CHEMISTRY 102A COURSE OUTLINE AND ASSIGNMENTS WEEK 1 (August 22-26) Lecture: Tuesday Discussion: Wednesday Topics: Introduction, Atomic Structure: subatomic particles and their properties, definition of mass number, atomic number, isotopes, ions Reading for lecture: Zumdahl Chapter 2: 2.1-2.6 Chapter 3: 3.2 Practice Problems: Zumdahl, Chapter 2: 28, 29 47, 50, 51, 53, 55, 57, 59, 61, 88 Chapter 3: 33, 34, 35, 37 Worksheet 0 – Calculations Lecture: Thursday Discussion: Friday Topics: Electromagnetic radiation, Bohr model: Quantum Mechanical Model of the atom: orbitals, quantum numbers Reading for lecture: Zumdahl Chapter 7: 7.1-7.6 Practice Problems: Zumdahl Chapter 7: 20, 37, 38, 41-44, 53, 55, 60, 61, 63, 64, 138-139, 155 Worksheet 1 – Atoms Quiz 1 – Scientific Measurement (Please look over Lecture 0 on LON-CAPA and Worksheet 0) WEEK 2 (August 29-September 2) Lecture: Tuesday Discussion: Wednesday Topics: Quantum Mechanical model of the atom: orbital shapes and energies, Pauli Exclusion Principle, polyelectronic atoms, electronic configurations, excited states Reading for lecture: Zumdahl Chapter 7: 7.7-7.11 Practice Problems: Zumdahl Chapter 7: 68-70, 73, 75, 77, 78, 91, 93 Chapter 8: 43, 44 Worksheet 2 – Electromagnetic Radiation and the Bohr Atom Lecture: Thursday Discussion: Friday Topics: Periodic Table: electronic configuration and the Periodic Table, periodic trends in atomic properties, effective nuclear charge Reading for lecture: Zumdahl Chapter 2: 2.7 Chapter 7: 7.10 - 7.12 Chapter 8: 8.4 (sizes of ions only) Practice Problems: Zumdahl, Chapter 2: 47, 49 Chapter 7: 99,101,103,104 106-108,112,117,147,148,163 Chapter 8: 51, 50, 129 Worksheet 3 – Electronic Structure of Atoms Quiz 2 – The Periodic Table and the Bohr atom (Worksheets 1 and 2) WEEK 3 (September 5-9) Lecture: Tuesday Discussion: Wednesday Topics: Bonding: types of chemical bonds, polarity, naming simple covalent molecules and ionic compounds, define molecular and empirical formula Reading for lecture: Zumdahl Chapter 8: 8.1-8.4 Chapter 2: 2.8 Practice Problems: Zumdahl Chapter 2: 63-70, 72, 77, 80, 89, 93-95 Chapter 7: 99,101,103,104 106-108,112,117,147,148,163 Worksheet 4 – Periodic Trends Lecture: Thursday Discussion: Friday Topics: Shapes of Molecules: Lewis Structures, Exceptions, Resonance (formal charge) Reading for lecture: Zumdahl Chapter 8: 8.9 - 8.12 Practice Problems: Zumdahl, Chapter 8: 79-89, 92, 97, 100, 101 Worksheet 5 – Chemical Bonding Quiz 3 – Quantum numbers and periodic properties (Worksheets 3 and 4) WEEK 4 (September 12-16) Lecture: Tuesday Discussion: Wednesday Topics: VSEPR and its link to polarity, Lewis structures and organic molecules Reading for lecture: Zumdahl Chapter 8: 8.13 Practice Problems: Zumdahl Chapter 8: 26, 105-115, 117-120 125,127,151,152,154 Worksheet 6 – Lewis Structures Lecture: Thursday Discussion: Friday Topics: Hybrid Orbitals Reading for lecture: