UNIT I - Safety & The Tools of Science 1 I. Laboratory Equipment A. Things on a Ring Stand OBJECT PURPOSE PICTURE OBJECT PURPOSE Metal Ring To support wire gauze or clay triangle & hold object above burner Funnel Stand To support a funnel so a beaker or other container may be placed under it Test Tube Clamp To hold a test tube securely on a ring stand Wire Gauze Placed on a metal ring. Supports beaker or other object over burner. Ring Stand To serve as a base for holding rings, Bunsen burners, funnel stands, etc. Clay Triangle Placed on metal ring. Supports crucible over burner PICTURE B. Objects Used to Manipulate Things OBJECT PURPOSE Scoopula To transfer granular solids from a container to another area. Also good for pulverizing solids. PICTURE side OBJECT PURPOSE Crucible Tongs To grab and move a hot crucible from one area to another. view To transfer small amounts of granular solids. Beral (plastic) Pipet To transfer small amounts of liquid from one area to another. Beaker Tongs To grab and move a hot beaker from one area to another. Forceps To grab and move solid objects. Pipet Bulb To draw liquids into a pipet. NEVER USE YOUR MOUTH!!! Volumetric Pipet To measusre out a specific volume of a liquid. NEVER USE YOUR MOUTH!! 10 mL Microspatula PICTURE UNIT I - Safety & The Tools of Science 2 C. Containers - NOTE: None of these are used for measurement OBJECT PURPOSE Erlenmeyer Flask Glass container with narrow neck. Good for holding and heating chemicals Test Tube Small glass tube with one open end. Commonly used for observing reactions. Squeeze Bottle Holds cleaning solution, reagent or distilled water. Used to rinse glassware. Reagent Bottle Glass container used to hold reagents. Comes in many shapes and sizes. PICTURE OBJECT PURPOSE Beaker Glass container with wide neck. Also good for holding and heating chemicals.. DO NOT USE TO MEASURE LIQUID VOLUMES!! Crucible Porcelain container used for high temperature heating. VERY FRAGILE. Evaporating Dish Lidless porcelain dish used for high temperature heating. VERY FRAGILE. Spot Plate Plastic plate with many wells. Used to perform many reactions next to each other for easy comparison. PICTURE D. Measuring Devices OBJECT PURPOSE Thermometer To measure temperatures of objects or substances. UNITS: oC PICTURE 43.5oC OBJECT PURPOSE Electronic Balance To measure the masses of substances. UNITS: g 13.45 g 30 Graduated Cylinder To measure volumes of liquids. UNITS: mL PICTURE 20 Volumetric Flask 10 A flask designed to very precisely measure one particular volume of liquid UNIT I - Safety & The Tools of Science 3 E. Miscellaneous other Items OBJECT PURPOSE Safety Goggles Protects eyes from damage. REQUIRED IN LAB AREA AT ALL TIMES UNLESS SPECIFICALLY TOLD BY INSTRUCTOR. Plastic Apron Protects torso and legs from damage. Hot Plate To heat substances in glass or porcelain containers. Stir Rod/ Stir Bar PICTURE Rod - Glass rod used to stir solutions Bar - Magnetic Bar used on hot/stir plate OBJECT PURPOSE Rubber Tubing Used to transfer a fluid (liquid or gas) safely from one container to another. Bunsen Burner Used for heating substances. Produces up to 950oC Stopper Used to close flasks and test tubes. Varieties include rubber and cork. Funnel Used to help transfer liquids from one container to another. Also used to make a filter with filter paper PICTURE F. Clues for Equipment Crossword ACROSS 5. Glass container used to hold chemicals. Its edges are slanted. 6. A ________ triangle holds crucibles when they Are being heated. 8. A stir ____ contains a magnet that is used to stir solutions on a stir plate. 11. A fragile porcelain dish used for heating chemicals is called an ____________ dish. 12. This is used to measure temperature. 