Significant Digits in Measurement of Matter PRELAB DISCUSSION Measurements are an important part of science; they are all a part of quantifying matter so that we can have a better understanding of the world. It is very important to be able to describe matter in a quantitative, or measurable, sense. No measured quantity can ever be exact; there will always be some uncertainty associated with it. The degree of certainty in a measurement is reflected in the number of significant digits contained in it. The significant digits in a measurement contain all of the certain digits – those of which we can be sure- and one uncertain digit. Just where the uncertainty lies depends on the instrument being used. Measuring instruments that have smaller divisions (Ex: mm instead of cm) allow greater certainty in measurement. PURPOSE To familiarize yourself with common laboratory measuring instruments for length, mass, and volume, and to learn about uncertainties in measurement. To express measurements and calculations using the proper number of significant digits. To indicate the accuracy in measurements by calculating percent error. MATERIALS balance calculator graduated cylinder, 10mL water metric ruler pennies test tube PROCEDURE 1. Measure the thickness of one penny, being certain to include one estimated number in your measurement. (Record: 1a) 2. Repeat step 1 for stacks of pennies containing 4, 7, and 10 pennies; be sure to obtain as many significant digits as are allowed for your ruler. (Record: 1b-d) As you measure the pennies, note if there is any observable variation in the thickness of each. 3. Carefully measure the length and width of the cover of your chemistry book in units of centimeters. The first time, measure it as if there were no millimeter markings on the ruler; that is estimate the tenths place in the measurement. (Record: 2 a-b) The second time, use the millimeter markings to estimate the hundredths place. (Record: 2 c-d) 4. Using the lab balance, find the individual masses of 5 of your pennies. Select pennies that have a variety of dates- some newer and some older. Use significant digits properly in your recorded values. (Record: 3) Do you notice any difference in the mass of a penny relative to the year it was minted? 5. Fill a test tube to the brim with water and carefully transfer all of it to your graduated cylinder. Using just your eye, measure the volume of water that the test tube contained. Be sure to include one estimated number in your measurement. (Record: 4a) Repeat this measurement of the volume of the same test tube two more times, being careful to fill the test tube to the brim each time. (Record: 4 bc) DATA 1. Number of pennies in a stack 1 Measured thickness (a)________ cm (b)_________ cm 7 10 (c)________ cm (d)_________ cm Number of pennies in a stack Measured thickness 2. nearest tenth 4 nearest hundredth Length of book (a)_________ cm (c)__________ cm Width of book (b)_________ cm (d)__________ cm 3. Mass of penny Year of penny ________g ________g ________g ________g ________g ________ _________ _________ ________ _________ 4. Volume of water (a) _______mL (b) _________ mL (c) ________mL CONCLUSION AND QUESTIONS. 1. Calculate the average thickness of one penny for each set of pennies, using significant digits properly. Number of pennies Average thickness 1 _______cm 4 ________cm 7 10 ________cm ________cm 2. Which of these numbers is the most representative for the average thickness of a penny? Explain. 3. Assume the true thickness of a penny is 1.4mm. Calculate % error using your most accurate average. 3. Calculate the area of the cover of your chemistry book (length x width) ; then calculate its perimeter (length + length + width + width). Record both the unrounded value and the value with the proper number of significant digits. Unrounded Using Significant Digits Area, using 2a-b _______ cm2 _________ cm2 Area, using 2c-d _______cm2 _________ cm2 Perimeter, using 2a-b _______ cm _________ cm Perimeter, using 2c-d _______ cm _________ cm 4. Which set of calculated quantities is closer to the actual, exact area and perimeterthose using 2a and 2b, or those using 2c and 2d? Explain. 5. In what decimal place was there uncertainty in the masses of the pennies? 6. Did you notice any age-related mass difference in the pennies? If so, what was it? 7. Calculate the average mass of a penny, expressing it with the proper number of significant digits. Is it possible for your average to be significantly different from that obtained by another group in your class? Explain. Average mass of a penny________ g 8. Calculate the average volume of water contained in your test tube. Average volume ____________ mL 9. In what decimal place is the uncertainty (precision) in your measurement of the water? 10. Do you think the average of three trials gives a more reliable (more accurate) value for the volume of the test tube than a single measurement? Why or why not?