the same time. This dependence is very marked. Even in our rough demonstration we get 8 times as much glycerine flowing through a pipe twice the radius of the other. (Theory says we should have got 16 times as much.) (iv) the coefficient of viscosity of the liquid. Water flows much more easily than glycerine. Had we gone through a mathematical analysis of the situation, we could show that Newton's law of viscosity would give the volume rate of flow, qv , of fluid of viscosity h, through a pipe of radius r and length l, when driven by a pressure difference ∆p as ∆p.r4!p qv = !lh!8 This is known as Poiseuille's law. The similarity between this equation and Ohm's law is very marked; most workers talk about "resistance" of a pipe. See post lecture material. Situations in which Poiseuille's law has important effects: Examples (i) Irrigation pipes. It is uneconomical to use spray irrigation too far from a river since the resistance of a pipe increases with its length, and you need too big a pump. (ii) Pipes from Warragamba Dam. Here ∆p and l are fixed (by geography), and the volume rate of flow is fixed by the requirements of the population of Sydney. When Sydney doubles in size, the Water Board will have to use twice as many pipes or replace the present pipes by ones of (2)1/4 times the radius. [This is an oversimplification, see post lecture.] PM4: Viscosity 43 (ii) Respiratory system: The flow of gas here is also Poiseuillean. The resistance to flow is determined primarily by the narrow tubes leading to the alveoli. Any general constriction of the pipes, as occurs in bronchospasm for instance, increases the resistance to flow and makes breathing much more difficult. (iv) Circulatory system: Two points are worth making. (a) There is a decrease in pressure across each section of the tubes. Blood pressure is highest when it leaves the heart (through the aorta) and lowest when it returns (through the inferior vena cava). Most pressure loss occurs over the capillaries. Why? (b)Any constriction of the tubes - for example a build up of cholesterol on the walls of the arteries increases the resistance and hence the pressure drop (it goes as r4 remember). So the heart has to work harder to compensate. And at times of stress, when an increased flow rate is required, there can be a breakdown. (v) Urinary tract. You work out the relevant physics. Anyhow, just remember that Poiseuille's law is essentially the same thing as Newton's law; and if a fluid obeys one it obeys the other. There are a large number of important liquids which do not obey these laws, and they are called non-newtonian liquids. One of the simplest ways to recognise a newtonian liquid is to examine its velocity profile, which should be parabolic for a liquid which obeys Newton's (or Poiseuille's ) law. Demonstration flow of syrup. 4-5 REYNOLDS NUMBER Poiseuille's Law shows that viscosity is responsible for loss of pressure - and hence is an energy dissipating phenomenon. We are not talking about energy loss due to turbulence, but about energy loss which occurs even when the flow is streamlined. It comes about through friction between the streamlines moving past one another. The criterion whether or not much energy is lost in this way, is therefore whether or not there is much of a velocity gradient throughout the whole of the liquid. Since most of this gradient occurs near a boundary (in the so called Boundary layer, it is the ratio of the size of the system to the size of the boundary layer which is important. System relatively large System relatively small energy mostly conserved much energy dissipated Fig 4.8 Effect of boundary layer in velocity profile As will be shown in the post-lecture, the ratio of total energy of flow to energy dissipated, is very closely related to the Reynolds number which we introduced in last lecture. So now we can appreciate another reason why the Reynolds number is important. Viscous effects can never be neglected (i.e. the energy dissipated is appreciable) in low Reynolds number situations: in thick liquids (h large), or in small slow flow systems. On the other hand viscous effects will not be important in thin liquids or in large, fast flow systems. (However in these latter systems remember that turbulence is always possible, and energy can be lost through that means.) 44 PM4: Viscosity In general then, flow patterns will be different in systems with low and with high Reynolds numbers. In particular, in very low Reynolds number systems, the flow is perfectly reversible since no turbulent effects can occur anywhere. Demonstration The method of swimming is quite different for fishes (R ~ 10,000) and spermatozoa (R ~ 0.0001). Modes of boat propulsion which work in thin liquids (water) will not work in thick liquids (glycerine). It is possible to stir glycerine up, and then unstir it completely. You cannot do this with water. POST-LECTURE 4-6 MORE ON POISEUILLE'S LAW Poiseuille's law can be derived from Newton's law; but to go through the complete derivation, even in post-lecture material, would be completely opposed to the philosophy of this course. If you feel you cannot do without it, there are plenty of books you can look up. But in broad outline the derivation follows these lines: (i) The force trying to push the fluid through the tube is of course due to the pressure difference ∆p. The retarding force comes from viscous drag, which acts to prevent shearing. If the flow is streamlined, then this shearing resistance acts all over the surface of imaginary tubes of fluids concentric with the tube trough which the fluid is flowing; and thus the retarding force will depend on the surface area of the tubes of fluid - and hence on the length of the tube. The flow speed must therefore increase until the resisting force balances the driving force; and when that happens you will get Dp on one side of the equation and l on the other. (ii) Trying to calculate how fast the fluid must flow to produce the necessary resisting force is where Newton's law comes in. There is most fluid-on-fluid slipping toward the outside of the tube (purely by geometry) so the velocity gradient is larges there, and is zero in the centre. In fact the velocity profile is a parabola. Velocity component Distance from axis of tube Fig 4.9 Parabolic velocity profile You can say therefore that the average flow speed is likely to depend on r2. And so the volume rate of flow (equal to the average speed • area of the tube) is likely to depend on r4. (iii) The factor p/8 you must take on faith, or work it out for yourself. 45 PM4: Viscosity The only point in going through even so sketchy a "derivation" is to point out two facts: (i) Poiseuille's law only applies to fluids that obey Newton's law, and (ii) The assumption of streamlined flow is also built in to Poiseuille's law. If turbulence occurs than you must be very careful about using Poiseuille's law to calculate flow rates. (You will recall that in the experiment done on screen glycerine flowed through the wide pipe more slowly than would be predicted by Poiseuille's law.) Q4.1 Why should turbulence mean that the volume rate of flow is less than in streamlined flow? Q4.2 When a builder designs the drainage system for the roof of a house, what factors should influence the choice of the size of the downpipe? Would he be correct in basing his calculations on Poiseuille's Law Q4.3 The experiment was done in chapter PM2 in which water rose, by capillary attraction, through two columns of soils. It was observed that the water rose faster in the column with the coarser grains. Can you say now why this is so? 4-7 ELECTRICAL ANALOGUE Ohm's Law says : V = Poiseuille's Law says : Dp = R I 8 l!h p r 4 ¥qv The comparison is obvious, and hence it is most convenient to talk about flow through any kind of tube in terms of resistance defined thus: 8l!h R ≡ p!r4 Note that the unit of this resistance is: kg. m-4. s-1. It is even possible to do this when the flow is turbulent. It only means that Poiseuille's equation is not valid, and you cannot use this explicit formula for the resistance. But it is still quite possible to define a resistance. Once you appreciate this, then you can use all the mathematical techniques of circuit analysis; in particular the rules for adding resistances in series and parallel. Q4.4 Consider water flowing along a l.0 m long pipe at a steady rate, 250 mm pressure 5.0 Pa A 750 mm B C Fig 4.10 Data for Q4.4 If you measured the fluid pressure at point B, what value would you get? pressure 1.0 Pa 46 PM4: Viscosity Q4.5 Consider these two different streamlined flow systems, B A C (a) B A C (b) Fig 4.11 Data for Q4.5 The lengths of the two pipes in the section BC are equal to the lengths AB in both cases. The radii of all three pipes in case (a) are the same; but in case (b) the radii of the two pipes in BC are half that of pipe AB. In both cases also, the pressure at A is 4 Pa, and at C is 1 Pa. What is the pressure at B in case (a) and case (b)? Can you guess from these two answers, the answer to the question posed in the lecture notes: "in the circulatory system, why does most pressure drop occur over the capillaries?" 4-8 MORE ON REYNOLDS NUMBER In the lecture, we talked about the ratio: Total!energy!of!flow!(per!unit!volume) Energy!dissipated!(per!unit!volume) We can easily evaluate this ratio, since the energy dissipated is just the work done by the viscous forces divided by unit volume. And, by the same arguments used in 4-5 of chapter PM3, this must be equal to the pressure drop. Hence this ratio 1 1 2 2 2!r!v 2!r!v = Dp ~ h!dv/dx (by Newton's law) Now, in a system where the boundary layer is comparable in size with the scale length of the system (L), we can approximate the velocity gradient in this expression by dv v ~ dx L r!vL and therefore the above ratio is = !2h which, apart from the factor 2, is just the definition of the Reynolds number 47 PM4: Viscosity Q4.6 If you were designing a circulatory system for the human body, where a prime requirement is that as little energy as possible should be dissipated, in order not to require the heart to pump any harder than absolutely necessary, what Reynolds number would you aim for? Compare this with the Reynolds number for blood, which is somewhere between 1000 and 2000. 