14. This is placed on a metal ring and is used to support a beaker placed over a burner. 18. Cork or rubber 19. If you don’t wear safety goggles, this part of your body is in danger. 20. This type of tubing is used to connect a bunsen. Burner to the gas outlet. 22. These are required in the lab at all times. DOWN 1. Attaches to ring stand and supports wire gauze or clay triangle. 2. Crucible _______ are used to move a hot crucible. 3. This type of glass pipet has a big bulge in the center. 4. Used to measure volumes of liquids. 7. Used for heating objects with flame. 8. An electronic _________ is used to get the mass of objects. 9. _____ ______ rack. 10. Small, fragile container placed on a clay triangle to heat chemicals 13. Erlenmeyer ________ 15. This is used to grab small objects. 16. A glass stir _______. 17. We set beakers on _____ gauze to heat. 21. Solid, liquid, and _______. UNIT I - Safety & The Tools of Science 4 G. Laboratory Safety Highlights 1. Safety Video 2. Symbols you should know: SYMBOL MEANING SYMBOL MEANING Flammable Solid RED - Flammable Gas or Liquid BLUE – Dangerous when wet Poisonous Strong Oxidizer Radioactive Corrosive Strong Irritant Biohazard 3. Other Safety Highlights from Past Experience a. Never directly smell or taste anything in the lab – learn to waft if smell is needed. b. Always listen to Teacher’s tips before the lab. c. Always READ THE DIRECTIONS FIRST!!!!! d. Stick to the lab directions. Unauthorized experiments = trouble. 4. MSDS Labels – “Material Safety Data Sheets” – rank chemicals in certain danger areas on a scale from 1-4. A. Flammability – 0 is nonflammable, 4 is very flammable * remember, in order to burn, oxygen must also be present B. Reactivity – 0 means it is very inert (doesn’t react with much), 4 is very reactive C. Health – 0 is safe (NaCl is a 1), 4 is very dangerous * remember, you should never eat things in the lab, even 0’s UNIT I - Safety & The Tools of Science 5 II. Rules of Significant figures - importance? A. All digits 1-9 are significant 1) 45.1 2) 0.153 B. All zeros in a “sandwich” are significant 1) 105 2) 4053.01 C. All zeros that end a decimal fraction are significant 1) 5.430 2) 6.0100 D. All zeros in front of a fraction and not in a sandwich are not significant 1) 0.00501 2) 0.0005 E. All zeros at the end of a number greater than 10 not in a sandwich are not significant. 1) 100 2) 1010 3) 100.0 F. A “lined” zero (θ) is significant. 1) 1θ0 2) 10θ Try the “Atlantic-Pacific” rule to remember: - If the decimal point is Present, count from the Pacific side - If the decimal point is Absent, count from the Atlantic side S. How many significant figures are there in: 1) 45.6 6) 5000 3 1 2) 150 2 3) 0.055 2 4) 0.0306 3 5) 10,000.1 7) 30.1 3 8) 30.10 4 9) 400.00 5 10) 0.000051 6 2 UNIT I - Safety & The Tools of Science 6 III. Multiplying and Dividing Significant Figures. When multiplying and dividing measurements, the answer should have a number of significant figures equal to the multiplicant with the least number of sig figs For example: 36.2 x 4.3 = 155.66 2 sig figs 3 sig figs 155.66 Calculator answer; needs to be rounded to 2 sig figs Keep these 2 digits 160 Final Rounded Answer Drop these digits T. Calculate the following. Make sure the answer has the correct number of sig figs. 3sf 1) 1sf 3 sf 4.11 x 5 2 0.55 20 5 sf 2) 4 sf 3 sf 5.00 x 5.00 25.0 25.0 1sf 1sf 3) 4.7152 x 3.446 16.24 85792 16.25 4) 6 x 6 3 6 40 3 sf 5) 3 sf 38.1 655 0.058167938 0.0582 4 sf 6) 4 sf 9.475 12.05 0.7863 07053 0.7863 S. Calculate the following. 3 sf 1) 3 sf 3) 3sf 3.65 x 5.01 18.2 865 18.3 3 sf 2) 3 sf 26.0 x 2.00 52.0 52.0 2 sf 4 sf 5) 4.0 381.3 0.010 490427 0.010 3 sf 0.0522 x 0.827 0.0431 694 0.0432 2 sf 4) 3 sf 5.2 x 20.0 10 4 1 0 3 sf 2 sf 6) 4.08 0.061 66. 