Safety Data Sheet
acc. to OSHA HCS
Page 1/17
Safety Data Sheet
acc. MSDS
to OSHA
HCS 226
1801 Morgan Street
Number:
Revision Date 04/07/2015
Print Date 04/07/2015
Rockford, IL 61102
Revision Date: 04/14/2015
· Product Identifier
· Product Identifier
Phone: (815) 968-9661
Supersedes Date:
04/12/2012
Page
1/17
· Trade Name: 204-2
· Trade Name: 204-2
Fax: · Application
(815) 968-9731
Data
Sheet
of the Substance or Safety
Mixture: Thinner
· Application of the Substance or Mixture: Thinner
www.gcelectronics.com
acc.
to
OSHA
HCS
· Details of the Supplier of the Safety Data Sheet (SDS)
Print Date 04/07/2015
Details of the Supplier of the Safety Data Sheet
(SDS)
· Details
of the Supplier of the Safety DataRevision
Sheet (SDS)
Print Date
04/07/2015
Date 04/07/2015
· Manufacturer
or Supplier:
· Manufacturer or Supplier:
Resinlab, LLC
Resinlab, LLC
· Product
Identifier
N109 W13300
Ellsworth Drive,
Complies
with
OSHA
Hazard
Communication
Standard
29 CFR 1910.1200
N109 W13300 Ellsworth
Drive,
· Germantown,
WI 53022
Trade Name:
204-2
Germantown, WI 53022
1-800-388-8605
· Application of the Substance or Mixture: Thinner
1-800-388-8605
www.resinlab.com
www.resinlab.com
· Information
· Details
of the Supplier
of theProduct
Safety
Data
Sheet· Information
(SDS)
Department:
Safety
Department:
msds@resinlab.com
Department: Product Safety Department: msds@resinlab.com
· Emergency
Manufacturer
or Supplier:
Telephone
Number:
· Emergency Telephone Number:
Resinlab,
LLC - Chemtrec: 1-800-424-9300 (24 hours)
North
America
North America - Chemtrec: 1-800-424-9300 (24 hours)
International
- Chemtrec:
01-703-527-3887
(24 IDENTIFICATION
hours)
N109 W13300
EllsworthAND
Drive,
SECTION
1. PRODUCT
COMPANY
International - Chemtrec: 01-703-527-3887 (24 hours)
Germantown, WI 53022
1-800-388-8605
www.resinlab.com
Product
Type:
Thinners/Solvent
Emergency Contact: Chemtrec
2 Hazard(s)
identification
· Information
2 Hazard(s)
identification
Department: Product Safety Department:
msds@resinlab.com
Product
Name:
Paint
Thinner
Phone:
(800) 424-9300
· Emergency Telephone Number:
· Hazard
Classification
· Hazard Classification
America - Chemtrec:
1-800-424-9300 (24 hours)
Part North
Number(s):
10-6702
International - Chemtrec: 01-703-527-3887 (24 hours)
GHS02 Flame
GHS02 Flame
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
2 Flam.
Hazard(s)
identification
SECTION
HAZARD(S)
IDENTIFICATION
Liq. 22:H225
Highly flammable
liquid and vapor.
· Hazard
Classification
GHS08 Health hazard
GHS02 Flame
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
GHS08 Health hazard
Muta. 1A
H340 May cause genetic defects.
Muta. 1A
H340 May cause genetic defects.
Flam. 1A
Liq. 2 H350
H225 May
Highly
flammable
Carc.
cause
cancer.liquid and vapor.
Carc. 1A
H350 May cause cancer.
Repr. 1A
H360 May damage fertility or the unborn child.
Repr. 1A
H360 May damage fertility or the unborn child.
STOT RE 2 H373 May cause damage to organs through prolonged
or2 repeated
exposure.
STOT
RE
H373 May
cause damage to organs through prolonged or repeated exposure.
GHS08 Health hazard
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
Asp. Tox. 1 H304 May be fatal if swallowed and enters airways.
Muta. 1A
H340 May cause genetic defects.
GHS07
Carc. 1A GHS07
H350 May cause cancer.
Repr. 1A
H360 May damage fertility or the unborn child.
STOT
RE22 H315
H373 Causes
May cause
or repeated
exposure.
Skin
Irrit.
skindamage
irritation.to organs through prolonged
Skin Irrit. 2
H315 Causes
skin irritation.
STOT
SE 3
or and
dizziness.
Asp. Tox.
1 H336
H304 May cause
be fataldrowsiness
if swallowed
enters airways.
STOT SE 3 H336 May cause drowsiness or dizziness.
· Label Elements
· Label Elements
· GHS label
elements The product is classified and labeled
according
to the Globally Harmonized System (GHS).
· GHS
GHS07
label elements
The product is classified and labeled according to the Globally Harmo
· Pictogram(s)
· Pictogram(s)
Skin Irrit. 2 H315 Causes skin irritation.
STOT SE 3 H336 May cause drowsiness or dizziness.
· Label Elements
GHS07 The
GHS08
· GHSGHS02
label elements
product is classified and labeled according
the GloballyGHS08
Harmonized System (GHS).
GHS02 to GHS07
· Pictogram(s)
· Signal Word Danger
· Signal Word Danger
· Hazard-determining Component(s)
· Hazard-determining Component(s)
Toluene
Toluene
Naphtha (petroleum), hydrotreated heavy
Naphtha (petroleum), hydrotreated heavy
benzene
benzene
GHS02
GHS07
GHS08
· Hazard statements
· Hazard statements
flammable
liquid and vapor.
· Highly
Highly flammable liquid and vapor.
Signal
Word Danger
Causes skin irritation.
Causes skin irritation.
· May
cause genetic defects. Component(s)
Hazard-determining
May cause genetic defects.
May
cause cancer.
Toluene
May cause cancer.
(Contd. on page 2)
Naphtha (petroleum), hydrotreated heavy
US
US
benzene
·
Part Number(s):
Page
Hazard 10-6702
statements
Highly flammable liquid and vapor.
Causes skin irritation.
1 of 21
1801 Morgan Street
Rockford, IL 61102
Phone: (815) 968-9661
Fax:
(815) 968-9731
www.gcelectronics.com
Print Date 04/07/2015
MSDS Number: 226
Revision Date: 04/14/2015
Safety Data She
2/17 04/12/2012
SupersedesPage
Date:
acc. to OSHA HC
Safety Data Sheet Print Date 04/07/2015
acc. to OSHA HCS
Trade Name: 204-2
MATERIAL SAFETY DATA SHEET
Trade Name: 204-2
Safety Data Sheet
acc. to OSHA HCS
Product
Name: PAINT THINNER
May damage fertility or the unborn child.
Print Date May
04/07/2015
cause drowsiness or dizziness.
May cause damage to organs through prolonged or repeated exposure.
Trade Name:
May 2:
be 204-2
fatal
if swallowed and
enters airways.
SECTION
HAZARD(S)
IDENTIFICATION
(CONTINUED)
Revision Date 04/07/2015
Page 2/17
May damage fertility or the unborn child.
May cause drowsiness or dizziness.
(Contd.through
of pageprolonged
1)
May cause damage to organs
or repeated exposure.
May be fatal if swallowed and enters airways.
Revision Date 04/07/2015
· Precautionary statements
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Use explosion-proof electrical/ventilating/lighting/equipment.
· Precautionary statements
Do not breathe dust/fume/gas/mist/vapors/spray.
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
(Contd.
of page
1) protection.
Wear protective gloves / eye
protection
/ face
Use
explosion-proof
electrical/ventilating/lighting/equipment.
May
damage fertility
or the unborn child.
Wear protective gloves.
DoMay
not breathe
dust/fume/gas/mist/vapors/spray.
cause drowsiness
or dizziness.
Ground/bond container and receiving equipment.
Wear
glovesto
/ eye
protection
protection.
Mayprotective
cause damage
organs
through/ face
prolonged
or repeated exposure.
Use only non-sparking tools.
Wear
Mayprotective
be fatal ifgloves.
swallowed and enters airways.
Take precautionary measures against static discharge.
Ground/bond container and receiving equipment.
Wash thoroughly after handling.
·
Precautionary
statements
Use only non-sparking tools.
Use only outdoors or in a well-ventilated area.
Keep
away from heat/sparks/open
surfaces. - No smoking.
Take
precautionary
measures againstflames/hot
static discharge.
Obtain special instructions before use.
Usethoroughly
explosion-proof
electrical/ventilating/lighting/equipment.
Wash
after handling.
Do not handle until all safety precautions have been read and understoo
Doonly
notoutdoors
breathe dust/fume/gas/mist/vapors/spray.
Use
or in a well-ventilated area.
If swallowed: Immediately call a poison center/doctor.
Wearspecial
protective
gloves /before
eye protection
/ face protection.
Obtain
instructions
use.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated cl
protective
DoWear
not handle
until gloves.
all safety precautions have been read and understood.
Specific treatment (see on this label).
Ground/bond
container call
and areceiving
equipment.
If swallowed:
Immediately
poison center/doctor.
IF INHALED: Remove victim to fresh air and keep at rest in a position c
Use
only
non-sparking
tools.
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with
Call water/shower.
a poison center/doctor if you feel unwell.
Take
precautionary
measures
against
static
discharge.
Specific treatment (see on this label).
IF exposed or concerned: Get medical advice/attention.
Wash thoroughly
after
handling.
IF INHALED:
Remove
victim
to fresh air and keep at rest in a position comfortable for breathing.
If skin irritation occurs: Get medical advice/attention.
Use
only outdoors
or in aifwell-ventilated
area.
Call
a poison
center/doctor
you feel unwell.
Get medical advice/attention if you feel unwell.
Obtain special
instructions
use.
IF exposed
or concerned:
Getbefore
medical
advice/attention.
Do NOT induce vomiting.
Do not
handle
until all
safety
precautions
have been read and understood.
If skin
irritation
occurs:
Get
medical
advice/attention.
In case of fire: Use for extinction: CO2, powder or water spray.
swallowed:
Immediately call
a poison
center/doctor.
GetIf medical
advice/attention
if you
feel unwell.
Take off contaminated clothing and wash it before reuse.
ON induce
SKIN (or
hair): Remove/Take off immediately all contaminated clothing. Rinse skin
withlocked
water/shower.
DoIF
NOT
vomiting.
Store
up.
Specific
treatment
on this CO2,
label).powder or water spray.
In case
of fire:
Use for(see
extinction:
Store in a well-ventilated place. Keep container tightly closed.
IF
INHALED:
Remove
victim
to
fresh
air
and
keep
at
rest
in
a
position
comfortable
for
breathing.
Take off contaminated clothing and wash it before reuse.
Store in a well-ventilated place. Keep cool.
Calllocked
a poison
Store
up. center/doctor if you feel unwell.
Dispose of contents/container in accordance with local/regional/nationa
IF
exposed
or
concerned:
Get
medical
advice/attention.
Store in a well-ventilated place. Keep container tightly closed.
·
If skin
occurs:place.
Get medical
advice/attention.
Hazard Rating System
Store
in airritation
well-ventilated
Keep cool.
Get medical
advice/attentioninifaccordance
you feel unwell.
Dispose
of contents/container
with local/regional/national/international ·regulations.
NFPA System
Do NOT induce vomiting.
· NFPA Ratings (scale 0 - 4)
· Hazard Rating
In case ofSystem
fire: Use for extinction: CO2, powder or water spray.
· NFPATake
off contaminated clothing and wash it before reuse.
System
Health = 2
Store Ratings
locked up. (scale 0 - 4)
· NFPA
Fire = 3
Store in a well-ventilated place. Keep container tightly closed.
Reactivity = 0
Store in a well-ventilated place. Keep cool.
Health = 2
Dispose of contents/container
in accordance with local/regional/national/international regulations.
