PT Unilever Oleochemical Indonesia Issuance Date Revision Date : : 1-Dec-14 - UNIOLEO FA C1499 Material Safety Data Sheet SECTION 1 : PRODUCT AND COMPANY IDENTIFICATION 1.1 Product Identifier Product Name CAS Number Formula 1.2 Intended Use of Product Use of the product 1.3 Supplier Detail Manufacturer Address : UNIOLEO FA C1499 : 544-63-8 : C14H28O2 : Industrial uses; personnal care, soap & detergent industry. Defoaming agents : PT Unilever Oleochemical Indonesia : Industrial Estate of Sei Mangkei Huta VI Sei Mangkei Bosar Maligas, Simalungun North Sumatra 21183-Indonesia Tel. +62-614520696 1.4 Emergency Contact Emergency Telephone : Tel. +62-614520696 SECTION 2 : HAZARD IDENTIFICATION 2.1 Classification of the substance or mixture Classification according to Regulation : Skin (Category 2), H315 (EC) No 1272/2008 Classification according to EU Directives : Xi, R38 67/548/EEC or 1999/45/EC 2.2 Label element Pictogram Signal word Hazard statement Precautoinary statements 2.3 Other Hazards None : : Warning : H315 Causes skin irritation : None Page 1 of 7 PT Unilever Oleochemical Indonesia : : Issuance Date Revision Date 1-Dec-14 - UNIOLEO FA C1499 Material Safety Data Sheet SECTION 3 : COMPOSITION/INFORMATION OF INGREDIENTS 3.1 Substance Synonyms Formula Molecul weight CAS No. EC No : Myristic Acid Tetradecanoic acid : C14H28O2 : 228,37 g/mol : 544-63-8 : 208-875-2 Hazardous ingredients according to Regulation (EC) No 1272/2008 Component Identification Classification CAS No. : 544-63-8 Myristic Acid Skin Irritant; H315 EC-No : 208-875-2 Hazardous ingredients according to Directive 1999/45/EC Component Identification CAS No. : 544-63-8 Myristic Acid EC-No : 208-875-2 Classification Concentration > 99 % Concentration Xi, R38 > 99 % For the full text of the H-statements and R-Phrases mentioned in this section, see section 16 SECTION 4 : FIRST AID MERASURES 4.1 Description of First aid Measures General advice Inhalation Skin contact Eye contact Ingestion : Consult a physician. Show this safety data sheet to doctor in attendance : If breath in, move person into frseh air. If no breathing, give artificial respiration. Consult a physician : Wash off with soap and plenty of water. Consult a physician : Rinse opened eye for several minutes under running water : Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician 4.2 Most important symptoms and effects, both acute and delayed The most important known symtoms and effects are described in the labelling and or section 11 4.3 Indication of any immediate medical attention and special treatment needed No data available Page 2 of 7 PT Unilever Oleochemical Indonesia Issuance Date Revision Date : : 1-Dec-14 - UNIOLEO FA C1499 Material Safety Data Sheet SECTION 5 : FIREFIGHTING MEASURES 5.1 Extinguishing Media Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or CO2 5.2 Special hazards arising from the substance or mixture Fire Hazard : Carbon oxides 5.2 Advice for Firefighters Wear self contained breathing apparatus for fire fighting if necessary SECTION 6 : ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions, Protective Equipment and Emergy Procedures Use personal protective equipment. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. For personal protection see section 8. 6.2 Environmental Precautions Avoid discharge into drains, water course or onto the ground. 6.3 Methods and materials for containment and cleaning up Methods for Cleaning Up : : Pick up and arrange disposal without creating dust. Sweep up and shovel. Collect leakage in sealable containers for disposal SECTION 7 : HANDLING AND STORAGE 7.1 Precautions for Safe Handling Avoid formation of dust and aerosols Avoid contact with skin and eyes Provide appropriate exhaust ventillation at places where dust is formed. 7.2 Conditions for Safe Storage, Including any incompatibilities Store in cool place. Keep container tightly closed in adry well-ventilated place. : In bulk, store at about 5 - 10 oC above melting point Storage temperature o In flake, store at maximum 35 C Suitable material for storage : In bulk, stainless steel is preferred for storage In flake, laminated paper bag Page 3 of 7 PT Unilever Oleochemical Indonesia Issuance Date Revision Date : : 1-Dec-14 - UNIOLEO FA C1499 Material Safety Data Sheet SECTION 8 : EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1. Control Parameters No occupational Exposure Limits (OELs) have been establish for this product or its chemical components 8.2. Exposure Controls Appropriate engineering controls Emergency eye wash should be available in the immediate victinity or any potential exposure Personal Protective Equipment : Safety glasses. Dust formation : dust mask Eye/Face protection Skin protection Respiratory