8852459 67 UNIT I - Safety & The Tools of Science 7 IV. Adding and Subracting Significant Figures. When adding and subtracting measurements, round your answer to the decimal place represented by the least precise number – round it to the “worst” decimal place For example: Nearest 1’s digit Nearest 0.01 Nearest 10’s digit 123 40.55 + 270 123 40.55 + 270 433.55 433.55 Keep this T. 1) 0.03694 + 0.0770 ----------0.11394 2) 38.5 0.051 + 100 -----------138.551 0.1139 S. 1) 0.450 + 0.034 7 ------------0.484 7 3) 100 4.3 14.6 2 + 327.9 -----------346.8 2 3) 346.8 V. Dealing with units in calculations - drop this 6.0098 - 2.51 -----------3.4998 3.50 2) 0.485 430 7 61.8 - 1 00 ---------6 61.8 700 * the units are treated just like variables in algebra A. Multiplying and Dividing In algebra: 2y x 4y = 8y2 Similarly: 4.5 cm x 10.2 cm = 45.9 cm2 46 cm2 Also: 35.44 g ----------------- = 6.56296 g/mL = 6.6 g/mL 5.4 mL B. Adding and Subtracting - ALL UNITS MUST BE EXACTLY THE SAME!!!! For example: However: 3.5 cm + 4.2 cm + 7.1 cm = 14.8 cm 3.6 cm + 0.21 km + 450 mm = Not Possible UNIT I - Safety & The Tools of Science 8 VI. Measurement Activity – 1) Measure the length and width of 4 tile squares on the lab floor to the nearest 0.001 m 2) Calculate the area of each square. Make sure to round the answer to the correct number of sig figs. 3) Add your four results to determine the total area of the big square made up by your 4 squares. Square Length (m) Width (m) Area (m2) 1 2 3 4 Total Area 4) Measure the length and width of the big square formed by the 4 squares you selected. Length (m) Width (m) Area (m2) Questions: 1) How do the area values for the big square compare between question #3 and #4? The areas should be fairly similar, but not exactly the same. How can that be? It’s the same square, isn’t it? 2) Why do you think a difference occurs? Every time, you take a measurement, there is a range of error that each measurement takes on. Every time you do a calculation with a measurement, the error increases as well. 3) Describe how the number of sig figs in a measurement relates to its precision. The more sig figs a number has, the more precise the measurement is. In the above example, using a more precise measuring device (more sig figs) should produce less error. As a result, the total areas in #3 and #4 should be more similar with the more precise measuring tool. UNIT I - Safety & The Tools of Science 9 VII. Scientific Notation a method used to express extremely large numbers or extremely small numbers base - must be greater than or equal to 1 and less than 10 4.56 x 105 power the number of sig figs in a number expressed in scientific notation corresponds to the number of sig figs in the base number Contest: How many molecules are there in 36.0 mL of water? _________________________________ S. How many sig figs in the following numbers? 1) 3.123 x 103 4 2) 5 x 1011 1 3) 4.010 x 10-11 4 T. Convert the following to scientific notation: - move the decimal point to the left or right until the base number is between one and ten. Large numbers (#1 & #2) have positive exponents. Small numbers (#3 & #4) have negative exponents. Make sure the base has the same number of sig figs as the original number. 