Fire = 3
NFPA special hazards (water reactivity and oxidizing property): None
· Hazard Rating System
Reactivity = 0
· HMIS System
· NFPA System
· HMIS Ratings (scale 0 - 4)
NFPA
special
hazards (scale
(water reactivity
· NFPA
Ratings
0 - 4) and oxidizing property): None
2
3
2
0
0
· HMIS System
· HMIS Ratings Health
(scale= 02 - 4)
Fire = 3
Reactivity = 0
*2
HEALTH
Health = *2
3 Fire = 3
FIRE
NFPA special hazards
(water
Reactivity
= 0 reactivity and oxidizing property): None
REACTIVITY 0
· HMIS System
· HMIS Ratings (scale 0 - 4)
2
3
3
0
· Other hazards
· Results
of PBT *2and vPvB assessment
HEALTH
Health = *2
· PBT: Not applicable.
3 Fire = 3
FIRE
· vPvB: Not applicable.
Reactivity = 0
REACTIVITY 0
· Other hazards
· Results of PBT and vPvB
· PBT: Not applicable.
· vPvB: Not applicable.
HEALTH
*2
FIRE
3
REACTIVITY 0
Health = *2
Fire = 3
Reactivity = 0
· Other hazards
· Results of PBT and vPvB
· PBT: Not applicable.
· vPvB: Not applicable.
assessment
US
(Contd. on page 3)
assessment
Part Number(s): 10-6702
US
(Contd. on page 3)
Page 2 of 21
1801 Morgan Street
Rockford, IL 61102
Phone: (815) 968-9661
Fax:
(815) 968-9731
www.gcelectronics.com
Print Date 04/07/2015
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
Safety Data Sheet
MATERIAL
SAFETY
acc. to
OSHASheet
HCSDATA SHEET
Safety
Data
acc. to OSHA HCS
Product Name: PAINT THINNER
Print
Date
04/07/2015
Trade
Name:
204-2
Trade Name: 204-2
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3 Composition/information on ingredients
3· Composition/information
on ingredients
Chemical Characterization: Mixtures
Page 3/17
Page 3/17
Revision Date 04/07/2015
Revision Date 04/07/2015
(Contd. of page 2)
(Contd. of page 2)
· Composition/Information
· Chemical
on Ingredients
Characterization: Mixtures
CAS:
64742-48-9
Naphthaon
(petroleum),
hydrotreated heavy
· Composition/Information
Ingredients
EINECS: 265-150-3
Asp. Tox. 1, H304
CAS:
64742-48-9
Naphtha
(petroleum),
hydrotreated heavy
Index Number: 649-327-00-6 Flam. Liq. 4, H227
EINECS: 265-150-3
Asp.
Tox.
1,
H304
CAS: 108-88-3
Toluene
Index Number: 649-327-00-6 Flam. Liq. 4, H227
EINECS: 203-625-9
Flam. Liq. 2, H225
CAS:
108-88-3
Muta. 1A, H340; Carc. 1A, H350; Repr. 1A, H360; STOT RE 2, H373; Asp. Tox. 1, H304
Index Number: 601-021-00-3 Toluene
EINECS:
203-625-9
Flam.Irrit.
Liq.2,2,H315;
H225 STOT SE 3, H336
Skin
RTECS: XS 5250000
Index Number: 601-021-00-3
Muta. 1A, H340; Carc. 1A, H350; Repr. 1A, H360; STOT RE 2, H373; Asp. Tox. 1, H304
· Classification System:
RTECS: XS 5250000
Skin Irrit. 2, H315; STOT SE 3, H336
· The Classifications were based on the Toxicological and Ecological Data of the substances/mixtures in the Section 11 and 12.
40-50%
40-50%
40-50%
40-50%
Classification System:
The Classifications were based on the Toxicological and Ecological Data of the substances/mixtures in the Section 11 and 12.
4 First-aid measures
4· First-aid
measures
SECTION
4: FIRST-AID
Description
of First AidMEASURES
Measures
· General Information
· Description
of First Aid Measures
may be delayed several hours after exposure; victims should be medically observed for at least 48 hours after exposure.
· Symptoms
General
Information
Ensure medical personnel are aware of exposure and take precautions for their personal protection; see Section 8 for the information of
Symptoms
may be delayed several hours after exposure; victims should be medically observed for at least 48 hours after exposure.
personal protection.
Ensure medical personnel are aware of exposure and take precautions for their personal protection; see Section 8 for the information of
· After
personal
protection.
Inhalation
Remove
victim
from exposure to fresh air. Keep person at rest. Provide oxygen if person is not breathing.
· After Inhalation
In case of unconsciousness place patient stably in side position for transportation.
Remove
victim
from
to fresh
air. Keep person at rest. Provide oxygen if person is not breathing.
Use a respiration
bagexposure
or breathing
device.
In
case
of unconsciousness
place
patient stably in side position for transportation.
Give
artificial
respiration if not
breathing.
Use
a respiration
bag or
breathingoxygen.
device.
If breathing
is difficult,
administer
Give
respiration
not breathing.
Seek artificial
immediate
medical ifadvice.
If breathing is difficult, administer oxygen.
· Seek
medical advice.
Afterimmediate
Skin Contact
all contaminated clothing and wash before reuse.
· Remove
After
Skin
Contact
Wash contaminated skin with water and soap and rinse thoroughly.
Remove
all contaminated
clothing and wash before reuse.
Seek immediate
medical advice.
Wash contaminated skin with water and soap and rinse thoroughly.
· After
Seek immediate
medical advice.
Eye Contact
opened eyes under running water for at least 15 minutes.
· Rinse
After
Contact
RemoveEye
contact
lenses if present and easy to do so; continue rinsing.
Rinse
opened eyes
underadvice.
running water for at least 15 minutes.
Seek immediate
medical
Remove contact lenses if present and easy to do so; continue rinsing.
· After
Seek immediate
medical advice.
Swallowing
victim is unconscious; never give anything by mouth.
· If
After
If victimSwallowing
is conscious, rinse out mouth with water.
If
unconscious;
Dovictim
NOTisinduce
vomiting.never give anything by mouth.
If
is conscious,
rinse out mouth
water.
If victim
vomiting
occurs spontaneously,
keepwith
victim's
head below hips to prevent aspiration of liquid into lungs.
Do
NOT
induce vomiting.
Seek
immediate
medical advice even there are no symptoms.
If vomiting occurs spontaneously, keep victim's head below hips to prevent aspiration of liquid into lungs.
· After
Seek immediate
medical
there are no at
symptoms.
Exposure
Get advice
medicaleven
advice/attention
once.
· After
Exposure
Get medical
advice/attention
at once.labels and/or (M)SDS ready when calling or visiting a medical center.
Information
for Doctor
Have
chemical containers,
· Indication of any Immediate Medical Attention and Special Treatment Needed
· Information
for Doctor Have chemical containers, labels and/or (M)SDS ready when calling or visiting a medical center.
frequent or high intense exposure, the following medical tests are recommended:
· After
Indication
of any Immediate Medical Attention and Special Treatment Needed
skin tests
After
frequent
or function
high intense
nervous
system
testsexposure, the following medical tests are recommended:
skin
tests
kidney
tests
nervous
liver testssystem function tests
kidney
tests system function tests
Reproductive
Part Number(s):
liver
tests10-6702
respiratory
system tests
Reproductive
function tests
Check sectionsystem
11 Toxicological
Information for further relevant information.
respiratory system tests
(Contd. on page 4)
Page 3 of 21
· Description of First Aid Measures
· General Information
Symptoms may be delayed several hours after exposure; victims should be medically observed for at least 48 hours after exposure.
Ensure medical personnel are aware of exposure and take precautions for their personal protection; see Section 8 for the information of
personal protection.
· After Inhalation
Remove victim from exposure to fresh air. Keep person at rest. Provide oxygen if person is not breathing.
In case of unconsciousness place patient stably in side position for transportation.
Use a respiration bag or breathing device.
Give artificial respiration if not breathing.
Morgan
Street
If breathing is
difficult, administer oxygen.
Seek immediate medical advice.
1801
Rockford, IL 61102
·
Skin 968-9661
Contact
Phone:After
(815)
Remove all contaminated clothing and wash before reuse.
contaminated
skin with water and soap and rinse thoroughly.
Fax: Wash(815)
968-9731
Seek immediate medical advice.
www.gcelectronics.com
·
After Eye Contact
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
Rinse opened eyes under running water for at least 15 minutes.
Remove contact lenses if present and easy to do so; continue rinsing.
Seek immediate medical advice.
· After
MATERIAL SAFETY DATA SHEET
Swallowing
Product
PAINT
If victimName:
is unconscious;
never giveTHINNER
anything by mouth.
If victim is conscious, rinse out mouth with water.
Do NOT induce vomiting.
If vomiting occurs spontaneously, keep victim's head below hips to prevent aspiration of liquid into lungs.
SECTION
FIRST-AID
MEASURES
(CONTINUED)
Seek 4:
immediate
medical advice
even there are
no symptoms.
· After
Exposure Get medical advice/attention at once.
Page 4/17
· Information for Doctor Have chemical containers, labels and/or (M)SDS ready when calling or visiting a medical center.
· Indication of any Immediate Medical Attention and Special Treatment Needed
After frequent or high intense exposure, the following
medical
testsHCS
are recommended:
acc. to
OSHA
skin tests
Print Date 04/07/2015
Revision Date 04/07/2015
nervous system function tests
kidney tests
Trade Name:
204-2
liver tests
Reproductive system function tests
respiratory system tests
(Contd. of page 3)
Check section 11 Toxicological Information for further relevant information.
(Contd. on page 4)
·
Safety Data Sheet
Additional Information
US
For additional information, please consult the corresponding first aid measures in the most current version of Emergency Response
Guidebook which is produced by the US Department of Transportation.
5 Fire-fighting
measures MEASURES
SECTION
5: FIRE-FIGHTING
· Extinguishing Media
· Suitable Extinguishing Agent(s)
Use fire fighting measures and extinguishing agents that suit the environment.
In case of fire, suitable extinguishing agents are:
Alcohol resistant foam.
Dry chemical or fire-extinguishing powder.
Carbon dioxide (CO₂).
Water spray or water fog.
· Unsuitable Extinguishing Agent(s) No relevant information.
· Firefighting Procedures
Isolate fire and deny unnecessary entry.
Eliminate all ignition sources if safe to do so.
Do not extinguish fire unless flow can be stopped.
Fight fire remotely due to the risk of explosion.
Burning liquids may be moved by flushing with water; protect personnel and minimize property damage.
Fight fire from protected location or safe distance.
Contain fire water runoff if possible to prevent environmental pollution.
· Special Hazards Arising in Fire
Caution! Highly flammable liquid or vapor.
In case of fire, following can be released:
Carbon dioxide (CO₂) and Carbon monoxide (CO)
· Advice for Firefighters
If employees are expected to fight fires, they must be trained and equipped as stated in the OSHA fire brigades standard (29 CFR
1910.156).
As with any fire, wear positive-pressure self-contained breathing apparatus and full protective gear that are NIOSH approved.
· Additional
Information Ensure adequate and functional fire fighting facilities equipped in working area at all times.
6 Accidental release measures
· Personal Precautions
Caution! Highly flammable liquid or vapor; wear fire resistant or retardant clothing during clean up.
Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during use.
Ensure personnel take precautions for their personal protection during clean up; see Section 8 for the specific requirements.
Part Number(s): 10-6702
· Environmental Precautions Keep away from sewage system or other water courses; do not penetrate ground/soil.
· Cleaning Up Methods
Page 4 of 21
· Suitable Extinguishing Agent(s)
Use fire fighting measures and extinguishing agents that suit the environment.
In case of fire, suitable extinguishing agents are:
Alcohol resistant foam.
Dry chemical or fire-extinguishing powder.
Carbon dioxide (CO₂).
Water spray or water fog.
· Unsuitable Extinguishing Agent(s) No relevant information.
· Firefighting Procedures
Isolate fire and deny unnecessary entry.
Eliminate all ignition sources if safe to do so.
DoMorgan
not extinguish
fire unless flow can be stopped.
1801
Street
Fight fire remotely due to the risk of explosion.
Rockford,
IL 61102
Burning liquids
may be moved by flushing with water; protect personnel and minimize property damage.
Fight fire from protected location or safe distance.
