K&E Sand and Gravel P.O. Box 369, Wyoming, Ontario. N0N 1T0 (519) 845-3396 Fax: (519) 845-3398 Material Safety Data Sheet For K&E Silica Sand Section 1- Material Identification and Use Material Name: Silica Sand Chemical Name: Silica, Quartz Chemical Family: Inorganic Silicon Compound Chemical Formula: Free SiO2 Synonyms: Free crystalline silica, Silicon Dioxide Trade Names: K&E 32, K&E 4.0, K&E 3.0, F-70, Locomotive sand, BodyShot, Pool Filtration Sand, All Purpose, Frac Sand, Dike Sand, Well Pack #1, #0, #00N, #2, #3, Traction Sand, 3/8” & 3/16” Pea stone, Salt and Pepper l Section 2- Hazardous Ingredients of Material Ingredient: Silica Crystalline or Quartz Approximate Concentration: 75-100% C.A.S. Registry Number: 14808 60 7 LD50: N/A LC50: N/A Section 3- Physical Data Physical State: Solid Specific Gravity: 2.65 Odor and Appearance: Odorless, white to light brown granules Solubility: Not soluble Melting Point: 3100oC Section 4- Fire and Explosion Hazard Data Flashpoint (c): N/A Explosive Limits: N/A Extinguishing Media: N/A Fire and Explosion Hazards: N/A TDG Flammability Classification: N/A Auto Ignition Temperature: N/A -2- M.S.D.S. Sheet for Silica Sand Section 5- Reactivity Data Chemical Stability: Stable, Non-reactive Incompatibility and Reactivity: Reacts with strong oxidizing chemicals (such as Hydrofluoric Acid, Fluorine, Magnesium Trioxide, etc. to generate volatile corrosive gas and cause fire) May be attacked by strong alkalis especially when hot. Hazardous Decomposition Products: None known Section 6- Toxicological Properties Inhalation: Prolonged or repeated inhalation to crystalline silica dust may cause severe scarring of the lungs, a disease called silicosis Eye Contact: May be irritating due to scratching Skin Absorption: No effect Ingestion: Possible discomforts if ingested Effects of Acute Inhalation Exposure: Repeated inhalation of crystalline free silica may cause severe scarring of the lungs, a disease called silicosis Exposure Limits: T.L.V.-T.W.A. –0.1mg/m3 maximum allowable respirable dust Sensitization of Material: None known Carcinogenicity, Reproductive Effects, Teratogenicity, Mutagenicity: Limited evidence for the carcinogenicity of crystalline silica to humans Section 7- Personal Protection –Respiratory Respiratory protection should be used whenever dust is generated. Use ministry of Labour respirator requirements for silica dust exposure Eye Protection: Safety Glasses Engineering Controls: Exhaust dust concentrations to acceptable levels by use of proper Ventilation such as dust collectors, cyclones, etc. Spill procedure: Clean up in a manner to control airborne dust. Whenever possible, wet down area with water to control dust Waste Disposal: Review current regulations. Can be used as a fill material Handling and Storage: Handle and store in a manner to control dust. Other Precautions: None -3- M.S.D.S. Sheet for Silica Sand Section 8- First Aid Inhalation: Move victim to fresh air. Obtain medical advice Skin: Wash with soap and water Eyes: Wash eyes with lukewarm water. If irritation continues seek medical advice. Ingestion: Seek medical advice if necessary Other Information: None known Section 9- Preparation Date of M.S.D.S. Additional Information: Use good housekeeping techniques. Only the respirable silica between 0.5-5.0 microns is dangerous to the respiratory system. Smoking and lung disorders may aggravate the effects of exposure. Sources of Information: CHEMINFO- Canadian Centre For Occupational Health and Safety, Occupational Health and Safety Act regarding Silica. Ministry of Labour Prepared by: Mr. Bill Esser Effective Date: February 01, 2016 K&E Sand and Gravel shall not be liable for any damages arising out of the use of the Material Safety Data Sheet howsoever caused, if the product is not employed in a normal or reasonable foreseeable use or circumstance.