Prof. Gabor Speier
Education:
Diploma, University of Dresden, 1966
Professional Experience:
Research Scientist: Lecturing on Basic Organic Chemistry,
Advanced Organic Chemistry, Bioinorganic Chemistry and Supervision of
Diploma and PhD works
Professional Honors:
Excellent Work Medal 1986
Excellent Inventor Gold 1987
Széchenyi Professorship 1995
Albert Szent-Györgyi Preis 2003
Master Teacher Medal 2008
With Knowledge for Hungary Medal 2001
Research Summary:
Publications:

Published Papers:
1 Speier, G.: Zur Chemie des 4,6-Diphenyl- -dithiopyrones.
Diploma Thesis 1966, Technical University Dresden
2 Speier, G.: The Activation of Small Molecules by Organometallic Complexes.
Doctoral Thesis 1968, University of Veszprém.
Veszprémi Vegyipari Egyetem Közleményei 1969, 11, 463-466
3
Faust, J.; Speier, G.; Mayer, R.: Organische Schwefelverbindungen 98. Zur
Chemie des 4,6-Diphenyl-2H-thiopyranthions-(2).
J. Prakt. Chem. 1969, 311, 61-70
4 Speier, G.; Markó, L.: Some Observation on Nitrogen and Hydrogen Complexes
of Cobalt. Preparation of Co(N2)(PPh3)3 and H2Co(PPh3)3.
Chim. Acta 1969, 3, 126-128
5
Speier, G.; Babos, B.; Markó, L.: Transition Metal Alkyls and Hydrides. IX.
The Activation of Dinitrogen and Dihydrogen by Organocobalt Catalysts (in
Hungarian).
Magy. Kém. Foly. 1970, 76, 59-62
6
Ötvös, I.; Speier, G.; Markó, L.: Chemistry of Transition Metal Nitrogen
Complexes. II. Phosphine Exchange in Nitrogen Complexes.
Acta Chim. Acad. Sci. Hung. 1970, 66, 27-28
1
7
Speier, G.; Markó, L.: Chemistry of Transition Metal Nitrogen Complexes. III.
Reduction of Tris-tertiary Phosphine Cobalt Nitrogen Complexes.
J. Organometal. Chem. 1970, 21, P46-P48
8
Kovács, J.; Speier, G.; Markó, L.: Chemistry of Transition Metal Nitrogen
Complexes. IV. Kinetics and Mechanism of Olefin Isomerisation with
Co(N2)(PPh3)3 as Catalyst.
Inorg. Chim. Acta 1970, 4, 412-414
9
Markó, L.; Speier, G.: Nitrogen Fixation under Mild Conditions,
in 'Newest Results of Chemistry ' (in Hungarian); Csákvári, B., Ed.; Akadémia
Kiadó: Budapest, 1970, Vol. 3, p.133
10 Aklan, G.; Förster, C.; Hergovich, É.; Speier, G.; Markó, L.: The Reaction of
CoL2X2-Complexes with Carbon Monoxide (in Hungarian).
Veszprémi Vegyipari Egyetem Közleményei 1971, 12, 131-138
11 Speier, G.; Ungváry, F.: Novel Method for the Preparation of
Triphenylphosphine Cobalt(I) Complexes.
Acta. Chim. Acad. Sci. Hung. 1974, 82, 25-28
12 Balogh-Hergovich, É.; Speier, G.; Markó, L.: Kinetics of the Homogeneous
Hydrogenation of Cyclohexene Catalysed by Hydridocobalt Complexes Formed
in Situ from CoH(N2)(PPh3)3.
J. Organometal. Chem. 1974, 66, 303-310
13 Speier, G.: The Preparation and Homogeneous Catalytic Activity of Tertiary
Phosphine Cobalt Complexes.
Candidate Thesis 1974, Hungarian Academy of Sciences, Budapest
14 Lappert, M. F.; Speier, G.: Binuclear Organometallic Compounds. VIII.
Oxidative Addition of S-H and Si-Cl Compounds to Low Valent Fe, Co, or Ni
Complexes Stabilised by Mono- and Bidentate Phosphines.
J. Organometal. Chem. 1974, 80, 329-339
15 Speier, G.: Oxidative Fission of the Carbon-Carbon Bond in
Ketones by Cuprous Chloride in Pyridine.
Inorg. Chim. Acta 1975, 13, L3-L4
-Hydroxy
16 Speier, G.: A Kinetic Study of Propylene Dimerization Catalysed by Cobalt
Dinitrogen Complexes.
J. Organometal. Chem. 1975, 97, 109-115
17 Speier, G.: Kinetics and Mechanism of the Dimerization of Ethylene Using
[Co(C2H4)(PPh3)3]2 as Catalyst.
Hung. J. Ind. Chem. 1975, 3, 449-458
2
18 Balogh-Hergovich, É.; Speier, G.: Oxygenation of Enamines Catalysed by a
Copper(I) Pyridine Complex.
React. Kinet. Cat. Lett. 1975, 3, 139-141
19 Kovács, J.; Pritzkow, W.; Speier, G.; Markó, L.: Kinetic Study of the
Isomerisation of 5-Vinyl-bicyclo(2.2.1)heptene-2 Catalysed by Co(N2)(PPh3)3.
Acta. Chim. Acad. Sci. Hung. 1976, 88, 177-182
20 Speier, G.; Simon, Á.; Markó, L.: The Reaction of Carbon Dioxide and
Dioxygen with Dinitrogentris(triphenylphosphine)cobalt(0).
Acta Chim. Acad. Sci. Hung. 1977, 92, 169-173
21 Balogh-Hergovich, É.; Speier, G.: The Oxygenation of Tryptophan and
Acetyltryptophan in the Presence of Copper(I) Chloride (in Hungarian).
Magy. Kém. Foly. 1977, 83, 188-190
Speier, G.: The Activation of Dioxygen by Metal Complexes (in Hungarian).
Magy. Kém. Lapja 1977, 32, 381-389
23 Simon, Á.; Palágyi, J.; Speier, G.; Füredi, Z.: Determination of Dienes in
Hydrocarbon Mixtures by Reaction Gaschromatography.
J. of Chromatography 1978, 150, 135-138
24 Speier, G.; Tyeklár, Z.: Darstellung und Reaktionen von cis,cis-2,4-Di-tertbutyl-muconsäureanhydrid.
Chem. Ber. 1979, 112, 389-391
25 Speier, G.: Oxo Transfer Reactions of Mo(VI) Complexes to Phosphines and
Phosphites.
Inorg. Chim. Acta 1979, 32, 139-141
26 Balogh-Hergovich, É.; Speier, G.; Winkelmann, É.: The Reaction of oPhenylenediamine and Some Aromatic Amines with Superoxide Anion Radical
and Molecular Oxygen.
Tetrahedron Lett. 1979, 20, 3541-3542
27 Speier, G.; Tyeklár, Z.: Studies on the Mechanism of Catechol Oxidation with
the CuCl - Pyridine - MeOH System.