Phone:
(815)
Contain fire water 968-9661
runoff if possible to prevent environmental pollution.
Fax:
(815)
968-9731
· Special
Hazards
Arising in Fire
Caution!
Highly
flammable
liquid or vapor.
www.gcelectronics.com
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
In case of fire, following can be released:
Carbon dioxide (CO₂) and Carbon monoxide (CO)
MATERIAL SAFETY DATA SHEET
· Advice for Firefighters
If employees are expected to fight fires, they must be trained and equipped as stated in the OSHA fire brigades standard (29 CFR
1910.156).
As with any fire, wear positive-pressure self-contained breathing apparatus and full protective gear that are NIOSH approved.
Product Name: PAINT THINNER
· Additional
Information Ensure adequate and functional fire fighting facilities equipped in working area at all times.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6 Accidental release measures
· Personal Precautions
Caution! Highly flammable liquid or vapor; wear fire resistant or retardant clothing during clean up.
Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during use.
Ensure personnel take precautions for their personal protection during clean up; see Section 8 for the specific requirements.
· Environmental
Precautions Keep away from sewage system or other water courses; do not penetrate ground/soil.
· Cleaning Up Methods
Eliminate heat, sparks, open flame and other ignition sources before clean up.
A vapor suppressing foam should be used to reduce vapors at first.
All equipment used for clean up must be grounded.
Don't touch or walk through spilled chemicals unless trained and equipped as stated in the OSHA fire brigades standardPage
(29 CFR
5/17
1910.156).
Ensure adequate ventilation.
Keep unauthorized personnel away.
acc. to OSHA HCS
For large spills:
source of leak if safe to do so.
Print Shut
Date off
04/07/2015
Revision Date 04/07/2015
Dike and contain.
Remove
with204-2
vacuum trucks or pump to storage/salvage vessels.
Trade
Name:
Absorb residues with liquid-binding materials.
For small spills:
(Contd. of page 4)
Ventilate and wash area after clean-up is complete.
Collect spills in suitable and properly labeled containers.
(Contd. on page 5)
Do not use solvents unless following safe handling practices and within the recommended exposure guidelines.
US
Dispose contaminated chemicals as waste according to Section 13.
Safety Data Sheet
· Additional
Information No further relevant information.
7 Handling
and storage
SECTION
7: HANDLING
AND STORAGE
· Handling
· Precautions for Safe Handling
Caution! Highly flammable liquid or vapor.
Obtain special instruction before use; do not handle until all safety precautions have been read and understood.
Do not breathe gas, vapors, dusts or mists if their inhalable particles occur during handling.
Keep away from heat, sparks, open flame and other ignition sources during handling.
Ensure good ventilation and/or exhaustion at workplace.
Keep away from incompatible material(s).
Avoid any release into the environment.
Keep container tightly closed when not in use if product is volatile so as to generate hazardous atmosphere.
Observe all the personal protection requirements in Section 8.
· Information about Protection Against Explosions and Fires
Keep away from heat, sparks, open flame and other ignition sources.
Protect against electrostatic charges during handling.
Metal containers involved must be grounded and bonded.
Use only non-sparking tools and equipment, especially when opening or closing containers of combustible contents.
Have approved respirators prepared.
· Storage
· Requirements to be Met by Storerooms and Receptacles
Caution! Highly flammable liquid or vapor; keep away from heat, sparks, open flame and other ignition sources during storage.
Store in tightly closed containers in a cool, and well-ventilated area.
Keep stored in accordance with local, regional, national, and international regulations.
· Information about Storage in One Common Storage Facility
Store away from incompatible material(s).
Store away from
foodstuffs.
Part Number(s):
10-6702
Avoid release to the environment.
· Additional
Information No further relevant information.
Page 5 of 21
acc. to OSHA HCS
Print
Date
04/07/2015
Trade
Name:
204-2
Revision Date 04/07/2015
Trade Name: 204-2
Collect spills in suitable and properly labeled containers.
Do not use solvents unless following safe handling practices and within the recommended exposure guidelines.
Collect
in suitablechemicals
and properly
labeled
containers.
Disposespills
contaminated
as waste
according
to Section 13.
Do not use solvents unless following safe handling practices and within the recommended exposure guidelines.
· Additional
Dispose contaminated
chemicals
wasterelevant
according
to Section 13.
Information
Noas
further
information.
· Additional
(Contd. of page 4)
(Contd. of page 4)
Information No further relevant information.
1801
Morgan and
Street
MSDS Number: 226
7 Handling
storage
Rockford,
IL 61102
Revision Date: 04/14/2015
7· Handling
Handling and storage
Phone:
(815)
968-9661
Supersedes Date: 04/12/2012
· Precautions for Safe Handling
· Handling
Fax:
(815)
968-9731
Caution!
Highly
flammable
liquid
or
vapor.
· Precautions for Safe Handling
Obtain special instruction before use; do not handle until all safety precautions have been read and understood.
www.gcelectronics.com
Caution!
Highly gas,
flammable
Do not breathe
vapors,liquid
dustsororvapor.
mists if their inhalable particles occur during handling.
Obtain
special
instruction
before
use;flame
do not
handle
all safety
precautions
have been read and understood.
Keep away
from
heat, sparks,
open
and
other until
ignition
sources
during handling.
Do
not breathe
gas, vapors,
dusts
or mists at
if their
inhalable particles occur during handling.
Ensure
good ventilation
and/or
exhaustion
workplace.
Keep
away from
from incompatible
heat, sparks, material(s).
open flame and other ignition sources during handling.
Keep away
Ensure
good
ventilation
and/or
exhaustion at workplace.
Avoid any
release
into the
environment.
Keep
fromtightly
incompatible
material(s).
Keep away
container
closed when
not in use if product is volatile so as to generate hazardous atmosphere.
Avoid
anyallrelease
into theprotection
environment.
Observe
the personal
requirements in Section 8.
Keep container tightly closed when not in use if product is volatile so as to generate hazardous atmosphere.
· Information
about
Protection
Against Explosions and Fires
Observe all the personal protection requirements in Section 8.
away from heat, sparks, open flame and other ignition sources.
· Keep
Information
about
Protection
Against
Explosions and Fires
Protect against electrostatic charges during
handling.
SECTION
HANDLING
AND
STORAGE
(CONTINUED)
Keep
away
from heat,
sparks,
open
flame andand
other
ignition
sources.
Metal 7:
containers
involved
must
be grounded
bonded.
Protect
electrostatic
during handling.
Use onlyagainst
non-sparking
tools charges
and equipment,
especially when opening or closing containers of combustible contents.
Metal approved
containersrespirators
involved must
be grounded and bonded.
Have
prepared.
Use only non-sparking tools and equipment, especially when opening or closing containers of combustible contents.
· Storage
Have approved respirators prepared.
· Requirements to be Met by Storerooms and Receptacles
· Storage
Highly flammable liquid or vapor; keep away from heat, sparks, open flame and other ignition sources during storage.
· Caution!
Requirements
tocontainers
be Met by
and Receptacles
Store in tightly closed
in a Storerooms
cool, and well-ventilated
area.
Caution!
Highly
flammable liquid
or vapor;
keepnational,
away from
heat,
sparks, open
flame and other ignition sources during storage.
Keep stored
in accordance
with local,
regional,
and
international
regulations.
Store in tightly closed containers in a cool, and well-ventilated area.
· Information
about Storage in One Common Storage Facility
Keep stored in accordance with local, regional, national, and international regulations.
away from incompatible material(s).
· Store
Information
Storage in One Common Storage Facility
Store away fromabout
foodstuffs.
Store
from
incompatible
material(s).
Avoid away
release
to the
environment.
Store away from foodstuffs.
· Additional
Avoid release
to the environment.
Information
No further relevant information.
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
· Additional
Information No further relevant information.
8 Exposure controls/personal protection
8· Exposure
controls/personal
SECTION
8: EXPOSURE
PROTECTION
Engineering
Measures orCONTROLS/PERSONAL
Controlsprotection
· Exposure Measures
· Engineering
Limit Values
that Require
or Controls
Monitoring at the Workplace
64742-48-9
Naphtha
(petroleum),
hydrotreated
heavy
· Exposure
Limit
Values that
Require
Monitoring at the Workplace
OSHA Short-term value: 400 mg/m³
64742-48-9 Naphtha (petroleum), hydrotreated heavy
108-88-3
Toluene value: 400 mg/m³
OSHA
Short-term
PEL Long-term value: 200 ppm
108-88-3 Toluene
Ceiling limit value: 300; 500* ppm
PEL Long-term
value:
*10-min peak
per 200
8-hr ppm
shift
Ceiling limit value: 300; 500* ppm
REL Short-term value: 560 mg/m³, 150 ppm
*10-min peak per 8-hr shift
Long-term value: 375 mg/m³, 100 ppm
REL Short-term value: 560 mg/m³, 150 ppm
TLV
Long-term value: 75 mg/m³, 20 ppm
Long-term value: 375 mg/m³, 100 ppm
BEI
acc. to OSHA HCS
TLV
Long-term value: 75 mg/m³, 20 ppm
100-41-4
Ethylbenzene
BEI
Print Date 04/07/2015
PEL Long-term value: 435 mg/m³, 100 ppm
100-41-4 Ethylbenzene
RELName:
Short-term
value: 545 mg/m³, 125 ppm
Trade
204-2value:
PEL Long-term
435 mg/m³, 100 ppm
Long-term value: 435 mg/m³, 100 ppm
REL Short-term value: 545 mg/m³, 125 ppm
Long-term value: 435 mg/m³, 100 ppm
Safety Data Sheet
TLV
Long-term value: 87 mg/m³, 20 ppm
BEI
71-43-2 benzene
PEL Short-term value: 15* mg/m³, 5* ppm
Long-term value: 3* mg/m³, 1* ppm
*table Z-2 for exclusions in 29CFR1910.1028(d)
REL Short-term value: 1 ppm
Long-term value: 0.1 ppm
See Pocket Guide App. A
TLV
Short-term value: 8 mg/m³, 2.5 ppm
Long-term value: 1.6 mg/m³, 0.5 ppm
Skin; BEI
Page 6/17
Revision Date 04/07/2015
(Contd. on page 6)
(Contd. of page 5)
US
(Contd. on page 6)
US
· Additional Information for the Limit Values
As a CLASSIFIED CARCINOGEN, there may be NO safe level of exposure; reduce all contact to the lowest possible level.
As a classified TERATOGEN to humans, there may be NO safe level of exposure; reduce all contact to the lowest possible level.
· Other Engineering Measures or Controls
Ventilation rates should be matched to conditions.
If applicable, use process enclosure(s), local exhaust ventilation, or other engineering controls to maintain airborne levels below
Part Number(s):
10-6702
recommended
exposure limits.
· Personal Protective
Page 6 of 21
1801 Morgan Street
Print Date 04/07/2015
Rockford,
IL 61102
Trade Name:
204-2968-9661
Phone:
(815)
Fax:
(815) 968-9731
www.gcelectronics.com
TLV
Long-term value: 87 mg/m³, 20 ppm
Safety Data Sheet
acc. to OSHA HCS
BEI
71-43-2 benzene
PEL Short-term value: 15* mg/m³, 5* ppm
Long-term value: 3* mg/m³, 1* ppm
*table Z-2 for exclusions in 29CFR1910.1028(d)
REL Short-term value: 1 ppm
Long-term value: 0.1 ppm
See Pocket Guide App. A
TLV
Short-term
value: 8 mg/m³,
2.5 ppm
SECTION
8: EXPOSURE
CONTROLS/PERSONAL
Long-term value: 1.6 mg/m³, 0.5 ppm
Skin; BEI
Page 6/17
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
Revision Date 04/07/2015
(Contd. of page 5)
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
PROTECTION (CONTINUED)
· Additional Information for the Limit Values
As a CLASSIFIED CARCINOGEN, there may be NO safe level of exposure; reduce all contact to the lowest possible level.
As a classified TERATOGEN to humans, there may be NO safe level of exposure; reduce all contact to the lowest possible level.