4-9 VALUES OF VISCOSITY As pointed out in last lecture, and as can be checked from the equation in 4-2, the units of viscosity are those of (pressure) ¥ (length)/(speed) or Pa.s. Some books of tables quote numbers in the old cgs unit - the poise. You can easily convert by remembering that 1 Pa.s = 10 poise Purely to show you what range the values of viscosity can have, here are some common fluids: FLUID VISCOSITY / Pa.s water (20°C) 1.0 ¥ 10-3 water (100°C) 0.3 ¥ 10-3 alcohol 1.2 ¥ 10-3 glycerine 1.5 mercury 1.8 ¥ 10-3 air 1.8 ¥ 10-5 48 PM5 RHEOLOGY Elephants are useful friends Equipped with handles at both ends. They have a wrinkled, moth-proof hide; Their teeth are upside down, outside. If you think the elephant preposterous You've probably never seen a rhinosterous. OBJECTIVES Aims In this chapter you will look at how many liquids have viscosity coefficients that change with the applied shearing stress. This is called non-newtonian behaviour. Visco-elastic effects, which combine fluid and solid properties are also discussed. Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1. Explain and use the following terms: rheology, non-newtonian flow, pseudo-plasticity, dilatancy, plasticity, thixotropy, visco-elasticity, creep, stress relaxation. 2. Describe, in terms of shear stress, shear, rate of shear, and time, the behaviour of the following materials: starch solution, cornflour solution, wet sand, toothpaste, quickclay, wool fibres, pitch, wet soil, blood. 3. Describe an experiment showing the different effect of shear stress on a newtonian fluid (e.g. glycerine-water mixture) and a non-newtonian fluid (e.g. starch solution). PRE-LECTURE 1. Refer back to chapter PM1 which discusses the behaviour of purely elastic materials. Note in particular that for these materials Hooke's Law is obeyed i.e. the stress is proportional to the strain. 2. Refer back to chapter PM4 which discusses viscous forces, forces which show themselves when a fluid flows. Note in particular that for simple fluids such as water the shear stress is proportional to the velocity gradient, a relationship which is known as Newton's law. Note as well that this law can be expressed alternatively as the shear stress is proportional to the rate of shear. LECTURE 5-1 NON-NEWTONIAN FLUIDS Rheology is the study of how bodies behave under the action of deforming forces. As the word is usually understood it deals with all materials except the purely elastic and those which are purely viscous and obey Newton's law. Most materials do not fall into these two extreme categories - in fact strictly speaking none do if the relevant parameters are varied widely enough. In this lecture we are going to look at some of the more complicated behaviour one can get. To start we consider the fluids that do not obey Newton's law - the non-newtonian fluids. For these, the shear stress is not proportional to the shear rate and thus their viscosities depend on shear rate. Basically, they fall into two different classes. Firstly there are the pseudo-plastics for which the coefficient of viscosity decreases as the shear rate increases. 49 PM5: Rheology Demonstration A solution of starch is pseudoplastic. Its pseudoplasticity can be easily demonstrated by letting it flow from a burette and comparing its flow with that of a suitable viscosity newtonian fluid flowing from an identical burette. (The newtonian fluid used was glycerine and water.) At the beginning the starch flowed faster than the glycerine; as both fluids started to slow, the starch slowed down more than the glycerine; finally the level of glycerine solution fell below that of the starch solution. In explaining this experiment we note that (i) the shear stress is related to the pressure difference driving the liquid (ii) the rate of shear is related to the flow rate. (iii) for a newtonian liquid (the glycerine-water mixture) the viscosity, that is the relation between the shear stress and the rate of shear is constant; as the burette emptied the shear stress (and the pressure) reduced while the rate of shear (and the flow rate) reduced correspondingly. (iv) for the non-newtonian liquid (the starch solution) the viscosity increased as the shear stress decreased (that is, as the head of liquid in the burette decreased). The increase in viscosity is shown by the disproportionate decrease in the flow rate. (v) the amount of glycerine in the solution was chosen so that the (constant) viscosity was originally greater but later less than that of the starch solution. glycerine-water (newtonian) Viscosity coefficient starch solution (pseudo-plastic) Shear rate Fig 5.1 Variation of viscosity coefficient with shear rate The second type of non-newtonian fluid is the so-called dilatant fluid which has the reverse behaviour to a pseudo-plastic fluid viz its viscosity increases as the shear rate increases. Examples One example of a dilatant fluid is a thin paste of cornflour. Other examples of dilatant fluids are printing inks, vinyl resin pastes and suspensions at high solid content such as wet beach sand which shows its dilatancy through the fact it stiffens when trodden on. Apart from these two main categories there is one other type of non-newtonian fluid which has the complicating feature that it does not flow, it does not behave as a fluid until a certain stress, the yield stress, has been exceeded. Once this stress has been exceeded, the viscosity either remains constant or decreases as the shear rate increases. These materials are called plastic. Examples An example of a plastic material is toothpaste. It is necessary that toothpaste will stay on the brush but it must be easily extrudable. Some other examples of plastic materials of which there are many, are good brushing paints and sewage sludge. 50 PM5: Rheology The flow characteristics of the different non-newtonian fluids may be summarised thus: plastic Shear stress pseudo-plastic newtonian dilatant Shear rate Fig 5.2 Variation of shear rate with shear stress for newtonian and non-newtonian fluids Another way in which the non-newtonian nature of a fluid can show itself is in its radial velocity profile as it flows through a narrow tube. For newtonian fluids this radial velocity profile is parabolic. For non-newtonian fluids the radial velocity profile is not parabolic. It is somewhat sharper for dilatant fluids and for pseudoplastics it is blunter. For plastic materials there is a completely flat region in the centre where the shearing stress is less than the yield value. Demonstration The protoplasmic flow in the plant known as "slime mould" has a distinctly non-parabolic radial velocity profile. Before leaving non-newtonian fluids, one further complication needs to be mentioned viz. that there are some fluids whose viscous behaviour depends very much on the time they have been sheared and the time they have been at rest. There are two types of these. The thixotropic fluids are like the pseudo-plastics in that the viscosity decreases with increasing shear rate but as well show the property that at constant shear rate the viscosity decreases with time. Further, after being sheared at high rates and left at rest, the fluid does not recover its higher viscosity behaviour until after a certain characteristic time has elapsed which may be as long as several hours. The other type is the rheopectic fluid which is akin to the dilatant fluid in the same way that the thixotropic fluid is akin to the pseudo-plastic fluid. It is important to realise that there is basically no difference between a thixotropic and a pseudo-plastic material. It is just that for a pseudo-plastic material the characteristic time is so small as to be not observed in normal circumstances. Demonstration Thus it is that if a thixotropic varnish which is like jelly after being left at rest for a long time is mixed up, it becomes quite liquid and stays like that for many minutes after the mixing has ceased. For a pseudo-plastic material, the return to its original state would be instantaneous. Demonstration This was shown by placing a paste of plaster of Paris on an inclined plane. It did not flow appreciably under these circumstances but when the table was vibrated it flowed freely. On stopping the vibration, however, the flow ceased instantaneously. If the material on the vibrating table has been "quick-clay", which is thixotropic, the flow would have continued when the vibration ceased. This would then have been a demonstration of what happens in certain earthquakes where buildings are destroyed because they were built on "quick-clay". 