J. Mol. Catal. 1980, 9, 233-235
28 Balogh-Hergovich, É.; Speier, G.: Oxygenation of Indoles by a Copper(I)
Chloride Pyridine Complex. A New Tryptophan 2,3-Dioxygenase Model
System.
J. Inorg. Biochem. 1980, 13, 297-303
29 Speier, G.; Tyeklár, Z.: The Oxygenolysis of 9,10-Phenanthrenequinone to
Copper(II) Diphenate Complexes by CuX (X = Cl, Br) Complexes Containing
Pyridine Type Ligands.
React. Kinet. Catal. Lett. 1980, 15, 91-93
3
30 Speier, G.; Markó, L.: The Kinetics and Mechanism of Homogeneous Hydrogen
Transfer from Alcohols to Benzylideneacetone Catalyzed by
Dichlorotris(triphenylphosphine)ruthenium(II).
J. Organometal. Chem. 1981, 210, 253-262
Speier, G.; Tyeklár, Z.: Kinetics and Mechanism of the Oxidation of 3,5-Di-tert-butyl-obenzoquinone with Hydrogen Peroxide in Aqueous Solution.
J. Chem. Soc., Perkin Trans. 2 1981, 1176-1179
32 El-Sukkary, M. M. A.; Speier, G.: Oxygenation of 3-Hydroxyflavones by
Superoxide Anion.
J. Chem. Soc., Chem. Commun. 1981, 745-745
33 Deli, J.; Speier, G.: Kinetics and Mechanism of the Oxygenation of
Triphenylphosphine by Bis(ethyl-L-cysteinato)dioxomolybdenum(VI).
Transition Met. Chem. 1981, 6, 227-229
Balogh-Hergovich, É.; Bodnár G.; Speier, G.: The Oxygenation of N-substituted oPhenylenediamines in the Presence of Copper(I) Chloride in Pyridine.
Acta Chim. Acad. Sci. Hung. 1981, 108, 37-42
35 Balogh-Hergovich, É.; Speier, G.: Reaction of Copper(I) Chloride Pyridine
Complexes with Dioxygen. A Kinetic Study.
Transition Met. Chem. 1982, 7, 177-180
36 Speier, G.; Tyeklár, Z.; Rockenbauer, A.: The Preparation and Characterization
of Some Solid Copper Dioxygen Complexes.
Inorg. Chim. Acta 1982, 66, L69-L70
37 Balogh-Hergovich, É.; Speier, G.; Tyeklár, Z.: A New and Convenient
Synthesis of 2,2'-Biphenyldicarboxylic Acids, and 2-Cyano-2'biphenyldicarboxylic Acids.
Synthesis 1982, 731-732
38 Balogh-Hergovich, É.; Speier, G.: Ring Cleavage and Ring Expansion of
Indoles by Superoxide Ion.
Tetrahedron Lett. 1982, 23, 4473-4476
39 Balogh-Hergovich, É.; Speier, G.: The Formation of Adducts of Some o- and pQuinones with Copper(I) Chloride and Bromide.
Inorg. Chim. Acta 1983, 74, 61-63
40 Speier, G.; Tyeklár, Z.: Studies on the Oxygenolysis of 9,10Phenanthrenequinone by CuXL (X=Cl or Br; L=Pyridine, 2,2'-Bipyridine, and
1,10-Phenanthroline) Complexes.
J. Chem. Soc., Dalton Trans. 1983, 1995-2000
41 Balogh-Hergovich, É.; Speier, G.: The Reactions of Indoles with Superoxide
Ion.
Ox. Com. 1983, 4, 337-344
4
42 Balogh-Hergovich, É.; Speier, G.: The Oxygenation of Tryptophan and Indoles
with Superoxide Ion in the Presence of Copper and Ruthenium Catalysts,
in 'Progress in Tryptophan and Serotonin Research' Schlossberger, H. B.;
Kochen, W.; Linzen, B.; Steinhart, H.; Eds.; Walter de Gruyter and Co., Berlin,
New York, 1984, p. 669-672
43 Balogh-Hergovich, É.; Speier, G.: Copper(I) Chloride Adducts of the
Monoimines of 9,10-Phenanthrenequinones and 1,2-Naphthoquinone and Their
Reaction with Molecular Oxygen.
Inorg. Chim. Acta 1984, 84, 129-134
44 Balogh-Hergovich, É.; Speier, G.: The Formation of Dinuclear Catecholato
Copper(II) Complexes from Strongly Oxidizing o-Quinones and Copper(I)
Halides.
Inorg. Chim. Acta 1985, 108, 59-62
Speier, G.: Biomimetic Oxidation Reactions.
Doctor of Sciences Thesis 1985, Hungarian Academy of Sciences, Budapest.
46 Speier, G.; Tyeklár, Z
-Diketones and o-Quinones with Metallic
Copper and Dioxygen,
in 'Copper Coordination Chemistry: Biochemical and Inorganic Perspectives',
Karlin, K. D.; Zubieta, J.; Eds.; Adenine Press: Guilderland, New York,
1986, p. 91-100
47 Speier, G.; Párkányi, L.: Cyclodehydrogenation of N-Benzylidene-ophenylenediamines to 2,2'-Diaryl-1,1'-bibenzimidazoles with Dioxygen
Catalyzed by Copper(I) Chloride in Pyridine. A Structural Study of 2,2'Di(3,4,5-trimethoxyphenyl)-1,1'-bibenzimidazole.
J. Org. Chem. 1986, 51, 218-221
Speier, G.: Copper-catalyzed Oxidation of Catechols by Dioxygen.
J. Mol. Catal. 1986, 37, 259-267
49 Balogh-Hergovich, É.; Speier, G.: Kinetics and Mechanism of the
Dehydrogenation of Indolines to Indoles.
J. Mol. Catal. 1986, 37, 309-316
50 Balogh-Hergovich, É.; Speier, G.: The Chlorination of Indoles by Copper(II)
Chloride.
J. Chem. Soc., Perkin Trans. 1 1986, 2305-2308
51 Speier, G.: Preparation of 2-Substituted Benzoxazoles from Phenolic Schiff's
Bases by Copper(I) Chloride Catalyzed Oxidation with Dioxygen in Pyridine.
J. Mol. Catal. 1987, 41, 253-260
Speier, G.: Copper-catalyzed Autoxidation of Acyloins.
Acta Chim. Hung. 1987, 124, 155-164
5
53 Rockenbauer, A.; Györ, M.; Speier, G.; Tyeklár, Z.: Electron Spin Investigation
of Copper(I) 9,10-Phenanthrenesemiquinone Complexes.
Inorg. Chem. 1987, 26, 3293-3297
54 Bakos, J.; Párkányi, L.; Speier, G.; Tyeklár, Z.: Synthesis and Structure of
Some 1,3,2-Oxazaphospholenes.