1) 47,000,000,000 4.7 x 1010 3) 0.0000000005 5 x 10-10 2) 2,600,000,000,000 2.6 x 1012 4) 0.0000001020 1.020 x 10-7 S. Convert the following to scientific notation: 1) 863,030,000,000,000 8.6303 x 1014 2) 953,000,000,000,000,000,000 9.53 x 1020 T. Convert the following to decimal notation: 3) 0.000000040101 4.0101 x 10-8 4) 0.00000000000000021 2.1 x 10-16 S. Convert the following to decimal notation: 1) 4 x 10-4 0.0004 1) 5.0 x 10-5 0.000050 2) 9.24 x 107 92,400,000 2) 6.73 x 108 673,000,000 3) 7.030 x 106 7,03θ,000 3) 8.923 x 10-10 0.000 000 000 8923 UNIT I - Safety & The Tools of Science 10 When using your calculator, the “EE” or “EXP” button is equivalent to “10 to the.....” Example: 4 x 105 x 3.2 x 10-2 is entered: 4 EE 5 * What do you get? 3 1.28 04 . EE 2 1.28 04 (-) 2 1.28 E 04 = or 12800 Either way, you must round the base to the correct number of sig figs: Answer: 1 x 104 S. Calculate the following. Make sure the answer has the correct number of sig figs. 1) (2.3 x 106)(4.2 x 10-11) = 9.7 x 10-5 2) (4.00 x 10-15)(3.0040 x 104) = 1.20 x 10-10 3) 8.5 x108 3x10 4 3 x 1012 8.05x10 5.9 x10 11 5) 6) 4) 4.00 x10 15 6.22 x105 7) 43,000,0000.00071 10.240.000000234 1.3 x 1010 8) 5.0404x10 3.2x10 7.020x10 6x10 4 x 10-48 7 14 3.1x10 1.5 x 10-17 5.444x10 1.0001x10 4.22 x 10-36 2.43x10 5.3063x10 8 23 10 30 6.43 x 10-21 22 10 5 40 UNIT I - Safety & The Tools of Science 11 VIII. Graphing - an important tool in scientific experiments * independent variable - x-axis; variable whose values are determined before the experiment * dependent variable - y-axis; variable whose values are measured during the experiment S. In each of the following statements, declare what is the independent variable and the dependent variable. 1. In my experiment, I checked the temperature of my heating water every 5 minutes. * independent variable - TIME * dependent variable - TEMPERATURE 2. I wanted to see the relationship between the pressure and volume of a trapped gas, so I increased the pressure on the gas 0.500 atm at a time and measured the volume at that pressure. * independent variable - PRESSURE directly proportional – as “x” increases, “y” increases y kx OR k y x * dependent variable - VOLUME inversely proportional – as “x” increases, “y” decreases xy k OR x y k S. Graph each of the following sets of data. Make sure you correctly label the independent variable and dependent variable. When the data points are plotted, draw a best-fit line and answer the question. * best-fit line – a line that approximates a linear pattern shown in data 1. Volume of an Enclosed Gas vs. Temperature Temp ( oC ) 25 30 35 40 45 50 55 60 65 70 Volume (mL) 10.0 11.7 13.4 15.0 16.7 18.4 20.1 21.7 23.4 25.1 a. Is the relationship linear? If so, draw a best-fit line. YES. See graph 2. Data From a Bike Trip Time (hrs) 0 1 2 3 4 5 6 7 8 Distance (km) 0 12 23 33 42 50 56 60 62 a. Is the relationship linear? If so, draw a best-fit line. NO UNIT I - Safety & The Tools of Science 12 b. Is the relationship directly proportional, inversely proportional, or neither? NEITHER. It is linear, but it does not intercept the origin b. Is the relationship directly proportional, inversely proportional, or neither? NEITHER. c. Calculate the slope of the line. c. Approximate when the biker will reach 100 km. m y2 y1 11.7 10.0 1.7 0.34 x2 x1 30 25 5 Hard to determine. No good pattern to the data. d. Use the slope-intercept formula to find the equation for the line. y mx b 10.0 0.3425 b 10.0 8.5 b b 10.0 8.5 1.5 V 0.34T 1.5 e. Using the equation, what will the volume be at 95oC? V 0.3495 1.5 32.3 1.5 33.8mL 3. Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 93.4 0.34T 1.5 91.9 0.34T 270 o C T 4. Rate of Decay for 238U at certain temperatures Water Temperature Fluctuations - 1991 Month f. Using the equation, at what temperature would the volume be 93.4 mL? Temperature ( oC ) 3.8 0.9 1.1 2.5 5.2 10.1 15.5 19.0 18.5 15.5 9.2 5.8 Time (min) 1 2 3 4 5 6 7 8 9 a. When is the peak month for swimming? AUGUST Number of Atoms 256 128 85 64 51 43 37 32 28 a. Is this a linear relationship? NO b. Does this lake freeze over? Explain. NO. The temperature never goes below zero c. Is this a linear relationship? If not, is there still a predictable pattern? NO. Yes, there is a general pattern to the