51 PM5: Rheology 5-2 VISCO-ELASTIC MATERIALS Having discussed the effect of time on non-newtonian fluids we are led naturally to the other major class of materials covered by the subject of rheology, viz the visco-elastic materials - the materials which are neither purely elastic nor purely viscous, materials which show the properties of both solids and liquids. Whether these behave as solids or liquids depends on how long the stress is applied. One way of distinguishing between an elastic solid and a viscous liquid is to apply a stress and maintain this stress. A liquid will continue to deform as long as the stress is applied, but for a solid there will be an instantaneous deformation and this will then remain constant with time. But many materials we normally class as solids do not behave like this. Demonstration If we take, for example, a copper wire and stress it, we do get an instantaneous deformation but if we keep the stress constant and observe over a period of a day or so, we find that if the stress is large enough then the wire will continue to deform appreciably over this period - it will have flowed slowly but continuously like a liquid. This phenomenon is known as creep. [Since it flows one can of course ascribe a viscosity to such a solid. Conventionally a material is taken to be a solid if its viscosity is >1014 Pa.s. At such a viscosity a 25 mm edge cube would support a man for a year and sink only 2.5 mm.] Another way to distinguish between a solid and a liquid is to produce a strain and maintain that strain. For a solid a certain stress is required to produce the strain, and to maintain the strain the stress must continue at this value. For a liquid, however, the stress instantaneously goes to zero once the strain is produced. Demonstration But if we take a wool fibre for example and carry out this experiment, we find that the stress does not remain constant nor drop instantaneously to zero. Rather, the stress to maintain a given strain gradually drops as shown in the following diagram: Elastic behaviour Viscous behaviour Stress Strain Time From here the strain is kept constant; the axis now represents time Fig 5.3 Stress-strain curve behaviour for a wool fibre. The curve shows elastic (solid) and viscous (liquid) effects This phenomenon is known as stress relaxation. The time for the stress to drop by e-1, (e is the exponential function) is known as the stress relaxation time, t. Conventionally, a material is called a solid if t > 104 s, and a liquid if t < 10-4 s. The materials in between are the visco-elastic materials. 52 PM5: Rheology There are many visco-elastic materials for example pitch, wool fibres, nylon, silk, vulcanised rubber and bakers' dough. Demonstrations A good example is the material known as "silly" putty. If this is stressed in short times, it behaves elastically - thus it will bounce. If, however, a stress is applied over a long time, it will flow - it behaves as a viscous liquid. Another example is egg white. This will flow but it also shows elastic properties in that it recoils if the flowing stream is broken or cut. We can see that the visco-elastic materials behave as solids when they are stressed in short times but as liquids when the stress is applied over long periods. << An interesting property of visco-elastic materials is the phenomenon known as the Weissenberg effect. Demonstration This is the effect that if a rod is rotated in a large mass of material, the material will climb the shaft. This is observed when cake mix is mixed with a rotating beater. >> 5-3 SOILS AND CLAYS A group of materials whose rheological properties are very important are the soils and clays which compose a large part of the surface of the earth. These materials are quite complicated. They are two-phase materials consisting of solid and liquid (usually water) and their properties depend very much on the concentration of water. The clays are particularly complex in that their properties depend markedly on the presence of electrolytes. Let us first consider these materials in the natural state, in the ground, where they are of importance to people like engineers who are interested in their weight-bearing properties. At low concentrations of water, these materials behave as solids, and if one does have a flow problem it can be considered as the flow of the water through the soil rather than as the flow of a composite material. Demonstration This is shown by maintaining a constant head of water over a bed of sand in a sheet pile structure and injecting dye into the top of the sand on the high pressure side. Water Dye lines Sand Fig 5.4 Flow of water through wet sand The dye follows well-defined lines which can be predicted mathematically. The dye lines show the velocity is fastest where the cross-section is narrowest, and thus illustrate the equation of continuity. As the water concentration in a soil or clay increases its properties change markedly. Clay for example can become either plastic or pseudo-plastic or indeed thixotropic and at all but the highest concentrations of water, is visco-elastic. Demonstration The reduction in the load-carrying capacity of a sand as the water content increases was shown. 53 PM5: Rheology Model building Level gradually raised Water Sand Sand Fig 5.5 Effect of increasing water content in wet sand Clays are not only important in the ground. They have found widespread application particularly in the ceramic industry. A method of ceramic manufacture known as "slip-casting" makes use of the thixotropy of certain clay-water mixtures and also of the pronounced effect of electrolytes on the viscosity of these. Demonstrations A clay-water mixture suitable for pouring into a mould or piping throughout a factory has to have quite a high concentration of water. A low viscosity mixture with very high clay content can be made, however, by adding a small volume of electrolyte (sodium silicate and soda ash). This process is known as deflocculation (the aggregation of the clays particles is greatly affected by the electrolyte). If a deflocculated clay-water suspension is placed in a plaster mould, the water is absorbed into the mould. As the water leaves, the wall of the casting gradually builds up. In the centre of the casting is a thixotropic clay-water mixture which, when the casting wall is sufficiently great, can be rendered liquid by agitation and poured off. 5-4 BLOOD Another material of obvious importance is blood. This has most interesting rheological properties. Blood is a complex fluid, consisting of a plasma in which are suspended a variety of cells, the predominant ones being the red cells. Demonstration To measure its viscous properties, special rotating viscometers have to be constructed and used, which work with very small samples. Measurement show that blood is thixotropic. At high shear rates, normal blood has a viscosity of between 5 and 6 times that of water; but at low shear rates it may be several hundred times that of water. The viscosity for people with certain diseases such as myocardial infarction and thrombosis is much higher, particularly at low shear rates. Demonstration The data presented on the screen, is taken from many patients at Sydney Hospital: 54 PM5: Rheology 10 Viscosity / Pa.s INFARCTION AND THROMBOSIS NORMAL MEN 1 0.1 0.01 0.01 0.1 1 10 100 0.01 0.1 1 10 100 Rate of shear / s-1 Fig 5.6 Blood flow data Notice the similarity between these figures, and figure 5.1. Blood's viscous behaviour is partly due to aggregation of the red cells. These aggregates can, and do, form when the shear rate is low, but at higher shear rates they break up, giving a lower viscosity. This however is not the whole story - the viscosity of the interior of the red cells plays a major part. If the red cells were rigid particles, when their concentration reached 65%, blood would have the consistency of concrete. This however does not happen. Blood is still very fluid even at 99% red cell concentration. The reason for this is that the red cells are not rigid but in fact fluid. Thus it is that blood can flow in the small capillaries - the cells deform as they flow. Any condition which leads to more rigid red cells leads to a much greater blood viscosity. Demonstration An important consequence of the rheological nature of blood is that when it is artificially pumped, as it is in certain types of heart surgery where the heart is by-passed, special pumps have to be used. These are of a roller type. They pump the blood so that the red cells are not damaged by too high shear rates but yet at a rate sufficiently great so that aggregation does not occur. One final aspect to mention is the effect of drugs on the blood flow. These in general affect the flow just by dilating or contracting the blood vessels. Demonstrations Thus it is that when a cigarette is smoked, there is a short term reduction in blood flow due to the nicotine constricting the blood vessels. This can be seen by measuring the blood flow in the vessels of the ear lobe by passing a light beam through it. It is thought, however, that as well, prolonged ingestion of nicotine has a long term effect leading to an increase in aggregation of cells and hence a higher viscosity and reduced blood flow. PM5: Rheology 55 POST-LECTURE 5-5 NOMENCLATURE Though most materials can be classified into broad categories such as those mentioned above it should be emphasised that some materials are very complex and don't neatly fit into such categories. Thus it is that some non-newtonian fluids also show pronounced visco-elastic behaviour. Further there are no sharp dividing lines between the categories, particularly as regards their time behaviour. Thus it is that the terms thixotropic and pseudoplastic are often used almost interchangeably. 5-6 PROBLEM Q5.1 List any materials of everyday experience, other than those given here, which you think are visco-elastic or non-newtonian. Categorise them and say why you think they fall into these categories. 5-7 REFERENCES "The emergence of rheology" Markovitz, Phy. Today , p 23, April 1968. "Quick clay" Kerr, Sci. Amer., p 132, November 1963. "The flow of matter" Reiner, Sci. Amer., p 122, December 1959. "Non-newtonian viscosity and some aspects of lubrication" Stanley, Phy. Educ., p 193, 1972. 56 PM6 FRICTION At midnight in the museum hall The fossils gathered for a ball. There were no drums or saxophones but just the clatter of their bones, A rolling, rattling, carefree circus Of mammoth polkas and mazurkas. Pterodactyls and brontosauruses Sang ghostly prehistoric choruses. Amid the mastodonic wassail I caught the eye of one small fossil. Cheer up, sad world, he said, and winked it's kind of fun to be extinct. OBJECTIVES Aims In this chapter you will study the phenomena of friction, determine the laws of friction and consider the explanation of these laws in terms of a microscopic model. The effects of naturally occluding surface layers on of lubricants on friction are discussed. Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1 Explain and use the following terms : friction, normal force, real area of contact, coefficient of friction, adhesion, cold-welding, lubrication, hydrodynamic lubrication, boundary lubrication, elasto-hydrodynamic lubrication. 