The Department of Chemistry Times An Electronic Newsletter of the Department of Chemistry State University of New York College at Brockport Volume 2, No. 5 Brockport, NY 14420 October 2003 inviting, and “fun” way. Some of the computational “tools” are designed to allow students to explore in “real-time” how changing variables affect the outcome of a problem. Other “tools” give students the flexibility to design their own models to solve problems. CMST Institute Opens for Business at SUNY Brockport By Mark P. Heitz Professor Mark P. Heitz worked this past summer with Professor Osman Yasar, Chairman of SUNY Brockport’s Department of Computational Science, and representatives of the Departments of Biological Sciences, Computer Science, Computational Science, Earth Science, Mathematics, and Physics on the first year of a five-year project to infuse computational science into the mathematics, science and technology curricula of local secondary schools (grades 7-12). A four-week long summer workshop, which took place during July 2003, trained 56 teachers from the Brighton and Rochester City School Districts in the use of several software packages that can be used to augment classroom lessons. The modules introduced in these workshops included training in Project Interactivate, Texas Instruments Graphing Calculators, Microsoft Excel, Agentsheets, Stella, and Interactive Physics. Each of these “tools” can be used by teachers to provide students with discoverylearning techniques to investigate math and science concepts. This project, dubbed the CMST Institute (CMST = Computational Math, Science and Technology), began operations this summer under a five-year, $3.4 million NSF grant awarded to Professor Yasar and co-PI’s from the Departments of Biological Sciences, Chemistry Computer Science, Education and Human Development, Mathematics and Physics. Under the terms of this grant, partnerships between the Rochester and Brighton school districts, local industries, and SUNY Brockport are to be developed to help secondary school students and their teachers build a strong sense of the interconnected nature of math and science. The central idea on which the project is based is that using computers to solve problems in the sciences will stimulate student curiosity in both math and science. More recently, Prof. Heitz developed a new collaboration between SUNY Brockport’s CMST Institute, the Corning School District and scientists from Corning Glass, Inc to implement regional training of teachers. The first of a series of workshops for Corning teachers was completed in October 2003. Monthly meetings will continue during the academic year to introduce teachers to new modules. These efforts will also foster and strengthen the partnerships between the teachers, schools, and local industry. Using the power of computers and computer simulations students will explore science and math concepts and problems in a new, Finley Publishes in JOC With Undergraduate Co-authors By Thomas W. Kallen 1 letting me use his "baby;" as I recall that he wouldn't let the organic chemists anywhere near it. Do I now hold a chemistry department record for the length of time from when a student worked on a research project to publication?!?!” In June of this year, Professor K. Thomas Finley published an article entitled “Regiospecificity in the Synthesis of Diaryl Sulfones” in the Journal of Organic Chemistry having three former SUNY Brockport undergraduates, as well as Professor Kenneth D. Schlecht, as co-authors (D. E. Allgier, S. A. Herbert, R. Nee, K. D. Schlecht and K. T. Finley, J. Org. Chem., 2003 (vol 68, No 12), 4988-4990). While publication by Professor Finley is not unusual, the time span over which the title study was conducted must be considered to be highly unusual. This work is published as a three-page “note” in the Journal of Organic Chemistry. “Notes are concise accounts of studies on a more limited scope” than articles. However, they go through the same peer review process as articles; and JOC is the premier journal in the area of organic synthesis. Daniel Allgier (‘72), who did most of the original synthetic work, began this study in the early 1970’s as an Independent Study project under Professor Finley. Rory Nee (‘76), one of Professor Kenneth D. Schlecht’s research students continued the study in the mid-70’s, obtaining 60 MHz NMR spectra and assigning peaks to the various isomers produced by Allgier. Sue Ann Herbert (‘98) picked up the study as a summer research project in the mid-90’s, collected 300 MHz NMR spectra and defined isomeric abundance as a function of the pH at which the synthesis was conducted. JOC is now Web-published as well to give researchers faster access to information contained therein. This note was Webpublished May 10, 2003 and published in hard-copy format in June 2003. The Times congratulates all who contributed to the completion of this paper! Chemistry Club Earns Honors By Thomas W. Kallen The Chair of the Department of Chemistry has been notified the President of the American Chemical Society that the Chemistry Club, a Student Affiliates chapter of the American Chemical Society, had been selected to receive a “Commendable” award for its chapter activities during the 2002-2003 academic year. The award winning chapters will be honored at the 227th ACS National Meeting in Anaheim, CA, on Sunday, March 28, 2004. They were also recognized in C & E News and in Chemistry, the student affiliates’ newsletter. Through all of this, Professor Finley has been unbelievably persistent in directing this project, putting the finishing touches on the work, and fighting the inevitable battles with referees. His co-authors owe a great deal to his determination and drive to get this work published in a “quality journal!”