Phosphorus and Sulphur 1987, 30, 758-758
55 Olmstead, M. M.; Power, P. P.; Speier, G.; Tyeklár, Z.: Synthesis and Structure
of a Tetranuclear Copper(II) 3,5-Di-tert-butylcatecholate Pyridine Complex,
[Cu(DTBC)py]4.2CH3CN.
Polyhedron 1988, 7, 609-614
56 Speier, G.; Tyeklár, Z.: The Reactions of 1,2-Dicarbonyls with Metallic Copper
under Argon and Dioxygen. Oxidative C,C Bond Scission by Metallic Copper.
J. Chem. Soc., Dalton Trans. 1988, 2663-2667
57 Balogh-Hergovich, É.; Speier, G.: The Formation and Characterization of
Copper(II) 1,4-Benzenediolate and p-Semiquinone Complexes.
Inorg. Chim. Acta 1988, 147, 51-54
58 Speier, G.: The Reaction of 9,10-Phenanthrenesemiquinonatobis(triphenylphosphine)-copper(I) with Organic Peroxides.
Inorg. Chim. Acta 1988, 143, 149-150
59 Speier, G.; Tyeklár, Z.; Fülöp, V.; Párkányi, L.: Formation of 2,3- Dihydro1,3,2-benzoxaza phospholes by Cheletropic Reaction of o-Quinone Monoimines with
Triphenylphosphane. Crystal and Molecular Structures of 2,3-Dihydro-2,2,2triphenylphenanthro[9,10-d]oxazaphosphole and 5,7-Di-tert-butyl-2,3-dihydro5
2,2,2-triphenyl-benzoxazaphosphole.
Chem. Ber. 1988, 121, 1685-1688
60 Fülöp, V.; Speier, G.: Organocopper Complexes with Benzoate and Pyridine
Ligands.
Z. Kristallogr. 1988, 185, 337-337
Speier, G.; Fülöp, V.: The Oxidative Addition of Dibenzoyl Peroxide on Metallic Copper.
The Crystal Structure of [(C6H5CO2)2Cupy]2.
J. Chem. Soc., Dalton Trans. 1989, 2331-2333
62 Speier, G.; Fülöp, V.; Balogh-Hergovich, É.; Tyeklár, Z.: Copper(I) and
Copper(II) 3-Hydroxyflavone Complexes and Their Relevance to Quercetinase.
J. Inorg. Biochem. 1989, 36, 329-329
Balogh-Hergovich, É.; Speier, G.: The Oxygenation of Indoles Catalyzed by
Bis(acetylacetonato)oxovanadium(VI).
J. Mol. Catal. 1989, 57, L9-L12
Speier, G.: Organometallic Oxidation Catalysts,
6
in 'The Chemistry of the Metal-Carbon Bond', Hartley, F. R.; Ed.; Wiley,
Chichester, 1989, Vol.5, p.147-p.198
Speier, G.; Tyeklár, Z.: The Reaction of Alkali Metal Catecholates with Dioxygen in
Aprotic Solvents.
J. Mol. Catal. 1990, 57, L17-L19
66 Balogh-Hergovich, É.; Speier, G.: The Cheletropic Reaction of Coordinated oBenzoquinone Diimines with Triphenylphosphine.
Phosphorus and Sulphur 1990, 48, 223-225
67 Speier, G.; Fülöp, V.; Párkányi L.: Chelated Flavonol Co-ordination in
Flavonolatobis-(triphenylphosphine)copper(I).
J. Chem. Soc., Chem. Commun. 1990, 512-513
68 Speier, G.; Fülöp, V.: The Oxidative Addition of Dibenzoyl Peroxide on
Copper(I) Chloride. Crystal and Molecular Structure of CuCl(PhCO2)2py2.
J. Chem. Soc., Chem. Commun. 1990, 905-906
69 Milaeva, E. R.; Speier, G.: Transition Metal Complexes with Redox Ligands
Based on Sterically Hindered Phenols.
Asian J. Chem. Revs. 1990, 1, 159-185
Speier, G.: Quercetin 2,3-Dioxygenase Mimicking Copper Chemistry,
in 'The Studies in Surface Science and Catalysis 66, Dioxygen Activation and
Homogeneous Catalytic Oxidation', Balatonfüred, Simándi, L. I.; Ed.; Elsevier,
Amsterdam, 1991, p. 269
71 Speier, G.; Fülöp, V.; Argay, Gy.: Synthesis, Crystal and Molecular Structure
Dinuclear Copper(I) Thiobenzoate Triphenylphosphine Complex.
Transition Met. Chem. 1991, 16, 576-578
of a
72 Czugler, M.; Tisza, S.; Speier, G.: Versatility in Inclusion Hosts. Unusual
Conformation in the Crystal Structure of the p-t-Butylcalix[8]arene:Pyridine 1:8
Chlathrate.
J. Inclusion. Phenom. 1991, 11, 323-331
73 Balogh-Hergovich, É.; Speier, G.; Argay, G.: The Oxygenation of Flavonol by
Copper(I) and Copper(II) Flavonolate Complexes. The Crystal and Molecular
Structure of Bis(flavonolate)copper(II).
J. Chem. Soc., Chem. Commun. 1991, 551-552
Speier, G.; Tisza, S.; Rockenbauer, A; Pierpont, C. G.; Boone, S. R.: A
Catecholate Complex and Its Quinone Adduct.
Inorg. Chem. 1992, 31, 1017-1020
Milaeva, E. R.; Speier, G.: Cobalt Tetraphenol-substituted Phthalocyanine. A
Spectroscopic Study of Its Redox Properties in Solution.
Inorg. Chim. Acta 1992, 192, 117-121
7
Copper(II)-
76 Speier, G.; Tyeklár, Z.: The Formation of Carboxylato Copper Oxygen
Complexes in the Reaction of Metallic Copper with 1,2-Dicarbonyls and
Dioxygen.
Transition Met. Chem. 1992, 17, 348-355
77 Rockenbauer, A.; Speier, G.; Szabó, L.: The Preparation of [Cu2+(TCNE2-]n
and Its Ligand-induced Intramolecular Electron Transfers.
Inorg. Chim. Acta 1992, 201, 5-6
78 Balogh-Hergovich, É.; Speier, G.: Oxidation of 3-Hydroxyflavones in the
Presence of Copper(I)- and Copper(II)-Chloride.
J. Mol. Catal. 1992, 71, 1-5
79 Speier, G.: Copper Dioxygenation Chemistry Relevant to Quercetin
Dioxygenase.
J. Bioinorg. Chem. 1992, 47, 31-31
80 Milaeva, E. R.; Speier, G.; Lever, A. B. P.: The Redox Chemistry of
Metallophthalocyanines,
in 'Pthtalocyanines, Principles and Applications', Lever, A. B. P.; Leznoff, C.