2 (i) Recall the experimental laws of sliding friction. (ii) Do simple calculations based on the second of these laws. (iii) Describe an experiment to verify these laws. 3 (i) Using a microscope model, explain the laws of friction. (ii) Describe how electrical measurements and radioactivity measurements can (separately) be used to confirm parts of this explanation. 4 Describe and explain how surface layers alter the value of the coefficient of friction. 5 Describe the process of polishing and explain how it is based on the fact that frictional forces are non-conservative. 6 State the differences among three types of lubrication (hydrodynamic, boundary and elasto-hydrodynamic) and give one example of each type. PRE-LECTURE 1. Remind yourself of the concept of a shear stress (Chapter PM1). 2. Recall that when a metal is subjected to increasing stress it normally goes through an elastic regime where the stress is proportional to strain and then into a plastic regime where there is flow of the metal at essentially a constant stress (Chapter PM1). 3. Remind yourself of the basic concepts of the flow of a viscous liquid and in particular of Newton's law of viscosity (Chapter PM4). PM6: Friction 57 LECTURE 6-1 OUR EVERYDAY EXPERIENCE OF FRICTION Demonstration To slide heavy objects requires considerable effort. The heavier the object the greater the effort. Fig 6.1 Sliding an object Demonstration It is a lot easier to move a heavy object by rolling it than by sliding it. Fig 6.2 Rolling an object We can express these facts by saying that there is a friction force resisting the motion. The force for rolling friction is less than for sliding friction. Demonstrations The force of sliding friction depends markedly on the surfaces involved. Friction is very small in skating and skiing. Friction plagues us in many contexts. Demonstration Considerable power is lost in overcoming friction in engines. Even more important than the power loss is the wear which results from friction. Lubricants can be used to reduce friction and wear. Early applications were the use of animal fats to lubricate chariot wheels. Though friction plagues us a lot, it is of considerable advantage in many contexts. Demonstrations Friction of a rope on something or on itself as in a knot enables large loads to be easily controlled. Friction enables the braking of moving vehicles. Traction of cars, bikes, trains etc. depends on friction. Traction in walking depends on friction. 6-2 LAWS OF SLIDING FRICTION The laws of sliding friction were first formulated by Leonardo da Vinci and re-discovered in 1699 by Admontons. They are empirical laws which give the dependence of the friction force on the relevant parameters. Demonstration One apparatus which can be used to find these laws is a tilting board on which an object is placed. The board is tilted until the object slides. From the measured angle the friction force, the tangential force resisting the motion, can be deduced. (See post lecture material.) PM6: Friction Fig 6.3 Sliding down an incline The laws were, however, determined using the following apparatus: Fig 6.4 An experiment to determine the laws of friction A steel block was placed on a horizontal sheet of steel and connected via a string which passed over a pulley to a weight-carrier which hung vertically. Weights were added to the carrier until the block was just on the point of sliding. The weight was recorded, this being the friction force. Friction force with 1 block = 4.5 N (steel on steel) The block was then turned over onto another face of smaller area and the measurement repeated. The weight was the same as before. Thus we have: First Law of Friction. The friction force Fr is independent of the area of contact. The experiment was then repeated with 2 and 3 blocks of the same weight with the following results: Friction force with 2 blocks = 10 N (steel on steel) Friction force with 3 blocks = 15 N (steel on steel) Thus we have: Second Law of Friction. The friction force F is proportional to the normal component of the contact force N. Thus F Ç N and so F = mN, where m is a constant known as the coefficient of friction. Often two values of this coefficient are given. One is called the static coefficient and corresponds to the force required to just get the object moving. The other is called the kinetic coefficient and corresponds to the force required to keep the object sliding at a constant velocity. The coefficient of friction depends on the surfaces involved. Demonstration This was shown by repeating the measurement for 3 blocks on a sheet of aluminium. 58 PM6: Friction Friction force with 3 blocks = 20 N 59 (steel on aluminium) The laws stated are crude laws, the sort obtained with crude apparatus. Even with this apparatus, complications are evident - the tendency of the object to stick again after it has started to slide. With more refined apparatus, these complications can be examined. As well, the dependence of friction on velocity can be investigated. Demonstration In a simple apparatus of this type, an object connected to a horizontal spring balance rests on a table which can be rotated underneath it. The spring balance measures the friction force. Fig 6.5 Using a spring balance to measure the frictional force This apparatus made evident the fluctuations which occur in the friction force and showed that whereas at low velocities the friction force was essentially independent of the velocity, it did decrease when the velocity became high. 6-3 EXPLANATION OF THE LAWS OF SLIDING FRICTION FOR METALS To explain the laws of friction, it is necessary to introduce additional experimental information. Firstly, a variety of techniques show that even when the surfaces look smooth, they are microscopically rough. This is shown by: Demonstrations Photographs taken with electron microscopes. The oblique sectional technique. If cuts at small angles to a surface are made, surface irregularities are magnified. Fig 6.6 An oblique section Since the surfaces are rough, it is tempting to think that the friction must be due to the intermeshing of the surfaces. But the sliding of such surfaces over each other is non-dissipative. That this cannot be the explanation is also shown by the fact that after a certain degree of polishing, further polishing results in an increase of the friction. Once it is realised the surfaces are rough, it is apparent however that the real area of contact must be small - the surfaces must only touch at a few points. Demonstration This was shown by placing two irregular lead plates in contact with each other. It was further shown that the real area of contact increased as the load increased. 60 PM6: Friction Contact points Fig 6.7 The "contact" between two plates, viewed at a microscopic level Demonstration The increase in area of contact with load was also shown by measuring the voltage drop across two surfaces in contact in the following circuit. The voltage drop depends on the resistance of the path; this resistance decreases as the (real) area of contact increases. Surfaces in "contact" Digital voltmeter V Ammeter A Fig 6.8 Experimental arrangement to measure the potential drop between the surfaces If precise experiments of this nature are made, it is found that the real area of contact increases proportionately with the load. This is so since even at the smallest loads the stresses at the contact points are large enough to make the metals deform plastically. The final important piece of experimental information is that strong adhesion occurs at the points of contact. The points of contact are in effect cold-welded forming a continuous solid. If the materials are to be slid over each other, these junctions have to be sheared. Demonstrations That strong junctions are formed can be shown by oblique sections of the friction tracks formed when one material is slid on another. These show that material is transferred from one surface to the other. This transfer can also be shown by sliding a radio-active metal on a non-radioactive metal. After sliding, radioactivity is detected on the non-radioactive metal. [As an aside, it should be noted that the transfer of metal which occurs when one metal is slid on another (which can occur in screwing or hammering) is of relevance in bone surgery. Since transfer can occur, it is very important to use tools of the same material as the metal plates etc. used to repair the bones. Otherwise, contact EMFs are set up which result in corrosion.] Bringing the various pieces of experimental information together, an explanation of the laws of friction can be given. If we assume the friction force is just that required to shear all the junctions then since the real area of contact increases with the load, then so must the friction force. This is the second law (see post-lecture material for further details). Further, since the real area of contact depends only on the load and not on the apparent areas of contact, the friction force is independent of the apparent areas of contact. This is the first law. Actually the friction force is not only that required to shear the junctions. There is also a contribution associated with the "ploughing" of the hills of one surface through the other surface. This is small unless one surface is very much harder than the other. PM6: Friction 61 6-4 OTHER FRICTIONAL BEHAVIOUR The above picture of sliding friction for metals is incomplete. Invariably, surface layers exist on the metals and these play a major part in determining the frictional behaviour. Indeed, it is only because surface layers exist that metals can be slid on each other. If the surfaces are cleaned in a vacuum and the metals slid on each other in the vacuum, it is found the surfaces bond together so that it is not only impossible to slide one on the other but it is impossible to pull them apart. Demonstration The existence of these strong forces was shown using two accurately plane gauge blocks which were first slid on each other to break