Zumdahl Chapter 9: 9.1 Practice Problems: Zumdahl, Chapter 9: 9, 11, 12, 23-28, 33, 60, 61, 79, 68 Worksheet 7 – Molecular Shapes Quiz 4 – Lewis Structures and Hybridization WEEK 5 (September 19-23) Lecture: Tuesday Discussion: Wednesday Topics: Hybridization and VSEPR model, delocalization Reading for lecture: Zumdahl Chapter 9: 9.1 Practice Problems: Zumdahl Chapter 9: 36, 37, 38, 59 Worksheet 8 – Hybridization Lecture: Thursday Discussion: Friday Review for HE I HOUR EXAM I: 7:00 pm THURSDAY, 9/22 (Location to be announced.) WEEK 6 (September 26-30) Lecture: Tuesday Discussion: Wednesday Topics: Stoichiometry: Balancing chemical equations, molar mass, empirical and molecular formula, percent composition, stoichiometric calculations Reading for lecture: Zumdahl Practice Problems: Zumdahl Chapter 3: 3.3-3.10 Chapter 3: 41, 42, 61, 63, 64, 70, 71, 72, 117, 119, 131, 75, 76, 80, 83, 100, 103, 99, 94, 96, 121, 135, 137, 138, 145 Worksheet 9 – Mass Percent and Empirical Formulas Lecture: Thursday Discussion: Friday Topics: Stoichiometry: combustion analysis, limiting reagents, percent yield Reading for lecture: Zumdahl, Chapter 3: 3.7, 3.11 Practice Problems: Zumdahl, Chapter 3: 84-86, 88, 107-109, 111, 114-116, 141, 152, 163 Worksheet 10 – Balancing Reactions, Stoichiometry and Limiting Reagents Quiz 5 – Empirical Formulas and Stoichiometry WEEK 7 (October 3-7) Lecture: Tuesday Topics: Discussion: Wednesday Gases: P, V, T relationships, Ideal gas Law, stoichiometry Reading for lecture: Zumdahl Chapter 5: 5.1-5.4 Practice Problems: Zumdahl Chapter 5: 23, 25, 26, 29, 41, 44, 48, 53, 55, 56, 65, 71, 73, 75-77 Worksheet 11 – Ideal Gas Law Lecture: Thursday Topics: Discussion: Friday Gases: Partial pressures, Kinetic Molecular Theory, Root mean Square velocity, effusion and diffusion, Real gases Reading for lecture: Zumdahl Chapter 5: 5.5-5.8 Practice Problems: Zumdahl Chapter 5: 27, 29, 30-32, 80, 81, 83, 87, 89, 91, 92, 99, 101104, 106, 124, 130, 132,133 Worksheet 12 – Partial Pressures and the Kinetic Molecular Theory of Gases Quiz 6 – Gas Laws WEEK 8 (October 10-14) Lecture: Tuesday Topics: Discussion: Wednesday Intermolecular Forces and Physical Properties Reading for lecture: Zumdahl Chapter 10: 10.1-10.2, 10.8 (vapor pressure discussion only) Practice Problems: Zumdahl Chapter 10: 5, 12-14, 21, 25, 33, 35-39, 117, 128 Worksheet 13 – Intermolecular Forces Lecture: Thursday Discussion: Friday Topics: Solution Properties Reading for lecture: Zumdahl Chapter 4: 4.3 Practice Problems: Zumdahl Chapter 4: 55-61, 63, 64, 27, 29, 31, 33, 35, 37, 39, 41, 91, 89, 100 Worksheet 14 – Solutions, Electrolytes and Concentration Quiz 7 – IMF and Solutions WEEK 9 (October 17-21) Lecture: Tuesday Discussion: Wednesday Topics: Solutions: Electrolytes and Precipitation reactions Reading for lecture: Zumdahl Chapter 4: 4.1-4.2, 4.5-4.7 Practice Problems: Zumdahl Chapter 4: 23-26, 15, 44, 45, 