C.; Eds.; VCH Publishers, Inc., New York, Vol. 3, 1993, p. 1-69
81 Speier, G.: Copper Dioxygenation Chemistry Relevant to Quercetin
Dioxygenase,
in 'Copper Coordination Chemistry: Bioinorganic Perspectives', Karlin, K. D.;
Tyeklár, Z.; Eds.; Chapman & Hall, New York, 1993, p. 382-394
Olmstead, M. M.; Speier, G.; Szabó, L.: Structure of [Cu(CN)(py)2].
Acta Cryst., Sect. C: Cryst. Struct. Commun. 1993, C49, 370-372
83 Speier, G.; Szabó, L.; Fülöp, V.: The Preparation and Crystal Structure of a
Norbornadiene Copper(I) Adipinate Pyridine Complex.
J. Organometal. Chem. 1993, 462, 375-378
84 Speier, G.; Tyeklár, Z.; Szabó, L., II; Tóth, P.; Pierpont, C. G.; Hendrickson,
D. N.: Evidence for Substrate Activation of Copper Catalyzed Intradiol Cleavage in
Catechols,
in 'The Activation of Dioxygen and Homogeneous Catalytic Oxidation'
Barton, D. H. R.; Martell, A. E.; Sawyer, D. T.; Eds.; Plenum Press, New
York, 1993, pp. 423-436
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.; Czugler, M.: Mechanistic Studies 85
in Model Quercetinase Reactions Using Flavonolato Copper Complexes.
J. Inorg. Biochem. 1993, 51, 148-148
Olmstead, M. M.; Speier, G.; Szabó L.: Bound and Non-bound 86
Tetracyanoethylene Radical Anion (TCNE•-) in Copper(I) Triphenylphosphine
Complexes. The Crystal Structures of Cu(TCNE)(PPh3)3,
8
[-(CN)Cu(PPh3)2(TCNE)Cu(PPh3)2-]n, and [(PPh3)3Cu(CN)Cu(PPh3)3]
[TCNE].
J. Chem. Soc., Chem. Commun. 1994, 541-543
87 Balogh-Hergovich, É.; Speier, G.: Reaction of 1,3-Phenylenediacetatodicopper(I) Pyridine Complex with Dioxygen, Hydrogen Peroxide and Carbon
Monoxide.
Transition Met. Chem. 1994, 19, 123-125
88 Speier, G.: Catechol Dioxygenase Chemistry: Copper Catecholate and
Semiquinone Complexes and Their Mechanism of the Oxidative Cleavage
Reaction.
New J. Chem. 1994, 18, 143-147
89 Balogh-Hergovich, É.; Speier, G.: Studies on Copper-containing Enzyme
Models. (in Hungarian)
Magy. Kém. Lapja 1994, 100, 403-408
90 Speier, G.; Tisza, S.; Tyeklár, Z.; Lange, C. W.; Pierpont, C. G.: ColigandDependent Shifts in Charge Distribution for Copper Complexes Containing 3,5Di-tert-butyl-catecholate and 3,5-Di-tert-butylsemiquinonate Ligands.
Inorg. Chem. 1994, 33, 2041-2045
Speier, G.; Párkányi, L.: The Structure of [Cu(PhCO2)2(tmeda)].
Z. Kristallogr. 1995, 210, 307-308
Speier, G.; Whalen, A. M.; Csihony, J.; Pierpont, C. G.: Iminosemiquinone 92
Complexes of Copper. Structural, Magnetic, and Electrochemical
Characterization of Complexes of the Phenoxazinolate Semiquinone Radical.
Inorg. Chem. 1995, 34, 1355-1360
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.; Huttner, G.; Zsolnai, L.: New 93
Copper Flavonolates as Quercetin 2,3-Dioxygenase Model.
J. Inorg. Biochem. 1995, 59, 687
Balogh-Hergovich, É.; Speier, G.; Huttner, G.; Zsolnai, L.: Some Copper 94
Nitronate Chemistry and Its Relevance to 2-Nitropropane Dioxygenase Action.
J. Inorg. Biochem. 1995, 59, 689
Speier, G.; Csihony, J.; Whalen, A. M.; Pierpont, C. G.: Iminoquinone 95
Coordination to Copper(I) in the [Cu(PhenoxBQ)( -Cl)]2 Dimer.
Inorg. Chim. Acta 1996, 245, 1-5
Speier, G.; Csihony, J.; Whalen, A. M.; Pierpont, C. G.: Studies on Aerobic 96
Reactions of Ammonia/3,5-Di-tert-butylcatechol Schiff-Base Condensation
Products with Cu, Cu(I), and Cu(II). Strong Cu(II)-Radical Ferromagnetic
Exchange and Observations on a Unique N-N Coupling Reaction.
Inorg. Chem. 1996, 35, 3519-3524
9
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.: Copper Mediated Conversion of 97
Nitro Compounds to Aldehydes or Ketones by Dioxygen.
Chem. Lett. 1996, 573-574
Balogh-Hergovich, É.; Speier, G.: The Benzoyloxylation of Norbornadiene and 98
Homologues by Copper(III) and Copper(II) Benzoate Complexes.
React. Kinet. Catal. Lett. 1996, 58, 269-274
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.: Synthesis and Characterization of 99
Copper(I) and Copper(II) Flavonolate Complexes with Phthalazine Ligand, and
their Oxygenation and Relevance to Quercetinase.
Inorg. Chim. Acta 1997, 256, 9-14
Speier, G.; Speier, E.; Noll, B.; Pierpont, C. G.: Reduction and Aerobic
100
Oxidation of Hexaketocyclohexane (C6O6) by Reaction with Metallic Copper.
Inorg. Chem. 1997, 36, 1520-1521
Lippai, I.; Speier, G.; Huttner, G.; Zsolnai, L.: Crystal and Molecular
101
Structure of a Ketocarboxylato Copper(II) Intermediate in the Oxygenation of a
Copper(I) Flavonolate Complex.
Chem. Commun. 1997, 741-742
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.; Huttner, G.; Zsolnai, L.: Ligandand Solvent-dependence of the Reaction of Copper Flavonolate 1,10Phenanthroline Complexes with Dioxygen.
J. Inorg. Biochem. 1997, 67, 75-75
102
Speier, G.; Speier, E.; Pierpont, C. G.; Noll, B. C.: The Unusual Formation of a
Croconato Oxalato Copper Complex by the Cu-mediated Oxygenation of
C6O6•8H2O.
Contribuciones Cientificas y Technologicas, Universidad de Santiago de Chile,
1997, 26, 115-115
103
Lippai, I.; Speier, G.; Huttner, G.; Zsolnai, L.: (2,2'-Bipyridine)flavonolato
copper(II) perchlorate.
Acta Cryst., Sect. C: Cryst. Struct. Commun. 1997, C53, 1547-1549
Balogh-Hergovich, É.; Speier, G.; Párkányi, L.: Crystal Structure of
(PPh3)2]2•2CH3COCH3.
Z. Kristallogr. 1998, 213, 265-266
104
105
of Speier, G.; Selmeczi, K.; Pintér, Z.; Huttner, G.; Zsolnai, L.: Crystal Structure
bis(benzoato)tris(pyridine)copper(II)-acetonitrile-pyridine(4/4/1),
4[Cu(PhCO2)2(Py)3]•4CH3CN•C5H5N.