down the surface layers. The presence of surface layers can result in a breakdown of the F = mN relationship - the coefficient of friction µ can vary with the load N. This can happen if the layers are such that they remain intact at low loads but break down at higher loads. The coefficient of friction then changes from that for surface layer sliding on surface layer to that of metal on metal or metal on surface layer. Layers of soft metal are placed on the surfaces of bearings to reduce friction. The sliding of non-metals on each is explainable in much the same way as it is for metals. Generally, however, the coefficient of friction is much more load-dependent. For some materials such as rubber this results from the materials deforming elastically rather than plastically at the points of contact. For other materials such as plastics this behaviour arises because they are viscoelastic. Demonstration An important non-metal as regards its frictional behaviour is teflon. This has a very low coefficient of friction of 0.05 - 0.1 arising from the nature of its molecular structure which is 'streamlined". Teflon is an important bearing material being used for example as one of the surfaces in artificial hip joints. Finally, a few words about rolling friction. One form of this is the traction type as in a car wheel on the road where frictional grip is essential. The other is "free" rolling. Demonstration "Free" rolling is typified by a ball-race. In "free" rolling, the coefficient of friction is very low, less than 0.001, which is much less than any coefficient for sliding friction. The mechanism for frictional energy loss is quite different from that for sliding friction. PM6: Friction 6-5 HEATING EFFECTS Friction is a non-conservative force. When objects slide on each other, kinetic energy is converted to heat resulting in increase in the temperature of the surfaces. Demonstrations An abrasive saw cutting a pipe produces sparks. Fire can be produced by the high speed rubbing of one piece of wood on another. Refined experiments show that very localised temperature increases of up to 2000 K for 10- 4 !seconds or less are produced. Demonstration These local hot spots are basic to the polishing process. When a metal such as a denture casting is polished, local thermal softening of the metal leads to flow and filling up of gaps. Obviously, a high melting point polishing agent is necessary for efficient polishing. It is the heating of the surfaces which causes the coefficient of friction to decrease at high velocities. The high temperature enhances the plastic flow, and if it is high enough a layer of essentially liquid metal is produced which acts as a lubricant. Demonstration The heating of the surfaces is basic to skiing. A lubricating layer of water is produced. As the ambient temperature decreases, it is harder to produce and maintain this layer and the skis stick. 6-6 LUBRICATION The reduction of friction between two surfaces by placing another material between them is known as lubrication. Demonstration A block will slide much easier on a table if a layer of oil is spread on it. Hydrodynamic lubrication The type of lubrication in which the surfaces are completely separated by a thin film of fluid is known as hydrodynamic lubrication. It results in very low coefficients of friction, of the order of 0.001 and completely eliminates wear. Demonstration This type of lubrication is used in journal bearings. A complete film is formed if the load is not too high and the speed of the rotating shaft is great enough. Lubricant Fig 6.9 Lubricant squeezed between a rotating shaft and its bearing (hydrodynamic lubrication) In this type of lubrication, the frictional energy loss is due only to the viscous forces in the lubricant (see post-lecture material). The viscosity cannot be reduced indefinitely, however, since the separation between the surfaces decreases as the viscosity decreases and eventually the surfaces come into contact. 62 PM6: Friction 63 Boundary lubrication When metal contact begins to occur as can happen if the speed of the journal is decreased, a continuous film of fluid no longer exists. If the journal speed is further decreased, the lubricant is reduced to localised patches a few molecules thick. Lubrication under these conditions is known as boundary lubrication. represent lubricant molecules Fig 6.10 A very thin film of lubricant, with molecules illustrated (boundary lubrication) In this type of lubrication, the coefficient of friction does not depend on the viscosity of the lubricant but rather on its chemical nature. A good boundary lubricant is one which will attach itself firmly to the clean metal surfaces formed as the cold-welded junctions are sheared. A layer is then formed which acts as a lubricating film, and if it can be easily sheared than the friction is low. Typically coefficients of friction of the order of 0.1 are obtained and the wear is slight. Elastohydrodynamic lubrication Of considerable interest is the lubrication of synovial joints in animals, such as the hip joint. This can be explained neither in terms of hydrodynamic nor boundary layer lubrication. Rather it seems that the lubrication is of another type known as elastohydrodynamic lubrication in which the surfaces deform appreciably, the elastic deformations being comparable with the lubricating film thickness so that it is maintained. In the synovial joints the cartilage elasticity is such as to allow this process. The rheological properties of the synovial fluid are also important; in particular the synovial fluid is thixotropic. This theory of synovial joint lubrication is supported by the fact that synovial fluid from rheumatoid arthritis cases is newtonian, and that wear in the joint occurs when hard calcifying material is deposited on the cartilage. (This decreases the cartilage elasticity.) PM6: Friction POST LECTURE 6-7 PROBLEMS Q 6.1 In the inclined plane apparatus used for measuring the coefficient of friction ,(shown in the diagram below) the block starts to move down the plane when the angle of the plane is q. Fig 6.11 Diagram for Q6.1 Derive an expression for the coefficient of friction in terms of this angle q. Q6.2. Friction is a dissipative force. Thus it has been stated in the lecture that friction cannot be understood in terms of intermeshing surfaces sliding over each other since this is a non-dissipative process. Explain why this sort of process is non-dissipative. 6-8 AN EXPLANATION OF THE SECOND LAW OF FRICTION The second law of friction can be explained in terms of the shearing of cold-welded junctions. If s is the shear strength of the junctions and A the total real area of contact, then the frictional force F is given by F = A s. Further, since plastic flow occurs at the junctions the normal force N is related to the area of contact by the expression N = Ap where p is the yield pressure, the stress at which plastic flow occurs. s Thus F = p N s and so m = p. If s and p are taken as those of the softer material, this expression predicts reasonable values for m. Really good agreement is not obtained because of the influence of surface layers. 64 65 PM6: Friction 6-9 MORE PROBLEMS Q6.3 Since friction is a dissipative force, the model which explains it in terms of the shearing of cold-welded junctions must involve energy dissipation. Explain how this energy dissipation occurs. Q6.4 A shaft of radius r is rotating with angular velocity w in a bearing. Assume that a thin film of lubricant of uniform thickness d exists between the shaft and the bearing and that the length of shaft supported by the bearing is Ú. Stationary bearing Rotating shaft r Lubricant d Fig 6.12 Diagram for Q6.4 (a) What is the velocity gradient in the film assuming that this gradient is uniform throughout the thickness of the film? (b) Determine the shear stress in the lubricant using Newton's law of viscosity. (c) Hence obtain an expression for the friction force at the surface of the shaft, the force at the surface of the shaft, the force which is resisting its rotation. (This result shows, as mentioned in the lecture, that to reduce the resistance to motion, the coefficient of viscosity has to be decreased. You should also note that the theory given here is that pertaining to the torsional viscometer which was described in chapter PM4.) 66 PM7 SOUND Some claim that pianists are human, And quote the case of Mr Truman. St Saens, upon the other hand, Considered them a scurvy band. Ape-like they are, he said, and simian, Instead of normal men and wimian. OBJECTIVES Aims In this chapter you will study the phenomena of sound. You will find that the speed of sound depends on the stiffness and the density of the medium it propagates through. The property specific acoustic impedance, of a medium is defined and its role in determining the reflection of sound from boundaries between two media is discussed. The physics involved in the ear and in hearing is discussed. Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1 Explain and use the following terms: acoustic impedance, specific acoustic impedance, impedance matching, Fourier analysis, Fourier synthesis. 2 Recall how the acoustic impedance of a medium depends on the bulk modulus and the density of the medium. 3 (i) Recall how the specific acoustic impedance of a medium depends on the bulk modulus and the density of the medium. (ii) Give a definition of sound power reflection coefficient between two media in terms of the amplitudes of incident and the reflected waves and in terms of the specific acoustic impedances of the two media. (iii) Describe an experiment to verify these laws. 4 Describe what is meant by an acoustic impedance mismatch; and describe a method by which the problems arising from such a mismatch may be avoided. 5 Describe an experiment to analyze the frequency components present in a musical note or other sound. 