FOOD TECHNOLOGY REPORT Ashland Specialty Ingredients ashland.com Page 1 of 7 FTR-016-1 (Supersedes FTR-016) Oil Reduction Strategies for Fried Asian Instant Noodles With Ashland cellulose gums Introduction Fried Asian instant noodles are growing in global popularity as manufacturers of instant noodles are constantly challenged with ingredient costs. Small price fluctuations in commodities such as palm oil can have a significant impact on the profitability of products. This report presents cost-effective solutions that help instant noodle manufacturers reduce the uptake of oil in instant noodles, and often improve the texture of the noodles. Background Although noodle manufacturers vary in their processes and formulations, there are common elements. Wheat flour predominates in the formulations, and typically the wheat flour is made into dough through the addition of kansui solutions. Kansui solutions are typically alkaline salt solutions composed of potassium carbonate, sodium carbonate, and sodium chloride salts. Instant noodle dough is then sheeted, reduced in thickness, and cut into individual noodle strands. The noodles are then steamed to gelatinize the wheat starch and further cooked through deep frying, typically in palm oil. This process is presented visually in Figure 1. Kansui preparation: Potassium carbonate, sodium carbonate, sodium chloride + water Wheat Flour Mixing Sheeting Cutting and block forming Steaming Frying, cooling, packaging Figure 1. Process for manufacturing fried instant noodles All statements, information, and data presented herein are believed to be accurate and reliable, but are not to be taken as a guarantee, an express warranty, or an implied warranty of merchantability or fitness for a particular purpose, or representation, express or implied, for which Ashland assumes legal responsibility. ®Registered trademark, Ashland or its subsidiaries, registered in various countries. ™Trademark, Ashland or its subsidiaries, registered in various countries. *Trademark owned by a third party. © 2013, 2014 Ashland. Rev. 9-2014 Page 2 of 7 Asian instant noodles are typically formed in blocks, and packaged as such. Consumers then quickly cook the noodles by immersing in hot water for 3 to 4 minutes. Because the noodles are precooked through the steaming and frying processes, the preparation process is rapid. There are health concerns in some regional markets about fat content of instant noodles because of the oil used for 1 frying. Fat content varies from 15–25% in the final product, depending upon brands and markets. The work described here represents an extensive, fundamental approach to understanding oil reduction in instant noodles, which has resulted in solutions that: • reduce total fat content by 2-3%, • result in 12% less oil being adsorbed compared to noodles without Ashland’s cellulose gum (sodium carboxymethylcellulose or CMC), • improve noodle texture, • and are easy to incorporate in manufacturing plants. These results were achieved through consulting global experts and through a series of trials undertaken at the Wheat Marketing Center in Portland, OR, USA. The Wheat Marketing Center has unique technical facilities for identifying the best products and approaches for incorporating cellulose gums into fried instant noodles and reducing oil uptake during the frying process. Methods The noodle processing scheme described in the Introduction is the basis for oil reducing strategies using Ashland CMC. Two primary mechanisms for incorporating the cellulose gum into fried instant noodles are recommended. This gives manufacturers options, depending upon the setup of their manufacturing process. The two methods are as follows: 1. Adding CMC to the kansui solution, and adding this kansui solution to the wheat flour. 