data b. Is it directly or inversely proportional (or neither)?INVERSELY PROPORTIONAL c. Write an equation that fits this relationship, including a proportionality constant (k) xy=k (t)(Atoms)=256 d. How many atoms will be remaining after 2.5 minutes? (2.5 min)(A)=256 A = 102 atoms UNIT I - Safety & The Tools of Science 13 UNIT I - Safety & The Tools of Science 14 UNIT I - Safety & The Tools of Science 15 IX. The Scientific Method - “The great tragedy of science--the slaying of a beautiful hypothesis by an ugly fact.” - Thomas Henry Huxley A. Definitions 1. Pure Science - science for its own sake * Einstein – discovered Theory of Relativity (E=mc2) which shows a relationship between Energy and mass i.e. mass can be converted into energy 2. Applied Science – science with practical application for society * Oppenheimer – using the Theory of Relativity, found that samples of Plutonium performed a fission chain reaction in which the mass of the nuclei was changed into energy; if the reaction was contained in a rigid steel casing, it could be used as a bomb 3. Technology – the products of applied science 4. Chemistry – the study of matter and energy B. Scientific Method: five steps - uses controlled experimentation 1) Stating a problem 2) Researching the nature of the problem - assign variables (remember to determine independent and dependent variables) 3) Forming a hypothesis (educated guess) * phrased: “As the [independent variable] increases, the [dependent variable] _______” 4) Designing an experiment 5) Collecting data (a series of measurements; requires units ( oC, m, mL, etc.) 6) Using data to decide validity of hypothesis - forming a theory (hypothesis shown to be true over repeated experiments) * law – an indisputable fact shown in experiment - example: “Newton’s Second Law: Force equals mass times acceleration (F = ma)” C. Accuracy vs. Precision 1. Accuracy – how close a measurement is to the actual value 2. Precision – the reproducibility of a measurement * Describe the following measurements: Actual Value: 3.532 m Trial 1 3.539m Trial 2 3.530m Trial 3 3.529m Accurate and precise Actual Value: 3.532 m Trial 1 4.192m Trial 2 0.035m Trial 3 10.112m Neither accurate nor precise Actual Value: 3.532 m Trial 1 4.523m Trial 2 4.520m Trial 3 4.529m Precise, but not accurate (perhaps the measuring tool is flawed) * Why is it not possible to be accurate but not precise with measurements? measurements can’t all be close to an accepted value, but be different from each other UNIT I - Safety & The Tools of Science 16 D. Observation vs. Inference 1. Observation – something seen, heard, etc. – indisputable * types of observations: qualitative (no measurement), quantitative(measurement) 2. Inference – an attempt to explain the cause of an observation; can be disputed. S. Label the following as inference(I), qualitative observation(QLO), or quantitative observation(QNO) I 1. From his scratching, that dog must have fleas. QNO QLO 3. The food smelled like sulfur. I 5. She is crying, so she must be hungry. QLO 7. The box is heavier than me. QLO 9. The fish had blue-green gills. I 11. Since the street is wet, it must have rained. I QNO I QLO 2. The fish weighed 1.75 pounds. 4. The food must have rotted. 6. The hat’s size is 7 3/4. 8. The box must be full of bricks. 10. The street is wet. ???? 12. “Boy is it hot! It must be 95o out!” E. Pre-Lab Observations 1. Observe a sugar cube dissolving in water. Note all the conditions under which this happened. * these are called variables. 