. E-mail from Rory Nee perhaps sets the proper context for this publication. Rory writes,” Dear Dr. Finley, What a wonderful surprise to get your letter and the JOC reprints! I very much appreciate your kind words and for sharing the authorship. I learned much about research from Drs. Bixler, Schlecht and yourself. As I recall, Dr. S. and I had that old NMR (I suspect it is now either in a museum or at the bottom of Lake Ontario) so finely tuned that it was literally "smoking" (from the low temp. liquid N2 sample probe)!! I still appreciate the confidence that Dr. S. showed in me by Last year’s Club officers who planned and carried out the activities recognized by the ACS, were: Amanda Sturdevant (’03), President; Jason Tubbs, Vice President; Andrea Topolnycky (’03), Treasurer, and Beth Mastin, Secretary. The President of the American Chemical Society extended “his warmest congratulations to the students…for setting such a fine example for other chapters.” 2 Professor Markus Hoffmann, Faculty Advisor of the Chemistry Club, also received special mention from the President of ACS who wrote, “Few faculty members are willing to make the great commitment of time and energy that a successful chapter requires of its advisors. It takes more than exceptional effort to be an award-winning chapter; it takes the nurturing attention of dedicated advisors. Professor Hoffmann’s efforts certainly represent the best in undergraduate science education and mentoring around the country.” on the “Solvation Properties of a Room Temperature Ionic Liquid;” and Penna (Professor Margaret E. Logan, research mentor) presented her research on “The Antioxidant Properties of Novel Diaryl Tellurides in a Linoleic Acid Free Radical System”. Bennett, (Professor Markus M. Hoffman, research mentor), delivered an oral presentation entitled “Surfactant Research Utilizing Hydrogen Nuclear Magnetic Resonance”. Of the 950 student affiliate chapters in the United States and Puerto Rico, 29 were honored as being “outstanding,” 52 were honored as being “commendable,” and 77 received “honorable mention.” Last year’s President of the Chemistry Club, Amanda Sturdevant, set the goal to “move up a notch.” They certainly did! This year’s President, Jason Tubbs, reports that their goal remains essentially the same, to “move up another notch to ‘outstanding!” Above: pictured from left to right, Jim Hutchings, Megan Bennett, Kristina Fuller and Alicia Penna, 5th Annual Robert Laudise Symposium presenters. This year’s officers, in addition to Tubbs, are Ashley Campanali, Vice President, Kristina Fuller, Treasurer, and JoAnn Viterna, Secretary. According to Professor Heitz, all of the student presentations were well received by the attendees at the symposium. Four Chemistry Students Present Papers at the 5th Annual Robert Laudise Undergraduate Research Symposium Hutchings’ research was funded last summer by Professor Hoffmann’s Camille and Henry Dreyfus Foundation grant, while Bennett’s research was funded by a summer research grant from Rochester Midland Corporation. By Mark P. Heitz On Saturday, October 11, Jim Hutchings, Megan Bennett, Kristina Fuller and Alicia Penna traveled to Union college, in Schenectady, NY, with Professor Mark P. Heitz to present papers at the 5th annual Robert Laudise Undergraduate Research Symposium. Fuller, recipient of the Morris Fellowship for Undergraduate Research in Chemistry, received support for her 2003 summer research from the Brockport Foundation. Penna, recipient of the Chemistry Alumni Fellowship for Undergraduate Research in Chemistry, received support for her summer 2003 research from the Brockport Foundation, the Bixler Fund, and the Rochester Midland Corporation. Hutchings, Fuller and Penna presented poster papers: Hutchings (Professor Markus M. Hoffman, research mentor) reported new results on the “Phase Behavior of Ionic Liquids in CO2;” Fuller (Professor Mark P. Heitz, research mentor) presented a poster 3 MMEP program began her project on health disparities and disease in Haiti. With Yale Medical School funding, students have the opportunity to research anywhere in the world, given an excellent proposal. Yale also offers undergraduate and post-baccalaureate students opportunities to embark on summer research internships. Specifically, the BIOSTEP program is designed for underrepresented students with some or no research experience to take part in a molecular biology and biophysics project. Another program that Yale offers is a postbaccalaureate program. This program allows students to take