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KNOW

Polyatomic Ions:

Acetate

Bicarbonate

Carbonate

Hydroxide

Hyperchlorite

Nitrate

Nitrite

Phosphate

Sulfate

Sulfite

Ammonium

C

2

H

3

O

2

-

HCO

3

-

Soluble

CO

3

2-

OH - The strongest base of all

OCl -

NO

3

-

NO

2

-

Soluble

PO

4

3-

SO

4

2-

SO

3

2-

NH

3

+

( H

3

0 +

is the strongest acid of all) (hydronium ion)

SOLUBLE:

All sodium (Na), potassium (K) and ammonium (NH

4

+

) compounds are soluble.

All nitrates are soluble (ex: NH

4

NO

3

– ammonium nitrate, used in fertilizer).

Most chlorides are soluble (except silver (Ag), mercury (Hg) and lead (Pb) chlorides)

Most sulfates are soluble (except strontium (Sr), barium (Ba) and lead (Pb) sulfate)

(ex: of soluble sulfate: Na

2

SO

4

- Sodium sulfate)

---------

INSOLUBLE:

Most carbonates are IN soluble (except those with Group 1A or NH

4

+

cations)

(Group 1A: Li, Na, K, Rb, Cs, Fr)

Most hydroxides and oxides are IN soluble (except those with Group 1A or NH

4

+

cations)

Most sulfides are IN soluble (except those with Group 1A or NH

4

+

cations)

(ex of insoluble sulfide: HgS – mercury sulfide)

1

STRONG ACIDS

HClO

4

H

2

SO

4

HI

HBr

HCl

HNO

3

From Group 7

ALWAYS

: A polyatomic ion with an “ H + ” will create an acid –

The H

+

will replace the “ - “ (negative sign for “ion”).

ALWAYS :

Group 1 A with a hydroxide ( OH ) will create a strong base

ALWAYS :

Strong base in the equation will always make the equation DOUBLE REPLACEMENT

ALWAYS :

Strong base with any acid will always create a WATER and SALT

Ex:

* HC

2

H

3

O

2

+ NaOH -----

H

2

O + NaC

2

H

3

O

2

(HC

2

H

3

O

2

is acetate with an “H”, creating Acetic acid)

2

Compound

Hydrochloric acid

Phosphorous acid

Phosphoric Acid

Hydrofluoric acid

Hydroselenic acid

Acetic acid

Formula

HCl

H

3

PO

3

H

3

PO

4

HF

H

2

Se

CH

3

COOH

H

2

CO

3

H

2

S

Relative Strength

STRONG ACID

Carbonic acid

Hydrosulfuric acid

Hypochlorite ion

Cyanide ion

Ammonia

Carbonate ion

Aluminum hydroxide

Phosphate ion

Silicate ion

Hydroxide ion

ClO -

CN

-

NH

3

CO

3

2-

Al(OH)

3

PO

43-

SiO

3

2-

OH -

Weak acid

Neutral solution

Weak base

STRONG BASE

STRONG BASES:

All the hydroxides of Group 1A: LiOH, NaOH, KOH, RbOH and CsOH are strong bases

The alkaline earth (Group 2A) hydroxides: Ca(OH)

2

, Ba(OH)

2

and Sr(OH)

2

are also strong bases.

From notes:

STRONG BASES (contain OH):

LiOH

NaOH

From Group 1A

KOH

Sr(OH)

2

Ca(OH)

2

Ba(OH)

2

From Group 2A

3

KNOW:

Deuterium

2 2

H aka:

1 1 d and

Tritium

3 3

H aka: t

1 1

NUCLEAR BELT OF STABILITY

Above the belt : TOO MANY NEUTRONS - beta emission

Below the belt : NOT ENOUGH NEUTRONS – positron emission

(either by spontaneous positron emission or by electron capture followed by positron emission, but either way, a positron comes flyin out)

THE RULES:

1.

Not enough neutrons : POSITRON emission through electron capture and then positron ( B

+

) emission or through spontaneous positron emission)

2.

Too many neutrons : Neutron is converted into a proton and the leftover Beta

(B ) particle is kicked out

3.

Atomic weight over 83

: Use the helium nuclei “equation” to kick out an alpha particle (positively charged)

FISSION: LESS MASS IN PRODUCT (“Mass Defect”)

What nuclear power plants there are in U.S. are fission.

Europe’s are breeder reactors.

4

[H

+

] of .1 M? pH is 1 pOH is 13

[OH-] is 10 -3

.001 M of NaOH

[OH-] is .001

.001 M Ba(OH)

2

[OH-] is .002 (because there’s 2x of OH)

[OH-] = .001 or 1 x 10

-3 pOH = 5 pH = 11

[H

+

] = 10

-11

[OH

-

] = .002 pOH = 2.7 pH = 11.3

[H + ] = 10 -11.3

and, the inverse log of (-11.3) is 5.01 X 10

-12

5

Strong electrolytes: Strong acids, strong bases and soluble ionic compounds

Weak electrolytes: Weak acids, weak bases

Non electrolytes: Covalent compounds or insoluble ionic compounds

Neutralization reaction example:

Question:

Al(OH)

3

+ HNO

2

----

H

2

0 + Al(NO

2

)

Answer:

Al(OH)

3

+ 3 HNO

2

--

3H

2

0 + Al(NO

2

)

3

Hydroxide with metals: ALWAYS FORMS BASES

ALL COVALENT Compounds with NITROGEN or PHOSPHOROUS are WEAK BASES

When strong acids & bases are all on the reactant side, use TWO arrows

KNOW:

Causes of acid rain (sulfur oxides & nitrogen oxides)

Where these come from (sulfur oxides are from coal-burning power plants and coalburning industries) – (nitrogen oxides are from transportation)

Normal pH of rain: 5.6

Limestone (statue) / acid rain equation:

CaCO

3

+ H

2

SO

4

---

CaSO

4

+ H

2

CO

3

H

2

CO

3

is further broken down (it’s carbonic acid)

Into: H

2

O + CO

2

6

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