電機所
九十九
第二學期
固態熱力學
Thermodynamics of Solids
N265600
材料科學
3
李炳鈞 bjli@mail.ncku.edu.tw
(06)2757575 ext. 62345
Monday(14:00-16:00)
Wednesday(14:00-16:00)
從熱力學出發，用較深入的理論基礎，
詳細探討固態材料的物理和化學特性和
相關計算問題。
This course is designed to bring students with diverse undergraduate backgrounds (in various scientific and engineering disciplines) to a common level in thermodynamics as applied to materials science and engineering.
1. Review of the first, second and third laws of thermodynamics
2. Statistical thermodynamics
3. Phase equilibrium in a one-component system
4. Behaviors of gases and solutions
5. Gibbs free energy-composition and phase diagrams of binary systems
6. Reaction involving gases, pure condensed phases and a gaseous phase
7. Reaction equilibria in systems containing components in condensed solution

8. Electrochemistry
9. Diffusion
10. Surface and interface
11. Defects
Gaskell: Ch01 Introduction and Definition of
Terms
Gaskell: Ch02 The First Law of Thermodynamics
Gaskell: Ch03 The Second Law of
Thermodynamics
Gaskell: Ch04 Statistical Interpretation of Entropy
Gaskell: Ch05 Auxiliary Functions
Gaskell: Ch06 Heat Capacity, Enthalpy, Entropy, and the Third Law of Thermodynamics
Gaskell: Ch07 Phase Equilibrium in a
One-component System
Gaskell: Ch08 Behavior of Gases:
Van der Waals Gas
Gaskell: Ch09 Behavior of Solutions
Gaskell: Ch10 Gibbs Free Energy - Composition and Phase Diagrams of Binary Systems
Midterm Exam
Ragone, I: Ch05 Chemical Equilibrium
Ragone, I: Ch06 Electrochemistry
Ragone, I: Ch07 Phase Rule
Ragone, II: Ch03 Defects in Solids
Ragone, II: Ch04 Surfaces and Interfaces
Ragone, II: Ch05 Diffusion
Ragone, II: Ch06 Transformations
Ragone, II: Ch07 Reaction Kinetics
Mansoori: Nanothermodynamics
Final Exam
1. R. A. Swalin, Thermodynamics of Solids,
2nd Edition, John Wiley & Sons, 1972.
2. R. Gaskell, Introduction to the thermodynamics of materials 3rd ed.
Washington, D.C.: Taylor & Francis, 1995.
3. Richard H. Dittman, Mark Waldo
Zemansky, Heat and Thermodynamics,
McGraw-Hill.
4.
J. B. Hudson, Thermodynamics of
Materials: A Classical and Statistical
Synthesis John Wiley, 1996.

5.
G. A. Mansoori, Principles of nanotechnology: molecular-based study of condensed matter in small systems : World
Scientific, 2005.
Midterm exam: 25%
Final exam: 25%
Homework: 25%
Discussion in Class: 25% http://moodle.ncku.edu.tw/