Z. Kristallogr. 1998, 213, 263-264
Lippai, I.; Speier, G.: Quercetinase Model studies. The Oxygenation of Flavonol
Catalyzed by a Cationic 2,2'-Bipyridine Flavonolate Complex.
J. Mol. Catal. 1998, 130, 139-148
10
Balogh-Hergovich, É.; Speier, G.; Huttner, G.; Zsolnai, L.: Copper-mediate
Oxygenation of Nitronate to Nitrite and Acetone in a Copper(I) Nitronate
Complex.
Inorg. Chem. 1998, 37, 6535-6537
108
Kaizer, J.; Balogh-Hergovich, É.; Speier, G.; Rutsch, P.; Huttner, G.: (3,3'109
Iminobis(N,N-dimethylpropylamine)(4'-methoxyflavonolato)zinc(II) perchlorate,
[Zn(idpaH)(4'-MeOfla)]ClO4.
Acta Cryst., Sect. C: Cryst. Struct. Commun. 1999, C55, 557-558
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.: Studies of Functional Quercetinase Models
with Copper and Zinc Ions.
J. Inorg. Biochem. 1999, 74, 74
Kaizer, J.; Pap, J.; Speier, G.: Catechol Oxidase and Dioxygenase Activity of
Copper and Zinc Complexes with N3-ligands.
J. Inorg. Biochem. 1999, 74, 303
111
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.; Fülöp, V.; Párkányi, L.: Quercetin
2,3-Dioxygenase Mimicking Ring Cleavage of the Flavonolate Ligand Assisted
by Copper. Synthesis and Characterization of Copper(I) Complexes
[Cu(PPh3)2(fla)] (fla = flavonolate) and [Cu(PPh3)2(O-bs)] (O-bs = Obenzoylsalicylate).
Inorg. Chem. 1999, 38, 3787-3795
112
Balogh-Hergovich, É.; Tapodi, B.; Speier, G.; Réglier, M.; Giorgi, M.: Crystal
Structure of 1,3-bis(2'-pyridylimino)isoindolinato(dichloro)iron(III), FeCl2(ind).
Z. Kristallogr. NCS 1999, 214, 579-580
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.; Argay, G.; Párkányi, L.: Kinetic
Studies on the Copper(II)-mediated Oxygenolysis of the Flavonolate Ligand. The
Crystal Structures of Cu(fla)2•2CHCl3 (fla = flavonolate) and
Cu(O-bs)2(py)3•2py (O-bs = O-benzoylsalicylate).
J. Chem. Soc., Dalton Trans. 1999, 3847-3854
Barhács, L.; Czaun, M.; Speier, E.; Speier, G.; Noll, B.; Pierpont, C. G.:
Dichloro(phenanthroline)pyridinecopper(II) Pyridine Solvate,
[CuCl2(C12H8N2)(C5H5N)•C5H5N].
Z. Kristallogr. NCS 2000, 214, 193-194
115
Kovács, T.; Speier, G.; Réglier, M.; Giorgi, M.; Huttner, G.; Zsolnai, L.;
Vértes, A.; Vankó, G.: Preparation and Characterization of Homoleptic and
Ethoxy-Bridged Nitronato Iron(III) Complexes.
Chem. Commun. 2000, 469-470
116
Barhács, L.; Kaizer, J.; Speier, G.: Kinetics and Mechanism of the Oxygenation
of Potassium Flavonate. Evidence for an Electron Transfer Mechanism.
J. Org. Chem. 2000, 65, 3449-3452
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.; Huttner, G.; Zsolnai, L.:
118
Copper-mediated Oxygenation of Flavonolate in the Presence of a Tridentate
11
114
117
N-ligand. Synthesis and Crystal Structures of [Cu(fla)(idpaH)]ClO4 and
[Cu(idpaH)(O-bs)]ClO4, [fla = flavonolate, idpaH = 3,3'-iminobis(N,Ndimethyl propylamine), O-bs = O-benzoylsalicylate].
Inorg. Chim. Acta 2000, 304, 72-77
Balogh-Hergovich, É.; Kaizer, J.; Kupán, Á.; Speier, G.: Reaction and
119
Mechanism of Catechols and Flavonols with Molecular Oxygen.
eds., TUM, Polyphenol Communications 2000, Martens, S.; Treutter, D.; Forkmann, G.
Vol. 2. p. 417
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.; Huttner, G.; Jacobi, A.:
Preparation and Oxygenation of (Flavonolato)copper Isoindoline
Complexes with Relevance to Quercetin Dioxygenase.
Inorg. Chem. 2000, 39, 4224-4229
120
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.: Kinetics and Mechanism of the
Cu(I) and Cu(II) Flavonolate-catalyzed Oxygenation of Flavonol. Functional
Quercetin 2,3-dioxygenase Models.
J. Mol. Catal. 2000, 159, 215-224
Kaizer, J., Kupán, Á., Pap, J., Speier, G., Giorgi, M., Réglier, M.: [3',3'iminobis(N'N-dimethylpropylamin)](flavonolato)zinc(II)perchlorate,
[Zn(fla)(idpaH)]ClO4.
Z. Kristallogr. NCS 2000, 215, 571-572
121
122
Kaizer, J.; Pap, J.; Speier, E.; Speier, G.: The Role of Metals, Ligands and Solvents in Model
Reactions of Oxidases, in Challenges for Coordination Chemistry in the New Century,
Melnik, M.; Sirota, A. eds., Slowak Technical University Press, Bratislava, 2001, 201-206
Kaizer, J.; Gréczi, Z.; Speier, G.: Copper-Mediated Acetylation of Alcohol by 2Nitropropane in the Presence of Dioxygen.
React. Kinet. Catal. Lett. 2001, 73, 91-97
Kaizer, J.; Speier, G.: Radical-initiated Oxygenation of Flavonols by Dioxygen.
J. Mol. Catal. 2001, 171, 33-36
Barhács, L.; Kaizer, J.; Speier, G.: Kinetics and Mechanism of the Stoichiometric
Oxygenation of the Ionic Zinc(II) Flavonolate Complex [Zn(fla)(idpaH)]ClO4 (fla =
flavonolate; idpaH = 3,3’-iminobis(N,N-dimethylpropylamine)).
J. Mol. Catal. 2001, 172, 117-125
Balogh-Hergovich, É.; Kaizer, J.; Kupán, Á.; Pap, J.; Speier, E.; Speier, G.:
Tuning the Chemoselectivity and Mechanism of Some Catecholate and Flavonolate
Complexes with Dioxygen.
J. Inorg. Biochem. 2001, 86, 100-100
12
Czaun, M.; Speier, G.: Comparison Between Functional Models of 2-methyl-3-hydroxy4(1H)-oxoquinoline 2,3-dioxygenase (MeQDO) and Quercetin 2,3-dioxygenase.