6 (i) Draw a schematic diagram of the ear, identifying the following : outer ear, auditory canal, eardrum (tympanic membrane), ossicles, oval window, cochlea. (ii) Draw a schematic diagram of the cochlea identifying the basilar membrane and the nerve cells. (iii) State the general form of the information processed in the cochlea and sent to the brain. (iv) Describe how ageing limits the frequency response of the ear. PM7: Sound 67 PRE-LECTURE Recall the following information from various lectures scattered throughout this course. (i) The definition of the Bulk Modulus, and Hooke's Law as it applies to substances which are deformed by volume compression stresses. (ii) In Electrical Circuit Theory there is a theorem called the power matching theorem. It concerns the problem of getting energy from a source (battery) to somewhere it can be used (load). In order to get efficient power transfer, it is found that it is necessary for the impedance (resistance) of the load to match the internal resistance of the battery. If either one of these two is much bigger than the other, then only a small fraction of the available energy appears in the load, most is dissipated in the source. This will be discussed in greater detail in the live lecture following this television lecture. In many, many cases involving the transport of energy from one place to another, the same kind of reasoning will be found to apply. There will be a source and a receiver (load); and there will be property of each which will effectively determine its ability to accept and transmit energy; this will usually be given the name impedance. Then, unless the impedance of the source is roughly the same as the impedance of the receiver, energy will not readily get from one to the other. (iii) A mathematical discussion of simple harmonic oscillations was given in lecture FE7. For a mass oscillating at the end of a spring, the force is given by Hooke's law pointing to the fact that this kind of oscillation is essentially an elastic phenomenon. You will recall from that discussion that the frequency of a simple harmonic oscillation was determined by (a) the mass of the object and (b) its spring constant (or alternately its Young's Modulus). Sound consists of elastic vibrations also (pressure oscillations in fact) and you would therefore expect that a mathematical analysis would yield a similar result: viz. that the parameters describing the propagation of sound waves through a medium would also depend on two quantities: the density or the medium, r and its Bulk Modulus k. (iv) Also in lecture FE7 you met the concept of fourier analysis, the breaking down of a complicated oscillation into a sum of simpler sinusoidal oscillations. Each of these sinusoidal components has an amplitude and a phase. The inverse problem, that of starting with simple oscillations and combining them into a more complicated shape is called fourier synthesis. LECTURE It is assumed that you already know a fair bit about sound, particularly how it is generated. We will concentrate on two aspects only: its propagation and its analysis. We do this with specific reference to the EAR and electrical hearing devices. PM7: Sound 7-1 ACOUSTIC IMPEDANCE The ear may be sketched schematically thus: Fig 7.1 Cross-section of the ear Sound waves impinge on the outer ear (A) and are conducted through the narrowing column of air (B) to the drum (C). There the vibrations of air pressure are translated into mechanical oscillations, which are carried with slight mechanical advantage due to lever action, by the ossicles (D) to another membrane, the oval window (E). Beyond that point the information in the sound is converted into electrical signals to be sent to the brain. To understand the structure of the outer ear, we must talk in general terms about the propagation of pressure waves through an elastic medium. Demonstration A mechanical model of an elastic medium might be: Fig 7.2 A mechanical model of an elastic medium The speed at which a disturbance will travel down this chain can be seen to depend on (i) the mass of the object. Clearly the heavier the objects, the more slowly will each mass move after being pushed by its neighbour, and the more slowly will the "wave" propagate. ii) the strength of the springs. Clearly the stronger the springs, the more quickly will they expand after being compressed, and so the more quickly will the "wave" propagate. Generalizing to a three dimensional rather than a linear medium, we might expect the speed of sound to increase as the density decreases, and as the bulk modulus increases.The formula is speed of sound: (k is the bulk modulus, r is the density.) c= k/r 68 PM7: Sound 69 Consider now the boundary between two media. What determines how a wave propagates from one to the other? *An extremely simple mechanical model is a row of billiard balls: Fig 7.3 A disturbance “propagating” through a row of billiard balls. The disturbance propagates with no net motion of the medium only if all balls are absolutely identical. [Why?] If any one ball is heavier or lighter than the others, then the disturbance will result in some reflection as well as propagation of kinetic energy. Demonstration A better mechanical model is again cars and springs. A disturbance will propagate with no net motion in the medium, only if all cars and all springs are identical. Reflection will occur at any point where there is as CHANGE of either mass or spring strength. Demonstration However, an increase in mass can, in part, be compensated for by a decrease in spring strength. Careful experimentation will show that you can maximize propagation and minimize reflection if you keep the product of mass and spring strength constant along the medium. Generalizing to three dimensions, we define a quantity called the specific acoustic impedance, z, by the equation z ≡ kr to serve as an index to tell us whether sound energy can efficiently be transferred from one medium to another. Clearly we could redefine this quantity (as is more usual) in terms of the velocity of sound, c: z = rc PM7: Sound The specific acoustic impedance is a property of the medium. A particular acoustic device will be described by a quantity called the acoustic impedance, which depends on both the shape and size of the device. The name impedance comes from the analogy with electrical circuit theory (as described in the pre-lecture material). It may be helpful in understanding this subject to realize that acoustic impedance plays a role analogous in some respects to resistance; and in the same way specific acoustic impedance is analogous to resistivity. Consider again the ear. Since both the density and bulk modulus of skin are much greater than that of air, the specific impedance of the eardrum is vastly different from that of the outside air. Hence there is an enormous mismatch of specific impedances, and only a tiny fraction of the energy of the sound wave can get from the air into the eardrum. The rest is simply reflected back. This is a bit of a simplification. As we said before, acoustic impedance depends also on the geometry of the device; and the narrowing of the auditory canal plays a most important role. The impedance of a layer of air near the drum is considerably greater than a layer of air near the outer ear. Crudely speaking, a narrow column of air is more difficult to get moving than completely free air, because of viscous effects at the side of the tube. Its impedance is increased by the narrowness of the tube. Fig 7.4 Impedance and width of tube (The use of a horn shape to get impedance matching comes into loudspeaker design, where the problem is to get energy from inside out into the air.) Nevertheless, the impedance of the air near the drum, and that of the drum itself are still badly mismatched, and most of any sound wave is reflected away. Demonstration Clinical measurements of drum impedance feed into the ear a sound of known intensity, and measure the intensity reflected from the drum. This gives the impedance of the drum (relative to that of air [see post-lecture]. Obviously, for example, if no sound is reflected, the impedance of the drum is exactly the same as that of air. 70 PM7: Sound 71 Since you know the elasticity and density of skin and bone, it should be possible to work out the acoustic impedance of a normal ear and how it is affected if you change the pressure, for example. This is rather an impossible calculation; but standard audiological procedure is to measure the way drum impedance varies with pressure and to compare with a known normal ear. By this means, it is possible to pick up certain specific defects in the drum or the ossicular chair - for example a perforated drum or a calcified ossicular chain. To sum up: there is an enormous impedance mismatch between the eardrum and the outside air, so you only detect a very small fraction of the energy in any sound wave. From this point of view, the ear is in an inefficient hearing device. Electrical hearing devices for example get over this problem by incorporating an AMPLIFIER as an essential component. 