· Other Engineering Measures or Controls
Ventilation rates should be matched to conditions.
If applicable, use process enclosure(s), local exhaust ventilation, or other engineering controls to maintain airborne levels below
recommended exposure limits.
· Personal Protective
· General Protective and Hygienic Measures
Avoid any skin contact.
Do not eat, drink or smoke during work.
Keep food, drink or feed away from working area.
Contaminated work clothing is not allowed out of workplace.
Avoid any skin contact.
Clean hands and exposed skin thoroughly after work and before breaks.
· Personal Protective Equipment (PPE)
· Breathing Equipment
Caution! Improper use of respirators is dangerous.
In case of brief exposure or low pollution, use a respiratory filter device.
In case of intensive or longer exposure, use a positive-pressure respiratory protective device that is independent of circulating air.
· Hand Protection
Protective gloves
Selection of glove material should take into consideration the penetration times, rates of diffusion, and the degradation.
Suggested glove type(s):
Nitrile Gloves
Butyl Rubber Gloves
· Eye
Protection
Safety Glasses
· Body
Protection No relevant information.
· Additional Information
All protective clothing (suits, gloves, footwear, headgear) should be clean, available every day, and put on before work.
The Engineering measures or controls, and PPE recommendations are only guidelines and may not apply to every situation. For additional
information, please consult the corresponding requirements under OSHA 29 CFR 1910.94-95, and 29 CFR 1910.132-138.
US
(Contd. on page 7)
Part Number(s): 10-6702
Page 7 of 21
1801 Morgan Street
Rockford, IL 61102
Phone: (815) 968-9661
Fax:
(815) 968-9731
www.gcelectronics.com
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
Page 7/17
Safety Data Sheet
Safety Data Sheet
MATERIAL
SAFETY
acc. to
OSHA HCSDATA SHEET
Print Date 04/07/2015
Product
PAINT THINNER
Trade Name:Name:
204-2
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Revision Date 04/07/2015
(Contd. of page 6)
9 Physical and chemical properties
· Information on Basic Physical
· Appearance:
· Form:
· Color:
· Odor:
· Odor Threshold:
and Chemical Properties
Liquid
Clear
Characteristic
Not determined.
· PH-Value:
Not determined.
· Change in Condition:
· Melting Point:
· Boiling Point:
· Flash Point:
· Decomposition Temperature:
· Flammability:
· Explosion:
· Explosion Limits:
· Lower:
· Upper:
· Vapor Pressure:
· Density at 20 °C (68 °F):
· Solubility in or Miscibility
· Water:
· Viscosity:
· Dynamic:
· Kinematic:
· Additional
Information
with
Not determined.
108 °C (226 °F)
4 °C (39 °F)
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
0.81 g/cm³ (6.759 lbs/gal)
Not miscible or difficult to mix.
Not determined.
Not determined.
No further relevant information.
10 Stability
reactivity
SECTION
10:and
STABILITY
AND REACTIVITY
· Physical
Hazard(s) Highly flammable liquid or vapor.
Reactivity and Chemical Stability May form explosive vapor-air mixtures when heated above the flash point.
· Hazardous
· Thermal Decomposition and Conditions to be Avoided
Highly flammable liquid or vapor; keep away from direct sunlight, heat, sparks, open flame and other ignition sources at all times.
· Possibility
of Other Hazardous Reaction(s) No further relevant information available.
· Incompatible Material(s)
Oxidizing agents
Bases (Alkalis)
Halogens
Strong acids
· Hazardous Decomposition Product(s)
Thermally decomposes during fire or very high heat. See Section 5 for fire hazards evolved during thermal decomposition.
· Hazardous Polymerization Product(s) No relevant information.
Part· Number(s): 10-6702
Additional Information No further relevant information.
Page 8 of 21
US
(Contd. on page 8)
· Upper:
Not determined.
· Vapor Pressure:
· Density at 20 °C (68 °F):
· Solubility in or Miscibility
· Water:
· Viscosity:
· Dynamic:
· Kinematic:
· Additional
with
Information
1801 Morgan Street
Rockford, IL 61102
10 Stability
and
reactivity
Phone:
(815)
968-9661
Not determined.
0.81 g/cm³ (6.759 lbs/gal)
Not miscible or difficult to mix.
Not determined.
Not determined.
No further relevant information.
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
· Physical
Fax:
(815)
968-9731
Hazard(s)
Highly flammable liquid or vapor.
·
www.gcelectronics.com
Hazardous Reactivity and Chemical Stability May form explosive vapor-air mixtures when heated above the flash point.
· Thermal Decomposition and Conditions to be Avoided
Highly flammable liquid or vapor; keep away from direct sunlight, heat, sparks, open flame and other ignition sources at all times.
MATERIAL SAFETY DATA SHEET
· Possibility
of Other Hazardous Reaction(s) No further relevant information available.
Product Name: PAINT THINNER
· Incompatible Material(s)
Oxidizing agents
Bases (Alkalis)
Halogens
SECTION
10: STABILITY AND
Strong acids
Safety Data Sheet
Page 8/17
REACTIVITY
(CONTINUED)
acc.
to OSHA HCS
Decomposition Product(s)
Print· Hazardous
Date 04/07/2015
Revision Date 04/07/2015
Thermally decomposes during fire or very high heat. See Section 5 for fire hazards evolved during thermal decomposition.
Trade
Name: 204-2
· Hazardous
Polymerization Product(s) No relevant information.
· Additional
Information No further relevant information.
11 Toxicological information
(Contd. of page 7)
US
(Contd. on page 8)
SECTION 11: TOXICOLOGICAL INFORMATION
· Acute
Toxicity
· Oral
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Oral LD50 >5000 mg/kg (rat)
Minimally Toxic. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 403
Reference: ExxonMobil SDS
108-88-3 Toluene
Oral LD50 >5580 mg/kg (rat)
Reference: Sigma Aldrich SDS 2015
100-41-4 Ethylbenzene
Oral LD50 3500 - 4700 mg/kg (rat)
Reference: ECHA (2011).
71-43-2 benzene
Oral LD50 4894 mg/kg (rat)
· Potential Health Effect(s):
abnormal pain
diarrhea
vomiting
See acute inhalative effect(s) for further information
· Dermal
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Dermal LD50 >5000 mg/kg (rab)
Minimally Toxic. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline 402
Reference: ExxonMobil SDS
108-88-3 Toluene
Dermal LD50 12267 mg/kg (rabbit) (males; occlusive; neat substance)
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Dermal LD50 15433 mg/kg (rabbit) (male; occlusive; neat substance; 24hr-exposure)
Calculated from LD50 of 17.8 mL/kg bw and the specific gravity of 0.867 g/ml.
Reference: ECHA (2011).
71-43-2 benzene
Dermal LD50 48 mg/kg (mouse)
· Potential Health Effect(s):
No further relevant information available; classification is not possible.
See acute inhalative effect(s) for further information.
· Inhalative
108-88-3 Toluene
Inhalative LC50/4 h 18 mg/l (rat) (Calculated from LC50 of 12.5, 28.1, 28.8, &33mg/L)
The LC50/4hrs of 18 mg/l was lower than 90% of the saturated vapor concentration (124.5 mg/l at 25 ℃) under a
Part Number(s): 10-6702
Page
saturated vapour pressure of 33 hPa (25 ℃); thus, the substance was considered as vapor containing substantially
no mist, and placed into Category 4 for the acute inhalative toxicity.
Reference: ECHA (2011).
9 of 21
Reference: Sigma Aldrich SDS 2015
100-41-4 Ethylbenzene
Oral LD50 3500 - 4700 mg/kg (rat)
Reference: ECHA (2011).
71-43-2 benzene
Oral LD50 4894 mg/kg (rat)
· Potential Health Effect(s):
abnormal pain
diarrhea
vomiting
1801 Morgan
Street
See acute
inhalative effect(s) for further information
·
Dermal
Rockford,
IL 61102
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Phone:
(815) 968-9661
Dermal LD50 >5000 mg/kg (rab)
Fax:
(815)Minimally
968-9731
Toxic. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD Guideline
Reference: ExxonMobil SDS
www.gcelectronics.com
402
108-88-3 Toluene
Dermal LD50 12267 mg/kg (rabbit) (males; occlusive; neat substance)
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Dermal LD50 15433 mg/kg (rabbit) (male; occlusive; neat substance; 24hr-exposure)
Calculated from LD50 of 17.8 mL/kg bw and the specific gravity of 0.867 g/ml.
Reference: ECHA (2011).
71-43-2 benzene
SECTION
11: TOXICOLOGICAL
INFORMATION (CONTINUED)
Dermal LD50
48 mg/kg (mouse)
· Potential Health Effect(s):
No further relevant information available; classification is not possible.
See acute inhalative effect(s) for further information.
· Inhalative
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
108-88-3 Toluene
Inhalative LC50/4 h 18 mg/l (rat) (Calculated from LC50 of 12.5, 28.1, 28.8, &33mg/L)
The LC50/4hrs of 18 mg/l was lower than 90% of the saturated vapor concentration (124.5 mg/l at 25 ℃) under a
saturated vapour pressure of 33 hPa (25 ℃); thus, the substance was considered as vapor containing substantially
no mist, and placed into Category 4 for the acute inhalative toxicity.
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Page 9/17
Inhalative LC50/4 h 17.2 mg/l (rat) (Inhalation: vapor)
The LD50 was calculated from 4000 ppm and a conversion factor of 1 ppm = 0.00434 mg/l. Due to 4000 ppm was
lower than 90% of the saturated vapor concentration (≈ 12500 ppm) under a saturated vapour pressure of 12.7 hPa
acc. to OSHA HCS
(25 ℃), the substance was considered as "vapor containing no mist".
Reference: ECHA (2011).
Print Date 04/07/2015
Revision Date 04/07/2015
71-43-2 benzene
Trade
Name:LC50/4
204-2 h 9980 mg/l (mouse)
Inhalative
· Potential Health Effect(s):
of page 8)
While not possible to classify the acute inhalative hazard due to missing data, the product may cause the following(Contd.
symptom(s):
headache
(Contd. on page 9)
US
passing out
· Skin Corrosion or Irritation
Safety Data Sheet
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Corrosion/Irritation mild irritation (Test species: n/a)
Mildly irritating to skin with prolonged exposure. Based on test data for structurally similar materials. Test(s) equivalent
or similar to OECD Guideline 404
Reference: ExxonMobil SDS
108-88-3 Toluene
Corrosion/Irritation irritating (rabbit) (EU Method B4; 0.5ml neat substance; 4hr-contact)
Erythema: 3.3 (Max. score: 4; mean score of all treated animals; Time point: 24+48+72 hrs); not fully reversible within
7 days.
Edema: 1.1(Max. score: 4; mean score of all treated animals; Time point: 24+48+72 hrs); not fully reversible within 7
days.
The substance was therefore considered as a moderate dermal irritant (Category 2).
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Corrosion/Irritation moderately irr. (rabbit) (shaved skin; occlusive; neat substance)
The substance was moderately irritating to skin and caused moderate necrosis after 10-20 time daily application with
undiluted substance to ear and shaved abdomen (occluded) of the treated rabbits.
Reference: ECHA (2011).
· Potential Health Effect(s):
Causes skin irritation.
In contact with skin, may cause:
redness and pain
· Eye Serious Damage or Irritation
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Damage/Irritation mild irritation (Test species: n/a)
May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. Test(s) equivalent
or similar to OECD Guideline 405
Reference: ExxonMobil SDS
Part Number(s): 10-6702
Page
108-88-3
Toluene
Damage/Irritation slightly (rabbit) (OECD TG 405; 0.1 ml neat substance)
10 of 21
(Contd. of page 8)
headache
passing out
· Skin
Corrosion or Irritation
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Corrosion/Irritation mild irritation (Test species: n/a)
Mildly irritating to skin with prolonged exposure. Based on test data for structurally similar materials. Test(s) equivalent
or similar to OECD Guideline 404
Reference: ExxonMobil SDS
108-88-3 Toluene
1801 Morgan Street
MSDS Number: 226
Corrosion/Irritation irritating (rabbit) (EU Method B4; 0.5ml neat substance; 4hr-contact)
Rockford, IL 61102
04/14/2015
Erythema: 3.3 (Max. score: 4; mean score of all treated animals; Time point: 24+48+72Revision
hrs); not fullyDate:
reversible
within
7 days.