46, 47, 49, 51, 52, 53, 54, 93, 103, 121 Worksheet 14 – Displacement Reactions Lecture: Thursday Topics: Discussion: Friday First Law of Thermodynamics Reading for lecture: Zumdahl Chapter 6: 6.1 Practice Problems: Zumdahl Chapter 6: 29, 31, 33, 35, 43 Worksheet 15 – 1st Law WEEK 10 (October 24-28) Lecture: Tuesday Discussion: Wednesday Review for HE II HOUR EXAM II: 7:00 pm TUESDAY, 10/25 (Location to be announced.) Lecture: Thursday Discussion: Friday Topics: Enthalpy and Calorimetry Reading for lecture: Zumdahl Chapter 6: 6.2 Practice Problems: Zumdahl Chapter 6: 49, 51, 53, 57, 59, 61, 63, 65 Worksheet 16 - Calorimetry WEEK 11 (October 31- November 4) Lecture: Tuesday Discussion: Wednesday Topics: Hess’ Law and Heats of Formation Reading for lecture: Zumdahl Chapter 6: 6.3-6.4 Practice Problems: Zumdahl Chapter 6: 69, 71, 75, 81, 97, 99 Worksheet 17 – Hess’ Law Lecture: Thursday Discussion: Friday Topics: Entropy Reading for lecture: Zumdahl Chapter 17: 17.1-17.2 Practice Problems: Zumdahl Chapter 17: 8, 27, 29, 35, 41, 43 Worksheet 18 - Entropy Quiz 8 – First Law and Calorimetry WEEK 12 (November 7-11) Lecture: Tuesday Discussion: Wednesday Topics: Free Energy Reading for lecture: Zumdahl Chapter 17: 17.3 - 17.4 Practice Problems: Zumdahl Chapter 17: 48, 49, 51, 53, 55, 57 Worksheet 19 – Standard Free Energy Lecture: Thursday Discussion: Friday Topics: Chemical Equilibrium Reading for lecture: Zumdahl, Chapter 13.1-13.4 Practice Problems: Zumdahl, Chapter 13: 10-14, 21, 23, 25, 27, 29, 33, 35, 37, 38, 43, 44 Worksheet 20 – Chemical Equilibrium Quiz 9 – Enthalpy and Entropy WEEK 13 (November 14-18) Lecture: Tuesday Discussion: Wednesday Topics: LeChatelier’s Principle Reading for lecture: Zumdahl, Chapter 13.5-13.7 Practice Problems: Zumdahl, Chapter 13: 15-20, 28, 29, 41, 47-49, 57, 59, 61, 63, 64, 67-69, 92, 93 Worksheet 21 – Le Chatelier’s Principle Lecture: Thursday Discussion: Friday Topics: Equilibrium Calculations Reading for lecture: Zumdahl, Chapter 13.5-13.7 Practice Problems: Zumdahl, Chapter 13: 15-20, 28, 29, 41, 47-49, 57, 59, 61, 63, 64, 67-69, 92, 93 Worksheet 20 – LeChatelier’s Principle Quiz 10 – Equilibrium ****************************************************************************** THANKSGIVING BREAK, NOVEMBER 19-27 ****************************************************************************** WEEK 14 (November 28-December 2) Lecture: Tuesday Discussion: Wednesday Review for HE III HOUR EXAM III: 7:00 pm WEDNESDAY, 11/30 (Location to be announced.) Lecture: Thursday Discussion: Friday Topics: Non-Standard Free Energy Reading for lecture: Zumdahl Chapter 17: 17.5 - 17.7 Practice Problems: Zumdahl Chapter 17: 59, 61 Worksheet 21 – Non-Standard Free Energy Quiz 11 – Free Energy WEEK 15 (December 5-9) Lecture: Tuesday Discussion: Wednesday Review for Final Exam Reading Day: Thursday December 8 FINAL EXAM for CHEM 102A: 1:30 – 4:30 Friday, December 9