J. Inorg. Biochem. 2001, 86, 193-193
Kaizer, J.; Speier, G.: Kinetic Studies on the Copper(II)-mediated Oxygenolysis of the
Flavonolate Ligand Processing via a 1,2-dioxetane Intermediate.
J. Inorg. Biochem. 2001, 86, 284-284
Kupán, Á.; Speier, G.: Oxygenolysis of Alkali Metal Catecholates.
J. Inorg. Biochem. 2001, 86, 302-302
Pap, J.; Kaizer, J.; Speier, G.: The Role of Metals in Model Reactions of Catechol Oxidases.
J. Inorg. Biochem. 2001, 86, 371-371
Selmeczi, K.; Réglier, M.; Speier, G.: Catalysis of Hydrolysis of Phosphate Esters with
Mono- and Dinuclear Copper(II) Complexes.
J. Inorg. Biochem. 2001, 86, 425-425
Speier, G.; Tyeklár, Z.; Tóth, P.; Speier, E.; Tisza, S.; Rockenbauer, A.; Whalen, A.M.;
Alkire, N.; Pierpont, C.G.: Valence Tautomerism and Metal-Mediated
Catechol Oxidation for Complexes of Copper Prepared with 9,10-Phenanthrenequinone.
Inorg. Chem. 2001, 40, 5653-5659
Kaizer, J.; Pap, J.; Speier, G.; Réglier, M.; Giorgi, M.: Crystal Structure of {( carbonato)bis[iminobis(N,N-dimethylpropylamine)]copper(II)} diperchlorate hydrate,
[(Cu(idpa))2(CO3)](ClO4)2
2O.
Z. Kristallogr. NCS 2001, 216, 519-520
Balogh-Hergovich, É.; Speier, G.: Kinetics and Mechanism of the Base-catalyzed
Oxygenation of Flavonol in DMSO-H2O Solution.
J. Org. Chem. 2001, 66, 7974-7978
Barhács, L.; Kaizer, J.; Pap, J.; Speier, G.: Kinetics and Mechanism of the Stoichiometric
Oxygenation of [CuII (fla)(idpa)]ClO4 [fla = flavonolate, idpa = 3,3’-imino-bis(N,Ndimethylpropylamine)] and the [CuII(fla)(idpa)]ClO4-catalysed Oxygenation of Flavonol.
Inorg. Chim. Acta 2001, 320, 83-91
Kaizer, J.; Gréczi, Z.; Speier, G.: Ferroxime(II)-catalyzed Oxygenation of Nitroalkanes by
tert-butyl Hyroperoxide and its Relevance to 2-nitropropane Dioxygenase.
J. Mol. Catal. 2002, 179, 35-39
Kaizer, J,; Csonka, R.; Speier, G.: TEMPO-initiated Oxidation of 2-aminophenol to 2aminophenoxazin-3-one.
J. Mol. Catal., 2002, 180, 91-96
Balogh-Hergovich, É.; Speier, G.; Réglier, M.; Giorgi, M.: Crystal Structure of 1,4-di(2’pyridyl)aminophthalazine, C18H14N6.
Z. Kristallogr. NCS , 2002, 217, 61-62
13
Kaizer, J.; Csonka, R.; Speier, G.: TEMPO-initiated Oxidation of o-Phenylenediamine to
2,3-Diaminophenazine.
React. Kinet. Catal. Lett. 2002, 75, 367-374
Balogh-Hergovich, É,; Gréczi, Z.; Kaizer, J.; Speier, G.; Réglier, M.; Giorgi, M.;
Párkányi, L.: Kinetics and Mechanism of the Copper-catalysed Oxygenation of 2Nitropropane.
Eur. J. Inorg. Chem. 2002, 1687-1696
Czaun, M.; Speier, G.: The Base-catalyzed Oxygenation of Quinoline
Derivatives.
Tetrahedron Lett. 2002, 43, 5961-5963
142
Kaizer, J.; Pap, J.; Speier. G.; Párkányi, L.; Korecz, L.; Rockenbauer, A.: Synthesis,
Structure and Catecholase Activity of Dinuclear Copper and Zinc Complexes with an N3ligand.
J. Inorg. Biochem. 2002, 91, 190-198
Kupán, Á.; Speier, G.: Novel Copper-containing functional catechol oxidase
enzyme model systems.
Polyphenols Communications, 2002, 1, 21-22
144
Selmeczi, K.; Réglier, M.; Giorgi, M.; Speier, G.; Peintler, G.: Catechol oxidase activity of
copper complexes with N-donor ligands.
Polyphenols Communications 2002, 1, 23-24
Pintér, Zs.; Speier, G.; Giorgi, M.; Slama, P.; Réglier, M.: New symmetric binuclear
copper(II) complexes as functional models for catechol oxidase enzymes; An unusual
inhibition of the oxidation reaction.
Polyphenols Communications, 2002, 1, 25-26
Kaizer, J.; Pap, J.; Speier, G.: TEMPO-catalyzed oxidation of 3,5-di-tertbutylcatechol.
Polyphenols Communications, 2002, 1, 31-32
147
Czaun, M.; Speier, G.: Oxygenation of 1H-2-phenyl-3-hdroxy-4-oxoquinoline
as a functional model reaction for 1H-3-hydroxy-4-oxoquinaldine 2,3dioxygenase.
Polyphenols Communications, 2002, 1, 41-42
148
Czaun, M.; Ganszky, I.; Speier, G.; Párkányi, L.: Crystal structure of 1H-2149
phenyl-3-hydroxy-4-oxoquinoline–dimethyl sulfoxide (1:1), C15H11NO2 .
C2H6SO.
Z. Kristallogr. NCS, 2002, 217, 379-380
Copper- Balogh-Hergovich, É.; Kaizer, J.; Pap, J.; Speier, G.; Huttner, G.; Zsolnai, L.:
Intermediates: mediated Oxygenolysis of Flavonols via Endoperoxide and Dioxetan
[CuII(L)(fla)2] [fla =
Synthesis and Oxygenation of [CuII(phen)2(fla)]ClO4 and
14
(bpy), N,N,N’,N’flavonol; L = 1,10-phenanthroline (phen), 2,2’-bipyridine
tetramethylethylenediamine (tmeda)] Complexes.
Eur. J. Inorg. Chem. 2002, 2287-2295
Vértes, A.: New Balogh-Hergovich, É.; Speier, G.; Réglier, M.; Giorgi, M.; Kuzmann, E.;
oxygenation.
-oxo-bridged diiron(III) complexes as catalysts for alkane
Eur. J. Inorg. Chem. 2003, 1735-1740
Kupán, Á.; Speier, G.; Giorgi, M.; Réglier, M.; Catechol oxidase activity of
152
copper(I) complexes with new monodentate N-donor ligands.
in Challenges for Coordination Chemistry in the New Century, Melnik, M.;
206
Sirota, A. eds., Slowak Technical University Press, Bratislava, 2003, pp. 201Kaizer, J.; Speier, G.; Giorgi, M.; Réglier, M.: New structural and functional
models for quercetin 2,3-dioxygenase.