Phone: (815) 968-9661
Supersedes Date: 04/12/2012
Edema: 1.1(Max. score: 4; mean score of all treated animals; Time point: 24+48+72 hrs); not fully reversible within 7
days.
Fax:
(815) 968-9731
The substance was therefore considered as a moderate dermal irritant (Category 2).
www.gcelectronics.com
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Corrosion/Irritation moderately irr. (rabbit) (shaved skin; occlusive; neat substance)
The substance was moderately irritating to skin and caused moderate necrosis after 10-20 time daily application with
undiluted substance to ear and shaved abdomen (occluded) of the treated rabbits.
Reference: ECHA (2011).
· Potential Health Effect(s):
Causes skin irritation.
contact with skin, may cause:
SECTIONIn
11:
TOXICOLOGICAL INFORMATION (CONTINUED)
redness and pain
· Eye Serious Damage or Irritation
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Damage/Irritation mild irritation (Test species: n/a)
May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials. Test(s) equivalent
or similar to OECD Guideline 405
Reference: ExxonMobil SDS
108-88-3 Toluene
Damage/Irritation slightly (rabbit) (OECD TG 405; 0.1 ml neat substance)
Cornea: 0/4 (Max. score: 4; Time point: 24h+48h+72h; mean score of all treated animals)
Iris: 0/2 (Max. score: 2; Time point: 24h+48h+72h; mean score of all treated animals)
Conjunctivae: 1.4/3 (Max. score: 3; Time point: 24h+48h+72h; mean score of all treated animals)
Chemosis: 0.4/3 (Max. score: 3; Time point: 24h+48h+72h; mean score of all treated animals)
The substance was therefore considered as slightly irritating (Category 2B) to rabbit eyes.
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Damage/Irritation slightly (rabbit)
Slight irritation to conjunctivae (perceptible irritation), but no changes to cornea were diagnosed after instillation with 2
drops of undiluted substance to rabbit eyes. The substance was therefore classified as slightly irritating (Category 2B) to
rabbit eyes.
Reference: ECHA (2011).
· Potential Health Effect(s): No further relevant information; classification is not possible.
· Respiratory
or Skin Sensitization
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Sensitization Skin
negative (Test species: n/a)
Page 10/17
Not expected to be a skin sensitizer. Based on test data for structurally similar materials. Test(s) equivalent or
similar to OECD Guideline 406
Reference: ExxonMobil SDS
acc. to OSHA HCS
108-88-3 Toluene
Print Date 04/07/2015
Revision Date 04/07/2015
Sensitization Skin
not sensitizing (guinea pig) (intradermal and epicutaneous; EU Method B6)
Only one treated pig showed a grade 1 reaction (discrete or patchy erythema) in response to a 50% solution.
Trade Name: 204-2
No other skin reactions were observed. The substance was therefore not classified as a skin sensitizer in this
study.
Reference: ECHA (2011).
(Contd. of page 9)
(Contd. on page 10)
Respiratory (No data available)
Safety Data Sheet
100-41-4 Ethylbenzene
Sensitization Skin
US
not sensitizing (Human) (maximization test)
A maximization test was carried out on 25 volunteers with a 10% concentration of the substance, and it
produced no sensitization reactions.
Reference: ECHA (2011).
Respiratory (No data available)
· Potential
Health Effect(s): No relevant information for respiratory sensitization; classification is not possible.
(Occupational Safety & Health Administration)
· OSHA-Ca
71-43-2 benzene
· Germ
Cell Mutagenicity
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Mutagenicity not expected (Test species: n/a)
Not expected to be a germ cell mutagen. Based on test data for structurally similar materials. Test(s) equivalent or similar to
OECD Guideline 471 473 474 476 478 479
Reference: ExxonMobil SDS
Part 108-88-3
Number(s):
10-6702
Page
Toluene
Mutagenicity negative (salmonella typhimurium) (In Vitro (Mammalian cell gene mutation assay))
11 of 21
Safety Data Sheet
1801 Morgan Street
Rockford, IL 61102
Print Date 04/07/2015
Phone:
(815) 968-9661
Trade Name:
204-2
Fax:
(815)
968-9731
www.gcelectronics.com
acc. to OSHA HCS
Page 10/17
MSDS Number: 226
Revision Date: 04/14/2015
Revision Date 04/07/2015
Supersedes
Date: 04/12/2012
(Contd. of page 9)
Respiratory (No data available)
100-41-4 Ethylbenzene
Sensitization Skin
not sensitizing (Human) (maximization test)
A maximization test was carried out on 25 volunteers with a 10% concentration of the substance, and it
produced no sensitization reactions.
Reference: ECHA (2011).
Respiratory (No data available)
SECTION· Potential
11: TOXICOLOGICAL
INFORMATION
(CONTINUED)
Health Effect(s):
No relevant information for respiratory sensitization; classification is not possible.
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
· OSHA-Ca
71-43-2 benzene
· Germ
(Occupational Safety & Health Administration)
Cell Mutagenicity
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Mutagenicity not expected (Test species: n/a)
Not expected to be a germ cell mutagen. Based on test data for structurally similar materials. Test(s) equivalent or similar to
OECD Guideline 471 473 474 476 478 479
Reference: ExxonMobil SDS
108-88-3 Toluene
Mutagenicity negative (salmonella typhimurium) (In Vitro (Mammalian cell gene mutation assay))
In Vitro (Mammalian cell gene mutation assay; OECD TG 476; L5178Y mouse lymphoma cells) - negative with and without
metabolic activation.
In Vitro (Bacterial reverse mutation assay; EU Method B13/14; S. typhimurium TA 1535, TA 1537, TA 98 and TA 100) negative with and without metabolic activation.
In Vivo (Chromosome aberration; Rat; Intraperitoneal with up to 0.25 ml/kg) - negative; there was no evidence of genotoxicity
observed.
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Mutagenicity negative (Human)
In Vitro (mammalian cell gene mutation assay; OECD TG 476; mouse lymphoma L5178Y cells) - negative with and without
metabolic activation
In Vitro (mammalian chromosome aberration test; OECD TG 473; Chinese hamster Ovary (CHO)) - negative with and
without metabolic activation
In Vivo (unscheduled DNA synthesis; OECD TG 486; mouse; inhalation with 1000ppm of the substance) - negative; the
substance did not induce DNA repair (as measured by unscheduled DNA synthesis) in the mouse liver.
In Vivo (micronucleus assay; OECD TG 474; mouse; up to 750 mg/kg/day) - negative; the substance did not increase the
rate of development of micronuclei in polychromatic erythrocytes.
Reference: ECHA (2011).
· Potential Health Effect(s): May cause genetic defects.
· Carcinogenicity
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Carcinogenicity not expected (Test species: n/a)
Not expected to cause cancer. Based on test data for structurally similar materials. Test(s) equivalent or similar to OECD
Guideline 451 453
Reference: ExxonMobil SDS
108-88-3 Toluene
Carcinogenicity negative (rat) (OECD TG 453; Inhalation: vapor)
NOAEC (Inhalation with up to 4.52 mg/l) = 4.52 mg/l; no increases in any tumor type observed.
Reference: ECHA (2011).
IARC: Group 3 Not classifiable as to it's carcinogenicity to humans.
100-41-4 Ethylbenzene
Carcinogenicity positive (Test species: n/a)
Classified as Group 2B by IARC and Category A3 by ACGIH; the substance was therefore classified as a suspected
human carcinogen (Category 2) by GHS-J.
Reference: GHS-J (2006).
· Potential Health Effect(s):
May cause cancer.
Not a known Carcinogen.
(Contd. on page 11)
US
Part Number(s): 10-6702
Page 12 of 21
Mutagenicity negative (Human)
In Vitro (mammalian cell gene mutation assay; OECD TG 476; mouse lymphoma L5178Y cells) - negative with and without
metabolic activation
In Vitro (mammalian chromosome aberration test; OECD TG 473; Chinese hamster Ovary (CHO)) - negative with and
without metabolic activation
In Vivo (unscheduled DNA synthesis; OECD TG 486; mouse; inhalation with 1000ppm of the substance) - negative; the
substance did not induce DNA repair (as measured by unscheduled DNA synthesis) in the mouse liver.
In Vivo (micronucleus assay; OECD TG 474; mouse; up to 750 mg/kg/day) - negative; the substance did not increase the
rate of development of micronuclei in polychromatic erythrocytes.
Reference: ECHA (2011).
· Potential Health Effect(s): May cause genetic defects.
· Carcinogenicity
1801 Morgan
Street
MSDS Number: 226
64742-48-9
Naphtha
(petroleum),
hydrotreated
heavy
Rockford, IL 61102
Revision Date: 04/14/2015
Carcinogenicity not expected (Test species: n/a)
Phone: (815) Not
968-9661
Supersedes
expected to cause cancer. Based on test data for structurally similar materials. Test(s)
equivalent orDate:
similar to04/12/2012
OECD
451 453
Fax:
(815) Guideline
968-9731
Reference: ExxonMobil SDS
www.gcelectronics.com
108-88-3 Toluene
Carcinogenicity negative (rat) (OECD TG 453; Inhalation: vapor)
NOAEC (Inhalation with up to 4.52 mg/l) = 4.52 mg/l; no increases in any tumor type observed.
Reference: ECHA (2011).
Page 11/17
IARC: Group 3 Not classifiable as to it's carcinogenicity to humans.
100-41-4 Ethylbenzene
acc. to OSHA HCS
Carcinogenicity positive (Test species: n/a)
Classified as Group 2B by IARC and Category A3 by ACGIH; the substance was therefore classified as a suspected
Print Date 04/07/2015
Revision Date 04/07/2015
human carcinogen (Category 2) by GHS-J.
SECTION 11: TOXICOLOGICAL
INFORMATION (CONTINUED)
Reference: GHS-J (2006).
Trade Name: 204-2
· Potential Health Effect(s):
May cause cancer.
(Contd. of page 10)
Not a known Carcinogen.
(Contd. on page 11)
· Reproductive Toxicity
MATERIAL SAFETY DATA SHEET
Safety Data Sheet
Product Name: PAINT THINNER
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Reproductive Toxi. not expected (Test species: n/a)
Not expected to be a reproductive toxicant. Based on test data for structurally similar materials. Test(s) equivalent or
similar to OECD Guideline 414 421 422
Reference: ExxonMobil SDS
108-88-3 Toluene
Reproductive Toxi. positive (Test species: n/a)
There were reproductive and/or developmental effects including increased incidence of natural abortion, abnormal
development, and malformation of newborns observed after chronic exposure to the substance in humans. Meanwhile,
there was evidence that it caused effects including increased incidences of foetal death, higher delayed ossification
rate, a decrease and unossification of sternebrae, a shift in rib profile, excess ribs, retarded skeletal development,
delayed reflex response, learning disability, early vaginal opening, and early testes descent at dosing levels not toxic
to dams from rat and mouse teratogenicity tests. Meanwhile, it was listed as a teratogen by California 65. The
substance was therefore classified as a suspected teratogen.
Reference: GHS-J (2006), California Proposition 65 (2009), and ECHA (2012).
100-41-4 Ethylbenzene
Reproductive Toxi. N/a (rat)
14% increase in incidence in pups with supernumerary ribs was observed at 1000 ppm dose level. Maternal effects in
dams at this dose consisted of increases in liver (approximately 22%), kidney (approximately 10%), and spleen
(approximately 10%) weights in the absence of histopathology changes. However, ECHA determined it was conclusive
but not sufficient to make a conclusion.
Reference: ECHA (2012).
· Potential Health Effect(s): May damage fertility or the unborn child.