protection Other Information : : : : Safety glasses or chemical goggles Chemically resistant protective gloves are recommended In case of inadequate ventillation wear respiratory protection When using, do not eat, drink or smoke SECTION 9 : PHYSICAL AND CHEMICAL PROPERTIES 9.1 Information on Basic Physical and Chemical Properties Physical state Appearance Odour Odour Threshold pH Melting point Freezing point Boiling point Flash point Evaporation rate Flammability (solid, gas) Upper/lower flammability or explosive limits Vapour pressure Vapour density Relative density Water solubility Partition coefficient : n-octanol/water Auto-ignation temperature Decomposition temperature : : : : : : : : : : : Solid White crystalline Characteristic No data available Not applicable 52 - 54 oC No data available ca. 300 °C > 113 °C-closed cup No data available No data available : No data available : : : : : : : No data available No data available No data available No data available No data available No data available No data available Page 4 of 7 PT Unilever Oleochemical Indonesia Issuance Date Revision Date : : 1-Dec-14 - UNIOLEO FA C1499 Material Safety Data Sheet SECTION 10 : STABILITY AND REACTIVITY : No data available 10.1 Reactivity : Stable under recommended storage conditions 10.2 Chemical stability 10.3 Possibility of Hazardous : No data available Reactions : No data available 10.4 Condition to avoid : Bases, Oxidizing agents 10.5 Incompatible material 10.6 Hazardous Decomposition Products : No data available. In event of fire : see section 5 SECTION 11 : TOXICOLOGICAL INFORMATION 11.1 Information On Toxicological Effects Acute toxicity LD50 Oral-rat Skin corrosion/irritation Serious eye demage/eye irritation Respiratory or skin sensitisation Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ toxicity=single exposure Specific target organ toxicity=repeat exposure Aspiration hazard Additional Information : : : : : : : 10000 mg/kg No skin irritation-24 hours (rabbit) Mild Eye irritation (Rabbit) No data available No data available No data available No data available : No data available : No data available : No data available : RTECS : QH4375000 Page 5 of 7 PT Unilever Oleochemical Indonesia Issuance Date Revision Date : : 1-Dec-14 - UNIOLEO FA C1499 Material Safety Data Sheet SECTION 12 : ECOLOGICAL INFORMATION 12.1 Toxicity No data available 12.2 Persistance and degradability No data available 12.3 Bioaccumulative Potential No data available 12.4 Mobility in Soil No data available 12.5 Other adverse effects No data available SECTION 13 : DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Waste disposal recommendation : Disposal must be made according to official regulation Do not dump into any sewers, on the ground, or into any body of water. SECTION 14 : TRANSPORTATION INFORMATION 14.1 UN number Land transport ADR/RID Maritime transport IMDG Air transport IATA : Not regulated : Not regulated : Not regulated 14.2 UN Proper Shipping Name Land transport ADR/RID Maritime transport IMDG Air transport IATA : Not applicable : Not applicable : Not applicable 14.3 Transport hazard class(es) Land transport ADR/RID Maritime transport IMDG Air transport IATA : Not applicable : Not applicable : Not applicable 14.4 Packaging group Land transport ADR/RID Maritime transport IMDG Air transport IATA : Not applicable : Not applicable : Not applicable Page 6 of 7 PT Unilever Oleochemical Indonesia Issuance Date Revision Date : : 1-Dec-14 - UNIOLEO FA C1499 Material Safety Data Sheet 14.5 Enviromental hazards Land transport ADR/RID Maritime transport IMDG Air transport IATA : No : No : No 14.6 Special precautions for use No data available SECTION 15 : REGULATORY INFORMATION Inventory status : Listed in TSCA, EINECS SECTION 16 : OTHER INFORMATION Full text of H-statements reffered to under section 2 and 3 Skin Irrit. : Skin irritation H318 : Causes skin irritation Full text of R-phrases reffered to under section 2 and 3 Xi : Irritant R38 : Irritating to skin MSDS creation date MSDS No. : 1-Dec-14 : TS-MSDS-03 All data are based on our current knowledge and believed to be correct. UOI, as provider of the data, disclaims any and all warranties, whether express or implied, including (without limitation) any warranties of merchantability or fitness for a particular purpose. Users shall determine the suitability of these products for their own purpose and carry out confirming tests (if necessary). UOI shall not be liable to you or to any third party for any direct, indirect, incidental, consequential, special or exemplary damages or lost profit resulting from any use or misuse of this data. No statement should be construed as a recommendation for any use which would violate any patent rights. Page 7 of 7