J. Inorg. Biochem. 2003, 96, 234
153
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.: Carboxylate-enhanced reactivity
in the oxygenation of copper flavonolate complexes.
J. Mol. Catal. A. 2003, 206, 83-87
154
Csonka, R.; Kaizer, J.; Pap, J.; Speier, G.: Kinetics and mechanism of the
reaction of
stable radicals with phenolic compounds.
Free Rad. Res. 2003, 37, 46
Selmeczi, K.; Speier, G.; Réglier, M.; Giorgi, M.; Peintler, G.: Catechol
Oxidase Activity of Dicopper Complexes with N-donor Ligands.
Coord. Chem. Rev. 2003, 245, 191-201
Selmeczi, K.; Réglier, M.; Speier, G.; Peintler, G.: Kinetic Studies of Dicopper
Complexes in Catechol Oxidase Model Reaction by Using an
Approximationless Evaulating Method.
React. Kinet. Catal. Lett. 2004, 81, 143-151
156
157
N—
Czaun, M.; Speier, G.; Párkányi, L.: Facile Copper-mediated Activation of the
H Bond and the Oxidative Cleavage of the C2—C3 Bond in 1H-2-phenyl-3-hydroxy-4oxoquinoline.
Chem. Comm. 2004, 1004-1005
159
Horváth, T.; Kaizer, J.; Speier, G.: Functional Phenoxazinone Synthase
Models. Kinetic Studies on the Copper-catalyzed Oxygenation of 2-aminophenol.
J. Mol. Catal. A. 2004, 215, 9-15
- 2 2-Peroxoand
Bis( -oxo)dicopper Complexes with Flavonol.
Eur. J. Inorg. Chem. 2004, 2253-2259
Kaizer, J.; Pap, J.; Speier, G.; Párkányi, L.: [1,3-Bis(2pyridylimino)isoindolinato](salicylato)(water)copper(II),
[Cu(ind)(sa)(H~2~O)].
Z. Kristallogr. NCS 2004, 141-142
15
161
2- Selmeczi, K.; Speier, G.; Réglier, M.; Giorgi, M.: [N,N-Bis(2-[2-pyridyl]ethyl)-162
(2-aminoethoxy)ethanol]copper(II) triflate, C18H25N3O2Cu.2CF3SO3.
Z. Kristallogr. NCS 2004, 143-144
Speier, G.: Dioxygen, Metalcomplexes, and Metalloenzymes (in Hungarian).
Magy. Kém. Foly. 2004, 109-110, 93
Balogh-Hergovich, É.; Speier, G.; Réglier, M.; Giorgi, M.; Kuzmann, E.;
164
Vértes, A.: Synthesis and Characterization of New Diiron(III) Complexes Containing 1,4to Soluble Methane
Di(pyridyl)aminophthalazine (PAP) Ligand and Their Relevance
Monooxygenase.
Inorg. Chim. Acta 2004, 357(12), 3689-3696
Kaizer, J.; Ősz, E.; Speier, G.; Giorgi, M.; Réglier, M.: The facile formation of
trioxanaphthacenes by a [4+2] addition of flavonols to 1,2-benzoquinone.
Tetrahedron Lett. 2004, 45/43, 8011-8013
165
novel 3- Kaizer, J.; Pap, J. Speier, G.: Synthesis, properties, and crystal structure of a
oxygenation
hydroxy-(4H)-benzopyran-4-one containing copper(II) complex, and its
and relevance to quercetinase.
Transition Met. Chem. 2004, 29, 630-633
Balogh-Hergovich, É.; Speier, G.: Catalytic oxidation of alcohols to carbonyl
compounds with hydrogen peroxide using dinuclear iron complexes.
J. Mol. Catal. A-Chem. 2005, 230, 79-83
167
Balogh-Hergovich, É.; Speier, G.; Réglier, M.; Giorgi, M.; Kuzmann, E.;
168
homoleptic Vértes, A.: Synthesis, structure and spectral properties of a novel stable
iron(II) complex of 1,3-bis(2’-pyridylimino)isoindoline, Fe(ind)2.
Inorg. Chem. Comm. 2005, 8, 457-459
to Pap, J.; Kaizer, J.; Speier, G.: DPPH-initiated oxygenation of 3-hydroxyflavone 169
O-benzoylsalicylic acid.
React. Kinet. Catal. Lett. 2005, 85, 115-121
by the Kaizer, J.; Pap, J.; Speier, G.: Modeling antioxidant properties of polyphenols
TEMPO-initiated reaction of 3,5-di-tert-butylcatechol with dioxygen.
Food Chem. 2005, 93, 425-430
Kaizer, J.; Zsigmond, Z.; Speier, G.: Studies on variable dentate copper
171
catecholate complexes and their reaction with dioxygen.
in Advances in Coordination, Bioinorganic and Inorganic Chemistry, Eds. M.
Melnik, J. Sima, and M. Tatarko, Slovak Technical University Press, Bratislava,
2005, 377-385
Kaizer, J.; Czaun, M.; Csay, T.; Speier, G.; Párkányi, L.; Giorgi, M.; Réglier,
172
phenylquinoline- M.: Synthesis and oxidation of copper complexes of 3-hydroxy-24(1H)-one.
in Advances in Coordination, Bioinorganic and Inorganic Chemistry, Eds. M.
Melnik, J. Sima, and M. Tatarko, Slovak Technical University Press, Bratislava,
16
2005, 111-121
Giorgi, M.; Réglier, M.: Synthesis, Kaizer, J.; Csonka, R.; Speier, G.;
and catecholase-like activity of anew dicopper(II) complex with structure
benzoylacetonate ligand.
J. Mol. Catal. A-Chem. 2005, 235, 81-87
173
and Kaizer, J.; Csonka, R.; Speier, G.; Giorgi, M.; Réglier, M.: Synthesis, structure 174
phenylglyoxylate and benzoate catalase-like activity of new dicopper(II) complexes with
ligands.
J. Mol. Catal. A-Chem. 2005, 236, 12-17
Kaizer, J.; Csay, T.; Czaun, M.; Speier, G.; Réglier, M.; Giorgi, M.: Copper175
catalyzed oxygenation of 3-hydroxy-2-phenylquinolin-4(1H)-one. Synthesis,
structure and spectral properties of [Cu(idpa)(N-baa)]ClO4, [idpa = 3,3’iminobis(N,N-dimethylpropylamine), N-baaH = N-benzoylanthranilic acid]
Inorg. Chem. Comm. 2005, 8, 813-816
Selmeczi, K. Giorgi, M.; Speier, G.; Farkas, E.; Réglier, M.: Mono vs
176
Complexes in Phosphodiester and DNA Hydrolysis. Copper(II) Binuclear
Eur. J. Inorg. Chem. 2006, 1022-1031
177
Kaizer, J.; Góger, S.; Speier, G.; Régler, M.; Giorgi, M.: (OBenzoylsalycilato)copper(II) complexes as synthetic enzyme-product (EP)
models for flavonol 2,4-dioxygenase.