free graduate biology courses for credit, and work with a mentor on a research project. This program is geared for students who wish to enter an MD, PhD, or an MD/PhD program. Above: Poster Session at the 5th Annual Robert Laudise Undergraduate Research Symposium at Union College Chemistry Student Participates in Yale University Minority Medical Education Program Yale Medical School has the no grade system for the first two years of medical school. The tests are optional and are confidential. The students are given a yearly evaluation, and that would constitute as somewhat of a "grade". The requirement, however, is successful completion of the USMLE Step 1 before entering the clinical phase of the curriculum, which is at the end of the second year. Other medical schools have letter grading, or passfail systems, and some do not even require successful completion of the USMLE Steps 1, 2, or 3 to receive the medical degree; future doctors need these steps for certification as a physician though.. The didactic education consists of lectures and group problem based scenarios. For the most part, the classes at MMEP were problem-based learning. By Luis Labrador-MMEP Program One of the greatest blessings that I have ever received was the opportunity to participate in the Minority Medical Education Program at Yale Medical School. This experience allowed me to essentially be a graduate student for the summer and learn about different career pathways in the biomedical field. Specifically, MMEP consisted of biomedical lecture series, an in depth MCAT preparation, writing and communications classes, an up close and personal participation in an autopsy, clinical applied basic sciences scenarios, a financial planning workshop, medical ethics lectures, biomedical lectures, an introduction to public health and epidemiolgy, interviews with members of the medical college admissions committee, and a series of mock medical school interviews. Enrichment programs such as MMEP allow undergraduate and post baccalaureate students the opportunity to explore the different career pathways in the biomedical field. It provides good preparation for what is to come in these graduate programs and the careers that follow, and it enables the participants to look at alternatives that may not have been considered previously. MMEP fortified my decision to pursue a career in medicine; for others it allowed them to research and pursue other careers within the biomedical field. Those who are interested in Yale University is in the top ten colleges known for its research. A requirement upon graduation from the medical school, epidemiolgy and public health, and other of its graduate programs involves an in depth research project and thesis. Most of the medical students do their research during the summer after the end of the first year of medical school. One particular medical student who was a teaching assistant for the 4 graduate school, especially within the biomedical field, should seriously consider an enrichment program; it provides insight in the decision making of the graduate program and career. “Hi Everyone, Phonesada and I have wonderful news to share. On Sunday, Oct. 12, at 5:32 PM, Pallas Brenna Hoffmann was born at Strong Memorial Hospital. Pallas’ birth weight was 6 lbs and 7 oz and she measured 19-1/4 inches long. Phonesada and Pallas both came home yesterday (October 14th) and we spent the first night together as a family at home. God is good. Markus” Editor’s Note: Luis is a Biological Sciences major, Chemistry minor and member of the SUNY Brockport’s CSTEP program. His CSTEP mentor is Professor Margaret E. Logan of the Department of Chemistry, a member of the College’s Premedical Advisory Committee. Luis participated in Yale University’s Minority Medical Education Program during the past summer. Alumni News By Thomas W. Kallen Rory Nee (’76) who married fellow chemistry major, Polly Ann Wells (’76), recently “bumped into” our Web site; and, after reading the back issues of The Department of Chemistry Times, sent the following email message, reproduced in its entirety following consultation with our lawyers. It’s A Girl! By Thomas W. Kallen It has been such a long time since a child was born to a faculty member in our department that the Times just could not pass-up the opportunity to announce formally the birth of “Hi KDS & TWK! During some recent net surfing I went to the SUNY Brockport Chem. Dept. web site and had a great time reading the issues of the Newsletter that are posted there. It was good to hear that you guys are still doing a great job preparing young folks for futures in science/chemistry. It seems like you have some very outstanding students to keep you motivated. I was particularly impressed with KDS's "Road Show" work with bringing chemistry to young kids in a fun way, and that the Chemistry Club has been very active. It was also great to read some of the alumni news of the "old folks" from back in the early/mid-70's. (If you want to really get depressed, I'll tell you that Polly and I are now knocking at the door of 50!) An update on us.... We live in Kalamazoo, MI, and I have now been at Pfizer (formerly Pharmacia, formerly Upjohn) nearly 25 years, working as a QA Specialist. You would probably be a wee bit disappointed that I have been "out of the lab" for a long time, solidly entrenched as a "bureaucrat," but there are many things that need to be done to bring you guys the high quality Lipitor, Viagra, Zoloft, Detrol, Rogaine and Kaopectate that you probably now need at your age; and it does a Above: the proud father, Markus, and his infant daughter, Pallas Brenna Hoffman. a baby girl to Markus and Phonesada Hoffmann! So, here it is, is Professor Markus M. Hoffmann’s own words: 5 great job with paying the bills for the high priced college educations of our kids. the first drop of oil on Schlecht's virgin garage floor of the newly built Hex House (I needed to change the oil in my car before we drove to Cleveland for the Pittsburgh Conference), watching the Celtics on Eiler's color TV, babysitting 1 year old Kendra Schlecht., home-made ice cream and wine coolers at Bixler's house, Frank Melia (chemistry major and weightlifter) lifting Schlecht over his head at a party in my apartment., Bill Stevens passing out in the closet of my apartment (same party), my all-time worst Brockport memory - losing to Mancuso in a 1 on 1 basketball game (I intend to stop by someday for a rematch. I heard he had some hip replacements, so I may have a chance), and my all-time best Brockport memory – meeting Polly (in a chem. lab; little did Schlecht know what he would start when he made Gen. Chem. Lab Assistant assignments that year).... and the list could go on and on! Thanks for the memories.... Rory & Polly Nee ('76)” You would probably be a bit more proud of Polly, as she has stayed very close to lab chemistry. She is the QA Manager at KAR Laboratories, which provides analytical services in both the environmental and pharmaceutical industries. Thru a contact from a previous job, they lured her away from Pharmacia about four years ago. She keeps the labs honest, making sure that all their methods are properly validated and executed so that only good data goes out the door. We have both had great careers, and are also thankful to you guys (and your past Smith Hall compatriots) for the part that you played in preparing us for it. We have two daughters, who were both adopted from South Korea as infants, who I think you guys have met when we stopped by a few years ago. Carmen (20) is a junior at Hope College (Holland, MI) doing a double major in Psychology and Kinesiology and is a "flyer" on the cheerleading squad (this is the kind of thing that makes you very grateful for good medical insurance). She is looking into grad schools in Psychology. Krista (18) is starting her freshman year in the Honors Program in Medicine at Northwestern Univ. She had to be interviewed and pre-accepted at the NU Medical School, and will spend 3 years at the campus in Evanston, IL (will get a degree in Chemistry!) and then moves to the med. school in downtown Chicago (only 1 block from the high-priced "Magnificent Mile" shopping district). We are very proud of both of them. We are also accepting donations. We are considering having our paychecks sent directly to Hope and Northwestern and letting them send us a small allowance to live on. All this editor can say to Rory is, “thanks for reminding us, the elderly, of all those “memories!” KDS doesn’t even remember being “pressed,” or was it “cleaned and jerked,” by Frank Melia! Lisa Stevens (’00) gave birth to twin boys on August 28th. Lisa writes, “Hello Everyone: Wanted to let you all know that the boys have arrived. Andrew Keith Pace Stephens was born at 11:59 am weighing 6 lbs 8 oz and Philip Timothy Pace Stephens was born at 12:01 pm weighing 4 lbs 2 oz -- on Aug. 28. Andrew and Lisa got to come home yesterday (Monday) but Philip had to stay in the special care nursery to grow a little. By God's grace who should be able to join us at home tomorrow. Thanks to all for your thoughts and prayers throughout my pregnancy. Take care, Lisa.” Michael Nicholson (’01), now a a thirdyear graduate student in Biochemistry at Johns Hopkins University in Baltimore MD, writes, “I am writing to share some We hope that all is well with you, your families, and the rest of the current and past "Smith Hall Gang." We have many fond memories…the "punch bowl" at the Dept. Christmas parties, "re-convening" at a local "establishment" after the Monday night research project seminars/meetings, spilling good new with you - my son, Graham Thomas was born on August 24. He was and is a very healthy baby (8 lbs 14 oz, 22 inches) and is growing like crazy - pretty soon he'll be 6 able to help his Dad out in lab. Sara is doing well, and is pleased to find that the little guy sleeps enough during the day that she has been able to get some work done on her dissertation. “The VOC's are easily detected by GC and all the instruments have auto samplers including the HPLC and ICP.” “This fall I am taking Fluid Flow in Environmental Systems, Contaminant Subsurface Hydrology, & Soil Physics. Next semester I hope to take Environmental Organic Chemistry, Pollution Prevention & Control, and Wetland Hydrology or the Bio/Geochemistry