7-2 FOURIER ANALYSIS Beyond the oval window in the inner ear is the cochlea, a snail like structure which, if it could be straightened out, might look in principle like this: Fig 7.5 A “straightened out” cochlea Pressure variations in the oval window are transmitted by fluid to the basilar membrane. Because of its geometrical shape, different parts of this membrane resonate with oscillations of different frequencies. Nerve cells connecting this membrane to the auditory nerve, tell the brain which part of the basilar membrane is vibrating - and thus what simple harmonic oscillations are present in the original sound wave. Fig 7.6 Helmholtz Spectrum Analyzer Demonstration A musical note of the correct frequency will cause one of these cavities to resonate. The increased amplitude of vibrations thus set up, are made to cause a gas jet to flicker up and down. Which cavity is resonating can then be detected in a rotating mirror system (this apparatus was built circa 1890). PM7: Sound Demonstration This apparatus is in principle capable of identifying all the harmonies present in any musical note. However, it is too cumbersome to use seriously. Modern spectrum analysis is all done electronically. Sound is fed into a microphone and the result displayed on an oscilloscope screen. You interpret the output thus: for a reasonably pure note you might get something like Fig 7.7 Spectrum of sound as seen on a spectrum analyzer screen [Note: in order to analyze the spectrum accurately the apparatus must listen to the note for some time and "count" how many oscillations occur in that time. That is why you see such a slow rate of scan. The slower the rate the more accurate the analysis.] *With the aid of a spectrum analyzer you can determine what gives the human voice or various musical instruments their distinctive sounds. It is just a question of what harmonics (or overtones) are present, and in what strength (amplitude). *In order to get a feeling for the relationship between a sound and its spectrum, just listen to the sounds as they are produced and see if you can correlate the most prominent features of the spectrum you see with what you hear. [Note: It seems to be the basic philosophy of much modern music that the older instruments have become stale and uninteresting. And indeed the spectrum of one wind instrument for example, is very like that of another. So musicians today are trying to get sounds out of all sorts of unlikely instruments - to produce completely new spectra for the ear to listen to.] To sum up: the cochlea is a device for translating a series of pressure vibrations into a coded set of electrical signals which the brain uses as a sensory input. And the information going to the brain is of the general form: (i) what simple harmonic frequencies are present, and (ii) what their amplitudes are. That this is a true representation of the ear can be confirmed by two observations. Demonstration (i) In some deaf schools, children are taught to speak by getting them to match the oscilloscope pattern of a sound made by the teacher. In the way this technique is usually used, the pattern the child has to reproduce is NOT the frequency spectrum but simply the pressure-time variations. However, you will notice that the teacher has obviously found from experience that it is most effective to change the scale every now and then, thus directing the child's attention to specific harmonics. [This technique is still not fully developed or accepted; and one suspects that it will not be until it is carried out with complete spectrum analyzers rather than simple oscilloscopes, that it will prove most effective.] Demonstration (ii) The inverse of a Fourier analyzer is a Fourier synthesizer - and electronic organs act as such when they build up a complicated oscillation from the fundamental and a few harmonics. 72 73 PM7: Sound For example: Fig 7.8 Fourier synthesis If you change only the phase of one of these Fig 7.9 Another example of Fourier analysis with a minor change from Fig 7.8 It is a demonstrable fact that the ear cannot distinguish between these two sounds. And though these two pressure-time patterns are quite different, they have the same fourier spectrum - the various harmonics present have the same amplitudes. It is only their phases which are different. *The new breed of musical instruments based on this simple electronic organ principle are given the generic name synthesizers. The most commonly known perhaps is the Moog. Demonstration The new breed of musical instruments based on this simple electronic organ principle are given the generic name synthesizers. The best known perhaps is the Moog. POST LECTURE 7-3 REFLECTION AND TRANSMISSION Actually to calculate how much energy is transmitted or reflected when a sound wave encounters an impedance mismatch, like for example at the ear or a microphone, is very complicated, because it is the mismatch of impedances of the device itself, and the small part of the air right next to it which must be analyzed. However when we consider the passage of a sound wave from one relatively large quantity of one medium to another, things are a little simpler. Then we need to consider only the bulk property of each medium - the specific acoustic impedances. If a wave of amplitude Ai is incident on a boundary between two media; and a wave of amplitude Ar is reflected from the boundary; then the sound power reflection coefficient ar, defined as the ratio of reflected sound energy to incident flow or sound energy, is given by ar = Ar 2 Ai2 = Ê z2 - z1 ˆ Á ˜ Ë z2 + z1 ¯ 2 where z1 and z2 are the specific acoustic impedances of the media before and after the boundary. It can be appreciated immediately that complete transmission (i.e. ar = 0) will only occur when the two media have exactly the same specific acoustic impedances. Q7.1: Why can you hear small sounds so much more clearly under water than in air? [ANS 9] PM7: Sound 7-4 IMPEDANCE MATCHING When there is an impedance mismatch between two media, it is possible to take steps to increase the transfer of energy between the two. One method, for specific devices, was mentioned in the lecture. For large quantities of the media, this can be done by intervening a third medium between the two. Then so long as the specific impedance of this third medium is intermediate between that of the first two, it is found that the transmission of energy is greatly increased. Perfect transmission of energy occurs, in theory, when z3 = z1 z2 (where z3 is the specific impedance of the intervening medium) and where the thickness of the medium is a quarter wavelength. You may recall from your optics lecture (L4) that a very similar condition - with refractive index rather than specific acoustic impedance - describes the ideal way to reduce reflections at air to glass boundaries in optical systems. 7-5 FREQUENCY RESPONSE OF THE EAR Because of physical limitations, the ear will not respond to all frequencies. The main limitation comes from the geometry of the cochlea. If you remember what you have learnt about resonance, then a solid body can resonate with a sound wave if its size is roughly similar to the wavelength of the sound (in that material). Hence if you consider the basilar membrane to look schematically like this Fig 7.10 A veryschematic representation of the basilar membrane The lowest frequency it can pick up well will correspond to the width of the big end, and the highest frequency will correspond to the width of where exactly the last nerve cell is located at the small end. However, there are other factors which limit the frequency range, especially at the high frequency and the most important is the elasticity of the eardrum. This determines its ability to follow a very high frequency vibration. It is found, and you would expect it to be so, that as people age, the elasticity of their skin decreases and so therefore does the highest frequency they can hear. For young people, the upper range is about 20 - 30 kHz, but in middle age, it is found that the upper limit of hearing can drop by 80 Hz every six moths. Also the state of the joints in the ossicular chain clearly influence frequency response, since these too must vibrate at the same frequency as the drum. Also the state of the joints in the ossicular chain clearly influence frequency response, since these too must vibrate at the same frequency as the drum. Q7.2: In general how would you expect that the frequency range of the ear would vary with the size of the animals? [Ans 25] 7-6 REFERENCES Bekesy “The Ear” Scientific American, August 1957, p 66. van Begerjk et al “Waves and the Ear”, Heinemann Science Study Series. 74 75 PM8 ULTRASONICS Puccini was Latin, and Wagner Teutonic, And birds are incurably philharmonic Suburban yards and rural vistas Are filled with avian Andrews Sisters. The skylark sings a roundelay, The crow sings The Road to Mandalay, The nightingale sings a lullaby And the seagull sings a gullaby. That's what shepherds listen to in Arcadia Before somebody invented the radia.. OBJECTIVES Aims In this chapter you will study ultrasonics. Much of the lecture is concerned with the applications of ultrasonics using techniques of echoscopy and the Doppler technique. Minimum Learning Goals When you have finished studying this chapter you should be able to do all of the following. 1. State the frequency range of ultrasound. 2. Do simple calculations relating the wavelength, frequency and speed of sound waves and ultrasonic waves. 3. Describe an ultrasonic transducer and explain how it is used to generate or detect ultrasound. 4. (i) Explain how the short wavelength of ultrasound makes it possible to focus a lot of energy into a small space. (ii) State two applications of this property. (ii) State an illustration of the Doppler effect with electromagnetic waves. (iii) State and describe two applications of the Doppler effect with ultrasonic waves. 5. (i) Describe what is meant by the Doppler effect. (ii) State one illustration of the Doppler effect with electromagnetic waves. (iii) State and describe two applications of the Doppler effect with ultrasonic waves. 6. Describe and distinguish the techniques of radar, sonar and echoscopy. 