2. Choose one variable whose effect you will test on the dissolving time of a sugar cube. a. Which one is the dependent variable? ____________________________ b. Which one is the independent variable? __________________________ 3. Design an experiment which will test this relationship. Make sure to do the following: a. Devise a hypothesis “As the (ind. var.) (increases/decreases), the (dep. var.) (increases/decreases) b. List any equipment needed to perform the experiment c. Devise a detailed, step-by-step procedure you will follow. d. Set up a data table that you will fill in when you do the experiment. UNIT I - Safety & The Tools of Science 17 X. Systeme’ Internationale (SI system) – developed and adopted in 1960; has seven base units; five are shown on table below (Ampere and Candela aren’t used in Chemistry) A. Metric System - Metric System devised in 1798 in Paris, FRA - Metric System Treaty (1875) – adopted by all industrialized nations (inc. USA) * by 1900, only British Commonwealth and USA didn’t use metric * late 1960’s, early 1970’s, Commonwealth adopts - Metric Conversion Act (1975) – USA will be under complete metric system by 1985 - Other non-metric countries (only 2)? B. Units used - SI Base Units; adding a prefix modifies the unit * How long is a meter (m)? centimeter (cm)? Unit kilometer (km)? Abbreviation Quantity meter gram second mole Kelvin m g s mol K length mass time number of items temperature C. Dimensional Analysis - a system used to solve any problem requiring proportional reasoning * requires a known value and an equivalency * example: I know 1m = 1000mm. How many meters are equivalent to 2430mm? 1. Write down the known value. 2. Set up your conversion factor. 3. Match units on the bottom of the conversion factor with the known value. 4. Put the units desired on the top. 5. Place the known equivalency into the conversion factor. 6. Simplify. 2430mm 2430mm x _________ 2430mm x _________ mm 2430mm x m mm 2430mm x 1 m 1000 mm 2430 mm x 1 m = 2.43 m 1000 mm T. 1) 3.54 x 106 nm = ? m 2) 4500 kg = ? mg 10 6 mg 4500kg 4.5 x10 9 mg 1kg 1m 3.54 x10 nm 9 0.00354m 10 nm 6 *When using the scale of metric prefixes on p. 18, the larger unit (higher up on the scale) gets a “1” next to it, regardless of whether it’s on the top or bottom of the conversion factor. The smaller unit gets a power of 10 that corresponds to the number of steps from the larger to smaller unit. In T #1, the 10 9 was on the bottom, so we divided by that number, in T#2, the 106 is on the top, so we multiply by that number. 3) Given: 1km = 0.6214mi 4) Given: $1.00 = 4.87 tuttles and 1 tuttle = 15 crowns How many kilometers is it from Holland to If you travel to Tuttleland with $150 in your Detroit? (186 miles) pocket, how many crowns can you get? 186mi 1km 299km 0.6214mi $150 4.87Tuttles 15crowns 10,957.5Crowns $1 1Tuttle *When given a conversion factor directly, as in #3 and #4 above, simply copy the numbers into their appropriate places on the conversion factor UNIT I - Safety & The Tools of Science 18 Giga- (G-) Mega- (M-) kilo- (k-) DEFINITIONS 1 ton = 2000 lbs 16 oz = 1 lb 1 gal = 4 qts 1 foot = 12 in APPROXIMATIONS 1 inch = 2.54 cm 1 liter = 1.06 qts 1 km = 0.6214 mi 1 kg = 2.2046 lbs (base) deci- (d-) centi- (c-) milli- (m-) micro- (u-) nano- (n-) pico- (p-) S. Complete the following conversions. 2) 3.71 x 10-11 km = ? nm 1) 78.0cm = ? um 78.0cm 10 4 um 78 ,000um 1cm 3.71x10 11 km 3) 450g = ? kg 450 g 4) 65.1 ms = ? s 1kg 0.45kg 10 3 g 65.1ms 3 10 mg 30 0mg 1g 3.54 x10 7 um 7) 5.66 inches = ? cm 5.66in 1s 0.0651s 10 3 ms 6) 3.45 x 107 um = ? km 5) 3.00g = ? mg 3.00 g 1012 nm 37.1nm 1km 1km 0.0345km 10 9 um 8) 355 mL = ? qts 2.54cm 14.4cm 1in 355mL 1L 1.06qts 0.376qts 3 1L 10 mL D. Combined Units - treated in many ways like variables in algebra * we’ll use rectangular stuff for simplicity 2.61 cm 1.1 cm 3.3 cm 3.55 cm 2.1 cm A = lw = (3.55cm)(2.61cm) = 9.27cm2 NOTE: 1 L = 1 dm3 V = lwh = (1.1cm)(2.1cm)(3.3cm) = 7.6 cm3 1 mL = 1 cm3