2. Dry addition of the CMC to the wheat flour, through mixing, before addition of the kansui. Table 1 shows the formulations used for trials. United States Hard Red Winter wheat, at about 14% protein, was used for the trials. A standard formula was used for the control product, and ingredients are listed on a “flour weight basis” (i.e., 33% water was not the actual water content of the wheat dough, but is relative to the flour used). Table 1. Formulations used in this study Ingredient Wheat flour Kansui solution Test formula for Test formula for CMC addition to the CMC addition to the k ansui solution (g) wheat flour (g) Control formula (g) 100 100 100 39.1 37.9 34.7 Water 37 35 33 Sodium chloride 1.5 1.5 1.5 Potassium carbonate 0.1 0.1 0.1 Sodium carbonate 0.1 0.1 0.1 CMC FR-A 0.4 0 0 CMC FR-B 0 0.2 0 139.1 137.9 134.7 Total Results were optimized for different use levels of CMC in addition to different types of CMC. A benefit that sets CMC apart from other hydrocolloids is the fact that it is available in a wide range of viscosity grades with varying degrees of substitution. In this report we are highlighting our most successful grade for addition to the kansui solution and our most successful grade for addition to the wheat flour. Page 3 of 7 Water level at the pilot plant was adjusted to compensate for the water absorbing ability of the CMC. More water was needed at higher CMC use levels. In general, a 0.1% (flour basis) increase in CMC was accompanied by a 1% (flour basis) increase in water. Kansui formulations were made to keep the amount of sodium chloride, potassium carbonate, and sodium carbonate constant, but water levels were adjusted. Process 1: CMC Addition to the Kansui Alkaline Salt Solution a. CMC type FR-A was added to the kansui solution at 0.4% on a flour basis, with mixing, until fully hydrated. An overhead mixer with moderate to high shear capability is the recommended method for incorporating into the kansui solution. Full hydration was judged by a homogenous appearance, without any visible beads, lumps or undissolved CMC. b. For pilot plant scale trials at the W heat Marketing Center, batches were based on 800 g of wheat flour. After the CMC/kansui solution was made, it was mixed into the 800 g of wheat flour in a horizontal mixer at 90 rpm for 2 minutes (see Figure 2). The mixer was then run for 10 minutes at 120 rpm. The dough was allowed to rest for 5 minutes at room temperature, prior to sheeting. Figure 2. Pilot plant scale mixer for mixing wheat flour and CMC/kansui solution c. The sheeting process was initiated by a compounding step, where the dough was formed between two pairs of rollers with a 3 mm gap. These two sheets were then layered and compounded through rollers with a 5 mm gap. d. The sheet was reduced in thickness by passing through a consecutive series of rollers with gaps of 4 mm, 3 mm, 2 mm and 1.5 mm (see Figure 3). The final roller was calibrated for a 1.0 mm thickness, ±0.03 mm, and noodles were cut at 1.0 mm. The cut noodles were then guided into a waved pattern using a waver as the noodles exited the cutter. Page 4 of 7 Figure 3. Size reduction process of dough sheets e. Noodles were passed through a continuous tunnel steamer for 4 minutes, steaming at 98–100°C. The noodles were then cut into 125 g blocks and fried in palm oil for 70 seconds at 150°C (see Figure 4). Figure 4. A noodle block after frying Process 2: Dry Addition of CMC to Wheat Flour Kansui solution (Table 1) is prepared normally and the CMC is added to the wheat flour, prior to being hydrated by the kansui solution. Prior to the 2 minute mixing of kansui and wheat flour, the wheat flour and CMC are mixed for a minimum of 10 minutes at 90 rpm, for thorough dispersion of the CMC throughout the wheat flour. CMC type FR-B was added to the wheat flour at 0.2% (flour basis, or 0.2 g of CMC type FR-B to each 100 g of wheat flour). The water level was adjusted to be 35% flour basis because of the added CMC. After thorough mixing of CMC type FR-B and wheat flour, steps b through e, as described in Process 1, were used for Process 2. Page 5 of 7 Mechanism The frying of foods, including instant noodles, results in the development of macroscopic and microscopic pores, that act as reservoirs to retain excess oil. We theorize that a key to oil reduction is to control the size, volume, and number of pores in fried foods, and reduce the available volume for excessive oil storage. Pores are created by the vaporization of internal water during the frying process, and rapid release through fissures 1 and cracks that extend to the surface of the noodles. Frying is essential to preparing a fully cooked noodle that is readily prepared for consumption by immersion in hot water, and is necessary for flavor and texture development. However, the excessive oil that is retained in unnecessarily large pores may contribute to excessive fat content, and is unneeded for the quality of the instant