Inorg. Chem. Commun. 2006, 9, 251-254
178
Tapodi, B.; Speier, G.; Funabiki, T.; Giorgi, M.; Réglier, M.: Preparation and
X-ray Structure of a Catecholato Copper(II) Complex with a Schönberg Adduct.
Inorg. Chem. Comm. 2006, 9, 367-370
179
Kaizer, J.; Góger, S.; Speier, G.; Giorgi, M.; Réglier, M.: Crystal structure of
-dichlorobis(N-benzyl-bis(2-pyridylmethyl)amino)dicopper(II) diperchlorate
ethanol solvate (1:2/3), [Cu2Cl2{N(C6H6N)2(C7H7)}2][ClO4]2•C2H5OH
Z. Kristallogr. NCS, 2006, 221, 75-76
Kaizer, J.; Balogh-Hergovich, É.; Czaun, M.; Csay, T.; Speier, G.: Redox and
nonredox metal assisted model systems with relevance to flavonol and 3hydroxyquinolin-4(1H)-one 2,4-dioxygenase.
Coord. Chem. Rev. 2006, 250, 2222-2233
180
Kaizer, J.; Durkó, N.; Czaun, M.; Speier, G.: Kinetics and mechanism of the
oxygenation of potassium nitronates. Evidence for single electron transfer
(SET) mechanism.
React. Kin. Catal. Lett. 2006, 88, 193-202
181
Kaizer, J.; Csay, T.; Speier, G.; Réglier, M.; Giorgi, M.: Synthesis, structure
and catalase-like activity of Cu(phen)(N-baa)2 , (phen = 1,10-phenanthroline, NbaaH = N-benzoylanthranilic acid).
Inorg. Chem. Comm. 2006, 9, 1037-1039
182
17
Balogh-Hergovich, É.; Kaizer, J.; Speier, G.: Chemical models relevant to
nitroalkane dioxygenase.
Comp. Rend. Chim. 2007, 10, 355-365
183
Kaizer, J.; Baráth, G.; Speier, G.; Réglier, M.; Giorgi, M.: Synthesis, structure and catalase
mimics of novel homoleptic manganese(II) complexes of 1,3-bis(2’pyridylimino)isoindoline, Mn(4R-ind)2 (R=H, Me).
Inorg. Chem. Comm. 2007, 10, 292-294
Giorgi, Kaizer, J.; Ganszky, I.; Csurka, K.; Speier, G.; Korecz, L.; Rockenbauer, A.; 185
hydroxy-4’- M.; Réglier, M.; Antonczak, S.: Cerium(IV)-mediated oxidation of 3tautomerism.
methylflavone to its dehydro dimer. Direct evidence for valence
. Inorg. Biochem. 2007, 101, 893-899
Kaizer, J.; Zsigmond, Z.; Ganszky, I.; Spier, G.; Giorgi, M.; Réglier, M.: New Functional
Model Complexes of Intadiol-cleaving Catechol Dioxygenases: Properties and Reactivity
of CuII(L)(O2Ncat).
Inorg. Chem. 2007, 46, 4660-4666
Baráth, G.; Csonka, R.; Kaizer, J.; Kupán, Á.; Speier, G.: Catechol oxidase activity of
copper and manganese isoindoline complexes.
Achievements in Coordination, Bioinorganic and Applied Inorganic Chemistry, Eds: M.
Melnik, J. Sima, and M. Tatarko, Slovak Technical University Press, Bratislava, 2007,
299-310
Kaizer, J.; Baráth, G.; Hujber, T.; Pap, J.; Speier, G.; Buják, R.: Synthesis and oxidation of
manganese and iron flavonolates with relevance to flavonol 2,4-dioxygenases.
Achievements in Coordination, Bioinorganic and Applied Inorganic Chemistry, Eds: M.
Melnik, J. Sima, and M. Tatarko, Slovak Technical University Press, Bratislava, 2007,
134-144
Baráth, G.; Kaizer, J.; Speier, G.; Giorgi, M.; Réglier, M.: Studies on iron-based flavonol
2,4-dioxgenase models.
J. Biol. Inorg. Chem. 2007, 12, 157-157
Baráth, G.; Kaizer, J.; Huber, T.; Pap, J.; Speier, G.: Kinetic studies on manganese(II)mediated oxygenolysis of the flavonolate ligand with relevance to flavonol 2,4dioxygenase.
J. Biol. Inorg. Chem. 2007, 12, 165-165
Kaizer, J.; Csonka, R.; Baráth, G.; Speier, G.: Synthesis, properties, and catalase-like
activity of the [1,4-di-(6’-methyl-2’-pyridil)aminophthalazine] dimanganese complex,
Mn2(6’Me2PAP)2Cl4.
Trans. Met. Chem. 2007, 32, 1047-1050
Ganszky, I.; Kaizer, J.; Czaun, M.; Speier, G.; Párkányi, L.: Crystal structure of 2phenylquinolin-3,4-dione, C15H9NO2.
Z. Kristallogr. NCS 2007, 222, 259-260
Kaizer, J.; Baráth, G.; Pap, J.; Speier, G.; Giorgi, M.; Réglier, M.: Manganese
and iron flavonolates as flavonol 2,4-dioxygenase mimics.
Chem. Commun. 2007, 5235-5237.
18
193
Kaizer, J.; Csay, T.; Kővári, P.; Speier, G.; Párkányi, L.: Catalase mimics of a
manganese(II) isoindoline complex. The effect of axial ligands and pH.
J. Mol. Catal.-A, 2008, 280, 203-209
Kaizer, J.; Baráth, G.; Csonka, R.; Speier, G.; Korecz, L.; Rockenbauer, A.; Párkányi, L.:
Catechol oxidase and phenoxazinone synthase mimics of manganese(II) isoindoline
complex.
J. Inorg. Biochem. in the press.

19
Patents:
J. Blahut, Z. Füredi, É. Balogh-Hergovich, L. Markó, G. Speier, Á. Simon and J. Palagyi:
Determination of Total Organic Carbon in Waste Water
Hung. Pat., 170907 (1975)
G. Speier and Á. Simon: A Composition for the Liming of Hide
Hung. Pat., 192421 (1984)
Á. Ruszbach, Á. Simon and G. Speier: The Preparation of Iron(II) Fumarate.
Hung. Pat., 195 831 (1985)
G. Speier: A New Composition for the Liming of Hide.
Hung. Pat., 204 899 (1989)
International Conferences:
Membership of Professional Bodies:
Hungarian Chemical Society,
Society of Biological Inorganic Chemistry
Hungarian Representative of COST (EU)
Advisory board: Asian Journal of Chemistry
Asian Journal of Chemistry Reviews
Reaction Kinetics and Catalysis Letters
Mailing Address:
20