· Specific
Target Organ Toxicity - Single Exposure
· Specific
Target Organ Toxicity - Repeated Exposure
US
64742-48-9 Naphtha (petroleum), hydrotreated heavy
STOT-Single negative (Test species: n/a)
Not expected to cause organ damage from a single exposure.
Reference: ExxonMobil SDS
108-88-3 Toluene
STOT-Single (Human) (Target: Nervous system via inhalation)
Based on human epidemiological studies, the substance caused fatigue, sleepiness, dizziness and mild respiratory irritation
after short term inhalation with 50-100 ppm of the substance.
Reference: US NIOSH (2011).
100-41-4 Ethylbenzene
STOT-Single (No data available)
· Potential Health Effect(s): May cause respiratory irritation.
64742-48-9 Naphtha (petroleum), hydrotreated heavy
STOT-Repeated negative (Test species: n/a)
Not expected to cause organ damage from prolonged or repeated exposure. Based on test data for structurally similar
materials. Test(s) equivalent or similar to OECD Guideline 408 413 422
Reference: ExxonMobil SDS
108-88-3 Toluene
STOT-Repeated (Human) (Nervous system, kidney, and liver via inhalation)
The substance induced nervous system effects including restricted vision, headache associated with nystagmus and
hearing loss, tremor, ataxia and amnesia; kidney and liver effects including cerebral atrophy in CT tests, renal
Part Number(s): 10-6702
Page
dysfunction manifested, hepatic toxicity associated with an increase in SGOT, fatty degeneration of hepatic cells,
and
lymphocytic infiltration after repeated exposure to the substance in human victims.
Reference: US NIOSH (2011).
13 of 21
14% increase in incidence in pups with supernumerary ribs was observed at 1000 ppm dose level. Maternal effects in
dams at this dose consisted of increases in liver (approximately 22%), kidney (approximately 10%), and spleen
(approximately 10%) weights in the absence of histopathology changes. However, ECHA determined it was conclusive
but not sufficient to make a conclusion.
Reference: ECHA (2012).
· Potential
· Specific
Health Effect(s): May damage fertility or the unborn child.
Target Organ Toxicity - Single Exposure
64742-48-9 Naphtha (petroleum), hydrotreated heavy
STOT-Single negative (Test species: n/a)
Not expected to cause organ damage from a single exposure.
1801 Morgan Reference:
Street ExxonMobil SDS
MSDS Number: 226
108-88-3
Toluene
Rockford, IL 61102
Revision Date: 04/14/2015
STOT-Single (Human) (Target: Nervous system via inhalation)
Phone:
(815)Based
968-9661
Supersedes
Date: irritation
04/12/2012
on human epidemiological studies, the substance caused fatigue, sleepiness, dizziness
and mild respiratory
short term inhalation with 50-100 ppm of the substance.
Fax:
(815)after
968-9731
Reference: US NIOSH (2011).
www.gcelectronics.com
100-41-4 Ethylbenzene
STOT-Single (No data available)
· Potential Health Effect(s): May cause respiratory irritation.
MATERIAL SAFETY DATA SHEET
· Specific
Target Organ Toxicity - Repeated Exposure
Product Name: PAINT THINNER
64742-48-9 Naphtha (petroleum), hydrotreated heavy
STOT-Repeated negative (Test species: n/a)
Not expected to cause organ damage from prolonged or repeated exposure. Based on test data for structurally similar
materials. Test(s) equivalent or similar to OECD Guideline 408 413 422
SECTION 11: TOXICOLOGICAL
INFORMATION (CONTINUED)
Page 12/17
Reference: ExxonMobil SDS
108-88-3 Toluene
STOT-Repeated (Human) (Nervous system, kidney, and
liver
inhalation)
acc.
toviaOSHA
HCS
The substance induced nervous system effects including restricted vision, headache associated with nystagmus and
Print Date 04/07/2015 hearing loss, tremor, ataxia and amnesia; kidney and liver effects including cerebral atrophy
Revision
Date
04/07/2015
in CT
tests,
renal
dysfunction manifested, hepatic toxicity associated with an increase in SGOT, fatty degeneration of hepatic cells, and
Trade Name: 204-2lymphocytic infiltration after repeated exposure to the substance in human victims.
Reference: US NIOSH (2011).
100-41-4 Ethylbenzene
(Contd. of page 11)
(Contd. on page 12)
STOT-Repeated (Rats and Mice)
US
Target: Liver, Lung, and Systemic effects (Category 2).
LOAEL (mouse; OECD TG 453; Inhalation: vapors; up to 750 ppm (3.25 mg/l) for 104 weeks) = 75 ppm: effects in liver,
lung, thyroid and pituitary pathology were observed in mice that inhaled ≥ 250 ppm (1.08 mg/L) of the substance for 2
years.
NOAEL (rat; OECD TG 407; oral with up to 750 mg/kg/day for 28 days) = 75 mg/kg bw/day; increased liver weight and
hepatocellular hypertrophy at higher dose levels.
Reference: ECHA (2011).
· Potential Health Effect(s): May cause damage to organs through prolonged or repeated exposure.
Safety Data Sheet
· Aspiration
Hazard
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Aspiration Hazard (Test species: n/a)
May be fatal if swallowed and enters airways. Based on physico-chemical properties of the material.
Reference: ExxonMobil SDS
108-88-3 Toluene
Aspiration Hazard positive (Test species: n/a) (As a hydrocarbon with viscosity of 0.65 mm²/s)
As a hydrocarbon with dynamic viscosity of 0.65 mm²/s (25℃), the substance was classified as a Category 1 aspiration
hazard.
Reference: GHS-J (2006).
100-41-4 Ethylbenzene
Aspiration Hazard (Test species: n/a)
The substance may cause chemical pneumonia due to mis-swallowing based on NIOSH ICSC. Meanwhile, the
substance was a hydrocarbon with the kinematic viscosity of 0.74mm²/s at 25 ℃. Thus, the substance was classified as
a Category 1 aspiration hazard based on the criteria.
Reference: GHS-J (2007).
· Potential Health Effect(s):
May be fatal if swallowed and enters airways.
If aspirated, causes coughing, gagging, distress, and rapidly developing pulmonary edema.
· Additional
Information No further relevant information.
12 Ecological information
· Aquatic
Environmental Toxicity
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Crustacean Toxicity 1000 mg/l (Daphnia magna (water flea))
108-88-3 Toluene
Algae Toxicity
207 mg/l (Chlorella vulgaris) (EC50 (3 hrs))
134 mg/l (Chlamydomonas angulosa) (EC50 (3 hrs))
Crustacean Toxicity 3.78 mg/l (Ceriodaphnia dubia) (LC50 (48 hrs); US EPA 600/4-91-003)
NOEC (7 days) = 0.74 mg/l
Based on the rapid degradability, the substance is not classified as a chronic hazard. Based on the acute LC50 <10
Part Number(s): 10-6702
Page
mg/l, the substance is classified as an Acute-2 environmental hazard.
Fish Toxicity
5.5 mg/l (Oncorhynchus mykiss (Rainbow trout)) (LC50 (96 hrs))
1.39 mg/l (Oncorhynchus kisutch) (NOEC (40 days); growth rate)
14 of 21
· Potential
· Aspiration
Health Effect(s): May cause damage to organs through prolonged or repeated exposure.
Hazard
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Aspiration Hazard (Test species: n/a)
May be fatal if swallowed and enters airways. Based on physico-chemical properties of the material.
Reference: ExxonMobil SDS
108-88-3 Toluene
Aspiration Hazard positive (Test species: n/a) (As a hydrocarbon with viscosity of 0.65 mm²/s)
As a hydrocarbon with dynamic viscosity of 0.65 mm²/s (25℃), the substance was classified as a Category 1 aspiration
hazard.
1801 Morgan Street
MSDS Number: 226
Reference: GHS-J (2006).
Rockford,
61102
Revision Date: 04/14/2015
100-41-4 IL
Ethylbenzene
Aspiration
Hazard968-9661
(Test species: n/a)
Phone:
(815)
Supersedes Date: 04/12/2012
The substance may cause chemical pneumonia due to mis-swallowing based on NIOSH ICSC. Meanwhile, the
Fax:
(815) 968-9731
substance was a hydrocarbon with the kinematic viscosity of 0.74mm²/s at 25 ℃. Thus, the substance was classified as
a Category 1 aspiration hazard based on the criteria.
www.gcelectronics.com
Reference: GHS-J (2007).
· Potential Health Effect(s):
May be fatal if swallowed and enters airways.
If aspirated, causes coughing, gagging, distress, and rapidly developing pulmonary edema.
MATERIAL SAFETY DATA SHEET
· Additional Information No further relevant information.
Product
Name: PAINT THINNER
12 Ecological
informationINFORMATION
SECTION
12: ECOLOGICAL
· Aquatic
Environmental Toxicity
64742-48-9 Naphtha (petroleum), hydrotreated heavy
Crustacean Toxicity 1000 mg/l (Daphnia magna (water flea))
108-88-3 Toluene
Algae Toxicity
207 mg/l (Chlorella vulgaris) (EC50 (3 hrs))
134 mg/l (Chlamydomonas angulosa) (EC50 (3 hrs))
Crustacean Toxicity 3.78 mg/l (Ceriodaphnia dubia) (LC50 (48 hrs); US EPA 600/4-91-003)
NOEC (7 days) = 0.74 mg/l
Based on the rapid degradability, the substance is not classified as a chronic hazard. Based on the acute LC50 <10
mg/l, the substance is classified as an Acute-2 environmental hazard.
Fish Toxicity
5.5 mg/l (Oncorhynchus mykiss (Rainbow trout)) (LC50 (96 hrs))
1.39 mg/l (Oncorhynchus kisutch) (NOEC (40 days); growth rate)
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Algae Toxicity
3.6 mg/l (Selenastrum capricornum) (LC50 (96 hrs); growth rate, TSCA 797.1050)
Page 13/17
7.7 mg/l (Skeletonema costatum) (LC50 (96 hrs); growth rate, TSCA 797.1050)
Crustacean Toxicity 1.81 - 2.38 mg/l (Daphnia magna (water flea)) (EC50 (48 hrs); static)
3.2 mg/l (Ceriodaphnia dubia) LC50(48
static; EPA
Whole Effluent Testing Program method)
acc. hrs;
to OSHA
HCS
Fish Toxicity
4.2 mg/l (Oncorhynchus mykiss (Rainbow trout)) (LC50 (96 hrs); OECD TG 203)
Print Date 04/07/2015
Revision Date 04/07/2015
5.1 mg/l (Menidia menidia) (LC50 (96 hrs); flow-through, TSCA 797.1440)
mg/l (Pimephales promelas) (LC50 (96 hrs); flow-through)
Trade Name: 204-2 12.1
Based on the acute LC50 < 10 mg/l and the non-rapid degradability, the substance was classified as a chronic-2
environmental hazard.
Reference: ECHA (2011) and OECD SIDS (2002).
(Contd. of page 12)
(Contd. on page 13)
· Aquatic Environmental Toxicity Assessment: No further relevant information; classification is not possible.
US
· Degradability and Stability
Safety Data Sheet
108-88-3 Toluene
Biodegradation
readily biodeg. (Test species: n/a) (Biodegradation (OECD TG 301C) = 100%)
Biodegradation (Direct analysis from GC; Chemical conc. 100 ppm; 2 weeks) = 100%
The substance is readily biodegradable.
Reference: CHRIP (2011).
Persistence
(Test species: n/a) (The substance is not persistent)
Although it was concluded to be persistent by Canada DSL, the substance was approved to be readily biodegradable
and fast photodegradable based on ECHA; assessment is not possible without further information.
Photodegradation 6.19E-12 cm³/molecule-sec (OH radical)
Half-life (5E5 OH/cm³) = 2.59 days
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Biodegradation
non-biodegrad. (Test species: n/a) (OECD TG 301C; Chemical conc. 100ppm; 4 weeks)
Biodegradation (Direct analysis from HPLC) = 0%
Biodegradation (Indirect analysis from BOD) = 0%
The substance is non-biodegradable.
Reference: CHRIP (2011).
Persistence
(Test species: n/a)
The substance is persistent.