noodle. Ashland Specialty Ingredients CMC grades are believed to reduce fat content of instant noodles by providing structural integrity to the instant noodles during the steaming, and particularly the frying processes, resulting in smaller pores, less volume and less pores. This will reduce the incremental oil uptake during frying processes that is unnecessary for organoleptic and cooking properties. Confocal Raman Spectroscopy is a technique that identifies fat residing in microscopic pores on the surface of the instant noodles. Figure 5 shows a series of images that display • a hexane extracted noodle, showing very little residual oil content, • a control instant noodle without polymer, • an instant noodle made with CMC FR-A at 0.4%, and • an instant noodle made with CMC FR-B at 0.2%. Figure 5. Confocal Raman spectroscopy images of various noodle formulations after frying To the right in Figure 5 is the scale (in arbitrary units) showing relative oil content. The highest oil content is found in regions imaged as darkest red, and the darkest blue regions have the least oil content. Page 6 of 7 Results • • • • reduce total fat content by 2–3%, resulting in 12% less oil being adsorbed compared to noodles without Ashland’s CMC, improve noodle texture, and are easy to incorporate in manufacturing plants. Oil and Moisture Content Analysis Oil and moisture content were measured by a Bruker Minispec MQ (Billerica, MA, USA) time-domain nuclear magnetic resonance (TD-NMR) instrument. Prior to measuring fat content with the TD-NMR instrument, a calibration curve was developed with palm oil used for frying, at known quantities. The TD-NMR calibration was further validated by the Mojonnier acid hydrolysis extraction method (Association of Analytical Communities; AOAC 922.06) performed by Silliker, Inc. (Allentown, PA, USA). The test formula for CMC addition to the kansui solution, using CMC type FR-A at 0.4% flour basis, reduced the oil uptake by just under 12% compared with the control. The test formula using dry addition to the wheat flour, with CMC type FR-B at 0.4% flour basis, resulted in just over 12% reduced oil uptake compared with the control. These data are listed in Table 2 and represented graphically in Figure 6. Table 2. Results of oil uptake and moisture analysis in Asian fried noodles Control formula Watera (%) 33 Number of Oil Number samples per Average trial (%) of trials Oil Standard Deviation 3 3 19.34 0.46 Oil Reduction % Change in Moisture Oil Standard Moisture Adsorption Average (%) Deviation 3.32 0.25 Test formula for CMC addition to the kansui solution 36 2 3 17.06 0.54 2.28 11.79 3.40 0.23 Test formula for CMC addition to the wheat flour 35 2 3 16.99 0.38 2.35 12.15 2.99 0.24 a Flour basis 21 20 Percentage 19 18 17 16 15 14 Test formula for CMC addition to the kansui solution Test formula for CMC addition to the wheat flour Control formula Figure 6. Average oil uptake of instant noodles Page 7 of 7 Texture Texture was evaluated by Texture Profile Analysis (TPA) using a Texture Technologies TA-XT2 texture analyzer. The 2 method described by Hou was used. Values of hardness, springiness, cohesiveness, adhesiveness, chewiness and resilience were obtained by the TPA method. No significant differences were observed for the six textural values between the control and test products. Conclusions Ashland CMC grades were found to reduce oil uptake for instant noodle manufacturers by about 12% at usage levels of 0.2 or 0.4% on a flour basis. Manufacturers who have the capability to add CMC to the kansui solutions, or prefer to do so, will likely have the best results with CMC FR-A at levels of 0.4%. Manufacturers who prefer to incorporate CMC through dry addition with the wheat flour, prior to the addition of kansui, will prefer using CMC FR-B, at levels around 0.2%. Each manufacturing process and each formulation will give slightly different results so it is recommended that instant noodle manufacturers experiment with usage levels, starting with the use levels recommended here, to find the optimal levels for their processes and formulations. References 1 Pinthus, Eli J., Weinberg, Pnina, and Saguy, Israel Sam. “Criterion for Oil Uptake During Deep-fat Frying.” Journal of Food Science. 58 (1993): 204–205, 222. 2 Hou, Gary G. Asian Noodles: Science, Technology, and Processing. Hoboken, NJ: John Wiley & Sons, 2010.