7. Describe and explain one example of the use of echoscopy. PRE-LECTURE Refer back to lecture PM7 to remind yourself of the concept of specific acoustic impedance and of its importance in the transmission of sound from one medium to another. PM8: Ultrasonics LECTURE 8-1 INTRODUCTION Sound experienced by human falls in the frequency range 0 - 20 kHz. Sound above this frequency is known as ultrasound. It can be detected by some animals. Demonstration A dog can hear low frequency ultrasound such as that produced by a Galton whistle (the principle of this whistle is discussed in the T.V. lecture). Ultrasound has many important applications some of which will be discussed in this lecture. These arise partly because sound at these high frequencies has short wavelengths and partly, just because it is sound, it is a pressure wave and hence will travel in materials. Though the use of ultrasound by man is of relatively recent origin, BATS have always used it. For a long time it was thought bats made no noise but by recording them on magnetic tape and playing the tapes back at a slower speed (this reduces the frequency of the recorded sound) it was found that they make sounds in the 40 - 55 kHz regime. They use this ultrasound for navigational purposes and also for locating their prey. The ultrasound is produced in short duration screeches of about l0 - l5 milliseconds and that part of it which has bounced off something back into the direction of the bat is heard by it. The elapsed time gives the bat information on how far the object reflecting the pulse of ultrasound is from it. 8-2 GENERATION AND DETECTION OF ULTRASOUND Demonstration Sound is produced when an object vibrates Fig 8.1 Production of sound using a tuning fork Ultrasound is produced in the same way but to get ultrasound we have to make a vibration at ultrasound frequencies. One device for doing this is the Galton whistle but ultrasond can be produced much more conveniently and efficiently by making use of piezo-electric materials such as barium titanate. These have the property that when a voltage is applied in a certain direction, the dimension of the material in that direction increases, and if the sense of the voltage is revesed then the dimension decreases. By applying a high frequency alternating voltage, the material is caused to vibrate at a high frequency and so ultrasound is produced. 76 PM6: Friction 77 Fig 8.2 Production of ultrasound using a transducer A device to produce ultrasound based on this principle is known as a transducer. These transducers can detect ultrasound by using them in reverse. Demonstration Ultrasound falling on one of them causes it to vibrate and hence a voltage is produced across it, a voltage which can be detected using, for example, an oscilloscope. Since ultrasound is at high frequency, its wavelength is short and so it can be focussed into small regions. When used at high power, this fact gives ultrasound a variety of important uses. Strongly focussed high power ultrasound can be used for example to kill microorganisms, to study cells by splitting them open, to produce small lesions in the brain, to treat a disease of the inner ear known as Meniere's disease, to remove hard deposits on the valves of the heart and so on. It can also be used for more prosaic applications such as drilling and cutting. Demonstration Ultrasound at high power is also used extensively for clearning. The ultrasound is produced in a bath of liquid in which the object to be clearned is placed. The high intensity ultrasound causes negative pressures in the liquid and as a result bubbles called "cavitation" bubbles are produced. Agitation produced by these cleans the object. If the object is kept too long in the cleaner, particularly if it is thin, it can be extensively damaged. 8-3 DOPPLER TECHNIQUES The frequency of a wave emitted by a moving source is different to a stationary observer from that when the source is stationary. This is known as the DOPPLER EFFECT. When the source is moving towards the observer, the frequency is increased and when the source is moving away the frequency is decreased. The effect also applies to a wave reflected from a moving object. Demonstration The police make use of the Doppler effect in their radar speed traps. (NOTE: It is difficult to upset a speeding conviction based on a radar trap, because you can demonstrate the device is working properly just by using a tuning fork). A common example of the Doppler effect is the sound of an ambulance siren as the ambulance approaches and passes. The "red shift" i.e. the shift to lower frequencies, of light from other galaxies is interpreted to mean that the galaxies are moving away from each other and hence the concept of the expanding universe. PM8: Ultrasonics Demonstration The effect can be demonstrated by having an ultrasound generator mounted on a car which can run on rails either towards or away from a stationary ultrasonic detector. The frequency of the detected sound can be measured with a digital frequency meter.. Detailed measurements with such apparatus show that the change in frequency is proportional to the velocity of the source. Since the change in frequencyu is proportional to the velocity, a measurement of this change can be used to determine the velocity of the source. Or, alternatively, if the wave is reflected from a moving surface the change in frequency of the reflected wave relative to the incident one gives the velocity of the moving surface. In this latter form there are many uses of Doppler techniques with ultrasound in medicine. For example it is possible to detect the foetal heartbeat as early as the l0th week, and by measuring the motion of blood vessel walls it is possible to learn about their elasticity. Demonstration In clinical medicine, the technique is used to detect blood flow in arteries and veins by means of an external probe. This is placed against the skin and more or less angled along the blood vessel. A paste is applied between the skin and probe to improve impedance matching and so lessen power loss by reflection. The ultrasound produced by the probe is reflected from the flowing blood and then detected by the probe. A probe such as this shows quite different sounds for arteries and veins. For arteries, the sound is characteristic of the pulsatile blood flow in arteries. In veins, it is more like a wind-storm which cycles with the respiration. The probe can detect blockages in arteries and veins. (N.B. The medical term "patent" which is used in describing this technique means "unblocked".) Doppler techniques have been used in a different way to measure the blood flow in research projects on animals. Demonstration Small probes are placed around arteries during an operation. They heal in place with the leads coming out of the skin. In an experiment, the leads are connected to a telemetering device carried in a package on the animal. In this way it is possible to look at patho-physiological conditions in conscious animals in realistic situations. This technique has been used for example on dogs which have been made hypertensive. It has also been used on small monkeys to study the effect of severe oxygen lack on the circulation. In a proposed experiment it is to be used on baboons to study the effect of diet on coronary disease. 8-4 ECHOSCOPY If a pulse of waves of known velocity is setn out from a transmitter and the time taken for the puse to return after being reflected from a distant object is measured then this time is a measure of the distance of the object. This technique is called the "pulse-echo" technique and with electro,magnetic waves is of course radar. This technique can also be used with ultrasound. It is of course the technique used by bats for navigation. It is used it as sonar for depth sounding, detection of submarines and shoals of fish. In medicine, the technique is used and is then known as echoscopy. If ultrasound travelling in one medium encounters another, in general some will be transmitted into the other medium as well as being reflected. How much energy is reflected depends on the sound power reflection coefficient, which in turn depends on the specific acoustic impedances of the two media If these are almost the same, little energy is reflected; if they are widely different, much energy is reflected. 78 79 PM6: Friction There are not large differences bvetween the specific acoustic impedances of the various soft tissues in the body (see post lecture material). Thus the pulse-echo technique can be used to obtain two-dimensional cross-sectional views through various organs in the body. As the ultrasound penetrates into the organ, some is reflected at a soft-tissue boundary but most is transmitted to suffer further reflections from successive boundaries. The time delays and amplitudes of the signals from the different boundaries make up the two dimensional picture called an echogram. In looking at an echogram it is important that it be not thought of in the same way as an x-ray picture. The latter is a three dimensional view compressed into the two dimensions of the x-ray plate. The echogram is, however, a true two dimensional cross-section through an object. Demonstration One use of this technique is in a machine designed to scan the eye. It can pick up retinal detachment and is extremely valuable in detecting tumours behind the eye. It should be noted that the acoustic impedances of the transducer and the eye are matched in this machine by having the transducer in water contained in a plastic membrane to which the eye, rubbed with a paste, is pressed. If the ultrasonic waves were sent through the air to the eye, most would be reflected at the outer surface of the eye. Demonstration This technique is also used in obstetrics to scan the pregnant uterus. The matching of acoustic impedances should again be noticed. The technique is of majeor importance in this field for unlike x rays, ultrasound appears to be completely safe. The technique gives information on the size of the foetus, how many there are, if it is growing at a reasonable rate, whether it has miscarried, whether there are any gross abnormalities etc.The technique can also be used for examining the non-pregnant abdomen for picking up tumours. POST-LECTURE 8-4 ACOUSTIC PROPERTIES OF VARIOUS MATERIALS The following table gives the acoustic properties of various materials. Material Velocity/m.s Density/103 kg.m– 3 Specific acoustic impedance/106 kg.s– 1.m– 2 water 1530 1.00 1.53 blood 1534 1.04 1.59 fat 1440 0.97 1.40 brain 1510 1.03 1.55 liver 1590 1.03 1.64 muscle 1590 1.03 1.64 bone 3360 2.00 6.62 air 340 0.00012 10–4 Q8.1 Why is the frequency of ultrasound which bats use so high? [Ans 6] Q8.2 Show the importance of acoustic impedance matching in echoscopy by comparing the fractional power reflected for a water-flesh interface with that for an air-flesh interface. [Ans. 13]