Reference: Canada DSL (2007).
Photodegradation (7-8)E-12 cm³/molecule-sec (OH radical)
Half-life = 1 day
Reference: OECD SIDS (2002).
Stability in water (Test species: n/a)
The substance does not contain any hydrolysable functional groups; hydrolysis is not expected.
Part Number(s): 10-6702
Page
Reference: OECD SIDS (2002).
· Bioaccumulation and Distribution
15 of 21
Page 13/17
Safety Data Sheet
acc. to OSHA HCS
Print Date 04/07/2015
Revision Date 04/07/2015
Trade Name: 204-2
1801 Morgan Street
MSDS Number: 226
Rockford, IL 61102
Revision(Contd.
Date:of 04/14/2015
page 12)
· Aquatic
Phone:
(815)Environmental
968-9661 Toxicity Assessment: No further relevant information; classification
Supersedes
Date: 04/12/2012
is not possible.
· Degradability
and Stability
Fax:
(815) 968-9731
108-88-3
Toluene
www.gcelectronics.com
Biodegradation
readily biodeg. (Test species: n/a) (Biodegradation (OECD TG 301C) = 100%)
Biodegradation (Direct analysis from GC; Chemical conc. 100 ppm; 2 weeks) = 100%
The substance is readily biodegradable.
Reference: CHRIP (2011).
Persistence
(Test species: n/a) (The substance is not persistent)
Although it was concluded to be persistent by Canada DSL, the substance was approved to be readily biodegradable
and fast photodegradable based on ECHA; assessment is not possible without further information.
Photodegradation 6.19E-12 cm³/molecule-sec (OH radical)
Half-life (5E5 OH/cm³) = 2.59 days
SECTION 12: ECOLOGICAL
INFORMATION (CONTINUED)
Reference: ECHA (2011).
100-41-4 Ethylbenzene
Biodegradation
non-biodegrad. (Test species: n/a) (OECD TG 301C; Chemical conc. 100ppm; 4 weeks)
Biodegradation (Direct analysis from HPLC) = 0%
Biodegradation (Indirect analysis from BOD) = 0%
The substance is non-biodegradable.
Reference: CHRIP (2011).
Persistence
(Test species: n/a)
The substance is persistent.
Reference: Canada DSL (2007).
Photodegradation (7-8)E-12 cm³/molecule-sec (OH radical)
Half-life = 1 day
Reference: OECD SIDS (2002).
Stability in water (Test species: n/a)
The substance does not contain any hydrolysable functional groups; hydrolysis is not expected.
Reference: OECD SIDS (2002).
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
· Bioaccumulation
and Distribution
108-88-3 Toluene
BCF
90 (Leuciscus idus (Ide or Orfe)) (The substance is not or low bioaccumulative)
Koc
(No data available)
LogPow 2.73 (Test species: n/a) (pH=7; at 20 ℃)
Reference: Canada DSL (2007) and ECHA (2011).
100-41-4 Ethylbenzene
BCF
1.1-15 (Test species: n/a)
The substance is not bioaccumulative.
Reference: Canada DSL (2007).
Koc
(No data available)
LogPow 3.13 - 3.15 (Test species: n/a)
Reference: OECD SIDS (2002).
· Degradability and Bioaccumulation Assessment: Non-rapidly degradable, and low bioaccumulative.
· Additional
Information No further relevant information.
13 Disposal
considerations
SECTION
13: DISPOSAL
CONSIDERATIONS
· Hazardous Waste List
· Description:
The product has not been evaluated for its hazards when disposed as a waste by RCRA.
However, it is necessary to contain and dispose of the product as a hazardous waste based on the Hazard Identification in Section 2.
· RCRA Waste:
108-88-3 Toluene
100-41-4 Ethylbenzene
U220 40-50%
D001 0.1-<1%
(Contd. on page 14)
US
Part Number(s): 10-6702
Page 16 of 21
1801 Morgan Street
Rockford, IL 61102
Phone: (815) 968-9661
Fax:
(815) 968-9731
www.gcelectronics.com
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
Safety
Data
Safety
Data Sheet
Sheet
MATERIAL
SAFETY
DATA SHEET
acc.
to OSHA HCS
Print Date 04/07/2015
Print Date 04/07/2015
Trade Name: 204-2
Trade Name: 204-2
acc. to OSHA HCS
Product Name: PAINT THINNER
SECTION 13: DISPOSAL CONSIDERATIONS (CONTINUED)
Page 14/17
Page 14/17
Revision Date 04/07/2015
Revision Date 04/07/2015
(Contd. of page 13)
(Contd. of page 13)
· Waste Treatment Recommendation:
· Waste Treatment Recommendation:
Generation of waste should be avoided or minimized wherever possible.
Generation
of waste
should
avoided or
wherever
possible.
Chemical waste,
even
smallbe
quantities,
is minimized
neither allowed
to be
poured down drains, sewage system or waterways; nor disposed with
Chemical
even small quantities, is neither allowed to be poured down drains, sewage system or waterways; nor disposed with
householdwaste,
garbage.
household
Dispose of garbage.
contents/containers in accordance with local, regional, national, and international regulations.
Dispose of contents/containers in accordance with local, regional, national, and international regulations.
· Unused and Uncontaminated Packagings
· Unused and Uncontaminated Packagings
· Recommendation Dispose of according to your local waste regulations.
· Recommendation Dispose of according to your local waste regulations.
14 Transport information
SECTION
14: TRANSPORT
14 Transport
informationINFORMATION
· UN-Number
· UN-Number
· DOT, ADR, IMDG, IATA
· DOT, ADR, IMDG, IATA
· UN Proper Shipping Name
· UN Proper Shipping Name
· DOT, ADR, IMDG, IATA
· DOT, ADR, IMDG, IATA
· Transport hazard class(es)
· Transport hazard class(es)
· DOT
· DOT
UN1993
UN1993
Flammable liquids, n.o.s. (Toluene, Naphtha )
Flammable liquids, n.o.s. (Toluene, Naphtha )
· Class
·
· Class
Label
· Label
3 Flammable liquids
3 Flammable liquids
3
3
· Class
·
· Class
Label
· Label
3 (F1) Flammable liquids
3 (F1) Flammable liquids
3
3
· Class
·
· Class
Label
· Label
3 Flammable liquids
3 Flammable liquids
3
3
· ADR
· ADR
· IMDG,
· IMDG,
IATA
IATA
· Packing group
· Packing group
· DOT, ADR, IMDG, IATA
II
· DOT, ADR, IMDG, IATA
II
· Environmental Hazards:
Not applicable.
· Environmental Hazards:
Not applicable.
· Special Precautions:
Warning: Flammable liquids
· Special Precautions:
Warning: Flammable liquids
· Danger
Code
(Kemler):
33
Part Number(s):
10-6702
· Danger Code (Kemler):
33
·
EMS
Number:
F-E,S-E
· EMS Number:
F-E,S-E
Page 17 of 21
· DOT
· Class
· Label
3 Flammable liquids
3
· ADR
1801 Morgan Street
Rockford, IL 61102
Phone: (815) 968-9661
Fax:
(815) 968-9731
· Class
www.gcelectronics.com
· Label
· IMDG,
IATA
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
3 (F1) Flammable liquids
3
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
· Class
3 Flammable liquids
SECTION· Label
14: TRANSPORT INFORMATION (CONTINUED)
3
· Packing
· DOT,
group
ADR, IMDG, IATA
· Environmental
Hazards:
Precautions:
Print· Special
Date 04/07/2015
Print Date 04/07/2015
·
Danger Code (Kemler):
Trade
204-2
· EMS
Number:
Trade Name:
Name:
204-2
Page 15/17
Page 15/17
II
Safety
Data
Safety
Data Sheet
Sheet
Not applicable.
acc.
acc. to
to OSHA
OSHA HCS
HCS
Warning: Flammable liquids
33
F-E,S-E
Revision Date 04/07/2015
Revision Date 04/07/2015
· Transport
in Bulk according to Annex II of
MARPOL73/78 and the IBC Code
Not applicable.
· Transport/Additional Information:
· Transport/Additional Information:
· DOT
· DOT
· Quantity
· Quantity
limitations
limitations
·
· ADR
ADR
· Excepted
· Excepted
· UN
· UN
"Model
"Model Regulation":
Regulation":
(Contd. on page 15)
US
On passenger aircraft/rail: 5 L
On
aircraft/rail:
On passenger
cargo aircraft
only: 60 L5 L
On cargo aircraft only: 60 L
quantities
quantities (EQ)
(EQ)
·
· IMDG
IMDG
· Limited quantities (LQ)
· Limited quantities (LQ)
· Excepted quantities (EQ)
· Excepted quantities (EQ)
(Contd. of page 14)
(Contd. of page 14)
Code: E2
Code:
E2 net quantity per inner packaging: 30 ml
Maximum
Maximum
net quantity
quantity per
per outer
inner packaging:
Maximum net
packaging: 30
500mlml
Maximum net quantity per outer packaging: 500 ml
1L
1L
Code: E2
Code:
E2 net quantity per inner packaging: 30 ml
Maximum
Maximum
net quantity
quantity per
per outer
inner packaging:
Maximum net
packaging: 30
500mlml
Maximum net quantity per outer packaging: 500 ml
UN1993, Flammable liquids, n.o.s. (Toluene, Naphtha)
UN1993,
Flammable liquids, n.o.s. (Toluene, Naphtha)
3, II
3, II
15 Regulatory information
15 Regulatory
informationINFORMATION
SECTION
15: REGULATORY
· USA
· USA
Regulation
Regulation Lists
Lists
· SARA (Superfund Amendments and Reauthorization Act of
· SARA (Superfund Amendments and Reauthorization Act of
· Section 302 (Extremely Hazardous Substances)
· Section 302 (Extremely Hazardous Substances)
None of the ingredients is listed.
None of the ingredients is listed.
· Section 313 (Toxics Release Inventory (TRI) reporting)
· Section 313 (Toxics Release Inventory (TRI) reporting)
108-88-3 Toluene
108-88-3 Toluene
100-41-4 Ethylbenzene
100-41-4 Ethylbenzene
71-43-2 benzene
71-43-2 benzene
·
· Section
Section 311/312
311/312 (Hazardous
(Hazardous Chemical
Chemical Inventory
Inventory Reporting)
Reporting)
108-88-3 Toluene
108-88-3 Toluene
· Hazard Abbreviations for SARA 311/312
· Hazard Abbreviations for SARA 311/312
A - Acute Health Hazard
A
Health
Hazard
C -- Acute
Chronic
Health
Hazard
C
Chronic
Health Hazard
F -- Fire
Hazard
F
Fire
Hazard
R - Reactive Hazard
R
ReactiveRelease
Hazard of Pressure Hazard
S -- Sudden
Part Number(s):
10-6702
S - Sudden Release of Pressure Hazard
· TSCA (Toxic Substances Control Act)
· TSCA (Toxic Substances Control Act)
1986)
1986)
40-50%
40-50%
0.1-<1%
0.1-<1%
0.1-<1%
0.1-<1%
A, C, F 40-50%
A, C, F 40-50%
Page 18 of 21
Maximum net quantity per outer packaging: 500 ml
· IMDG
· Limited quantities (LQ)
· Excepted quantities (EQ)
· UN
1L
Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
"Model Regulation":
UN1993, Flammable liquids, n.o.s. (Toluene, Naphtha)
3, II
1801 Morgan Street
15 Regulatory
information
Rockford,
IL 61102
Phone:
968-9661
· USA (815)
Regulation
Lists
· (815)
Fax:
968-9731 Amendments and Reauthorization Act of 1986)
SARA (Superfund
· Section 302 (Extremely Hazardous Substances)
www.gcelectronics.com
None of the ingredients is listed.