of Trace Metals.” In other news, I passed my qualifying exams this past spring and I'm gearing up for my first Thesis committee meeting. I've also started writing my first paper - we hope to have it submitted by the New Year. I hope all is well with you all, and please forward this to anyone I unintentionally left out.” “My advisor is great and his “post doc” is extremely helpful. I am playing Flag Football on the departmental intramural team (both faculty and students) and hope to tryout for the UF Roller Hockey Club team in October, time permitting.” Gordon Brown (’03), now a first-year graduate student in Environmental Engineering at the University of Florida in Gainesville, writes “Hi there Profs, from down here in sunny and hot (Yikes!) Florida. So far I have made a very smooth transition into my graduate work at the Environmental Engineering Sciences department at UF.” “Beka is doing very well in her job at Shand's Hospital. She passed her Nursing boards, so she is working as an RN on a medical/surgical floor. It’s the premier hospital in the state, much like Strong Hospital in Rochester. They even cancelled her last 2 weeks of training because she impressed them so much.” “Dr. Annable, my research advisor, and I have decided that I should evaluate the effectiveness of “surfactant (SDBS) enhanced air sparging of DNAPL's.” Much to my liking, the work will incorporate both lab experiments and lots of fieldwork. This year will be mostly lab work with some trips to field sites in Seattle (TCE at Air Force Base) and Jacksonville (TCE & PCE at the site of a dry cleaner).” “We rented a house in the northwest side of town with a fenced yard for our dogs, but they don't go outside for long because it’s too humid. Winters are supposed to be milder. Now it rains ever day, for 20-30 minutes in the afternoon.” “Next summer I will be in Waterloo, Canada monitoring the surfactant air sparging remediation of a TCE/PCE release at Borden CFB. We will be measuring both groundwater and contaminant mass flux before and after remediation to evaluate the effectiveness. Does 75% mass removal decrease contaminant mass flux into groundwater? It is pretty exciting stuff for me. The work is a part of a three-part grant from the EPA to study the effectiveness of three remediation techniques, with the U of Arkansas and the U of Texas involved with the modeling and vapor remediation technique. The PhD I'm under is evaluating mass flux of DNAPL co-solvent flushing with ethanol.” “We are going to our first “Gators” football game Saturday against San Jose State. It's definitely the talk of the town.” “Anyway, that's a quick summary for now. Feel free to pass this on or contact me anytime. Hope you all had a productive summer and have a great fall semester. Even though we are both making new friends and settling in down here, we do miss you all and Upstate NY. Gordon.” Jason Carr (’03), who is now a graduate student at the SUNY at Buffalo, writes, “Greetings and salutations!! I hope the fall semester has been pleasant so far. I just 7 thought I'd drop a line or three to let you know how life's been treating me. The Department of Chemistry Times is posted on the Department of Chemistry Web site at irregular intervals by Professor, Chairman and Editor Dr. Thomas W. Kallen, Department of Chemistry, SUNY College at Brockport, 350 New Campus Drive, Brockport NY 14420-2971. You may visit the Department of Chemistry Web site at www.brockport.edu/~chemistry/. E-mail messages to the Times should be addressed to Professor Kallen at tkallen@brockport.edu. My first couple of weeks at UB have been quite nice... I did well enough in the battery (more like battering...) of ACS exams that I had the pick of the litter as far as what 3 classes I was to take. I'm in Analytical, Organic, and Physical (Surprise Dr. Hoffmann!!!) and God as my witness, I actually think P-Chem will be the easiest of the three! I will be conducting 2 recitations (and TA-ing the lab immediately after) each week starting with the week of the 8th. I will also have 2 office hours every week, during which I'll be the only CHE 101 (general chemistry) TA available for the 1000 (yes, that's ONE THOUSAND) students taking the course. Along with the 500 others taking CHE 107 (chem for engineers, if memory serves me well), I will be a busy little beaver. I'm also close to choosing an advisor to do my research under (if he'll have me...). He's heavy into Mass Spectrometry (which I enjoyed) and seems like he'd be easy to work with. On the personal front, Lynn is expecting in early October so I'll then have 3 rug rats, total, to deal with... I personally can't wait, but don't tell Lynn that, I'm getting mileage out of it. I also miss you all quite a bit. Keep in touch and I'll do the same. I'm giving ya'll my E-Mail address. Feel free to forward it to students considering UB, I can answer lots, if not all, of the questions they might have. Take care... Jason Carr” If you have news about yourself that you wish to have included in the “Alumni News” section of The Department of Chemistry Times, please send it by e-mail to the editor, Tom Kallen, at tkallen@brockport.edu. 8