· Section
MATERIAL
SAFETY
DATA
313 (Toxics
Release Inventory
(TRI) reporting)
SHEET
108-88-3 Toluene
100-41-4 Ethylbenzene
71-43-2 benzene
Product Name: PAINT THINNER
· Section
311/312 (Hazardous Chemical Inventory Reporting)
SECTION
REGULATORY INFORMATION (CONTINUED)
108-88-315:
Toluene
· Hazard Abbreviations for SARA
A - Acute Health Hazard
C - Chronic Health Hazard
F - Fire Hazard
R - Reactive Hazard
S - Sudden Release of Pressure Hazard
· TSCA
MSDS Number: 226
Revision Date: 04/14/2015
Supersedes Date: 04/12/2012
40-50%
0.1-<1%
0.1-<1%
A, C, F 40-50%
311/312
(Toxic Substances Control Act)
All ingredients are listed.
· Proposition
65
Known to Cause Cancer
· Chemicals
100-41-4 Ethylbenzene
71-43-2 benzene
· Chemicals
108-88-3 Toluene
· Chemicals
Print Date 04/07/2015
71-43-2 benzene
Known to Cause Reproductive Toxicity for Females
Safety Data Sheet
Page 16/17
acc. to OSHA HCS
Known to Cause Reproductive Toxicity for Males
Revision Date 04/07/2015
Trade Name:· Chemicals
204-2
Known to Cause Developmental Toxicity
108-88-3 Toluene
71-43-2 benzene
· Carcinogenic
Categories
· EPA (Environmental Protection Agency)
108-88-3 Toluene
100-41-4 Ethylbenzene
71-43-2 benzene
· IARC
(International Agency for Research on Cancer)
108-88-3 Toluene
100-41-4 Ethylbenzene
71-43-2 benzene
· NTP
(National Toxicology Program)
· TLV
(Threshold Limit Value Established by ACGIH)
71-43-2 benzene
108-88-3 Toluene
100-41-4 Ethylbenzene
71-43-2 benzene
· NIOSH-Ca
71-43-2 benzene
· International
· Canadian
(Contd. of page 15)
(Contd. on page 16)
US
D
D
A, K/L
3
2B
1
K
A4
A3
A1
(National Institute for Occupational Safety and Health)
Regulation Lists
Domestic Substance Listings:
All ingredients are listed.
· Canadian
Ingredient Disclosure list (limit 0.1%)
Part 100-41-4
Number(s):
10-6702
Ethylbenzene
71-43-2 benzene
Page 19 of 21
Trade Name:
Name: 204-2
Trade
204-2
(Contd.
(Contd. of
of page
page 15)
15)
·· Carcinogenic
Carcinogenic Categories
Categories
·· EPA (Environmental Protection
108-88-3
108-88-3
100-41-4
100-41-4
71-43-2
71-43-2
Agency)
EPA (Environmental Protection Agency)
Toluene
Toluene
Ethylbenzene
Ethylbenzene
benzene
benzene
D
D
D
D
A,
A, K/L
K/L
1801 Morgan
Street
·· IARC
IARC (International
(International Agency
Agency for
for Research
Research on
on Cancer)
Cancer)
Rockford,
61102
108-88-3 IL
Toluene
108-88-3
Toluene
100-41-4
Ethylbenzene
Phone:
(815)
968-9661
100-41-4
Ethylbenzene
71-43-2
benzene
benzene
Fax:71-43-2(815)
968-9731
· NTP (National Toxicology Program)
·
www.gcelectronics.com
NTP (National Toxicology Program)
71-43-2
71-43-2 benzene
benzene
·· TLV (Threshold
108-88-3
108-88-3
100-41-4
100-41-4
71-43-2
71-43-2
Value
by
MATERIAL
SAFETY
DATA
TLV (Threshold Limit
Limit
Value Established
Established
by ACGIH)
ACGIH)
Toluene
Toluene
Ethylbenzene
Ethylbenzene
benzene
benzene
·· NIOSH-Ca
MSDS Number: 226
Revision Date: 04/14/2015
3
3
2B
Supersedes Date: 04/12/2012
2B
1
1
SHEET
Product Name: PAINT THINNER
NIOSH-Ca (National
(National Institute
Institute for
for Occupational
Occupational Safety
Safety and
and Health)
Health)
K
K
A4
A4
A3
A3
A1
A1
71-43-2
benzene
SECTION
REGULATORY INFORMATION (CONTINUED)
71-43-2 15:
benzene
·· International Regulation Lists
International Regulation Lists
·· Canadian Domestic Substance
Listings:
Canadian Domestic Substance Listings:
All ingredients
ingredients are
are listed.
listed.
All
·· Canadian Ingredient
Canadian Ingredient Disclosure
Disclosure list
list (limit
(limit 0.1%)
0.1%)
100-41-4
100-41-4
71-43-2
71-43-2
Ethylbenzene
Ethylbenzene
benzene
benzene
·· Canadian
Canadian
108-88-3
108-88-3 Toluene
Toluene
Ingredient
Ingredient Disclosure
Disclosure list
list (limit
(limit 1%)
1%)
·· Chinese Chemical
Chinese Chemical
All ingredients
ingredients are
are listed.
listed.
All
108-88-3
108-88-3
100-41-4
100-41-4
71-43-2
71-43-2
·· Japanese
Japanese
Toluene
Toluene
Ethylbenzene
Ethylbenzene
benzene
benzene
Inventory of
of Existing
Existing Chemical
Chemical Substances:
Substances:
Inventory
Existing
Existing and
and New
New Chemical
Chemical Substance
Substance List:
List:
·· Korean Existing
Korean Existing
All ingredients
ingredients are
are listed.
listed.
All
Chemical Inventory:
Inventory:
Chemical
·· European Pre-registered substances:
European Pre-registered substances:
All
ingredients
All ingredients are
are listed.
listed.
·· REACh - Substances of Very High Concern
REACh - Substances of Very High Concern (SVHC)
(SVHC) List:
List:
None
None of
of the
the ingredients
ingredients is
is listed.
listed.
·· Restriction of Hazardous
(RoHS)
Restriction of Hazardous Substances
Substances
Directive
(RoHS) list:
list:
Safety Directive
Data Sheet
None of
of the
the ingredients
ingredients is
is listed.
listed.
None
Print Date 04/07/2015
16
information
16 Other
Other
information
SECTION
16OTHER INFORMATION
Trade
Name:
204-2
Page 17/17
acc. to OSHA HCS
Revision Date 04/07/2015
This information
information is
is based
based on
on our
our present
present knowledge.
knowledge. However,
However, this
this shall
shall not
not constitute
constitute a
a guarantee
guarantee for
for any
any specific
specific product
features and
and
This
product features
shall
shall not
not establish
establish a
a legally
legally valid
valid contractual
contractual relationship.
relationship.
(Contd. of page 16)
·· Contact:
msds@resinlab.com
Department
Issuing
Department
Issuing (M)SDS:
(M)SDS: Product
Product Safety
Safety Department
Department
(Contd.
(Contd. on
on page
page 17)
17)
·
Abbreviations and acronyms:
US
US
ACGIH: American Conference of Governmental Industrial Hygienists
ACToR: US EPA Aggregated Computational Toxicology Resource
ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road
BCF: Bioconcentration Factor
CAS: Chemical Abstracts Service (division of the American Chemical Society)
CCRIS: US NLM TOXNET Chemical Carcinogenesis Research Information System
CHRIP: Japan NITE Information on Biodegradation and Bioconcentration of the Existing Chemical Substances in the Chemical Risk
Information Platform
DOT: US Department of Transportation
DSL: Canada Domestic Substance List
ESIS: European Chemical Substances Information System
HMIS: US National Paint & Coatings Association (NPCA) Hazardous Materials Identification System
HSDB: US NLM TOXNET Hazardous Substances Databank
HSNO CCID: New Zealand Hazardous Substances and New Organisms Chemical Classification Information Database
IARC: International
Agency for Research on Cancer developed by United Nations World Health Organisation (WHO)
Part Number(s):
10-6702
Page 20
IATA-DGR: Dangerous Goods Regulations (DGR) by the International Air Transport Association (IATA)
ICAO-TI: Technical Instructions (TI) by the International Civil Aviation Organization (ICAO)
of 21
Page 17/17
Safety Data Sheet
acc. to OSHA HCS
Print Date 04/07/2015
Revision Date 04/07/2015
Trade Name: 204-2
1801 Morgan Street
Rockford, IL 61102
· Contact: msds@resinlab.com
Phone:
(815) 968-9661
·
and acronyms:
Fax: Abbreviations
(815) 968-9731
ACGIH: American Conference of Governmental Industrial Hygienists
www.gcelectronics.com
ACToR: US EPA Aggregated Computational Toxicology Resource
MSDS Number: 226
Revision(Contd.
Date:of 04/14/2015
page 16)
Supersedes Date: 04/12/2012
ADR: European Agreement Concerning the International Carriage of Dangerous Goods by Road
BCF: Bioconcentration Factor
CAS: Chemical Abstracts Service (division of the American Chemical Society)
CCRIS: US NLM TOXNET Chemical Carcinogenesis Research Information System
CHRIP: Japan NITE Information on Biodegradation and Bioconcentration of the Existing Chemical Substances in the Chemical Risk
Information Platform
DOT: US Department of Transportation
DSL: Canada Domestic Substance List
ESIS: European Chemical Substances Information System
SECTION
16- OTHER INFORMATION (CONTINUED)
HMIS: US National Paint & Coatings Association (NPCA) Hazardous Materials Identification System
HSDB: US NLM TOXNET Hazardous Substances Databank
HSNO CCID: New Zealand Hazardous Substances and New Organisms Chemical Classification Information Database
IARC: International Agency for Research on Cancer developed by United Nations World Health Organisation (WHO)
IATA-DGR: Dangerous Goods Regulations (DGR) by the International Air Transport Association (IATA)
ICAO-TI: Technical Instructions (TI) by the International Civil Aviation Organization (ICAO)
ICSC: International Chemical Safety Cards
IMDG: International Maritime Dangerous Goods; the principal international rules for International Carriage of Dangerous Goods by SEA
under the Recommendations on the Transport of Dangerous Goods by United Nations (RTDG)
Koc: Partition coefficient, soil Organic Carbon to water
LC50/LD50: Lethal Concentration/Dose, 50 percent
N/a: Not available or Not applicable
NFPA: US National Fire Protection Association
NIOSH: US National Institute of Occupational Safety and Health
NITE: National Institute of Technology and Evaluation, Japan
OECD: Organisation for Economic Co-operation and Development
OSHA: US Occupational Safety and Health Administration
P: Marine Pollutant
RCRA: Resource Conservation and Recovery Act (USA)
REACh: EU Registry, Evaluation and Authorisation of Chemicals
RID: the Regulations Concerning the International Carriage of Dangerous Goods by Rail; published by the Central Office for
International Carriage by Rail (OTIF)
RTDG: the Recommendations on the Transport of Dangerous Goods by United Nations (UN)
RTECS: US Registry of Toxic Effects of Chemical Substances
SARA: US Superfund Amendments and Reauthorization Act
SIDS: OECD existing chemicals Screening Information Data Sets
SVHC: EU ECHA Substance of Very High Concern
TEEL: Temporary Emergency Exposure Limit developed by US Subcommittee on Consequence Assessment and Protective Actions
(SCAPA) of US Department of Energy (DOE)
TOXLINE: US NLM bibliographic database search system
TSCA: US Toxic Substance Control Act
· Date of preparation / last revision 04/07/2015 / -
MATERIAL SAFETY DATA SHEET
Product Name: PAINT THINNER
US
GC Electronics believes that the information contained herein is accurate and reliable as of the date of this
material safety data sheet, but no representation guarantee or warranty, express or implied, is made as to the
accuracy, reliability or completeness of the information. Persons receiving information are encouraged to make
their own determination as to the information’s suitability and completeness for their particular application.
NO INFORMATION CONTAINED HEREIN CONSTITUTES A PRODUCT WARRANTY OF ANY KIND, WHETHER
EXPRESS OR IMPLIED; AND ALL IMPLIED WARRANTIES OF MERCHANT ABILITY AND OF FITNESS FOR A
PARTICULAR PURPOSE ARE HEREBY DISCLAIMED BY GC ELECTRONICS.
Part Number(s): 10-6702
Page
212ofof21
Page
7